{"id":149008,"date":"2018-08-06T06:00:25","date_gmt":"2018-08-05T22:00:25","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=149008"},"modified":"2018-08-06T10:01:36","modified_gmt":"2018-08-06T02:01:36","slug":"adv-energy-mater-%e5%8f%8d%e8%9b%8b%e7%99%bd%e7%9f%b3%e7%bb%93%e6%9e%84%e7%a2%b3%e5%8c%85%e8%a6%86%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e7%a1%ab%e5%8c%96%e7%89%a9%e9%87%8f%e5%ad%90%e7%82%b9%e7%ba%b3","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=149008","title":{"rendered":"Adv. Energy Mater.: \u53cd\u86cb\u767d\u77f3\u7ed3\u6784\u78b3\u5305\u8986\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u91cf\u5b50\u70b9\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7528\u4e8e\u9ad8\u6027\u80fd\u50a8\u94a0"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u00a0 \u00a0 \u00a0 \u00a0 \u94a0\u79bb\u5b50\u7535\u6c60(SIBs) \u5177\u5907\u50a8\u91cf\u4e30\u5bcc\u3001\u6210\u672c\u4f4e\u7b49\u4f18\u52bf\uff0c\u6709\u671b\u6210\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7406\u60f3\u66ff\u4ee3\u54c1\u3002\u7136\u800c\uff0c\u5e38\u89c1\u7684SIB\u8d1f\u6781\u6750\u6599\u7406\u8bba\u6bd4\u5bb9\u91cf\u4f4e\uff0c\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u5747\u4e0d\u7406\u60f3\u3002\u4e3a\u4e86\u7f13\u89e3\u4ee5\u4e0a\u7f3a\u9677\uff0c\u672c\u6587\u8bbe\u8ba1\u4e86\u4e00\u79cd\u7b80\u5355\u3001\u53ef\u9760\u7684\u65b9\u6cd5\uff0c\u5236\u5907\u5f97\u5230\u4e86\u50a8\u94a0\u6027\u80fd\u4f18\u5f02\u7684\u53cd\u86cb\u767d\u77f3\u7ed3\u6784\u78b3\u5305\u8986\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u91cf\u5b50\u70b9\u7eb3\u7c73\u590d\u5408\u6750\u6599\u3002\u7814\u7a76\u53d1\u73b0\uff1a\u8be5\u590d\u5408\u6750\u6599\u4e3a3D\u6709\u5e8f\u591a\u5b54\u7ed3\u6784\uff0c\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u91cf\u5b50\u70b9\u5728\u5bfc\u7535\u78b3\u57fa\u8d28\u4e2d\u5747\u5300\u5206\u6563\uff1b\u5bfc\u7535\u78b3\u57fa\u8d28\u5f15\u5165\u4e0d\u4ec5\u53ef\u4ee5\u6709\u6548\u7f13\u51b2\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4f53\u79ef\u53d8\u5316\u5f15\u8d77\u7684\u5e94\u53d8\uff0c\u800c\u4e14\u53ef\u4ee5\u6709\u6548\u6539\u5584\u7535\u6781\u7684\u5bfc\u7535\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u00a0 \u00a0 \u00a0 \u00a0 \u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u6d77\u897f\u7814\u7a76\u9662\u7684\u6e29\u73cd\u6d77\u6559\u6388<\/strong>\u548c\u798f\u5dde\u5927\u5b66\u7684\u8a79\u7ea2\u5175\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\uff0c\u901a\u8fc7\u6a21\u677f\u6cd5\u5c06\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u91cf\u5b50\u70b9\u5d4c\u5165\u5230\u4e09\u7ef4\u5927\u5b54\u78b3\u9aa8\u67b6\u4e2d\uff0c\u6210\u529f\u5236\u5907\u4e86\u53cd\u86cb\u767d\u77f3\u7ed3\u6784\u7684\u78b3\u5305\u8986\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u91cf\u5b50\u70b9\u7eb3\u7c73\u590d\u5408\u6750\u6599(3DOM TMs-QDs@NC)\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e:\u8be5\u7eb3\u7c73\u590d\u5408\u6750\u6599\u4f5c\u4e3aSIB\u8d1f\u6781\u6750\u6599\u65f6\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u8d85\u8fc72000\u6b21\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cReliable and General Route to Inverse Opal Structured Nanohybrids of Carbon-Confined Transition Metal Sulfides Quantum Dots for High-Performance Sodium Storage\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Energy Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u793a\u610f\u56fe<\/strong>-1<\/strong>.<\/strong> 3DOM TMs-QDs@NC<\/strong>\u7684\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u56fe<\/strong>-1. 3DOM Co9<\/sub>S8<\/sub>-QDs@NC<\/strong>\u590d\u5408\u6750\u6599\u7684\u7535\u955c\u56fe\u7247\u53ca\u5143\u7d20\u5206\u5e03<\/strong><\/p>\n

\"\"<\/p>\n

(a)-(c) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u590d\u5408\u6750\u6599\u7684FE-SEM\u56fe\u50cf\uff1b<\/p>\n

(d)-(f) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u590d\u5408\u6750\u6599\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

(g) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u590d\u5408\u6750\u6599\u7684\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c(HR-TEM)\u56fe\u50cf\uff1b<\/p>\n

(h) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u590d\u5408\u6750\u6599\u7684\u6697\u573aSTEM\u56fe\u50cf\uff1b<\/p>\n

(i) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u590d\u5408\u6750\u6599\u7684EDX\u5143\u7d20\u5206\u5e03\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong>-2. 3DOM Co9<\/sub>S8<\/sub>-QDs@NC<\/strong>\u590d\u5408\u6750\u6599\u7684<\/strong>XRD<\/strong>\u56fe\u50cf\u53ca<\/strong>Co9<\/sub>S8<\/sub><\/strong>\u7684\u7acb\u65b9\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"(a) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u590d\u5408\u6750\u6599\u7684XRD\u56fe\u50cf\uff1b<\/p>\n

(b) Co9<\/sub>S8<\/sub>\u7684\u7acb\u65b9\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>-3. 3DOM Co9<\/sub>S8<\/sub>-QDs@NC<\/strong>\u590d\u5408\u6750\u6599\u7684\u62c9\u66fc\u5149\u8c31\u3001<\/strong>XPS<\/strong>\u80fd\u8c31\u3001\u6c2e\u6c14\u5438\u9644\u8131\u9644\u7b49\u6e29\u7ebf\u53ca\u5176\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(a) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u590d\u5408\u6750\u6599\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n

(b) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u590d\u5408\u6750\u6599\u7684XPS\u80fd\u8c31\uff1b<\/p>\n

(c)-(e) Co, S, N\u5bf9\u5e94\u7684\u9ad8\u5206\u8fa8\u7387XPS\u80fd\u8c31\uff1b<\/p>\n

(f) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u590d\u5408\u6750\u6599\u7684\u6c2e\u6c14\u5438\u9644\u8131\u9644\u7b49\u6e29\u7ebf\u53ca\u5176\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong>-4. 3DOM Co9<\/sub>S8<\/sub>-QDs@NC<\/strong>\u590d\u5408\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(a) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u5faa\u73af\u4f0f\u5b89(CV)\u66f2\u7ebf\uff1b<\/p>\n

(b) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(c) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u5faa\u73af\u6027\u80fd\u66f2\u7ebf\uff1b<\/p>\n

(d) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u500d\u7387\u6027\u80fd\u66f2\u7ebf\uff1b<\/p>\n

(e) \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff1b<\/p>\n

(f) \u4e0d\u540c\u8d1f\u6781\u6750\u6599\u7684\u500d\u7387\u6027\u80fd\u5bf9\u6bd4\uff1b<\/p>\n

(g) \u7535\u6d41\u5bc6\u5ea6\u4e3a1 A\u2219g-1<\/sup>\u65f6\uff0c3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u5faa\u73af\u6027\u80fd\u53ca\u5e93\u4f26\u6548\u7387\u3002<\/p>\n

\u56fe<\/strong>-5. <\/strong>\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u6837\u54c1\u7684<\/strong>CV<\/strong>\u66f2\u7ebf\u53ca\u5bb9\u91cf\u8d21\u732e\u5206\u5e03\u60c5\u51b5<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

(b) \u4e0d\u540c\u6c27\u5316-\u8fd8\u539f\u72b6\u6001\u4e0b\u7535\u6d41\u4e0e\u626b\u901f\u4e4b\u95f4\u7684\u5173\u7cfb\u66f2\u7ebf\uff1b<\/p>\n

(c) \u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0c3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u4e2d\u7535\u5bb9\u6027\u5bb9\u91cf\u5bf9\u603b\u5bb9\u91cf\u7684\u8d21\u732e\u7387\u5bf9\u6bd4\u56fe\uff1b<\/p>\n

(d) \u626b\u63cf\u901f\u7387\u4e3a6 mV\u2219s-1<\/sup>\u65f6\uff0c3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u7535\u5bb9\u578b\u5bb9\u91cf\u548c\u6269\u6563\u63a7\u5236\u578b\u5bb9\u91cf\u5bf9\u603b\u5bb9\u91cf\u7684\u8d21\u732e\u5bf9\u6bd4\u56fe\uff1b<\/p>\n

(e) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u548cCo9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u5faa\u73af\u540e\u7684Nyquist\u66f2\u7ebf\uff1b<\/p>\n

(f) \u4f4e\u9891\u533a3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u548cCo9<\/sub>S8<\/sub>-QDs@NC \u7535\u6781\u4e2d\u89d2\u901f\u5ea6\u4e0e\u7535\u963b\u4e4b\u95f4 \u7684\u5173\u7cfb\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong>-6. 3DOM Co9<\/sub>S8<\/sub>-QDs@NC<\/strong>\u548c<\/strong>Co9<\/sub>S8<\/sub>-QDs@NC<\/strong>\u7535\u6781\u7684\u6a2a\u622a\u9762<\/strong>SEM<\/strong>\u56fe\u50cf\u4ee5\u53ca\u76f8\u5e94\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u521d\u59cb\u72b6\u6001\u4e0b3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

(b) \u521d\u59cb\u72b6\u6001\u4e0bCo9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

(c) \u6ee1\u5145\u72b6\u6001\u4e0b3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

(d) \u6ee1\u5145\u72b6\u6001\u4e0bCo9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

(e) \u4e0d\u540c\u5145\u653e\u7535\u500d\u7387\u4e0b3DOM Co9<\/sub>S8<\/sub>-QDs@NC\u548cCo9<\/sub>S8<\/sub>-QDs@NC\u7535\u6781\u5185\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>-8. 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\/Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub><\/strong>\u94a0\u79bb\u5b50\u5168\u7535\u6c60\u793a\u610f\u56fe\u53ca\u5176\u5bf9\u5e94\u7684\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(a) 3DOM Co9<\/sub>S8<\/sub>-QDs@NC\/Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>\u7535\u6781\u5bf9\u6784\u6210\u7684\u94a0\u79bb\u5b50\u5168\u7535\u6c60\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(b) \u7535\u6d41\u5bc6\u5ea6\u4e3a0.5 A\u2219g-1<\/sup>\u65f6\uff0c\u94a0\u79bb\u5b50\u5168\u7535\u6c60\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(c) \u7535\u6d41\u5bc6\u5ea6\u4e3a0.5 A\u2219g-1<\/sup>\u65f6\uff0c\u94a0\u79bb\u5b50\u5168\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u901a\u8fc7\u6a21\u677f\u6cd5\u5236\u5907\u5f97\u5230\u4e86\u53cd\u86cb\u767d\u77f3\u7ed3\u6784\u7684\u4e09\u7ef4\u78b3\u5305\u8986\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u91cf\u5b50\u70b9\u7eb3\u7c73\u590d\u5408\u6750\u6599\u3002\u7814\u7a76\u53d1\u73b0\uff1a\u8be5\u7eb3\u7c73\u590d\u5408\u6750\u6599\u5177\u5907\u4f18\u5f02\u7684\u50a8\u94a0\u6027\u80fd\uff1b\u7279\u6b8a\u7684\u5fae-\u7eb3\u7ed3\u6784\u6709\u6548\u589e\u5f3a\u4e86\u7535\u6781\u6750\u6599\u7684\u79bb\u5b50\u4f20\u8f93\u548c\u7535\u5b50\u4f20\u9012\u6548\u7387\uff0c\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf\u548c\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u80fd\u3002\u8be5\u65b9\u6cd5\u4e3a\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u7eb3\u7c73\u6750\u6599\u5728\u80fd\u6e90\u50a8\u5b58\u4e0e\u8f6c\u5316\u9886\u57df\u7684\u5e94\u7528\u62d3\u5bbd\u4e86\u65b0\u7684\u9053\u8def\u3002<\/p>\n

\u3010\u6587\u732e\u4fe1\u606f\u3011<\/strong><\/p>\n

Reliable and General Route to Inverse Opal Structured Nanohybrids of Carbon-Confined Transition Metal Sulfides Quantum Dots for High-Performance Sodium Storage<\/a> (Adv. Energy Mater. 2018, DOI\uff1aDOI: 10.1002\/aenm.201801452<\/a>)<\/p>\n

 <\/p>\n

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\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>!<\/u><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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