{"id":15398,"date":"2016-05-25T08:00:11","date_gmt":"2016-05-25T00:00:11","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=15398"},"modified":"2016-05-25T10:02:49","modified_gmt":"2016-05-25T02:02:49","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e4%b9%85%e7%ad%89%e4%ba%86%ef%bc%8c%e8%bf%99%e6%98%af%e4%bd%a0%e4%bb%ac%e7%9a%84%e7%ba%b3%e7%b1%b3%e6%99%b6%e7%94%9f%e9%95%bf%e6%9c%ba%e5%88%b6%e6%80%bb%e7%bb%93","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=15398","title":{"rendered":"\u5b66\u672f\u5e72\u8d27 | \u4e45\u7b49\u4e86\uff0c\u8fd9\u662f\u4f60\u4eec\u7684\u7eb3\u7c73\u6676\u751f\u957f\u673a\u5236\u603b\u7ed3"},"content":{"rendered":"

\u5bf9\u4e8e\u5f62\u8c8c\u53ca\u5c3a\u5bf8\u53ef\u63a7\u7684\u7eb3\u7c73\u6676\u4f53\u5408\u6210\uff0c\u662f\u7eb3\u7c73\u6750\u6599\u7814\u7a76\u70ed\u95e8\u9886\u57df\u3002\u5728\u5408\u6210\u4e2d\uff0c\u5bf9\u7eb3\u7c73\u6676\u5f62\u8c8c\u8c03\u63a7\u53ca\u5176\u529f\u80fd\u5316\u662f\u5176\u5b9e\u73b0\u5e94\u7528\u7684\u5173\u952e\u6240\u5728\u3002\u7814\u7a76\u8005\u4eec\u5e0c\u671b\u80fd\u5b9e\u73b0\u5bf9\u7eb3\u7c73\u6676\u751f\u957f\u8fc7\u7a0b\u7684\u63a7\u5236\u5e76\u5728\u9884\u671f\u9636\u6bb5\u505c\u6b62,\u4ece\u800c\u5f97\u5230\u53ef\u63a7\u5c3a\u5bf8\u3001\u5f62\u6001\u3001\u7ed3\u6784\u548c\u7ec4\u6210\u786e\u5b9a\u7684\u7eb3\u7c73\u6676\u3002<\/p>\n

\u7eb3\u7c73\u6676\u4e3b\u8981\u5305\u62ec\u91d1\u5c5e\u7eb3\u7c73\u6676\u3001\u6c27\u5316\u7269\u7eb3\u7c73\u6676\u548c\u91cf\u5b50\u70b9\uff0c\u91cf\u5b50\u70b9\u662f\u5c3a\u5bf8\u5c0f\u4e8e10nm\u7684\u534a\u5bfc\u4f53\u7eb3\u7c73\u6676\u3002\u7ecf\u5178\u7684\u5f62\u6838\u957f\u5927\u7406\u8bba\u8ba4\u4e3a\uff0c\u7eb3\u7c73\u9897\u7c92\u7684\u751f\u957f\u4e3b\u8981\u6709\u4e24\u79cd\u673a\u5236\uff1a\u8868\u9762\u53cd\u5e94\u673a\u5236\u548c\u5355\u4f53\u6269\u6563\u673a\u5236\u3002\u76ee\u524d\u6587\u732e\u4ecb\u7ecd\u7684\u5173\u4e8e\u7eb3\u7c73\u6676\u751f\u957f\u673a\u7406\u4e3b\u8981\u6709LaMer\u7406\u8bba\u3001Ostwald\u719f\u5316\u4e0eDigestive\u719f\u5316\u3001Finke-Watzky\u673a\u5236\u3001Orientated Attachment\u548cIntraparticle Growth\u3002\u4e0b\u9762\u6211\u5c06\u4e3a\u5927\u5bb6\u4e00\u4e00\u7684\u4ecb\u7ecd\u8fd9\u4e9b\u673a\u7406\uff0c\u5e0c\u671b\u5bf9\u4e8e\u5404\u4f4d\u6750\u6599\u4eba\u5728\u79d1\u7814\u8fc7\u7a0b\u4e2d\u6709\u6240\u5e2e\u52a9\u3002<\/p>\n

\u4e00\u3001LaMer \u673a\u7406<\/strong><\/p>\n

LaMer\u7406\u8bba\u4e3b\u8981\u662f\u5f62\u6838\u7406\u8bba\uff0c\u9996\u5148\u5c06\u5f62\u6838\u4e0e\u751f\u957f\u8fdb\u884c\u6982\u5ff5\u6027\u5730\u5206\u79bb\uff0c\u8ba4\u4e3a\u5f62\u6838\u751f\u957f\u8fc7\u7a0b\u53ef\u5206\u4e3a\u4e09\u4e2a\u9636\u6bb5\uff1a(\u2160)\u5355\u4f53\u6d53\u5ea6\u9010\u6e10\u589e\u52a0\u81f3\u9971\u548c\u72b6\u6001\uff0c\u8fc7\u7a0b\u4e2d\u6ca1\u6709\u7eb3\u7c73\u9897\u7c92\u751f\u6210\uff1b\uff08\u2161\uff09\u5355\u4f53\u6d53\u5ea6\u8fc7\u9971\u548c\uff0c\u8fbe\u5230\u4e00\u5b9a\u7a0b\u5ea6\u540e\u5f00\u59cb\u5927\u91cf\u6210\u6838\uff0c\u6b64\u65f6\u5355\u4f53\u6d53\u5ea6\u6025\u5267\u964d\u4f4e\uff0c\u6210\u6838\u7ec8\u6b62\uff1b\uff08\u2162\uff09\u4ee5\u6838\u4e3a\u4e2d\u5fc3\u5e76\u901a\u8fc7\u5355\u4f53\u6269\u6563\u957f\u5927\uff1bLaMer\u7406\u8bba\u751f\u957f\u673a\u5236\u793a\u610f\u56fe\u5982\u4e0b\u56fe\u6240\u793a\u3002<\/p>\n

\"QQ\u56fe\u724720160524160354\"<\/p>\n

\u4e8c\u3001Ostwald\u719f\u5316\u673a\u5236\u548cDigestive\u719f\u5316<\/strong><\/p>\n

Ostwald\u719f\u5316\u673a\u5236\u7684\u57fa\u672c\u4f9d\u636e\u662fGibbs-Thompson\u7406\u8bba<\/p>\n

\"QQ\u56fe\u724720160524161347\"<\/p>\n

\u7531\u4e8e\u6bdb\u7ec6\u7ba1\u6548\u5e94\uff0c\u5c0f\u5c3a\u5bf8\u7c92\u5b50\u5468\u56f4\u7684\u6bcd\u76f8\u6d53\u5ea6\u9ad8\u4e8e\u5927\u5c3a\u5bf8\u7c92\u5b50\u5468\u56f4\u7684\u6bcd\u76f8\u6d53\u5ea6\uff0c\u4e24\u8005\u95f4\u7684\u6d53\u5ea6\u68af\u5ea6\u9020\u6210\u7ec4\u5143\u5411\u4f4e\u6d53\u5ea6\u533a\u6269\u6563\uff0c\u4ece\u800c\u4e3a\u5927\u9897\u7c92\u7ee7\u7eed\u5438\u6536\u8fc7\u9971\u548c\u7ec4\u5143\u800c\u7ee7\u7eed\u957f\u5927\u63d0\u4f9b\u6240\u9700\u8981\u7684\u7ec4\u5143\u6210\u5206\uff0c\u8fd9\u8fc7\u7a0b\u5c31\u81f4\u4f7f\u5c0f\u9897\u7c92\u4f18\u5148\u6eb6\u89e3\u5e76\u5728\u5927\u9897\u7c92\u8868\u9762\u6790\u51fa\uff0c\u4ece\u800c\u5927\u9897\u7c92\u8d8b\u4e8e\u957f\u5927\uff0c\u8fd9\u4e00\u8fc7\u7a0b\u53ef\u4ee5\u770b\u4f5cOswald\u957f\u5927\u673a\u5236\uff0c\u751f\u957f\u793a\u610f\u56fe\u5982\u4e0b\u56fe\u6240\u793a\u3002\u800cDigestive\u719f\u5316\u6b63\u597d\u4e0eOstwald\u719f\u5316\u76f8\u53cd\uff0c\u5c0f\u5c3a\u5bf8\u7c92\u5b50\u957f\u5927\u800c\u5927\u5c3a\u5bf8\u7c92\u5b50\u53d1\u751f\u6eb6\u89e3\uff0c\u8fd9\u662f\u7531\u4e8e\u7c92\u5b50\u7684\u957f\u5927\u53d7\u8868\u9762\u80fd\u63a7\u5236\u3002<\/p>\n

\"QQ\u56fe\u724720160524160703\"<\/p>\n

\u4e09\u3001Finke-Watzky\u4e24\u6b65\u673a\u5236<\/strong><\/p>\n

Finke-Watzky\u4e24\u6b65\u673a\u5236\u8ba4\u4e3a\u5f62\u6838\u548c\u957f\u5927\u4e24\u4e2a\u8fc7\u7a0b\u662f\u540c\u65f6\u8fdb\u884c\u7684\u3002\u7b2c\u4e00\u9636\u6bb5\u662f\u4e00\u4e2a\u6bd4\u8f83\u7f13\u6162\u7684\u8fde\u7eed\u5f62\u6838\u8fc7\u7a0b\uff0c\u5373\uff1aA\u2192B\uff1b\u7b2c\u4e8c\u9636\u6bb5\u662f\u4e0d\u53d7\u6269\u6563\u63a7\u5236\u7684\u81ea\u50ac\u5316\u957f\u5927\u8fc7\u7a0b\uff0c\u5373A+B\u21922B\uff0c\u5176\u4e2dA\u8868\u793a\u5355\u4f53\uff0cB\u8868\u793a\u4e8c\u805a\u4f53\u3002\u8fd9\u4e00\u8fc7\u7a0b\u662f\u5728\u7814\u7a76\u7528\u73af\u5df1\u70ef\u8fd8\u539f\u8fc7\u6e21\u91d1\u5c5e\u76d0\u7684\u8fc7\u7a0b\u4e2d\u53d1\u73b0\u7684\u3002\u76ee\u524d\uff0c\u8fd9\u4e00\u65b9\u6cd5\u80fd\u5f88\u597d\u5730\u89e3\u91ca\u73af\u5df1\u70ef\u8fd8\u539f\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\u3002\u4e0e\u7ecf\u5178\u5f62\u6838\u7406\u8bba\u4e00\u6837\uff0c\u5f62\u6838\u8fc7\u7a0b\u4e2d\u4e5f\u5b58\u5728\u4e34\u754c\u5f62\u6838\u5c3a\u5bf8\u3002\u8be5\u7406\u8bba\u80fd\u5f88\u597d\u5730\u9002\u7528\u4e8e\u94f1\u3001\u94c2\u3001\u948c\u548c\u94d1\u7b49\u7eb3\u7c73\u6676\u7684\u751f\u957f\u8fc7\u7a0b\u3002<\/p>\n

\u56db\u3001\u5b9a\u5411\u8fde\u63a5\u673a\u5236\u548c\u805a\u5408\u673a\u5236<\/strong><\/p>\n

\u5b9a\u5411\u8fde\u63a5\u751f\u957f\u673a\u5236\uff08Orientated Attachment\uff09\u6700\u65e9\u662f\u7531Penn\u548cBanfield\u4e24\u4eba\u5408\u4f5c\u63d0\u51fa\u6765\u7684\u3002\u4ed6\u4eec\u5728\u7814\u7a76\u6c34\u70ed\u5408\u6210TiO2\u7eb3\u7c73\u6676\u7684\u65f6\u5019\uff0c\u53d1\u73b0TiO2\u7eb3\u7c73\u6676\u53ef\u4ee5\u5f62\u6210\u4e00\u7ef4\u94fe\u72b6\u7ed3\u6784\uff0c\u800c\u4e14\u8fd9\u4e2a\u7ed3\u6784\u662f\u7531\u4e00\u4e9b\u7eb3\u7c73\u5fae\u6676\u7ec4\u6210\u7684\uff0c\u4ed6\u4eec\u5229\u7528\u9ad8\u5206\u8fa8\u7535\u955c\u7814\u7a76\u53d1\u73b0\uff0c\u8fd9\u4e9b\u7eb3\u7c73\u5fae\u6676\u7684\u6676\u4f53\u53d6\u5411\u662f\u5b8c\u5168\u4e00\u81f4\u7684\uff0c\u6240\u4ee5\u4ed6\u4eec\u63d0\u51fa\u4e86\u5b9a\u5411\u751f\u957f\u7684\u6982\u5ff5\uff0c\u4e5f\u5c31\u662f\u8bf4\u7eb3\u7c73\u9897\u7c92\u95f4\u53ef\u4ee5\u901a\u8fc7\u5171\u7528\u4e00\u4e2a\u6676\u9762\u800c\u8fde\u63a5\u5f62\u6210\u66f4\u5927\u7684\u9897\u7c92\u3002\u5176\u5b9e\u8fd9\u79cd\u7c7b\u4f3c\u7684\u73b0\u8c61\u5728\u5f88\u65e9\u4ee5\u524d\u5c31\u88ab\u53d1\u73b0\u8fc7\uff0c\u6bd4\u5982Averback\u7b49\u4eba\u5728\u505a\u94dc\u7247\u4e0a\u6c89\u79efAg\u7684\u65f6\u5019\u5c31\u53d1\u73b0\u4e86\u7c7b\u4f3c\u7684\u73b0\u8c61\uff0c\u4e0d\u8fc7\u4ed6\u4eec\u628a\u5b83\u79f0\u4f5c\u201c\u63a5\u89e6\u5916\u5ef6\u751f\u957f\uff08contact epitaxy\uff09\u201d\u3002\u56e2\u805a\u673a\u5236\uff08Coalescence\uff09\u4e0e\u5b9a\u5411\u8fde\u63a5\u751f\u957f\uff08Orientated Attachment\uff09\u7684\u5341\u5206\u76f8\u4f3c\uff0c\u533a\u522b\u5728\u4e8e\u56e2\u805a\u673a\u5236\u4e2d\u7eb3\u7c73\u5fae\u6676\u7684\u53d6\u5411\u5e76\u4e0d\u4e00\u81f4\uff0c\u5b83\u662f\u7531\u591a\u4e2a\u53d6\u5411\u4e0d\u4e00\u81f4\u7684\u7eb3\u7c73\u56e2\u5fae\u6676\u76f4\u63a5\u8fde\u63a5\u800c\u6210\u7684\u3002<\/p>\n

\"QQ\u56fe\u724720160524164645\"<\/p>\n

(a)\u94c2\u7eb3\u7c73\u5fae\u6676\u7ecf\u56e2\u805a\u673a\u5236\u5f62\u6210\u7684\u94c2\u7eb3\u7c73\u7ebf (b)\u75314\u4e2a\u5c0f\u7684\u949b\u7eb3\u7c73\u5fae\u6676\u901a\u8fc7\u53d6\u5411\u751f\u957f\u673a\u5236\u5f62\u6210\u4e00\u4e2a\u5927\u5c3a\u5bf8\u7684\u949b\u7eb3\u7c73\u6676<\/p>\n

\u4e94\u3001\u7c92\u5b50\u5185\u751f\u957f\u673a\u5236<\/strong><\/p>\n

\u7c92\u5b50\u5185\u751f\u957f\u673a\u5236\uff08Intraparticle Growth\uff09\u662f\u7531Peng\u7b49\u4eba\u63d0\u51fa\u6765\u7684\uff0c\u8be5\u673a\u5236\u8ba4\u4e3a\u5355\u4f53\u6cbf\u7740\u8868\u9762\u6269\u6563\u5c06\u6539\u53d8\u9897\u7c92\u7684\u5f62\u72b6\u3002\u5f53\u5355\u4f53\u5728\u6eb6\u6db2\u4e2d\u7684\u80fd\u91cf\u4f4e\u4e8e\u7eb3\u7c73\u7c92\u5b50\u67d0\u4e00\u6676\u9762\uff0c\u6b64\u65f6\u4e0d\u5b58\u5728\u51c0\u6269\u6563\uff0c\u56e0\u800c\u6ca1\u6709\u591a\u4f59\u7684\u5355\u4f53\u6d41\u5411\u7c92\u5b50\u8868\u9762\u3002\u7531\u4e8e\u4e0d\u540c\u6676\u9762\u7684\u8868\u9762\u80fd\u4e0d\u540c\uff0c\u9ad8\u80fd\u91cf\u6676\u9762\u5c06\u4f1a\u53d1\u751f\u6eb6\u89e3\uff0c\u4f4e\u80fd\u91cf\u6676\u9762\u5c06\u4f1a\u957f\u5927\u3002<\/p>\n

\u6b64\u5916\uff0c\u5bf9\u4e8e\u751f\u957f\u8fc7\u7a0b\u7684\u63cf\u8ff0\uff0c\u8fd8\u6709\u4e00\u7c7b\u975e\u5e38\u8457\u540d\u7684\u7406\u8bba\u201cAggregative Growth\u7406\u8bba\u201d\u3002\u8be5\u7406\u8bba\u6307\u51fa\u7eb3\u7c73\u9897\u7c92\u4e4b\u95f4\u53ef\u4ee5\u901a\u8fc7\u76f4\u63a5\u878d\u5408\u7684\u65b9\u5f0f\u5f62\u6210\u5927\u7c92\u5b50\u3002Aggregative Growth\u7406\u8bba\u751f\u957f\u673a\u5236\u793a\u610f\u56fe\u5982\u4e0b\u56fe\u6240\u793a\u3002<\/p>\n

\"QQ\u56fe\u724720160524161248\"<\/p>\n

\u603b\u7ed3\uff1a<\/strong><\/p>\n

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