{"id":152433,"date":"2018-08-31T08:00:52","date_gmt":"2018-08-31T00:00:52","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=152433"},"modified":"2018-09-02T21:27:30","modified_gmt":"2018-09-02T13:27:30","slug":"%e5%a4%a7%e8%bf%9e%e7%89%a9%e5%8c%96%e6%89%80joule%ef%bc%9a%e5%9f%ba%e4%ba%8e%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%e7%94%b5%e5%af%b9%e6%9e%84%e7%ad%91%e4%ba%86%e8%a1%a8%e8%a7%82%e9%87%8f%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=152433","title":{"rendered":"\u5927\u8fde\u7269\u5316\u6240Joule\uff1a\u57fa\u4e8e\u6c27\u5316\u8fd8\u539f\u7535\u5bf9\u6784\u7b51\u4e86\u8868\u89c2\u91cf\u5b50\u6548\u7387\u8d8510\uff05\u7684\u53ef\u89c1\u5149\u50ac\u5316\u5168\u5206\u89e3\u6c34\u5236\u6c22\u4f53\u7cfb"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240<\/strong>\u7684\u674e\u707f\u9662\u58eb<\/strong>\u548c\u7ae0\u798f\u7965\u7814\u7a76\u5458<\/strong>\uff08\u5171\u540c\u901a\u8baf\uff09\u4f5c\u8005\u7b49\u4eba\uff0c\u4ee5[Fe(CN)6<\/sub>]3\u2012<\/sup>\/[Fe(CN)6<\/sub>]4\u2012<\/sup>\u4e3a\u6c27\u5316\u8fd8\u539f\u7535\u5bf9\uff08\u4f18\u70b9\uff1a\u5355\u7535\u5b50\u8f6c\u79fb\u3001\u9002\u5b9c\u4e2d\u6027\u73af\u5883\u3001\u4f4e\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff09\uff0c\u4ee5BiVO4<\/sub>\u5149\u50ac\u5316\u5242\u4e3a\u4ea7\u6c27\u7aef\uff08\u5438\u6536\u5e26\u8fb9ca. 540 nm\uff0c\u5177\u6709\u6676\u9762\u7535\u8377\u5206\u79bb\u6548\u5e94\uff09\uff0cZrO2<\/sub>\u4fee\u9970\u7684TaON\u4e3a\u4ea7\u6c22\u7aef\uff08\u5438\u6536\u5e26\u8fb9ca. 510 nm\uff09\u6784\u7b51\u4e86\u9ad8\u6548\u7684Z\u673a\u5236\u50ac\u5316\u5168\u5206\u89e3\u6c34\u4f53\u7cfb\u3002\u7814\u7a76\u53d1\u73b0\u91d1\u5c5eAu\u52a9\u50ac\u5316\u5242\u6709\u5229\u4e8e\u4fc3\u8fdb\u7535\u5b50\u7531BiVO4<\/sub>\u5411[Fe(CN)6<\/sub>]3\u2012<\/sup>\u7684\u8f6c\u79fb\uff0c\u540c\u65f6\u53cc\u52a9\u50ac\u5316\u5242\uff08Au\/CoOx<\/sub>\uff09\u5728BiVO4<\/sub>{010}\u548c{110}\u6676\u9762\u4e0a\u7684\u9009\u62e9\u6027\u6c89\u79ef\u53ef\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u7535\u8377\u5206\u79bb\u5e76\u63d0\u5347\u4ea7\u6c27\u6027\u80fd\uff0c\u5728\u6b64\u57fa\u7840\u4e0a\u5b9e\u73b0AQE\u8fbe10.3%\uff08420 nm\u6fc0\u53d1\uff09\u3002\u8fd9\u9879\u5de5\u4f5c\u7a81\u51fa\u4e86\u52a9\u50ac\u5316\u5242\u7684\u79cd\u7c7b\u3001\u62c5\u8f7d\u7b56\u7565\u53ca\u5176\u6c89\u79ef\u4f4d\u70b9\u5728\u52a0\u901f\u7535\u8377\u5206\u79bb\u548c\u4fc3\u8fdb\u8868\u9762\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u4f5c\u7528\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Redox-Based Visible-Light-Driven Z-Scheme Overall Water Splitting with Apparent Quantum Efficiency Exceeding 10%<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Joule<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 <\/strong>\u53ef\u89c1\u5149<\/strong>Z<\/strong>\u673a\u5236\u50ac\u5316\u5168\u5206\u89e3\u6c34\u673a\u7406\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong> 2 BiVO4<\/sub><\/strong>\u4e0a<\/strong>Au<\/strong>\u548c<\/strong>CoOx<\/sub><\/strong>\u53cc\u52a9\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u6c89\u79ef<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09Au\/CoOx<\/sub>-BiVO4<\/sub>\u6837\u54c1\u7684FESEM\u56fe\u50cf\uff1b<\/p>\n

\uff08B\uff09Au\/CoOx<\/sub>-BiVO4<\/sub>\u6837\u54c1\u4e2dAu\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08C\uff09Au\/CoOx<\/sub>-BiVO4<\/sub>\u6837\u54c1\u4e2dCoOx<\/sub>\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong> 3 <\/strong>\u53ef\u89c1\u5149<\/strong>Z<\/strong>\u673a\u5236\u50ac\u5316\u5168\u5206\u89e3\u6c34\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

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\uff08B\uff09\u4e0d\u540c\u6ce2\u957f\u4e0b\u7684\u8868\u89c2\u91cf\u5b50\u6548\u7387\u4e0e\u4ea7\u6c22\u7aef\u548c\u4ea7\u6c27\u7aef\u7d2b\u5916\u53ef\u89c1\u6f2b\u53cd\u5c04\u5438\u6536\u5149\u8c31\u8d8b\u52bf\u5bf9\u6bd4\u56fe\u3002<\/p>\n

\u56fe<\/strong> 4 <\/strong>\u52a9\u50ac\u5316\u5242\u7684\u529f\u80fd\u548c\u53cc\u52a9\u50ac\u5316\u5242\u4fc3\u8fdb\u7535\u8377\u5206\u79bb<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09BiVO4<\/sub>\/FTO\uff0cPd-BiVO4<\/sub>\/FTO\uff0cAg-BiVO4<\/sub>\/FTO\uff0cAu-BiVO4<\/sub>\/FTO\u7535\u6781\u5728K3<\/sub>[Fe(CN)6<\/sub>]\u6eb6\u6db2\u4e2d\u7684LSV\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08B\uff09BiVO4<\/sub>\/FTO\uff0cPd-BiVO4<\/sub>\/FTO\uff0cAg-BiVO4<\/sub>\/FTO\uff0cAu-BiVO4<\/sub>\/FTO\u7535\u6781\u5728K3<\/sub>[Fe(CN)6<\/sub>]\u6eb6\u6db2\u4e2d\u7684EIS\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08C\uff09BiVO4<\/sub>\uff0cAu\/BiVO4<\/sub>\uff0cCoOx<\/sub>\/BiVO4<\/sub>\uff0cAu\/CoOx<\/sub>\/BiVO4<\/sub>\u6837\u54c1\u7684\u8868\u9762\u5149\u7535\u538b\u8c31\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u53d1\u73b0\u7535\u5b50\u4f20\u8f93\u4ecb\u8d28\u4e0e\u4ea7\u6c22\u7aef\/\u4ea7\u6c27\u7aef\u95f4\u7684\u7535\u8377\u4f20\u8f93\u662f\u6784\u5efa\u53ef\u89c1\u5149Z\u673a\u5236\u50ac\u5316\u5168\u5206\u89e3\u6c34\u4f53\u7cfb\u7684\u5173\u952e\u6b65\u9aa4\u4e4b\u4e00\u3002Au\u52a9\u50ac\u5316\u5242\u7684\u62c5\u8f7d\u6709\u5229\u4e8e\u4eceBiVO4<\/sub>\u62bd\u53d6\u7535\u5b50\u5411[Fe(CN)6<\/sub>]3<\/sup>\u2012<\/sup>\u8f6c\u79fb\uff0c\u8fdb\u4e00\u6b65\u5229\u7528\u53cc\u52a9\u50ac\u5316\u5242\uff08Au\/CoOx<\/sub>\uff09\u5728BiVO4<\/sub>\u7684{010}\u548c{110}\u6676\u9762\u4e0a\u7684\u9009\u62e9\u6027\u6c89\u79ef\u7b56\u7565\u53d6\u5f97\u4ea7\u6c27\u6027\u80fd\u7684\u5927\u5e45\u63d0\u5347\u3002\u5728\u6b64\u57fa\u7840\u4e0a\u901a\u8fc7\u8026\u5408\u5177\u6709\u8f83\u5bbd\u53ef\u89c1\u5149\u54cd\u5e94\u7684\u4ea7\u6c22\u7aef\uff0c\u5b9e\u73b0\u4e86\u9ad8\u6548\u7684Z\u673a\u5236\u50ac\u5316\u5168\u5206\u89e3\u6c34\uff0c\u5176\u6700\u4f73\u7684AQE\u503c\u4e3a10.3\uff05\uff08420 nm\u6fc0\u53d1\uff09\uff0c\u592a\u9633\u80fd\u5230\u6c22\u80fd\uff08STH\uff09\u7684\u8f6c\u5316\u6548\u7387\u4e3a0.5\uff05\u3002\u5237\u65b0\u4e86\u8be5\u56e2\u961f\u4ee5\u524d\u4fdd\u6301\u76846.8%\uff08420nm\u6fc0\u53d1\uff09\u7684\u8bb0\u5f55\uff0c\u4e5f\u662f\u76ee\u524d\u53ef\u89c1\u5149Z\u673a\u5236\u5168\u5206\u89e3\u6c34\u7c89\u672b\u60ac\u6d6e\u4f53\u7cfb\u7684\u6700\u9ad8\u503c\u3002[Fe(CN)6<\/sub>]3\u2012<\/sup>\/[Fe(CN)6<\/sub>]4\u2012<\/sup>\u7535\u5bf9\u7684\u5e94\u7528\u4e3a\u6784\u5efa\u9ad8\u6548\u7684Z\u673a\u5236\u50ac\u5316\u5168\u5206\u89e3\u6c34\u4f53\u7cfb\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Redox-Based Visible-Light-Driven Z-Scheme Overall Water Splitting with Apparent Quantum Efficiency Exceeding 10%<\/a><\/strong>\uff08Joule, 2018, DOI: 10.1016\/j.joule.2018.07.029\uff09\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1<\/strong>tougao@cailiaoren.com<\/strong>\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/strong>\u3002<\/p>\n

\u6750\u6599\u725b\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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