{"id":154212,"date":"2018-09-27T08:00:33","date_gmt":"2018-09-27T00:00:33","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=154212"},"modified":"2018-09-26T22:01:56","modified_gmt":"2018-09-26T14:01:56","slug":"%e8%8b%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6%e9%a9%ac%e4%b8%87%e9%87%8cjoule-%e8%81%9a%e5%90%88%e7%89%a9%e7%a9%ba%e7%a9%b4%e4%bc%a0%e8%be%93%e6%9d%90%e6%96%99%e7%94%a8%e4%ba%8e%e8%b6%85%e4%bd%8e%e8%83%bd","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=154212","title":{"rendered":"\u82cf\u5dde\u5927\u5b66\u9a6c\u4e07\u91ccJoule: \u805a\u5408\u7269\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\u7528\u4e8e\u8d85\u4f4e\u80fd\u91cf\u635f\u5931\u7684\u03b1-CsPbI3\u9499\u949b\u77ff\u7eb3\u7c73\u6676\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n

\u7531\u4e8e\u79d1\u5b66\u5bb6\u5728\u9ad8\u6548\u6709\u673a-\u65e0\u673a\u5364\u5316\u7269\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5f00\u53d1\u4e2d\u7684\u52aa\u529b\uff0c\u8fd9\u4e2a\u9886\u57df\u5f97\u5230\u4e86\u5feb\u901f\u7684\u53d1\u5c55\u3002\u51ed\u501f\u5176\u8f83\u9ad8\u7684\u5438\u5149\u7cfb\u6570\u3001\u8f83\u4f4e\u7684\u6fc0\u5b50\u7ed3\u5408\u80fd\u548c\u957f\u7535\u8377\u8f7d\u4f53\u6269\u6563\u957f\u5ea6\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5728\u8fc7\u53bb\u7684\u516b\u5e74\u4e2d\u4ee5\u524d\u6240\u672a\u6709\u7684\u901f\u5ea6\u53d1\u5c55\uff0c\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u53ef\u8fbe23%\u3002<\/p>\n

\u9650\u5236\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5546\u4e1a\u5316\u8fdb\u7a0b\u7684\u91cd\u8981\u539f\u56e0\u662f\u5176\u5728\u73af\u5883\u4e2d\u7684\u4e0d\u7a33\u5b9a\u6027\uff0c\u6bd4\u5982MAPbI3<\/sub>\u53ef\u5728\u6c34\u4efd\u7684\u5b58\u5728\u4e0b\u5206\u89e3\u6210PbI2<\/sub>\u548cCH3<\/sub>NHI3<\/sub>\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u7814\u7a76\u76ee\u5149\u96c6\u4e2d\u5728\u66f4\u7a33\u5b9a\u7684\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e0a\uff0c\u6bd4\u5982CsPbI3<\/sub>\u3002\u7acb\u65b9CsPbI3<\/sub>\u7684\u76f8\u8f6c\u5316\u6e29\u5ea6\u9ad8\u8fbe350\u2103\uff0c\u5f53\u653e\u7f6e\u5728\u5916\u754c\u73af\u5883\u4e2d\u65f6\uff0c\u5176\u4f1a\u8f6c\u5316\u4e3a\u6b63\u4ea4\u6676\u76f8\u3002\u8bb8\u591a\u79cd\u65b9\u6cd5\u88ab\u5f00\u53d1\u7528\u4e8e\u7a33\u5b9a\u7acb\u65b9\u6676\u578b\uff0c\u7136\u800c\u8fd9\u4e9b\u65b9\u6cd5\u5728\u6eb6\u6db2-\u8584\u819c\u7684\u7ed3\u6676\u8fc7\u7a0b\u4e2d\u9700\u8981\u7cbe\u786e\u63a7\u5236\u3002\u8fd1\u6765\uff0c\u9499\u949b\u77ff\u91cf\u5b50\u70b9\u592a\u9633\u80fd\u7535\u6c60\u5728\u89e3\u51b3\u7a33\u5b9a\u7684\u95ee\u9898\u4e0a\u5438\u5f15\u4e86\u5e7f\u5927\u7684\u6ce8\u610f\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u82cf\u5dde\u5927\u5b66<\/b><\/strong>\u9a6c\u4e07\u91cc<\/b><\/strong>\u6559\u6388\u56e2\u961f\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u5f20\u6865\u6559\u6388\u5408\u4f5c(\u901a\u8baf\u4f5c\u8005)<\/b><\/strong>\u62a5\u5bfc\u4e86\u4e00\u79cd\u53ef\u8fdb\u884c\u4f4e\u6e29\u6eb6\u6db2\u52a0\u5de5\u7684\u3001\u5728\u5927\u6c14\u73af\u5883\u4e2d\u5236\u5907\u7684\u5168\u65e0\u673a\u9499\u949b\u77ff\u7eb3\u7c73\u6676\u4f53\u592a\u9633\u80fd\u7535\u6c60\u3002CsPbI3<\/sub>\u9499\u949b\u77ff\u91cf\u5b50\u70b9\u592a\u9633\u80fd\u7535\u6c60\u62e5\u6709\u63a5\u8fd113%\u7684\u6548\u7387\uff0c\u5728\u65e0\u63ba\u6742\u7684\u805a\u5408\u7269\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\u4f7f\u7528\u4e2d\uff0c\u5177\u6709\u6781\u4f4e\u7684\u80fd\u91cf\u635f\u5931\u3002\u8fd9\u79cdCsPbI3<\/sub>\u91cf\u5b50\u70b9\u592a\u9633\u80fd\u7535\u6c60\u5229\u7528\u805a\u5408\u7269\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\uff0c\u5728\u805a\u5408\u7269\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\u548c\u91cf\u5b50\u70b9\u754c\u9762\u53ef\u83b7\u5f97\u6709\u6548\u7684\u7535\u8377\u5206\u79bb\uff0c\u4ee5\u53ca\u6709\u6548\u5730\u907f\u514d\u5668\u4ef6\u4e0d\u7a33\u5b9a\u3002\u8fd9\u4e2a\u5de5\u4f5c\u5bf9\u672a\u6765\u9499\u949b\u77ff\u91cf\u5b50\u70b9\u5728\u592a\u9633\u80fd\u7535\u6c60\u4e0a\u7684\u5e94\u7528\u4f1a\u6709\u5f88\u5927\u7684\u5e2e\u52a9\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Band-Aligned Polymeric Hole Transport Materials for Extremely Low Energy Loss <\/b><\/strong>\u03b1<\/b><\/strong>-CsPbI3 Perovskite Nanocrystal Solar Cells<\/b><\/strong>“\u53d1\u8868\u5728Joule<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

Figure <\/b><\/strong>1<\/b><\/strong>.<\/b><\/strong>\u6750\u6599\u548c\u91cf\u5b50\u70b9\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a).\u5668\u4ef6\u7ed3\u6784\u548c\u622a\u9762SEM\u56fe<\/p>\n

(b).\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\u5316\u5b66\u7ed3\u6784<\/p>\n

(c).MeOAc\u5904\u7406\u8fc7\u7684CsPbI3<\/sub>\u91cf\u5b50\u70b9\u548c\u5171\u8f6d\u805a\u5408\u7269\u80fd\u7ea7<\/p>\n

Figure <\/b><\/strong>2<\/b><\/strong>.<\/b><\/strong>CsPbI<\/b><\/strong>3<\/b><\/sub><\/strong>\u91cf\u5b50\u70b9\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>3<\/b><\/strong>.<\/b><\/strong>CsPbI<\/b><\/strong>3<\/b><\/sub><\/strong>\u91cf\u5b50\u70b9\u6676\u4f53\u548c\u7ec4\u4efd\u4fe1\u606f<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a).CsPbI3<\/sub>\u91cf\u5b50\u70b9\u8584\u819c\u76842D GIWAXS\u56fe\u6848<\/p>\n

(b).\u7528\u9971\u548cPb(NO3<\/sub>)2<\/sub>\uff0cMeOAc\u6eb6\u6db2\u5904\u7406\u8fc7\u7684CsPbI3<\/sub>\u91cf\u5b50\u70b9\u8584\u819c\u76842D GIWAXS\u56fe\u6848<\/p>\n

(c).2D GIWAXS\u7684\u5782\u76f4\u65b9\u5411\u4e00\u7ef4\u79ef\u5206\u66f2\u7ebf<\/p>\n

(d).CsPbI3<\/sub>\u91cf\u5b50\u70b9\u8584\u819c\u548c\u5904\u7406\u8fc7\u540e\u7684CsPbI3<\/sub>\u91cf\u5b50\u70b9\u8584\u819c\u7684Cs\u548cPb XPS\u56fe<\/p>\n

\u56fe<\/b><\/strong>4<\/b><\/strong>.<\/b><\/strong>\u00a0CsPbI<\/b><\/strong>3<\/b><\/sub><\/strong>\u91cf\u5b50\u70b9\u8584\u819c\u7684\u65f6\u95f4\u5206\u8fa8\u6fc0\u5149\u5171\u805a\u7126\u6210\u50cf<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a).CsPbI3<\/sub>\u91cf\u5b50\u70b9\u8584\u819c\uff0c\u548c\u9876\u90e8\u6709spiro-OMeTAD\u3001P3HT\u3001PTB7\u7684CsPbI3<\/sub>\u91cf\u5b50\u70b9\u8584\u819c\u7684\u5149\u81f4\u53d1\u5149\u7ed3\u679c<\/p>\n

(b).CsPbI3<\/sub>\u91cf\u5b50\u70b9\u8584\u819c\uff0c\u548c\u9876\u90e8\u6709spiro-OMeTAD\u3001P3HT\u3001PTB7\u7684CsPbI3<\/sub>\u91cf\u5b50\u70b9\u8584\u819c\u7684\u5bff\u547d\u6210\u50cf<\/p>\n

(c).\u6bcf\u4e00\u79cd\u6837\u54c1\u4e8c\u7ef4\u5bff\u547d\u6210\u50cf\u7684\u76f4\u65b9\u56fe<\/p>\n

(d).\u4e8c\u7ef4\u8584\u819c\u77e2\u91cf\u56fe<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>.<\/b><\/strong>\u5668\u4ef6\u6548\u7387<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a).\u6587\u732e\u62a5\u9053\u7684\u5168\u65e0\u673a\u9499\u949b\u77ff\u7535\u6c60PCE\u548c\u9499\u949b\u77ff\u6d3b\u6027\u5c42\u5236\u5907\u6e29\u5ea6\u53d8\u5316<\/p>\n

(b). \u6587\u732e\u62a5\u9053\u7684\u5168\u65e0\u673a\u9499\u949b\u77ff\u7535\u6c60eVoc<\/sub>\u968f\u9499\u949b\u77ff\u6d3b\u6027\u5c42Eg<\/sub>\u7684\u53d8\u5316<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u5728\u5ba4\u6e29\u5927\u6c14\u6761\u4ef6\u4e0b\u5236\u5907\u4e86\u53ef\u6eb6\u6db2\u52a0\u5de5\u7684FTO\/TiO2<\/sub>\/CsPbI3<\/sub>\u91cf\u5b50\u70b9\/HTM\/MoO3<\/sub>\/Ag\u592a\u9633\u80fd\u7535\u6c60\u3002\u5229\u7528\u4f20\u7edf\u7684\u5171\u8f6d\u805a\u5408\u7269\u4f5c\u4e3a\u7a7a\u7a74\u4f20\u8f93\u5c42\uff0c\u5728\u65e0\u9700\u8fdb\u884c\u63ba\u6742\u7684\u6761\u4ef6\u4e0b\uff0c\u57fa\u4e8e\u9499\u949b\u77ff\u91cf\u5b50\u70b9\u592a\u9633\u80fd\u7535\u6c60\u5177\u6709\u8f83\u9ad8\u7684\u5668\u4ef6\u6548\u7387\u548c\u6781\u4f4e\u7684\u80fd\u91cf\u635f\u5931\u3002\u8fd9\u4e2a\u5de5\u4f5c\u4f1a\u4e3a\u672a\u6765\u9499\u949b\u77ff\u91cf\u5b50\u70b9\u5728\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u7ed3\u6784\u8bbe\u8ba1\u548c\u5e94\u7528\u63d0\u4f9b\u91cd\u8981\u7684\u5b9e\u9a8c\u8def\u5f84\u3002<\/p>\n

Band-Aligned Polymeric Hole Transport Materials for Extremely Low Energy Loss \u03b1-CsPbI3 Perovskite Nanocrystal Solar Cells<\/a><\/p>\n

(Joule, 2018, DOI: 10.1016\/j.joule.2018.08.011)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead\u3002 \u00a0<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7531\u4e8e\u79d1\u5b66\u5bb6\u5728\u9ad8\u6548\u6709\u673a-\u65e0\u673a\u5364\u5316\u7269\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5f00\u53d1\u4e2d\u7684\u52aa\u529b\uff0c\u8fd9\u4e2a\u9886\u57df\u5f97\u5230\u4e86\u5feb\u901f\u7684\u53d1\u5c55\u3002\u51ed\u501f\u5176\u8f83\u9ad8\u7684\u5438\u5149\u7cfb\u6570\u3001\u8f83\u4f4e\u7684\u6fc0\u5b50\u7ed3\u5408\u80fd\u548c\u957f\u7535\u8377\u8f7d\u4f53\u6269\u6563\u957f\u5ea6\uff0c\u9499…<\/p>\n","protected":false},"author":7336,"featured_media":154236,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3583],"class_list":["post-154212","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-3583"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/154212"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7336"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=154212"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/154212\/revisions"}],"predecessor-version":[{"id":154761,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/154212\/revisions\/154761"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/154236"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=154212"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=154212"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=154212"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}