{"id":150890,"date":"2018-08-23T06:17:25","date_gmt":"2018-08-22T22:17:25","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=150890"},"modified":"2018-08-23T20:22:13","modified_gmt":"2018-08-23T12:22:13","slug":"%e5%8d%8e%e4%b8%ad%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6%e8%b0%ad%e5%bf%85%e6%81%a9%e6%95%99%e6%8e%88macromol-rapid-commun-%ef%bc%9a%e5%8f%af%e6%ba%b6%e8%b6%85%e6%94%af%e5%8c%96%e5%a4%9a%e5%ad%94","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=150890","title":{"rendered":"\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u8c2d\u5fc5\u6069\u6559\u6388Macromol. Rapid Commun. \uff1a\u53ef\u6eb6\u8d85\u652f\u5316\u591a\u5b54\u6709\u673a\u805a\u5408\u7269"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\uff08POPs\uff09\u4f5c\u4e3a\u591a\u5b54\u6750\u6599\u7684\u91cd\u8981\u5206\u652f\uff0c\u5728\u5438\u9644\u3001\u5206\u79bb\u3001\u50ac\u5316\u3001\u6709\u673a\u5149\u7535\u7b49\u9886\u57df\u663e\u793a\u51fa\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u7136\u800c\uff0c\u591a\u6570POPs\u6750\u6599\u5728\u5408\u6210\u4e4b\u521d\u5747\u4ee5\u7c89\u4f53\u5f62\u5f0f\u5b58\u5728\uff0c\u96be\u4ee5\u52a0\u5de5\u6210\u578b\uff0c\u5bf9\u5176\u5b9e\u9645\u5e94\u7528\u5e26\u6765\u4e86\u6781\u5927\u7684\u9650\u5236\u3002\u56e0\u6b64\uff0c\u53d1\u5c55\u53ef\u6eb6POPs\uff0c\u6210\u4e3a\u591a\u5b54\u6750\u6599\u5b9e\u9645\u5e94\u7528\u8fdb\u7a0b\u4e2d\u7684\u4e00\u5927\u70ed\u70b9\u3002\u76ee\u524d\uff0c\u53ef\u6eb6POPs\u7684\u79cd\u7c7b\u548c\u6570\u91cf\u5341\u5206\u6709\u9650\uff0c\u5df2\u6709\u7684\u81ea\u5177\u5fae\u5b54\u805a\u5408\u7269\uff08PIMs\uff09\u3001\u53ef\u6eb6\u5171\u8f6d\u5fae\u5b54\u805a\u5408\u7269\uff08SCMPs\uff09\u3001\u53ef\u6eb6\u5171\u8f6d\u805a\u5408\u7269\u7eb3\u7c73\u7c92\u5b50\uff08SCPNs\uff09\u7b49\u6750\u6599\u5b58\u5728\u6210\u672c\u9ad8\u6602\u3001\u8def\u7ebf\u590d\u6742\u7b49\u5f0a\u7aef\uff0c\u964d\u4f4e\u4e86\u5b9e\u9645\u5e94\u7528\u7684\u53ef\u884c\u6027\uff0c\u53d1\u5c55\u4f4e\u6210\u672c\u3001\u6613\u4e8e\u52a0\u5de5\u7684\u5408\u6210\u8def\u7ebf\u5341\u5206\u5fc5\u8981\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u8c2d\u5fc5\u6069\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u7814\u7a76\u56e2\u961f\u5728\u5b66\u672f\u671f\u520aMacromol. Rapid Commun.<\/b><\/strong>\u00a0\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u00a0\u201cSoluble Hyperbranched Porous Organic Polymers<\/b><\/strong>\u201d\u7684\u6587\u7ae0\uff0c\u5c06\u8d85\u652f\u5316\u805a\u5408\u7269\uff08HBPs\uff09\u4e0e\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\u7684\u6982\u5ff5\u76f8\u7ed3\u5408\uff0c\u63d0\u51fa\u4e86\u5236\u5907\u53ef\u6eb6POPs\u7684\u65b0\u7b56\u7565\u3002\u4ed6\u4eec\u4ee5AB2\u578b\u521a\u6027\u6709\u673a\u5355\u4f53\u4f5c\u4e3a\u6784\u7b51\u5355\u5143\uff0c\u901a\u8fc7\u7b80\u5355\u9ad8\u6548\u7684Frediel-Crafts\u53cd\u5e94\u4e00\u6b65\u805a\u5408\u5f97\u5230\u4e86\u53ef\u6eb6\u8d85\u652f\u5316\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\u3002\u8be5\u7c7b\u6750\u6599\u517c\u5177HBPs\u7684\u6709\u673a\u6eb6\u89e3\u6027\u53caPOPs\u7684\u5b54\u6027\u8d28\uff0c\u6bd4\u8868\u9762\u79ef\u6700\u9ad8\u8fbe\u5230646 m2<\/sup>\u00a0g-1<\/sup>\uff0c\u5728\u6eb6\u89e3\u6210\u819c\u4e4b\u540e\u4ecd\u80fd\u4fdd\u6301\u9ad8\u5ea6\u7684\u591a\u5b54\u6027\uff0c\u5728\u6c14\u4f53\u50a8\u5b58\u548c\u5206\u79bb\u3001\u5149\u7535\u3001\u836f\u7269\u91ca\u653e\u7b49\u9886\u57df\u5177\u6709\u663e\u8457\u7684\u5e94\u7528\u4f18\u52bf\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

Poly(CDM)-x <\/b><\/strong>\u548c<\/b><\/strong>\u00a0Poly(DCDM)-x<\/b><\/strong>\u7684\u5408\u6210\u8def\u7ebf\u3002\u5355\u4f53\uff1a(<\/b><\/strong>a<\/b><\/strong>\uff09\u4e8c\u82ef\u6c2f\u7532\u70f7\uff1b(<\/b><\/strong>\u00a0b<\/b><\/strong>\uff09\u4e8c\u6c2f\u4e8c\u82ef\u7532\u70f7<\/b><\/strong><\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u56fe<\/b><\/strong>1 <\/b><\/strong>\u00a0(<\/b><\/strong>a<\/b><\/strong>)<\/b><\/strong>\u00a0<\/b><\/strong>\u4e01\u8fbe\u5c14\u6548\u5e94\u68c0\u6d4b<\/b><\/strong>St-co-MAA<\/b><\/strong>\u4e73\u6db2\u3001<\/b><\/strong>poly(CDM)-215 \/THF<\/b><\/strong>\u6eb6\u6db2\u53ca<\/b><\/strong>poly(DCDM)\/THF<\/b><\/strong>\u6eb6\u6db2\uff1b(<\/b><\/strong>d<\/b><\/strong>)<\/b><\/strong>\u00a0poly(DCDM)-335<\/b><\/strong>\u819c<\/b><\/strong>\u00a0<\/b><\/strong>\uff1b(<\/b><\/strong>b, e<\/b><\/strong>\uff09<\/b><\/strong>poly(DCDM)-335<\/b><\/strong>\u819c\u7684<\/b><\/strong>SEM<\/b><\/strong>\u56fe\uff1b(<\/b><\/strong>c, f<\/b><\/strong>\uff09\u65e5\u5149\u706f\u4e0b\u548c\u7d2b\u5916\u706f\u7167\u5c04\u4e0b\uff08\u5185\u90e8\uff09\u7684<\/b><\/strong>poly(CDM)-215\/PS <\/b><\/strong>\u819c\u548c<\/b><\/strong>poly(DCDM)-335\/PS <\/b><\/strong>\u819c<\/b><\/strong><\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u56fe<\/b><\/strong>2 <\/b><\/strong>\u00a0<\/b><\/strong>a<\/b><\/strong>\uff09<\/b><\/strong>Poly(CDM)-x<\/b><\/strong>\uff08\u5b9e\u5fc3\uff09\u548c<\/b><\/strong>poly-(DCDM)-x<\/b><\/strong>\uff08\u7a7a\u5fc3\uff09\u7684\u91cd\u5747\u5206\u5b50\u91cf\uff08<\/b><\/strong>M<\/b><\/strong>w,LS<\/b><\/sub><\/strong>\uff0c\u7ea2\uff09\u548c\u5206\u5b50\u91cf\u5206\u5e03\u6307\u6570\uff08<\/b><\/strong>PDI<\/b><\/strong>LS<\/b><\/sub><\/strong>\uff0c\u84dd\uff09\uff1b<\/b><\/strong>b, e) poly(CDM)-155 <\/b><\/strong>\u548c<\/b><\/strong>poly-(DCDM)-155<\/b><\/strong>\u7684<\/b><\/strong>SEM<\/b><\/strong>\u56fe\uff1b<\/b><\/strong>c, f) poly(CDM)-155<\/b><\/strong>\u548c<\/b><\/strong>poly(DCDM)-155<\/b><\/strong>\u7684<\/b><\/strong>TEM<\/b><\/strong>\u56fe\uff1b<\/b><\/strong>d, g)poly(CDM)-155<\/b><\/strong>\u548c<\/b><\/strong>poly(DCDM)-155<\/b><\/strong>\u7684HR<\/b><\/strong>TEM<\/b><\/strong>\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u56fe<\/b><\/strong>3 <\/b><\/strong>\u00a0(<\/b><\/strong>a<\/b><\/strong>\uff09<\/b><\/strong>poly(DCDM)-395 (<\/b><\/strong>\u84dd<\/b><\/strong>)<\/b><\/strong>\u548c<\/b><\/strong>poly(DCDM)-395-CHCl<\/b><\/strong>3<\/b><\/sub><\/strong>-Anti (<\/b><\/strong>\u7ea2<\/b><\/strong>) <\/b><\/strong>\u5728<\/b><\/strong>77.3 K<\/b><\/strong>\u4e0b\u7684\u6c2e\u6c14\u5438\u9644<\/b><\/strong>–<\/b><\/strong>\u89e3\u5438\u9644\u66f2\u7ebf\uff1b(<\/b><\/strong>b<\/b><\/strong>\uff09<\/b><\/strong>poly(DCDM)-395 (<\/b><\/strong>\u84dd<\/b><\/strong>)<\/b><\/strong>\u548c<\/b><\/strong>poly(DCDM)-395-CHCl<\/b><\/strong>3<\/b><\/sub><\/strong>-Anti <\/b><\/strong>\uff08\u7ea2\uff09\u5728<\/b><\/strong>77.3 K<\/b><\/strong>\u4e0b\u7684\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\uff1b(<\/b><\/strong>c<\/b><\/strong>\uff09<\/b><\/strong>poly(DCDM)-395-CHCl<\/b><\/strong>3<\/b><\/sub><\/strong>\u00a0<\/b><\/strong>\u5728<\/b><\/strong>273 K<\/b><\/strong>\u4e0b\u7684<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u5438\u9644\u66f2\u7ebf\u3002\u5185\u90e8\uff1a\u91c7\u7528\u975e\u672c\u5f81\u5bc6\u5ea6\u6a21\u578b\u8ba1\u7b97\u5f97\u5230\u7684\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\uff1b(<\/b><\/strong>d<\/b><\/strong>\uff09<\/b><\/strong>poly(DCDM)-395<\/b><\/strong>\uff08\u84dd\uff09<\/b><\/strong>, poly(DCDM)-395-CHCl<\/b><\/strong>3<\/b><\/sub><\/strong>\uff08\u9ed1\uff09\u548c<\/b><\/strong>\u00a0poly(DCDM)-395-CHCl<\/b><\/strong>3<\/b><\/sub><\/strong>-Anti<\/b><\/strong>\uff08\u7ea2\uff09\u5728<\/b><\/strong>273 K<\/b><\/strong>\u4e0b\u7684<\/b><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u5438\u9644<\/b><\/strong>–<\/b><\/strong>\u89e3\u5438\u9644\u66f2\u7ebf\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u56fe<\/b><\/strong>4 Poly(CDM)-x<\/b><\/strong>\uff08<\/b><\/strong>a<\/b><\/strong>\uff09\u548c<\/b><\/strong>poly(DCDM)-x<\/b><\/strong>\uff08<\/b><\/strong>b<\/b><\/strong>\uff09\u7684\u8367\u5149\u53d1\u5c04\u5149\u8c31\u3002\u5185\u90e8\u4e3a\u7d2b\u5916\u706f\u7167\u5c04\u4e0b<\/b><\/strong>poly(CDM)-x<\/b><\/strong>\u7684\u6c2f\u4eff\u6eb6\u6db2\u548c<\/b><\/strong>poly(DCDM)-x<\/b><\/strong>\u7684\u6c2f\u4eff\u6eb6\u6db2\uff1b(<\/b><\/strong>c<\/b><\/strong>\uff09<\/b><\/strong>CCK-8<\/b><\/strong>\u6cd5\u7ec6\u80de\u6d3b\u529b\u68c0\u6d4b\uff0c\u5f85\u6d4b\u5de5\u4f5c\u6db2\u6d53\u5ea6\u4e3a<\/b><\/strong>0-100 \u03bcg\/mL<\/b><\/strong>\uff1b(<\/b><\/strong>d<\/b><\/strong>\uff09<\/b><\/strong>poly(DCDM)-335<\/b><\/strong>\u7684\u836f\u7269\u91ca\u653e\u66f2\u7ebf\u3002\u7ea2\u7ebf\u4e3a\u62df\u5408\u66f2\u7ebf\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

\u672c\u6587\u6210\u529f\u5730\u8bbe\u8ba1\u548c\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u5206\u5b50\u91cf\u53ef\u9884\u6d4b\u7684\u53ef\u6eb6\u8d85\u652f\u5316\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\u3002\u8d85\u652f\u5316\u805a\u5408\u7269\u7684\u7ed3\u6784\u4f7f\u5176\u80fd\u5728\u6eb6\u89e3\u540e\u5f88\u5927\u7a0b\u5ea6\u4e0aPOPs\u7684\u6bd4\u8868\u9762\u79ef\u3002\u5728\u4e0d\u8003\u8651\u52a0\u5de5\u6761\u4ef6\u7684\u60c5\u51b5\u4e0b\uff0c\u53ef\u6eb6\u8d85\u652f\u5316\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\u7684\u6bd4\u8868\u9762\u79ef\u8f83\u5927\uff0c\u6709\u671b\u7528\u4e8e\u6c14\u4f53\u5438\u9644\u4e0e\u5206\u79bb\u3002\u540c\u65f6\uff0c\u5b83\u8fd8\u5177\u6709\u9ad8\u8f7d\u836f\u7387\u53ca\u8367\u5149\u6027\u80fd\uff0c\u4fc3\u8fdb\u4e86\u540e\u7eed\u805a\u5408\u7269\u591a\u5b54\u819c\u65b9\u9762\u7684\u7814\u7a76\u3002<\/p>\n

\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\u4e3a\u7b2c\u4e00\u5b8c\u6210\u5355\u4f4d\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a2015\u7ea7\u535a\u58eb\u751f\u6768\u7389\u7696\uff0c\u8c2d\u5fc5\u6069\u6559\u6388\u4e3a\u8bba\u6587\u901a\u8baf\u4f5c\u8005\uff1b\u8bba\u6587\u4f5c\u8005\u8fd8\u5305\u62ec\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u751f\u547d\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u96622015\u7ea7\u7855\u58eb\u751f\u51af\u51cc\u4e91\uff1b\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u96622014\u7ea7\u7855\u58eb\u751f\u5218\u4e91\u98de\u3001\u672c\u79d1\u751f\u4efb\u4fca\uff1b\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\u526f\u6559\u6388\u91d1\u5c1a\u5f6c\uff1b\u751f\u547d\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u9662\u6559\u6388\u82cf\u8389\uff1b\u6fb3\u5927\u5229\u4e9aCSIRO\u7684Colin Wood\u535a\u58eb\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Soluble Hyperbranched Porous Organic Polymers<\/a>\u00a0<\/b><\/strong>\uff08\u00a0Macromol. Rapid Commun.\u00a02018\uff0cDOI: 10.1002\/marc.201800441\u00a0\u00a0\uff09<\/p>\n

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