{"id":153490,"date":"2018-09-14T06:06:37","date_gmt":"2018-09-13T22:06:37","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=153490"},"modified":"2018-09-13T20:07:23","modified_gmt":"2018-09-13T12:07:23","slug":"john-b-goodenough%e5%be%b7%e5%85%8b%e8%90%a8%e6%96%af%e5%a4%a7%e5%ad%a6angew%ef%bc%9a%e5%ae%a4%e6%b8%a9%e6%b6%b2%e4%bd%93na-k%e8%b4%9f%e6%9e%81%e8%86%9c","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=153490","title":{"rendered":"John B. Goodenough\u5fb7\u514b\u8428\u65af\u5927\u5b66Angew\uff1a\u5ba4\u6e29\u6db2\u4f53Na-K\u8d1f\u6781\u819c"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u901a\u5e38\u6db2\u6001Na-K\u5408\u91d1\u5728\u7535\u6c60\u4e2d\u4f5c\u4e3a\u8d1f\u6781\u9700\u8981\u8fc7\u91cf\uff0c\u4f18\u5316\u7684\u8d1f\u8f7d\u548c\u907f\u514d\u5728\u53cd\u5e94\u6027\u6db2\u4f53Na-K\u5408\u91d1\u4e0a\u53d1\u751f\u4efb\u4f55\u53cd\u5e94\u3002\u4e24\u79cd\u4e0d\u6df7\u6eb6\u7684\u6db2\u4f53\u4e4b\u95f4\u5f62\u6210\u7684\u4efb\u4f55\u76f8\u95f4\uff0c\u53ea\u6709\u5728\u5b83\u662f\u56fa\u76f8\u65f6\u624d\u80fd\u662f\u7a33\u5b9a\u3002\u572825\u2103\u4e0b\uff0cNa-K\u5408\u91d1\u662f\u4e00\u79cd\u6210\u5206\u8303\u56f4\u8f83\u5bbd\u7684\u6db2\u4f53\u3002\u867d\u7136\u5728\u78b1\u6027\u79bb\u5b50\u53ef\u5145\u7535\u7535\u6c60\u7684\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u4e2d\uff0c\u6db2\u6001\u5408\u91d1\u662f\u4e0d\u6df7\u6eb6\u7684\uff0c\u4f46\u662f\u5728\u5ba4\u6e29\u4e0b\uff0c\u5b83\u80fd\u591f\u63d0\u4f9b\u5177\u6709\u6db2-\u6db2\u9633\u6781\u7535\u89e3\u8d28\u754c\u9762\u7684\u65e0\u6811\u679d\u72b6\u6db2\u6001\u78b1\u91d1\u5c5e\u7535\u6c60\u3002\u4e24\u79cd\u6db2\u4f53\u5404\u81ea\u56fa\u5b9a\u5728\u591a\u5b54\u57fa\u4f53\u4e2d\u3002\u5728420\u2103\u4e0b\uff0c\u5408\u91d1\u6da6\u6e7f\u7684\u78b3\u7eb8\u5e38\u7528\u4e8e\u56fa\u5b9a\u5408\u91d1\u7684\u591a\u5b54\u57fa\u4f53\uff1b\u5728\u5ba4\u6e29\u4e0b\uff0c\u5408\u91d1\u4fdd\u7559\u5728\u7eb8\u4e2d\u3002\u672c\u6587\u603b\u7ed3\u4e86\u5982\u4f55\u5236\u5907\uff0c\u4f7f\u7528\u548c\u518d\u5faa\u73af\u6db2\u6001Na-K\u8d1f\u6781\u819c\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5ba4\u6e29<\/strong>\u53ef\u5145\u7535\u6db2\u4f53\u78b1\u5408\u91d1\u7535\u6c60\uff0c\u63d0\u4f9b\u6db2\u4f53\u7535\u89e3\u8d28\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821<\/strong>\u7684John B. Goodenough<\/strong>\uff08\u901a\u8baf\uff09<\/strong>\u4f5c\u8005\u7b49\u4eba\uff0c\u53d1\u73b0\u5408\u91d1\u53ef\u4ee5\u5728\u5ba4\u6e29\u548c\u771f\u7a7a\u6761\u4ef6\u4e0b\uff0c\u6db2\u4f53Na-K\u5408\u91d1\u53ef\u4ee5\u6e17\u900f\u5230\u591a\u5b54Cu\u6216Al\u819c\u4e2d\uff1b\u5728\u56fa\u5b9a\u5316\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u4e2d\uff0c\u6db2\u6001\u5408\u91d1\u80fd\u591f\u53d1\u751f\u53ef\u9006\u5730\u5265\u79bb\/\u7535\u9540\uff1b\u53e6\u5916\uff0c\u6db2\u4f53Na-K\u4e0d\u6eb6\u4e8e\u6db2\u4f53\u78b3\u9178\u76d0\u7535\u89e3\u8d28\uff0c\u56e0\u6b64\u6ca1\u6709\u89c2\u5bdf\u5230\u81ea\u8eab\u7535\u8377\u3002\u56e0\u6b64\uff0c\u5728\u5ba4\u6e29\u4e0b\uff0c\u6db2\u6001\u78b1\u91d1\u5c5e\u8d1f\u6781\u53ef\u4ee5\u5b89\u5168\u5730\u8fdb\u884c\u5236\u5907\u548c\u5265\u79bb\/\u7535\u9540\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Room-Temperature Liquid Na-K Anode Membranes<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Angewandte Chemie-International Edition<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 <\/strong>\u5ba4\u6e29\u4e0b\uff0c<\/strong>Na-K<\/strong>\u78b1\u5408\u91d1\u6db2\u5316\u548c\u771f\u7a7a\u6e17\u900f\u56fa\u5b9a\u4e8e\u591a\u5b54\u819c\u7684\u8fc7\u7a0b\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728\u6ca1\u6709\u4efb\u4f55\u5916\u529b\u4e0b\uff0c\u5f53\u91d1\u5c5e\u94a0\u4e0e\u91d1\u5c5e\u94be\u76f8\u9047\u65f6\u81ea\u53d1\u5730\u53d8\u6210\u6db2\u4f53\uff1b<\/p>\n

\uff08b\uff09\u5c06\u591a\u5b54\u819c\u6d78\u5165Na-K\u5408\u91d1\u6db2\u4f53\u4e2d\uff0c\u5728\u8154\u5ba4\u5185\u62bd\u771f\u7a7a\uff0c\u6c29\u6c14\u4ece\u591a\u5b54\u819c\u4e2d\u62bd\u51fa\uff1b<\/p>\n

\uff08c\uff09\u91ca\u653e\u771f\u7a7a\uff0c\u6c29\u6c14\u5c06Na-K\u6db2\u4f53\u63a8\u5165\u591a\u5b54\u819c\u4e2d\u3002<\/p>\n

\u56fe<\/strong> 2 <\/strong>\u591a\u5b54\u94dc<\/strong>\/<\/strong>\u94dd\u819c\u5438\u6536\u6db2\u6001<\/strong>Na-K<\/strong>\u5408\u91d1\u524d\u540e\u7684\u56fe\u50cf<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u591a\u5b54\u94dc\u819c\u5438\u6536\u6db2\u6001Na-K\u5408\u91d1\u4e4b\u524d\u7684\u5149\u5b66\u56fe\u7247\uff1b<\/p>\n

\uff08b\uff09\u591a\u5b54\u94dc\u819c\u5438\u6536\u6db2\u6001Na-K\u5408\u91d1\u4e4b\u540e\u7684\u663e\u5fae\u56fe\u50cf\uff1b<\/p>\n

\uff08a\uff09\u591a\u5b54\u94dd\u819c\u5438\u6536\u6db2\u6001Na-K\u5408\u91d1\u4e4b\u524d\u7684\u5149\u5b66\u56fe\u7247\uff1b<\/p>\n

\uff08b\uff09\u591a\u5b54\u94dd\u819c\u5438\u6536\u6db2\u6001Na-K\u5408\u91d1\u4e4b\u540e\u7684\u663e\u5fae\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong> 3 <\/strong>\u5ba4\u6e29\u4e0b\uff0c\u6db2\u6001<\/strong>Na-K-Cu\/Al<\/strong>\u7535\u6781\u4e0e\u7535\u89e3\u8d28\u6eb6\u5242\u7684\u76f8\u5bb9\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u6db2\u4f53Na-K\u4e0ePC\u6eb6\u5242\u63a5\u89e6\u65f6\u7559\u5728\u591a\u5b54\u94dc\u4e2d\uff1b<\/p>\n

\uff08b\uff09\u6db2\u4f53Na-K\u4e0e\u4e0eDEGDME\u6eb6\u5242\u63a5\u89e6\u65f6\u4f1a\u88ab\u6392\u51fa\uff1b<\/p>\n

\uff08c\uff0cd\uff09\u5728\u591a\u5b54\u94dd\u4e2d\u5438\u6536\u7684\u6db2\u4f53Na-K\u53d1\u751f\u76f8\u540c\u7684\u884c\u4e3a\u3002<\/p>\n

\u56fe<\/strong> 4 <\/strong>\u5ba4\u6e29\u4e0b\uff0c\uff08<\/strong>–<\/strong>\uff09<\/strong>Na-K-Al\/NaClO4<\/sub><\/strong>\u548c<\/strong>PC-FEC\/Na2\/3<\/sub>Ni1\/3<\/sub>Mn2\/3<\/sub>O2<\/sub><\/strong>\uff08<\/strong>+<\/strong>\uff09\u7535\u6c60\u7684\u7535\u538b<\/strong>–<\/strong>\u65f6\u95f4\u66f2\u7ebf\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong> 5 <\/strong>\u5728<\/strong>1 C<\/strong>\u4e0b\uff0c<\/strong>Na2\/3<\/sub>Ni1\/3<\/sub>Mn2\/3<\/sub>O2<\/sub><\/strong>\u548c<\/strong>K2<\/sub>MnFe<\/strong>\uff08<\/strong>CN<\/strong>\uff09<\/strong>6<\/sub><\/strong>\u6b63\u6781\u7684\u7535\u6c60\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u57281 C\u4e0b\uff0c\u91c7\u75281 M NaClO4<\/sub>\u7535\u89e3\u8d28\u3001Na-K-Al\u8d1f\u6781\u548cNa2\/3<\/sub>Ni1\/3<\/sub>Mn2\/3<\/sub>O2<\/sub>\u6b63\u6781\u7684\u7535\u6c60\u7684\u5145\u7535\/\u653e\u7535\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08b\uff09\u57281 C\u4e0b\uff0c\u91c7\u75281 M NaClO4<\/sub>\u7535\u89e3\u8d28\u3001Na-K-Al\u8d1f\u6781\u548cNa2\/3<\/sub>Ni1\/3<\/sub>Mn2\/3<\/sub>O2<\/sub>\u6b63\u6781\u7684\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u56fe\uff1b<\/p>\n

\uff08c\uff09\u57281 C\u4e0b\uff0c\u91c7\u75281 M NaClO4<\/sub>\u7535\u89e3\u8d28\u3001Na-K-Al\u8d1f\u6781\u548cK2<\/sub>MnFe(CN)6<\/sub>\u6b63\u6781\u7684\u7535\u6c60\u7684\u5145\u7535\/\u653e\u7535\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08d\uff09\u57281 C\u4e0b\uff0c\u91c7\u75281 M NaClO4<\/sub>\u7535\u89e3\u8d28\u3001Na-K-Al\u8d1f\u6781\u548cK2<\/sub>MnFe(CN)6<\/sub>\u6b63\u6781\u7684\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u56fe\u3002<\/p>\n

\u56fe<\/strong> 6 <\/strong>\u5728\u5ba4\u6e29\u4e0b\uff0c\u6db2\u6001<\/strong>Na-K<\/strong>\u5408\u91d1\u7535\u6c60\u8d1f\u6781\u7684\u5236\u5907\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u5728\u5ba4\u6e29\u4e0b\uff0c\u6db2\u6001Na-K\u5408\u91d1\u6e17\u900f\u5230\u591a\u5b54\u819c\u4e2d\uff0c\u7528\u4f5c\u65e0\u6811\u679d\u72b6\u7684\u94a0\uff08\u6216\u94be\uff09\u8d1f\u6781\u3002\u771f\u7a7a\u6e17\u900f\u6280\u672f\u9002\u7528\u4e8e\u8bb8\u591a\u591a\u5b54\u819c\uff0c\u5305\u62ec\u78b3\uff0c\u954d\uff0c\u94dc\u548c\u94dd\u3002\u572825\u2103\u4e0b\uff0c\u6db2-\u8d1f\u6781\u819c\u53ef\u4ee5\u4e0e\u53ef\u63a5\u53d7\u7684\u9633\u79bb\u5b50\u7684\u6709\u673a\u78b3\u9178\u76d0\u7535\u89e3\u8d28\u4e00\u8d77\u4f7f\u7528\u3002\u76f8\u5bf9\u6765\u8bb2\uff0cNa-K\u5728\u919a\u4e2d\uff0c\u5177\u6709\u7684\u8f7b\u5fae\u6eb6\u89e3\u6027\uff0c\u4e0e\u6709\u673a\u919a\u7535\u89e3\u8d28\u4e0d\u76f8\u5bb9\u3002\u672c\u6587\u603b\u7ed3\u4e86\u5982\u4f55\u5236\u5907\uff0c\u4f7f\u7528\u548c\u518d\u5faa\u73af\u6db2\u6001Na-K\u8d1f\u6781\u819c\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5ba4\u6e29\u53ef\u5145\u7535\u6db2\u4f53\u78b1\u5408\u91d1\u7535\u6c60\uff0c\u63d0\u4f9b\u6db2\u4f53\u7535\u89e3\u8d28\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Room-Temperature Liquid Na-K Anode Membranes<\/a><\/strong>\uff08Angew, 2018, DOI: 10.1002\/anie.201809622\uff09\u3002<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u91d1\u5c5e\u7f16\u8f91\u90e8\u5f20\u91d1\u6d0b\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>cailiaokefu<\/strong>\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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