{"id":154545,"date":"2018-09-28T06:30:39","date_gmt":"2018-09-27T22:30:39","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=154545"},"modified":"2018-09-27T20:03:47","modified_gmt":"2018-09-27T12:03:47","slug":"%e5%b7%b2%e6%a0%a1%e7%a8%bf-adv-mater-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e7%94%a8%e4%ba%8e%e8%83%bd%e6%ba%90%e5%82%a8%e5%ad%98%e3%80%81%e8%bd%ac%e6%8d%a2%e5%92%8c%e7%94%9f%e4%ba%a7%e7%9a%84%e4%b8%ad","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=154545","title":{"rendered":"Adv. Mater.\u7efc\u8ff0\uff1a\u7528\u4e8e\u80fd\u6e90\u50a8\u5b58\u3001\u8f6c\u6362\u548c\u751f\u4ea7\u7684\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u8bbe\u8ba1"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784\u5728\u80fd\u6e90\u5b58\u50a8\u3001\u8f6c\u6362\u548c\u751f\u4ea7\u6280\u672f\u65b9\u9762\u5c55\u73b0\u51fa\u4e86\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5728\u8fc7\u53bb\u5341\u5e74\u4e2d\uff0c\u7814\u7a76\u8005\u4eec\u81f4\u529b\u4e8e\u8bbe\u8ba1\u548c\u5408\u6210\u5177\u6709\u4e0d\u540c\u7ec4\u6210\u548c\u51e0\u4f55\u7279\u5f81\u7684\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u3002\u7136\u800c\uff0c\u5b83\u4eec\u7684\u7ed3\u6784\u4e0e\u50a8\u80fd\u6027\u80fd\u4e4b\u95f4\u7684\u76f8\u5173\u6027\u5c1a\u672a\u5728\u6587\u732e\u4e2d\u8fdb\u884c\u6df1\u5165\u5b8c\u6574\u7684\u62a5\u9053\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4e2d\u79d1\u9662\u8fc7\u7a0b\u5de5\u7a0b\u7814\u7a76\u6240\u7684\u738b\u4e39\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u4e0e\u65af\u5766\u798f\u5927\u5b66\u7684\u5d14\u5c79\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7684\u56e2\u961f\u5728Advanced Materials\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cDesign of Hollow Nanostructures for Energy Storage, Conversion and Production\u201d\u7684\u6587\u7ae0\u3002\u6587\u7ae0\u4e2d\u91cd\u70b9\u4ecb\u7ecd\u4e86\u8bbe\u8ba1\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u4ee5\u6709\u6548\u89e3\u51b3\u80fd\u6e90\u76f8\u5173\u6280\u672f\u95ee\u9898\u7684\u4e00\u4e9b\u4ee3\u8868\u6027\u5b9e\u4f8b\uff0c\u5982\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\uff0c\u9502\u786b\u7535\u6c60\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff0c\u7535\u50ac\u5316\uff0c\u4ee5\u53ca\u5149\u7535\u5316\u5b66\u7535\u6c60\u3002\u5e76\u4e14\u6df1\u5165\u8ba8\u8bba\u4e86\u6750\u6599\u7ed3\u6784\u5bf9\u5176\u6027\u80fd\u7684\u5de8\u5927\u5f71\u54cd\u3002\u8fd9\u4e9b\u63a2\u7a76\u80fd\u66f4\u597d\u5730\u6307\u5bfc\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u7684\u8bbe\u8ba1\uff0c\u4ee5\u6ee1\u8db3\u7279\u5b9a\u5e94\u7528\u7684\u8981\u6c42\uff0c\u540c\u65f6\u4e30\u5bcc\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u7cfb\u5217\u7684\u591a\u6837\u6027\u3002\u6700\u540e\uff0c\u6587\u7ae0\u8fd8\u6307\u51fa\u4e86\u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784\u8bbe\u8ba1\u7684\u672a\u6765\u65b9\u5411\uff0c\u4ee5\u89e3\u51b3\u65b0\u51fa\u73b0\u7684\u6311\u6218\u5e76\u8fdb\u4e00\u6b65\u6539\u5584\u80fd\u6e90\u76f8\u5173\u6280\u672f\u7684\u6027\u80fd\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154645\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u5fae\u4fe1\u56fe\u7247_20180926104857.png\" alt=\"\" width=\"600\" height=\"228\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u5fae\u4fe1\u56fe\u7247_20180926104857.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u5fae\u4fe1\u56fe\u7247_20180926104857-300x114.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\u7efc\u8ff0\u5bfc\u89c8\u56fe<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 <\/strong><strong>\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u5e94\u7528\u4e8e\u80fd\u6e90\u5b58\u50a8\u7684\u4f18\u52bf\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154551\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/1-24.png\" alt=\"\" width=\"600\" height=\"562\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/1-24.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/1-24-300x281.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe2 <\/strong><strong>\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u7684\u591a\u6837\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154553\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/2-23.png\" alt=\"\" width=\"600\" height=\"232\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/2-23.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/2-23-300x116.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe3 <\/strong><strong>\u786c\u6a21\u677f\u6cd5\u5236\u5907\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154554\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/3-24.png\" alt=\"\" width=\"600\" height=\"645\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/3-24.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/3-24-279x300.png 279w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09SiMP@Gr\u86cb\u9ec4-\u58f3\u7ed3\u6784\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p>\uff08b\uff09\u7845\u77f3\u69b4\u7ed3\u6784\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p>\uff08c\uff09\u4e2d\u7a7a\u78b3\u7ba1\u5305\u8986\u7845\u7eb3\u7c73\u9897\u7c92\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p>\uff08d\uff09\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u5305\u88f9\u786b\u7ed3\u6784\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p>\uff08e\uff09\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7403\u4fee\u9970Cu\u7535\u6781\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p>\uff08f\uff09\u6c22\u8fd8\u539fTiO<sub>2<\/sub>\u53cd\u86cb\u767d\u77f3\u7ed3\u6784\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p><strong>\u56fe4 <\/strong><strong>\u6b21\u5e8f\u6a21\u677f\u6cd5\u5236\u5907\u591a\u58f3\u5c42\u7a7a\u5fc3\u5fae\u7403<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154555\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/4-21.png\" alt=\"\" width=\"600\" height=\"624\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/4-21.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/4-21-288x300.png 288w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u6b21\u5e8f\u6a21\u677f\u6cd5\u5408\u6210\u91d1\u5c5e\u6c27\u5316\u7269\u591a\u58f3\u5c42\u7a7a\u5fc3\u5fae\u7403\u7684\u793a\u610f\u56fe<\/p>\n<p>\uff08b-m\uff09\u591a\u58f3\u5c42\u7a7a\u5fc3\u5fae\u7403\u900f\u5c04\u7535\u955c\u56fe\u50cf\uff1ab) ZnO\uff0cc) \u0251-Fe<sub>2<\/sub>O<sub>3<\/sub>\uff0cd) Co<sub>3<\/sub>O<sub>4<\/sub>\uff0ce) SnO<sub>2<\/sub>\uff0cf) Mn<sub>2<\/sub>O<sub>3<\/sub>\uff0cg) TiO<sub>2<\/sub>\uff0ch) NiO\uff0ci) MnO<sub>2<\/sub>\uff0cj) V<sub>2<\/sub>O<sub>5<\/sub>\uff0ck) LiMn<sub>2<\/sub>O<sub>4<\/sub>\uff0cl) TiO<sub>2<\/sub>\/Fe<sub>2<\/sub>TiO<sub>5<\/sub>\uff0cand m) (Co<sub>2\/3<\/sub>Mn<sub>1\/3<\/sub>)(Co<sub>5\/6<\/sub>Mn<sub>1\/6<\/sub>)<sub>2<\/sub>O<sub>4<\/sub>\uff0c\u6807\u5c3a\u4e3a200 nm<\/p>\n<p>\uff08n\uff09\u901a\u8fc7\u8c03\u8282\u7145\u70e7\u8fc7\u7a0b\u63a7\u5236\u591a\u58f3\u5c42ZnO\u7a7a\u5fc3\u5fae\u7403\u7684\u58f3\u58c1\u95f4\u9699<\/p>\n<p>\uff08o\uff09\u901a\u8fc7\u8c03\u8282\u5438\u9644\u6761\u4ef6\u63a7\u5236\u591a\u58f3\u5c42Co<sub>3<\/sub>O<sub>4<\/sub>\u7a7a\u5fc3\u5fae\u7403\u7684\u58f3\u5c42\u6570<\/p>\n<p>\uff08p\uff09V<sub>2<\/sub>O<sub>5<\/sub>\u7a7a\u5fc3\u7ed3\u6784\u51e0\u4f55\u53c2\u6570\u7684\u63a7\u5236<\/p>\n<p>\uff08q\uff09\u901a\u8fc7\u8c03\u8282Co\/Mn\u7684\u6469\u5c14\u6bd4\u6765\u63a7\u5236Co<sub>x<\/sub>Mn<sub>y<\/sub>O<sub>z<\/sub>\u7684\u58f3\u5c42\u6570<\/p>\n<p><strong>\u56fe5 <\/strong><strong>\u8f6f\u6a21\u677f\u6cd5\u5236\u5907\u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154556\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/5-14.png\" alt=\"\" width=\"600\" height=\"561\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/5-14.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/5-14-300x281.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u4e2d\u7a7a\u805a\u5408\u7269\u5fae\u7403\uff0c\u7a7a\u5fc3\u78b3\u7403\u5305\u88f9Pt\u7eb3\u7c73\u9897\u7c92\u6216PtCo\u53cc\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\uff08Pt@HCS\uff0cPtCo@HCS\uff09\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p>\uff08b\uff09PtCo@HCS\u7684\u626b\u63cf\uff0c\u626b\u63cf\u900f\u5c04\u7535\u955c\uff0c\u548c\u5143\u7d20\u5206\u5e03\u56fe\u50cf<\/p>\n<p>\uff08c\uff09\u4f7f\u7528\u6eb4\u5316\u5341\u516d\u70f7\u57fa\u4e09\u7532\u94f5\uff08CTAB\uff09\u6a21\u677f\u5f62\u6210Cu<sub>2<\/sub>O\u4e2d\u7a7a\u7ed3\u6784<\/p>\n<p>\uff08d-g\uff09\u5355\u5c42\u3001\u53cc\u5c42\u3001\u4e09\u5c42\u3001\u56db\u5c42\u7684Cu<sub>2<\/sub>O\u4e2d\u7a7a\u7ed3\u6784\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p><strong>\u56fe6 <\/strong><strong>\u901a\u8fc7\u67ef\u80af\u8fbe\u5c14\u6548\u5e94\u5236\u5907\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154557\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/6-13.png\" alt=\"\" width=\"600\" height=\"295\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/6-13.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/6-13-300x148.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p align=\"left\"><span lang=\"EN-US\">\uff08a\uff09 <\/span><span lang=\"EN-US\">Pt<sub>3<\/sub>Ni<\/span>\u4e2d\u7a7a\u7eb3\u7c73\u6846\u67b6\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p align=\"left\">\uff08<span lang=\"EN-US\">b-e<\/span>\uff09\u5728\u56db\u4e2a\u5178\u578b\u9636\u6bb5\u83b7\u5f97\u7684\u6837\u54c1\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf\uff1a<span lang=\"EN-US\">b<\/span>\uff09\u521d\u59cb\u56fa\u4f53<span lang=\"EN-US\">PtNi<sub>3<\/sub><\/span>\u591a\u9762\u4f53\uff0c<span lang=\"EN-US\">c<\/span>\uff09<span lang=\"EN-US\">PtNi<\/span>\u4e2d\u95f4\u4f53\uff0c<span lang=\"EN-US\">d<\/span>\uff09\u4e2d\u7a7a<span lang=\"EN-US\">Pt<sub>3<\/sub>Ni<\/span>\u7eb3\u7c73\u6846\u67b6\uff0c\u548c<span lang=\"EN-US\">e<\/span>\uff09\u9000\u706b\u540e\u7684<span lang=\"EN-US\">Pt<sub>3<\/sub>Ni<\/span>\u7eb3\u7c73\u6846\u67b6<\/p>\n<p><strong>\u56fe7 <\/strong><strong>\u901a\u8fc7Ostwald ripening<\/strong><strong>\u5236\u5907\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154558\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/7-9.png\" alt=\"\" width=\"600\" height=\"322\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/7-9.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/7-9-300x161.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u5236\u5907(Cu<sub>2<\/sub>O@)<sub>n<\/sub>Cu<sub>2<\/sub>O\uff08n = 1-4\uff09\u6838-\u58f3\u548c\u86cb\u9ec4-\u58f3\u7ed3\u6784\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p>\uff08b\uff09\u540c\u5fc3\u56db\u58f3\u5c42\u86cb\u9ec4-\u58f3\u6837\u54c1\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08c\uff09 \u4e09\u58f3\u5c42\u8c46\u835aCu<sub>2<\/sub>O\u4e2d\u7a7a\u7ed3\u6784\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p><strong>\u56fe8 <\/strong><strong>\u901a\u8fc7\u79bb\u5b50\u4ea4\u6362\u6cd5\u5236\u5907\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154559\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/8-6.png\" alt=\"\" width=\"600\" height=\"678\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/8-6.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/8-6-265x300.png 265w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u5f62\u6210NiCo<sub>2<\/sub>S<sub>4<\/sub>\u7a7a\u5fc3\u7403\u7684\u793a\u610f\u56fe\u3002\u9636\u6bb5I\uff0c\u901a\u8fc7\u9634\u79bb\u5b50\u4ea4\u6362\u5728\u8868\u9762\u5f62\u6210NiCo<sub>2<\/sub>S<sub>4<\/sub>\u3002\u9636\u6bb5II\uff0cS<sup>2-<\/sup>\u79bb\u5b50\u7684\u6269\u6563\u548cNiCo<sub>2<\/sub>S<sub>4<\/sub>\u5728\u5185\u90e8NiCo-\u7518\u6cb9\u9178\u916f\u6838\u5fc3\u4e0a\u7684\u5f62\u6210\u3002\u9636\u6bb5\u2162\uff0c\u9634\u79bb\u5b50\u4ea4\u6362\u53cd\u5e94\u5b8c\u6210\u3002\u5176\u4e2d\uff0cM<sup>2+<\/sup>\u662f\u6307\u5305\u62ecNi<sup>2+<\/sup>\u548cCo<sup>2+<\/sup>\u79bb\u5b50\u7684\u91d1\u5c5e\u9633\u79bb\u5b50\u3002<\/p>\n<p>\uff08b\uff09\u5728N<sub>2<\/sub>\u4e2d\u9000\u706b\u540eNiCo<sub>2<\/sub>S<sub>4<\/sub>\u7a7a\u5fc3\u7403\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08c\uff09\u5728N<sub>2<\/sub>\u4e2d\u9000\u706b\u540eNiCo<sub>2<\/sub>S<sub>4<\/sub>\u7a7a\u5fc3\u7403\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p><strong>\u56fe9 <\/strong><strong>\u901a\u8fc7\u9009\u62e9\u6027\u523b\u8680\u5236\u5907\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154560\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/9-6.png\" alt=\"\" width=\"600\" height=\"615\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/9-6.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/9-6-293x300.png 293w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09Au NP@SiO<sub>2<\/sub>\u7684\u86cb\u9ec4-\u58f3\u7ed3\u6784\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p>\uff08b\uff09Au NP@ SiO<sub>2<\/sub>\u572860\u2103\u6c34\u4e2d\u4fdd\u6e2910\u5c0f\u65f6\u540e\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08c\uff09Au NP@ SiO<sub>2<\/sub>\u572860\u2103\u5f02\u4e19\u9187\u4e2d\u4e8e\u4fdd\u6e2910\u5c0f\u65f6\u540e\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08d\uff09Au NP@ SiO<sub>2<\/sub>\u572860\u2103\u5f02\u4e19\u9187\u4e2d\u4e8e\u4fdd\u6e2910\u5c0f\u65f6\u540e\uff0c\u7136\u540e\u88ab\u6807\u51c6\u65b9\u6cd5\u8680\u523b\u540e\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08e\uff09Au NP@ SiO<sub>2<\/sub>\u5305\u8986\u8f6f\u58f3\uff0c\u7136\u540e\u5206\u79bb\uff0c\u518d\u572860\u2103\u5f02\u4e19\u9187\u4e2d\u786c\u531672\u5c0f\u65f6\uff0c\u91cd\u590d\u4e09\u6b21\u8fd9\u4e2a\u8fc7\u7a0b\u540e\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08f\uff09e\u56fe\u4e2d\u7684Au NP@ SiO<sub>2<\/sub>\u901a\u8fc7\u6807\u51c6\u65b9\u6cd5\u8680\u523b\u540e\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p><strong>\u56fe10 <\/strong><strong>\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154561\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/10-3.png\" alt=\"\" width=\"600\" height=\"572\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/10-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/10-3-300x286.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09Co<sub>3<\/sub>O<sub>4<\/sub>\u4e2d\u7a7a\u5fae\u7403\u4e0e\u5546\u4e1a\u7eb3\u7c73\u7c92\u5b50\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u8bd5\u9a8c<\/p>\n<p>\uff08b\uff09\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0bCo<sub>3<\/sub>O<sub>4<\/sub>\u4e09\u58f3\u5c42\u4e2d\u7a7a\u5fae\u7403\u548c\u5546\u4e1a\u7eb3\u7c73\u9897\u7c92\u7684\u653e\u7535\u5bb9\u91cf<\/p>\n<p>\uff08c\uff09Li<sup>+<\/sup>\u5d4c\u5165\/\u8403\u53d6\u8fc7\u7a0b\u4e2dCo<sub>3<\/sub>O<sub>4<\/sub>\u7ed3\u6784\u53d8\u5316\u7684\u793a\u610f\u56fe<\/p>\n<p>\uff08d-i\uff09TiO<sub>2<\/sub>\u7a7a\u5fc3\u5fae\u7403\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf\uff1ad\uff09\u5355\u5c42\uff0ce\uff09\u53cc\u5c42\uff0cf\uff09\u4e09\u5c42\uff0c\u548c\u6700\u5916\u4e24\u58f3\u5c42\u76f8\u8ddd\u8f83\u8fd1\u7684g\uff09\u53cc\u5c42\uff0ch\uff09\u4e09\u5c42\uff0c\u548ci\uff09\u56db\u5c42\u7a7a\u5fc3\u7403<\/p>\n<p>\uff08j\uff09TiO<sub>2<\/sub>\u7a7a\u5fc3\u5fae\u7403\u57281C\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n<p>\uff08k\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n<p>\uff08l-q\uff09l\uff09\u8584\u5355\u5c42\u548cm\uff09\u53cc\u5c42\uff0cn\uff09\u539a\u4e09\u5c42\uff0co\uff09\u539a\u5355\u58f3\uff0cp\uff09\u8584\u4e09\u5c42\uff0c\u548cq\uff09\u591a\u5c42V<sub>2<\/sub>O<sub>5<\/sub>\u7a7a\u5fc3\u5fae\u7403\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08r\uff09V<sub>2<\/sub>O<sub>5<\/sub>\u7a7a\u5fc3\u5fae\u7403\u548c\u7eb3\u7c73\u7247\u57281000 mA g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n<p>\uff08s\uff09\u591a\u58f3\u5c42V<sub>2<\/sub>O<sub>5<\/sub>\u7a7a\u5fc3\u7403\u548cV<sub>2<\/sub>O<sub>5<\/sub>\u7eb3\u7c73\u7247\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\uff08EIS\uff09\u6d4b\u8bd5<\/p>\n<p><strong>\u56fe11 <\/strong><strong>\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u7684\u7845\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154562\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/11-3.png\" alt=\"\" width=\"600\" height=\"424\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/11-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/11-3-300x212.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a-b\uff09Si-SiO<sub>x<\/sub>\u53cc\u58c1\u7eb3\u7c73\u7ba1\u5faa\u73af\u524d\u540e\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08c\uff091C\u81f320C\u7684\u4e0d\u540c\u901f\u7387\u4e0b\u7684\u53cc\u58c1Si-SiO<sub>x<\/sub>\u7eb3\u7c73\u7ba1\u7684\u5bb9\u91cf<\/p>\n<p>\uff08d-e\uff09\u9502\u5316\u524d\u540e\u7845\u77f3\u69b4\u7ed3\u6784\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08f\uff09\u7845\u77f3\u69b4\u7ed3\u6784\u548c\u5176\u4ed6\u7ed3\u6784\u7684\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n<p>\uff08g-h\uff09\u975e\u586b\u5145\u78b3\u6d82\u8986\u7684\u591a\u5b54\u7845\u5fae\u7c92\u9502\u5316\u524d\u540e\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08i\uff09\u5177\u6709\u4e0d\u540c\u6d82\u5c42\u7684\u591a\u5b54\u7845\u5fae\u7c92\u7684\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n<p>\uff08j-k\uff09SiMP@Gr\u7ed3\u6784\u9502\u5316\u524d\u540e\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08l\uff09SiMP@Gr\u7684\u534a\u7535\u6c60\u8131\u9502\u80fd\u529b\u3002\u5176\u4e2d\uff0cSiMP@Gr\u7535\u6781\u4e2d\u672a\u6dfb\u52a0\u5bfc\u7535\u5242\uff0c\u672a\u5305\u8986\u7684\u548c\u65e0\u5b9a\u5f62\u78b3\u6d82\u8986\u7684SiMP\u5bf9\u7167\u6837\u54c1\u7535\u6781\u4e2d\u6dfb\u52a0\u78b3\u9ed1\u5bfc\u7535\u6dfb\u52a0\u5242\u3002<\/p>\n<p><strong>\u56fe12 <\/strong><strong>\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u5728\u9502\u91d1\u5c5e\u8d1f\u6781\u4e0a\u7684\u5e94\u7528<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154563\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/12-4.png\" alt=\"\" width=\"600\" height=\"747\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/12-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/12-4-241x300.png 241w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><span lang=\"EN-US\">\uff08a\uff09<\/span>\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7403\u5305\u8986\u5728<span lang=\"EN-US\">Cu<\/span>\u57fa\u5e95\u4e0a\u4ee5\u7a33\u5b9a<span lang=\"EN-US\">SEI<\/span>\u5c42\u7684\u793a\u610f\u56fe<\/p>\n<p><span lang=\"EN-US\">\uff08b\uff09<\/span>\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7403\u7684\u6a2a\u622a\u9762\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n<p><span lang=\"EN-US\">\uff08c\uff09<\/span>\u7531\u4e8e\u78b3\u5c42\u548c<span lang=\"EN-US\">Cu<\/span>\u57fa\u5e95\u4e4b\u95f4\u7684\u7ed3\u5408\u8f83\u5f31\uff0c\u6c89\u79ef\u7684<span lang=\"EN-US\">Li<\/span>\u5c06\u4e2d\u7a7a\u78b3\u7eb3\u7c73\u7403\u5c42\u6258\u8d77\u6765\u4e86<\/p>\n<p><span lang=\"EN-US\">\uff08d\uff09<\/span>\u5728<span lang=\"EN-US\">0.5<\/span>\u6216<span lang=\"EN-US\">1.0 mA cm<sup>-2<\/sup><\/span>\u5d4c\u9502\u7535\u5bb9\u91cf\u4e0b\u6d82\u8986\u4e86\u7a7a\u5fc3\u78b3\u7eb3\u7c73\u7403\u548c\u88f8\u94dc\u7535\u6781\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u6bd4\u8f83<\/p>\n<p><span lang=\"EN-US\">\uff08e\uff09<\/span>\u5728\u7a7a\u5fc3\u78b3\u7403\u5185\u5d4c\u5165<span lang=\"EN-US\">Au<\/span>\u7eb3\u7c73\u9897\u7c92\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u7eb3\u7c73\u80f6\u56ca\u8bbe\u8ba1\u793a\u610f\u56fe<\/p>\n<p><span lang=\"EN-US\">\uff08f\uff09<\/span>\u5728\u70f7\u57fa\u78b3\u9178\u76d0\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u65f6\u4e0d\u540c\u7535\u6781\u7684\u5e93\u4ed1\u6548\u7387<\/p>\n<p><strong>\u56fe13 <\/strong><strong>\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u5728\u9502\u786b\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154564\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/13-5.png\" alt=\"\" width=\"600\" height=\"480\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/13-5.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/13-5-300x240.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><span lang=\"EN-US\">\uff08a\uff09<\/span>\u5229\u7528\u7a7a\u5fc3\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u6709\u6548\u6355\u83b7\u591a\u786b\u5316\u7269\u7684\u8bbe\u8ba1\u793a\u610f\u56fe<\/p>\n<p><span lang=\"EN-US\">\uff08b\uff09<\/span><span lang=\"EN-US\">C\/5<\/span>\u548c<span lang=\"EN-US\">C\/2<\/span>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u7535\u538b<span lang=\"EN-US\">&#8211;<\/span>\u5bb9\u91cf\u66f2\u7ebf<\/p>\n<p><span lang=\"EN-US\">\uff08c\uff09<\/span><span lang=\"EN-US\">C\/5<\/span>\u548c<span lang=\"EN-US\">C\/2<\/span>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n<p><span lang=\"EN-US\">\uff08d\uff09<\/span><span lang=\"EN-US\">S-TTCN<\/span>\u590d\u5408\u6750\u6599\u7684\u626b\u63cf\u900f\u5c04\u7535\u955c\u56fe\u50cf\u548c\u5143\u7d20\u5206\u5e03\u56fe\u50cf<\/p>\n<p><span lang=\"EN-US\">\uff08e\uff09<\/span><span lang=\"EN-US\">S-TTCN<\/span>\u590d\u5408\u6750\u6599\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u653e\u7535<span lang=\"EN-US\">\/<\/span>\u5145\u7535\u7279\u6027<\/p>\n<p><span lang=\"EN-US\">\uff08f\uff09<\/span><span lang=\"EN-US\">S-TTCN<\/span>\u590d\u5408\u6750\u6599\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u500d\u7387\u6027\u80fd<\/p>\n<p><span lang=\"EN-US\">\uff08g\uff09<\/span>\u653e\u7535\u81f3<span lang=\"EN-US\">1.7 V<\/span>\u524d\u540e\u7684\u786b\u6b63\u6781\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p><span lang=\"EN-US\">\uff08h\uff09<\/span>\u78b3\u8868\u9762\u4e0e<span lang=\"EN-US\">S<\/span>\uff0c<span lang=\"EN-US\">LiS<\/span>\u548c<span lang=\"EN-US\">Li<sub>2<\/sub>S<\/span>\u4e4b\u95f4\u76f8\u4e92\u4f5c\u7528\u7684\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97<\/p>\n<p><span lang=\"EN-US\">\uff08i\uff09<\/span>\u590d\u5408\u7ed3\u6784\u7684\u6a2a\u622a\u9762\u626b\u63cf\u7535\u955c\u56fe\u50cf\u663e\u793a\u786b\u9897\u7c92\u5d4c\u5728\u8fd8\u539f\u540e\u7684<span lang=\"EN-US\">TiO<sub>2<\/sub><\/span>\u7eb3\u7c73\u7403\u4e2d<\/p>\n<p><span lang=\"EN-US\">\uff08j\uff09<\/span>\u4e0d\u540c\u7535\u6d41\u901f\u7387\u4e0b\u7684\u7535\u538b\u66f2\u7ebf<\/p>\n<p><span lang=\"EN-US\">\uff08k\uff09<\/span>\u590d\u5408\u6b63\u6781\u7684\u500d\u7387\u6027\u80fd<\/p>\n<p><strong>\u56fe14 <\/strong><strong>\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154565\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/14-3.png\" alt=\"\" width=\"600\" height=\"495\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/14-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/14-3-300x248.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u7af9\u72b6\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08b\uff09\u572810\u5230100 mV s<sup>-1<\/sup>\u4e4b\u95f4\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u7535\u6781\u7684\u7535\u6d41\u7535\u538b\uff08CV\uff09\u66f2\u7ebf<\/p>\n<p>\uff08c\uff09\u78b3\u7535\u6781\u572810 A g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n<p>\uff08d\uff09\u7a7a\u5fc3\u7eba\u9524\u5f62RuO<sub>2<\/sub>\u00b7xH<sub>2<\/sub>O\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08e\uff09\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u6d4b\u91cf\u7684\u5faa\u73af\u4f0f\u5b89\u56fe<\/p>\n<p>\uff08f\uff09RuO<sub>2<\/sub>\u00b7xH<sub>2<\/sub>O\u7535\u6781\u7684\u5faa\u73af\u6027\u80fd<\/p>\n<p>\uff08g\uff09\u6d77\u80c6\u72b6MnO<sub>2<\/sub>\u7a7a\u5fc3\u7eb3\u7c73\u7403\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08h\uff09\u4e0d\u540c\u7ed3\u6784\u7684MnO<sub>2<\/sub>\u57285 mV s<sup>-1<\/sup>\u626b\u63cf\u901f\u7387\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/p>\n<p>\uff08i\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u7535\u5bb9<\/p>\n<p><strong>\u56fe15 <\/strong><strong>\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u5728\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154566\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/15-1.png\" alt=\"\" width=\"600\" height=\"368\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/15-1.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/15-1-300x184.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><span lang=\"EN-US\">\uff08a\uff09<\/span><span lang=\"EN-US\">ZnO<\/span>\u7a7a\u5fc3\u7403\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf\uff08\u6807\u5c3a\u4e3a<span lang=\"EN-US\">300 nm<\/span>\uff09<\/p>\n<p><span lang=\"EN-US\">\uff08b\uff09<\/span>\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff08<span lang=\"EN-US\">DSSC<\/span>\uff09\u7684<span lang=\"EN-US\">J-V<\/span>\u66f2\u7ebf<\/p>\n<p><span lang=\"EN-US\">\uff08c\uff09<\/span>\u76f8\u5e94\u7684\u7d2b\u5916<span lang=\"EN-US\">&#8211;<\/span>\u53ef\u89c1\u5149\u6f2b\u53cd\u5c04\u5149\u8c31<\/p>\n<p><span lang=\"EN-US\">\uff08d\uff09<\/span>\u663e\u793a<span lang=\"EN-US\">ZnO<\/span>\u7a7a\u5fc3\u5fae\u7403\u591a\u6b21\u53cd\u5c04\u5149\u7684\u793a\u610f\u56fe<\/p>\n<p><span lang=\"EN-US\">\uff08e\uff09<\/span>\u4e94\u5c42\u58f3<span lang=\"EN-US\">SnO<sub>2<\/sub><\/span>\u7a7a\u5fc3\u5fae\u7403\uff08<span lang=\"EN-US\">5S-SnO<sub>2<\/sub>-HMS<\/span>\uff09\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p><span lang=\"EN-US\">\uff08f\uff09<\/span>\u7531<span lang=\"EN-US\">6 \u03bcm<\/span>\u539a\u7684<span lang=\"EN-US\">5S-SnO<sub>2<\/sub>-HMS<\/span>\uff08\u9876\u90e8\uff09\u548c<span lang=\"EN-US\">10 \u03bcm<\/span>\u539a\u7684<span lang=\"EN-US\">P25<\/span>\u5c42\uff08\u5e95\u90e8\uff09\u7ec4\u6210\u7684\u5149\u9633\u6781\u7684<span lang=\"EN-US\">J-V<\/span>\u66f2\u7ebf<\/p>\n<p><strong>\u56fe16 <\/strong><strong>\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u5728\u7535\u50ac\u5316\u5242\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154567\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/16.png\" alt=\"\" width=\"600\" height=\"607\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/16.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/16-297x300.png 297w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><span lang=\"EN-US\">\uff08a\uff09<\/span><span lang=\"EN-US\">MW-CoS<\/span>\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p><span lang=\"EN-US\">\uff08b\uff09<\/span><span lang=\"EN-US\">GC<\/span>\uff0c<span lang=\"EN-US\">ST-CoS<\/span>\u548c<span lang=\"EN-US\">MW-CoS<\/span>\u5728<span lang=\"EN-US\">1.0 M<\/span>\u78f7\u9178\u76d0\u7f13\u51b2\u6db2\uff08<span lang=\"EN-US\">pH = 7<\/span>\uff0c<span lang=\"EN-US\">2 mV s<sup>-1<\/sup><\/span>\u548c<span lang=\"EN-US\">2000 rpm<\/span>\uff09\u4e0b\u7684\u6781\u5316\u66f2\u7ebf<\/p>\n<p><span lang=\"EN-US\">\uff08c\uff09<\/span><span lang=\"EN-US\">MW-CoS<\/span>\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/p>\n<p><span lang=\"EN-US\">\uff08d\uff09<\/span><span lang=\"EN-US\">ST-CoS<\/span>\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/p>\n<p><span lang=\"EN-US\">\uff08e\uff09<\/span>\u626b\u63cf\u901f\u7387\u5bf9\u5e94\u4e8e<span lang=\"EN-US\">ST-CoS<\/span>\u548c<span lang=\"EN-US\">MW-CoS<\/span>\u7684\u7535\u6d41\u5bc6\u5ea6\uff08<span lang=\"EN-US\">-0.15V vs SHE (<\/span>\u6807\u51c6\u6c22\u7535\u6781<span lang=\"EN-US\">)<\/span>\uff09<\/p>\n<p><span lang=\"EN-US\">\uff08f\uff09<\/span><span lang=\"EN-US\">\u03b1-Ni(OH)<sub>2<\/sub><\/span>\u7a7a\u5fc3\u7403\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p><span lang=\"EN-US\">\uff08g\uff09<\/span>\u5bf9\u4e8e\u88f8<span lang=\"EN-US\">GC<\/span>\u7535\u6781\u548c\u5305\u542b<span lang=\"EN-US\">\u03b1-<\/span>\u548c<span lang=\"EN-US\">\u03b2- Ni(OH)<sub>2<\/sub><\/span>\u7eb3\u7c73\u6676\u4f53\uff0c<span lang=\"EN-US\">RuO<sub>2<\/sub><\/span>\u548c<span lang=\"EN-US\">20wt<\/span>\uff05<span lang=\"EN-US\">Pt \/ C<\/span>\u7684\u6539\u6027<span lang=\"EN-US\">GC<\/span>\u7535\u6781\uff0c\u5728\u7b2c<span lang=\"EN-US\">100<\/span>\u6b21\u5faa\u73af\u8bb0\u5f55\u7684<span lang=\"EN-US\">CV<\/span>\u7684\u6bd4\u8f83<\/p>\n<p><span lang=\"EN-US\">\uff08h\uff09<\/span>\u4ece\uff08<span lang=\"EN-US\">g<\/span>\uff09\u5f97\u5230\u7684<span lang=\"EN-US\">OER<\/span>\u7535\u6d41\u7684<span lang=\"EN-US\">Tafel<\/span>\u56fe<\/p>\n<p><span lang=\"EN-US\">\uff08i\uff09<\/span><span lang=\"EN-US\">NCNTFs<\/span>\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n<p><span lang=\"EN-US\">\uff08j\uff09<\/span><span lang=\"EN-US\">Pt \/ C<\/span>\u548c<span lang=\"EN-US\">NCNTFs<\/span>\u7684<span lang=\"EN-US\">LSV<\/span>\u66f2\u7ebf\uff08<span lang=\"EN-US\">1600 rpm<\/span>\uff09<\/p>\n<p><span lang=\"EN-US\">\uff08k\uff09<\/span><span lang=\"EN-US\">0.6 V<\/span>\u4e0b\u7684\u8ba1\u65f6\u7535\u6d41\u54cd\u5e94<\/p>\n<p><span lang=\"EN-US\">\uff08l\uff09<\/span><span lang=\"EN-US\">PtCu<sub>3<\/sub><\/span>\u7eb3\u7c73\u7b3c\u7684\u9ad8\u500d\u653e\u5927\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p><span lang=\"EN-US\">\uff08m\uff09<\/span>\u5728<span lang=\"EN-US\">0.1 <sub>M<\/sub> HClO<sub>4<\/sub><\/span>\u6eb6\u6db2\uff08<span lang=\"EN-US\">20 mV s<sup>-1<\/sup><\/span>\uff09\u4e2d\u7684<span lang=\"EN-US\">PtCu<sub>3<\/sub><\/span>\u7acb\u65b9\u7eb3\u7c73\u7b3c\uff0c<span lang=\"EN-US\">PtCu<sub>x<\/sub><\/span>\u56fa\u4f53\u7eb3\u7c73\u7c92\u5b50\u548c<span lang=\"EN-US\">Pt<\/span>\uff08<span lang=\"EN-US\">JM<\/span>\uff09\u7684<span lang=\"EN-US\">CV<\/span>\u8c31<\/p>\n<p><span lang=\"EN-US\">\uff08n\uff09<\/span><span lang=\"EN-US\">PtCu<sub>3<\/sub><\/span>\u7eb3\u7c73\u7b3c\uff0c<span lang=\"EN-US\">PtCu<sub>x<\/sub><\/span>\u56fa\u4f53\u7eb3\u7c73\u7c92\u5b50\u548c<span lang=\"EN-US\">Pt<\/span>\uff08<span lang=\"EN-US\">JM<\/span>\uff09\u5728<span lang=\"EN-US\">0.1 <sub>M<\/sub> HClO<sub>4 <\/sub>+ 1 <sub>M<\/sub> MeOH<\/span>\u6eb6\u6db2\uff08<span lang=\"EN-US\">20 mV s<sup>-1<\/sup><\/span>\uff09\u4e2d\u6c27\u5316\u7684<span lang=\"EN-US\">CV<\/span>\u7ed3\u679c<\/p>\n<p><b>\u56fe<span lang=\"EN-US\" style=\"margin: 0px; color: #222222; font-family: 'Times New Roman',serif; font-size: 12pt;\">17 <\/span>\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u5728\u5149\u7535\u5316\u5b66\u7535\u6c60\u4e2d\u7684\u5e94\u7528<\/b><\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154568\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/17.png\" alt=\"\" width=\"600\" height=\"464\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/17.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/17-300x232.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u6d77\u80c6\u72b6TiO<sub>2<\/sub>\u9635\u5217\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08b\uff09\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u6cd5\u6d4b\u91cf\u6d77\u80c6\u72b6TiO<sub>2<\/sub>\u548cTiO<sub>2<\/sub>\u5fae\u7403\u7535\u6781<\/p>\n<p>\uff08c\uff09\u5728\u65bd\u52a0\u504f\u538b0 V\uff0c100 mW cm<sup>-2<\/sup>\u7167\u660e\u4e1430 s\u5faa\u73af\u5f00-\u5173\u4e0b\u7684\u7535\u6d41I-t\u66f2\u7ebf<\/p>\n<p>\uff08d\uff09CdS QD\u654f\u5316TiO<sub>2<\/sub>\u53cd\u86cb\u767d\u77f3\uff08IO\uff09\/ ZnO\u7eb3\u7c73\u7ebf\u6742\u5316\u7eb3\u7c73\u5149\u9633\u6781\u7684\u6a2a\u622a\u9762\u573a\u53d1\u5c04\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08e\uff09CdS QD\u654f\u5316\u5149\u9633\u6781\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u6cd5\u6d4b\u91cf\uff0c\u5728100 mW cm<sup>-2<\/sup>\u6a21\u62df\u592a\u9633\u5149\u7167\u5c04\u4e0b\u6536\u96c6\u7684\u6d4b\u91cf\u7ed3\u679c<\/p>\n<p>\uff08f\uff09 \u5728\u65bd\u52a0\u7535\u4f4d\u4e3a0 V\uff0c100 mW cm<sup>-2<\/sup>\u7167\u5c04\u4e1450 s\u5faa\u73af\u5f00-\u5173\u4e0b\u7684CdS QD\u654f\u5316\u5149\u7535\u9633\u6781\u7684\u5bf9\u5e94\u4e8eAgCl \/ Ag\u7684\u5b89\u57f9J-t\u66f2\u7ebf\uff0c<\/p>\n<p>\uff08g\uff09CuO-TiO<sub>2-x<\/sub>N<sub>x<\/sub>\u4e2d\u7a7a\u7eb3\u7c73\u7acb\u65b9\u4f53\u7684\u900f\u5c04\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08h\uff09CuO-TiO<sub>2-x<\/sub>N<sub>x<\/sub>\u4e2d\u7a7a\u7eb3\u7c73\u7acb\u65b9\u4f53\u7684\u573a\u53d1\u5c04\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n<p>\uff08i\uff09CuO-TiO<sub>2-x<\/sub>N<sub>x<\/sub>\u7eb3\u7c73\u7acb\u65b9\u4f53\u548cCuO\u5bf9\u7167\u6837\u54c1\u7684UV-vis\u6f2b\u53cd\u5c04\u5149\u8c31<\/p>\n<p>\uff08j\uff09\u5728CO<sub>2 <\/sub>\/ H<sub>2<\/sub>O\uff08g\uff09\u548cAr \/ H<sub>2<\/sub>O\uff08g\uff09\u4e2d\u7684Cu-TiO<sub>2-x<\/sub>N<sub>x<\/sub>\u4e2d\u7a7a\u7eb3\u7c73\u7acb\u65b9\u4f53\u5728\u592a\u9633\u8f90\u5c04\u4e0b\u7684\u7532\u70f7\u4ea7\u751f\u7387\uff08ppm g<sup>-1<\/sup> h<sup>-1<\/sup>\uff09\uff0c\u4ee5\u53ca\u6765\u81eaCuO\uff0cTiO<sub>2<\/sub>\uff0cCuO @ TiO<sub>2<\/sub>\uff0cCu<sub>3<\/sub>N\u548cTiO<sub>2<\/sub>@Cu<sub>3<\/sub>N\u5bf9\u7167\u6837\u54c1\u5728CO<sub>2<\/sub> \/ H<sub>2<\/sub>O\uff08g\uff09\u4e2d\u7684\u7684\u6570\u636e<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u6587\u7ae0\u5f3a\u8c03\u4e86\u901a\u8fc7\u8bbe\u8ba1\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\uff0c\u4ee5\u6709\u6548\u5730\u89e3\u51b3\u80fd\u91cf\u5b58\u50a8\uff0c\u8f6c\u6362\u548c\u751f\u4ea7\u6280\u672f\u7684\u5b9e\u9645\u5e94\u7528\u6311\u6218\u3002\u901a\u8fc7\u63a2\u7d22\u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784\u4e0e\u80fd\u6e90\u76f8\u5173\u5e94\u7528\u6027\u80fd\u4e4b\u95f4\u7684\u76f8\u5173\u6027\uff0c\u672c\u6587\u63d0\u51fa\u4e86\u5bf9\u7ed3\u6784\u7279\u5f81\u5bf9\u6027\u80fd\u5f71\u54cd\u7684\u6df1\u5165\u7406\u89e3\uff0c\u4ee5\u66f4\u597d\u5730\u8bbe\u8ba1\u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784\u6765\u6ee1\u8db3\u7279\u5b9a\u5e94\u7528\u7684\u8981\u6c42\uff0c\u540c\u65f6\u4e30\u5bcc\u4e86\u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784\u7684\u591a\u6837\u6027\u3002\u6211\u4eec\u8ba4\u4e3a\uff0c\u672a\u6765\u5e94\u8be5\u81f4\u529b\u4e8e\u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784\u7684\u8bbe\u8ba1\u3001\u5408\u6210\u53ca\u5e94\u7528\uff0c\u4ee5\u8fdb\u4e00\u6b65\u63a8\u52a8\u8fd9\u4e00\u9886\u57df\u7684\u53d1\u5c55\u3002<\/p>\n<p><strong>\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p><span 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Mater. 2017, 29, 1602914.<\/span><\/span><\/li>\n<\/ol>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"https:\/\/doi.org\/10.1002\/adma.201801993\">Design of Hollow Nanostructures for Energy Storage, Conversion and Production <\/a>(Advanced Materials 2018, <a href=\"https:\/\/doi.org\/10.1002\/adma.201801993\">https:\/\/doi.org\/10.1002\/adma.201801993<\/a>)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4\u952e\u4ed4\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c<u>\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/u>\u3002<\/p>\n<p><strong>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/strong><strong>\u3002<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784\u5728\u80fd\u6e90\u5b58\u50a8\u3001\u8f6c\u6362\u548c\u751f\u4ea7\u6280\u672f\u65b9\u9762\u5c55\u73b0\u51fa\u4e86\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5728\u8fc7\u53bb\u5341\u5e74\u4e2d\uff0c\u7814\u7a76\u8005\u4eec\u81f4\u529b\u4e8e\u8bbe\u8ba1\u548c\u5408\u6210\u5177\u6709\u4e0d\u540c\u7ec4\u6210\u548c\u51e0\u4f55\u7279\u5f81\u7684\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u3002\u7136\u800c\uff0c\u5b83\u4eec\u7684&#8230;<\/p>\n","protected":false},"author":9726,"featured_media":154548,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[3590],"class_list":["post-154545","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu","tag-3590"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/154545"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/9726"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=154545"}],"version-history":[{"count":9,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/154545\/revisions"}],"predecessor-version":[{"id":154898,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/154545\/revisions\/154898"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/154548"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=154545"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=154545"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=154545"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}