{"id":144900,"date":"2018-07-06T06:30:27","date_gmt":"2018-07-05T22:30:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=144900"},"modified":"2018-07-06T10:33:32","modified_gmt":"2018-07-06T02:33:32","slug":"%e6%96%b0%e5%8a%a0%e5%9d%a1%e5%9b%bd%e7%ab%8b%e5%a4%a7%e5%ad%a6%e8%b0%a2%e5%bb%ba%e5%b9%b3accounts%ef%bc%9a%e9%98%90%e8%bf%b0%e9%87%91%e5%b1%9e%e7%ba%b3%e7%b1%b3%e5%9b%a2%e7%b0%87%e7%9a%84%e5%85%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=144900","title":{"rendered":"\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u8c22\u5efa\u5e73Accounts\uff1a\u9610\u8ff0\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u5168\u5408\u6210"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

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\u786b\u9187\u4fdd\u62a4\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\uff08Nanocluster, NC\uff09\u662f\u4e00\u7c7b\u5c3a\u5bf8\u8d85\u5c0f\uff08< 3 nm\uff09\u7684\u7eb3\u7c73\u9897\u7c92\u3002\u5728\u8fd9\u4e00\u8d85\u5c0f\u5c3a\u5ea6\u4e0b\uff0c\u5b83\u4eec\u8868\u73b0\u51fa\u4e00\u4e9b\u72ec\u7279\u7684\u7c7b\u5206\u5b50\u6027\u8d28\u3002\u9996\u5148\uff0c\u5b83\u4eec\u5177\u6709\u7cbe\u786e\u5230\u539f\u5b50\u7684\u7ec4\u6210\u53ca\u7ed3\u6784\uff0c\u4ece\u800c\u53ef\u4ee5\u7528\u7c7b\u4f3c\u4f20\u7edf\u5206\u5b50\u7684\u201c\u5206\u5b50\u5f0f\u201d\u5982[Mn<\/i><\/sub><\/em>(SR)m<\/i><\/sub><\/em>]q<\/i><\/sup><\/em>\u8868\u793a\uff08m<\/i><\/em>, n<\/i><\/em>, \u548cq<\/i><\/em>\u5206\u522b\u4e3a\u5355\u4e2a\u56e2\u7c07\u4e2d\u91d1\u5c5e\u539f\u5b50M\uff0c\u786b\u9187\u914d\u4f53SR\uff0c\u4ee5\u53ca\u51c0\u7535\u8377\u7684\u6570\u76ee\uff09\u3002\u4ece\u800c\u5de7\u5999\u907f\u5f00\u4e86\u4f20\u7edf\u7eb3\u7c73\u9897\u7c92\uff08> 3 nm\uff09\u96be\u4e8e\u5b9e\u73b0\u7cbe\u786e\u5230\u539f\u5b50\u5408\u6210\u7684\u6280\u672f\u96be\u9898\u3002\u5176\u6b21\uff0c\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u8fd8\u5177\u6709\u663e\u8457\u533a\u522b\u4e8e\u4f20\u7edf\u7eb3\u7c73\u9897\u7c92\uff08> 3 nm\uff09\u7684\u7c7b\u5206\u5b50\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u6bd4\u5982\u79bb\u6563\u7684\u7535\u5b50\u80fd\u7ea7\uff0c\u5f3a\u53d1\u5149\u4ee5\u53ca\u672c\u5f81\u65cb\u5149\u6027\u7b49\u3002\u800c\u8fd9\u4e9b\u7c7b\u5206\u5b50\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u90fd\u8868\u73b0\u51fa\u6781\u5f3a\u7684\u5c3a\u5bf8\u76f8\u5173\u6027\uff1a\u6570\u4e2a\u751a\u81f3\u4e00\u4e2a\u539f\u5b50\u7684\u6539\u53d8\u5c31\u4f1a\u5bfc\u81f4\u6027\u8d28\u7684\u663e\u8457\u53d8\u5316\u3002\u8fd9\u4e00\u654f\u611f\u7684\u5c3a\u5bf8\u76f8\u5173\u6027\u4e3a\u8ffd\u8e2a\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u751f\u957f\u8def\u5f84\u63d0\u4f9b\u4e86\u6709\u6548\u7684\u624b\u6bb5\u3002\u56e0\u800c\uff0c\u786b\u9187\u4fdd\u62a4\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u53ef\u4ee5\u4e3a\u65e0\u673a\u529f\u80fd\u7eb3\u7c73\u6750\u6599\u7684\u5168\u5408\u6210\u7814\u7a76\u63d0\u4f9b\u7406\u60f3\u7684\u5e73\u53f0\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

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\u56fe2. \u8fd8\u539f\u751f\u957f\u6cd5\u5408\u6210\u786b\u9187\u4fdd\u62a4\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07<\/b><\/strong>
\n \"\"<\/b><\/strong><\/p>\n

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\u56fe<\/b><\/strong>3<\/b><\/strong>.<\/b><\/strong>\u00a0<\/b><\/strong>\u901a\u8fc7\u8fd8\u539f\u751f\u957f\u6cd5\u5408\u6210[<\/b><\/strong>Au<\/b><\/strong>25<\/b><\/sub><\/strong>(SR)<\/b><\/strong>18<\/b><\/sub><\/strong>]<\/b><\/strong>–<\/b><\/sup><\/strong>\u56e2\u7c07<\/b><\/strong>
\n \"\"<\/b><\/strong><\/p>\n

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\"\"<\/p>\n

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\u81f4\u8c22\uff1a<\/b><\/strong>\u4e0a\u8ff0\u76f8\u5173\u7814\u7a76\u5f97\u5230\u4e86\u65b0\u52a0\u5761\u6559\u80b2\u90e8(Grant No. R-279-000-481-112)\u7684\u8d44\u52a9\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

Yao, Q.; Chen, T.; Yuan, X.; Xie, J. Toward Total Synthesis of Thiolate-Protected Metal Nanoclusters. Acc. Chem. Res.<\/i><\/em>\u00a02018<\/b><\/strong>, 51<\/i><\/em>, 1338-1348.<\/p>\n

\u672c\u6587\u7531\u4f5c\u8005\u56e2\u961f\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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\u6295\u7a3f\u53ca\u5185\u5bb9\u5408\u4f5c\u8bf7\u52a0\u5fae\u4fe1cailiaokefu\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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