{"id":145616,"date":"2018-07-11T06:30:27","date_gmt":"2018-07-10T22:30:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=145616"},"modified":"2018-07-11T17:22:09","modified_gmt":"2018-07-11T09:22:09","slug":"%e6%83%b3%e8%a6%81%e7%9f%a5%e9%81%93%e6%9c%89%e6%9c%ba%e9%87%91%e5%b1%9e%e6%a1%86%e6%9e%b6%e7%9a%84%e4%bd%9c%e7%94%a8%ef%bc%8c%e8%af%b7%e4%bb%8e%e8%bf%99%e5%8d%81%e7%af%87%e7%bb%bc%e8%bf%b0%e5%bc%80","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=145616","title":{"rendered":"\u60f3\u8981\u77e5\u9053\u6709\u673a\u91d1\u5c5e\u6846\u67b6\u7684\u4f5c\u7528\uff0c\u8bf7\u4ece\u8fd9\u5341\u7bc7\u7efc\u8ff0\u5f00\u59cb\uff01"},"content":{"rendered":"<p><strong>\u4e00\u3001\u4ec0\u4e48\u662f\u6709\u673a\u91d1\u5c5e\u6846\u67b6\u7ed3\u6784\uff1f<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-145629\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/1-31.jpg\" alt=\"\" width=\"600\" 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alt=\"\" width=\"600\" height=\"731\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/3-29.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/3-29-246x300.jpg 246w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u91d1\u5c5e\u548c\u6709\u673a\u914d\u4f4d\u5f62\u6210\u7279\u5b9a\u7684\u6846\u67b6\u7ed3\u6784\uff0c\u8fd9\u79cd\u7ed3\u6784\u4e0d\u4ec5\u5177\u6709\u91d1\u5c5e\u7684\u6d3b\u6027\uff1b\u540c\u65f6\u4e5f\u83b7\u5f97\u4e86\u6709\u673a\u914d\u4f53\u7684\u67d4\u6027\u3001\u5b98\u80fd\u56e2\u7684\u9009\u62e9\u6027\u548c\u5176\u4ed6\u7269\u7406\u5316\u5b66\u6027\u80fd\uff1b\u8fd8\u6709\u914d\u4f4d\u5f62\u6210\u7684\u7279\u6b8a\u7a7a\u95f4\u7ed3\u6784\u3002\u8fd9\u4e09\u79cd\u6709\u529b\u56e0\u7d20\u7684\u5b8c\u7f8e\u7ed3\u5408\uff0c\u4e3aMOF\u6750\u6599\u7684\u5e7f\u6cdb\u5e94\u7528\u63d0\u4f9b\u4e86\u57fa\u7840\u6761\u4ef6<span style=\"color: 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style=\"color: #ff0000;\">[4]<\/span>\u3002<\/p>\n<p><strong>\u4e94\u3001\u6709\u673a\u91d1\u5c5e\u6846\u67b6\u7684\u50ac\u5316\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-145625\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/5-20.jpg\" alt=\"\" width=\"600\" height=\"355\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/5-20.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/5-20-300x178.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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style=\"color: #ff0000;\">[6]<\/span>\u3002<\/p>\n<p><strong>\u4e03\u3001\u6709\u673a\u91d1\u5c5e\u6846\u67b6\u7684\u751f\u7269\u5b66\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-145623\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/7-9.jpg\" alt=\"\" width=\"600\" height=\"464\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/7-9.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/7-9-300x232.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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style=\"color: #ff0000;\">[7]<\/span>\u3002<\/p>\n<p><strong>\u516b\u3001\u6709\u673a\u91d1\u5c5e\u6846\u67b6\u7684\u50a8\u6c22\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-145622\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/8-9.jpg\" alt=\"\" width=\"600\" height=\"904\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/8-9.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/8-9-199x300.jpg 199w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>MOF\u50a8\u6c22\u7684\u7ed3\u5408\u80fd\u548c\u50a8\u5b58\u5bb9\u91cf\u6b63\u5728\u4e0d\u65ad\u589e\u52a0\uff0c\u5176\u4e2d\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u3001\u7a7a\u4f4d\u914d\u4f4d\u70b9\u548c\u5f3a\u8868\u9762\u5076\u6781\u77e9\u8d77\u5230\u4e86\u663e\u8457\u4f5c\u7528\u3002\u5176\u4e2dZn<sub>4<\/sub>O(BDC)<sub>3<\/sub>\u7684H<sub>2<\/sub>\u5438\u6536\u91cf\u4e3a\u8d28\u91cf\u768410%\u548c66 g L<sup>-1<\/sup>\u3002\u9884\u8ba1\u8fd9\u79cd\u7ed3\u6784\u7684\u91cd\u91cf\u5bb9\u91cf\u6539\u5584\u4e0d\u4f1a\u635f\u5931\u6c14\u4f53\u7684\u50a8\u5b58\u5bc6\u5ea6\u3002\u4f46\u662f\u572825\u2103\u4e0b\uff0cMOF\u6750\u6599\u9700\u8981\u5f3a\u7684\u8868\u9762\u5076\u6781\u5b50\u548c\u5f00\u653e\u7684\u91d1\u5c5e\u914d\u4f4d\u70b9\u589e\u52a0H<sub>2<\/sub>\u7684\u4eb2\u548c\u529b\uff0c\u624d\u53ef\u4ee5\u63d0\u9ad8\u6750\u6599\u7684\u50a8\u6c22\u6027\u80fd\u3002MOF\u6750\u6599\u50a8\u6c22\u7684\u96be\u70b9\u5728\u4e8e\u8bbe\u8ba1\u6865\u63a5\u7684\u914d\u4f53\u3001\u8868\u9762\u5b98\u80fd\u56e2\u548c\u91d1\u5c5e\u79bb\u5b50\u7684\u9009\u62e9\uff0c\u8fdb\u800c\u5f62\u6210\u50a8\u6c22\u6846\u67b6\u7ed3\u6784\u3002\u672a\u6765MOF\u6750\u6599\u7684\u7a33\u5b9a\u6027\u3001\u6210\u672c\u53ca\u5927\u89c4\u6a21\u751f\u4ea7\u7684\u4ea7\u4e1a\u5316\u7684\u50a8\u6c22\u7814\u7a76\uff0c\u5c06\u6781\u5927\u7684\u6539\u5584H<sub>2<\/sub>\u7684\u50a8\u5b58\u548c\u4f7f\u7528\u95ee\u9898<span style=\"color: #ff0000;\">[8]<\/span>\u3002<\/p>\n<p><strong>\u4e5d\u3001\u6709\u673a\u91d1\u5c5e\u6846\u67b6\u7684\u5149\u5b66\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-145621\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/9-9.jpg\" alt=\"\" width=\"600\" height=\"1027\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/9-9.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/9-9-175x300.jpg 175w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/9-9-598x1024.jpg 598w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4e0e\u50a8\u6c14\u3001\u5206\u79bb\u548c\u591a\u76f8\u50ac\u5316\u76f8\u6bd4\uff0c\u53d1\u5149MOF\u6750\u6599\u7684\u7814\u7a76\u76f8\u5bf9\u8f83\u5f31\uff0c\u4ec5\u4ec5\u5efa\u7acb\u4e86\u53d1\u5149MOF\u591a\u529f\u80fd\u6750\u6599\u7684\u57fa\u672c\u539f\u5219\u3002\u56e0\u6b64\u53d1\u5149MOF\u4ecd\u7136\u9700\u8981\u8fdb\u884c\u5168\u9762\u7684\u5b9e\u9a8c\u7814\u7a76\u3002\u53d1\u5149MOF\u7684\u5f71\u54cd\u56e0\u7d20\u4e3b\u8981\u6709\u6e29\u5ea6\u3001\u6fc0\u53d1\u6ce2\u957f\u3001\u91cf\u5b50\u4ea7\u7387\u3001\u5bff\u547d\u53ca\u5176\u53d1\u5149\u673a\u7406\u7b49\u3002\u5176\u4e2d\uff0c\u6709\u673a\u914d\u4f53\u7684\u9009\u62e9\u5bf9\u4e8eMOF\u6750\u6599\u7684\u53d1\u5149\u6027\u8d77\u51b3\u5b9a\u6027\u4f5c\u7528\u3002\u76ee\u524d\uff0c\u5177\u6709\u9ad8\u5171\u8f6d\u03c0\u7535\u5b50\u7684\u6709\u673a\u914d\u4f53\u5e7f\u6cdb\u7528\u4e8e\u529f\u80fd\u6027\u53d1\u5149MOF\u7684\u7814\u7a76\u3002\u53e6\u5916\uff0cMOF\u5185\u7684\u7ed3\u6784\u3001\u5b54\u5f84\u548c\u529f\u80fd\u4f4d\u70b9\u4f1a\u5f71\u54cd\u53d1\u5149MOF\u7684\u9ad8\u7075\u654f\u5ea6\u548c\u9009\u62e9\u6027\u3002\u53d1\u5149\u4f20\u611f\u548c\u5fae\u5b54\u7ed3\u5408\u5141\u8bb8\u5c0f\u5206\u5b50\u901a\u8fc7\uff0c\u6392\u9664\u8f83\u5927\u7684\u7269\u8d28\uff0c\u53ef\u4ee5\u5f62\u6210\u5c0f\u5206\u5b50\u9ad8\u7075\u654f\u5ea6\u4f20\u611f\u5668\u3002Kitagawa\u7b49\u4eba\u5f00\u53d1\u7684\u7b80\u5355\u89e3\u7801\u65b9\u6cd5\u662f\u529f\u80fd\u53d1\u5149MOF\u63a2\u7d22\u7684\u7a81\u7834\u4e4b\u4e00\u3002\u8fd9\u79cd\u65b9\u6cd5\u5f15\u53d1\u4e86\u4eba\u4eec\u5e7f\u6cdb\u7684\u7814\u7a76\uff0c\u4e0d\u4ec5\u4ec5\u662f\u7531\u4e8e\u5bfc\u901a\u53d1\u5c04\u548c\u591a\u8272\u53d1\u5149\u7684\u7ed3\u5408\u4f1a\u5f62\u6210\u53d1\u5149MOF\uff0c\u4e5f\u53ef\u4ee5\u83b7\u5f97MOF\u4f20\u611f\u5668\u3002\u672a\u6765\u5c06\u7eb3\u7c73\u7ea7\u7535\u81f4\u53d1\u5149MOF\u7ed3\u5408\u5728\u4e24\u4e2a\u5bfc\u4f53\u4e4b\u95f4\uff0c\u53ef\u4ee5\u5236\u5907\u7535\u5b50\u5668\u4ef6\uff1b\u5236\u6210\u8584\u819c\uff0c\u53ef\u5236\u5907\u4f20\u611f\u88c5\u7f6e\uff1b\u5e94\u7528\u5230\u836f\u7269\u4f20\u8f93\u65b9\u9762\uff0c\u53ef\u4ee5\u7814\u7a76\u836f\u7269\u8f93\u9001\u76d1\u6d4b\u548c\u6cbb\u7597<span style=\"color: #ff0000;\">[9]<\/span>\u3002<\/p>\n<p><strong>\u5341\u3001\u6709\u673a\u91d1\u5c5e\u6846\u67b6\u7684\u78c1\u5b66\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-145620\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/10-7.jpg\" alt=\"\" width=\"600\" height=\"510\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/10-7.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/07\/10-7-300x255.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>MOF\u6750\u6599\u7684\u78c1\u6027\u80fd\u4e0e\u914d\u4f53\uff08\u4f4e\u805a\u7269\uff09\u7684\u94fe\u3001\u5c42\u548c3D\u7f51\u7edc\u6709\u5173\uff0c\u5b83\u4eec\u5f71\u54cd\u4e86\u4e0d\u540c\u957f\u7a0b\u6709\u5e8f\u57fa\u6001\u78c1\u94c1\u3001\u94c1\u78c1\u4f53\u3001\u53cd\u94c1\u78c1\u4f53\u3001\u503e\u659c\u53cd\u94c1\u78c1\u4f53\u3001\u5927\u591a\u6570\u4e0d\u5bfb\u5e38\u7684\u8d85\u78c1\u4f53\u548c\u77ed\u7a0b\u6709\u5e8f\u72b6\u6001\u7684\u5355\u5206\u5b50\u78c1\u94c1\u548c\u5355\u94fe\u78c1\u94c1\u7684\u78c1\u6027\u3002\u8fd9\u79cd\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u7c92\u5b50\u76f8\u7ed3\u5408\u7684\u65b0\u6846\u67b6\u7ed3\u6784\u53ef\u4ee5\u6539\u5584\u6750\u6599\u7684\u7ed3\u6784\u548c\u6027\u8d28\uff0c\u8bbe\u8ba1\u7279\u5b9a\u7684\u78c1\u6027\u6750\u6599\uff0c\u8c03\u8282\u4e0d\u540c\u57fa\u6001\u4e4b\u95f4\u7684\u78c1\u6027\u3002\u53e6\u5916\uff0c\u53ef\u4ee5\u901a\u8fc7\u81ea\u65cb\u4ea4\u53c9\u5f15\u5165\u53cc\u529f\u80fd\u6027\uff0c\u5bfc\u7535\u6027\uff0c\u4ecb\u7535\u6027\uff0c\u6df7\u5408\u6548\u4ef7\u548c\u5149\u5b66\u6548\u5e94\u3002\u7814\u7a76\u53d1\u73b0\uff0cMOF\u6750\u6599\u7684\u78c1\u6027\u8f6c\u53d8\u6e29\u5ea6\u9ad8\u4e8e\u6db2\u6c2e\u548c\u78c1\u6027\u786c\u5ea6\u5927\u4e8e60 kOe\uff0c\u8d85\u8fc7\u6240\u6709\u5df2\u77e5\u7684\u6c27\u5316\u7269\u78c1\u94c1\uff0c\u5e76\u4e14\u5bf9\u53d1\u5c55\u9014\u5f84\u6ca1\u6709\u9650\u5236\uff0c\u56e0\u6b64\u5bf9\u78c1\u6027\u6750\u6599\u7684\u7814\u7a76\u662f\u975e\u5e38\u6709\u610f\u4e49\u7684<span style=\"color: #ff0000;\">[10]<\/span>\u3002<\/p>\n<p><strong>\u3010\u7efc\u8ff0\u76ee\u5f55\u3011<\/strong><\/p>\n<p>[1] Kitagawa S, Matsuda R. <a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0010854507001464\" target=\"_blank\" rel=\"noopener\">Chemistry of coordination space of porous coordination polymers<\/a>[J]. 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Chemical Society Reviews, 2009, 38(5):1353-1379.<\/p>\n<p>\u672c\u6587\u7531\u65b0\u80fd\u6e90\u7ec4Materials_1219\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c<strong>\u6295\u7a3f\u90ae\u7bb1<\/strong><strong>tougao@cailiaoren.com<\/strong>\u3002<\/p>\n<p>\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<strong>cailiaokefu<\/strong>\u3002<\/p>\n<p>\u6750\u6599\u725b\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\"><strong>\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u4ec0\u4e48\u662f\u6709\u673a\u91d1\u5c5e\u6846\u67b6\u7ed3\u6784\uff1f \u6709\u673a\u91d1\u5c5e\u6846\u67b6\uff08Metal-organic framework\uff0cMOF\uff09\u662f\u65b0\u6750\u6599\u9886\u57df\u7814\u7a76\u7684\u70ed\u70b9\u3002\u81ea\u4ece1990\u5e74\uff0c\u7f8e\u56fdYaghi\u8bfe\u9898\u7ec4&#8230;<\/p>\n","protected":false},"author":7035,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[2592,2490,245],"class_list":["post-145616","post","type-post","status-publish","format-standard","hentry","category-zhuanlan","tag-2592","tag-2490","tag-mof"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/145616"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7035"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=145616"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/145616\/revisions"}],"predecessor-version":[{"id":145913,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/145616\/revisions\/145913"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=145616"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=145616"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=145616"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}