{"id":154648,"date":"2018-09-27T06:00:15","date_gmt":"2018-09-26T22:00:15","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=154648"},"modified":"2018-09-27T09:22:16","modified_gmt":"2018-09-27T01:22:16","slug":"%e3%80%90iop%e4%b8%93%e6%a0%8f%e3%80%91%e5%ae%89%e5%be%bd%e5%a4%a7%e5%ad%a6%e6%9c%b1%e6%bb%a1%e6%b4%b2%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9f%e8%81%94%e5%90%88rongchao-jin-%e6%95%99%e6%8e%88nano-futures","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=154648","title":{"rendered":"\u3010IOP\u4e13\u680f\u3011\u5b89\u5fbd\u5927\u5b66\u6731\u6ee1\u6d32\u6559\u6388\u56e2\u961f\u8054\u5408Rongchao Jin \u6559\u6388Nano Futures\uff1a\u901a\u8fc7\u914d\u4f53\u548c\u5408\u91d1\u5316\u6765\u8c03\u63a7\u5177\u670932\u4e2a\u91d1\u5c5e\u539f\u5b50\u7c07\u5408\u7269\u7684\u7ed3\u6784"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u7531\u4e8e\u5408\u91d1\u7eb3\u7c73\u9897\u7c92\u4e2d\u5404\u7ec4\u4efd\u95f4\u4e30\u5bcc\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u4f7f\u5f97\u5408\u91d1\u7eb3\u7c73\u56e2\u7c07\u5907\u53d7\u9752\u7750\u3002\u539f\u5b50\u7cbe\u786e\u7684\u5408\u91d1\u7c07\u5408\u7269\u7684\u53ef\u63a7\u5408\u6210\u4e0d\u4ec5\u6709\u52a9\u4e8e\u6df1\u5165\u7406\u89e3\u7ed3\u6784\u4e0e\u6027\u8d28\u4e4b\u95f4\u7684\u5173\u8054\uff0c\u800c\u4e14\u8fd8\u53ef\u4ee5\u901a\u8fc7\u91d1\u5c5e\u534f\u540c\u4f5c\u7528\u6765\u8c03\u63a7\u7eb3\u7c73\u56e2\u7c07\u7684\u7406\u5316\u6027\u80fd\u3002\u5728\u91d1\u5c5e\u63ba\u6742\u8fc7\u7a0b\u4e2d\uff0c\u914d\u4f53\u4ee5\u53ca\u5408\u91d1\u5316\u90fd\u53ef\u80fd\u6539\u53d8\u5355\u91d1\u5c5e\u7c07\u5408\u7269\u7684\u7ed3\u6784\u3002\u5982\u4f55\u5229\u7528\u914d\u4f53\u548c\u91d1\u5c5e\u6548\u5e94\u53ef\u63a7\u5408\u6210\u65b0\u578b\u7c07\u5408\u7269\u662f\u503c\u5f97\u63a2\u7a76\u7684\u524d\u6cbf\u95ee\u9898\u4e4b\u4e00\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p><strong><b>\u8fd1\u65e5\uff0c<\/b><\/strong><strong><b>\u5728<\/b><\/strong><strong><b>\u5b89\u5fbd\u5927\u5b66\u6731\u6ee1\u6d32\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u5361\u8010\u57fa\u6885\u9686\u5927\u5b66\u7684<\/b><\/strong><strong><b>Ron<\/b><\/strong><strong><b>gchao Jin\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong><strong><b>\u7684\u6307\u5bfc\u4e0b<\/b><\/strong><strong><b>\uff0c\u90b9\u96ea\u5a1f\u548c\u91d1\u5c71\uff08\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff09<\/b><\/strong>\u5229\u7528\u914d\u4f53\u4ee5\u53ca\u5408\u91d1\u5316\u4f5c\u7528\u8c03\u63a732\u4e2a\u91d1\u5c5e\u539f\u5b50\u7c07\u5408\u7269\u7684\u7ed3\u6784\u3002\u6b64\u5408\u91d1\u7c07\u5408\u7269\u6709\u4e00\u4e2aAg<sub>17<\/sub>\u7684\u5185\u6838\u7ed3\u6784\uff0c\u5916\u56f4\u88ab\u5927\u7684Ag<sub>3<\/sub>Cu<sub>12<\/sub>(SR)<sub>14<\/sub>(Dppm)<sub>6<\/sub>Br<sub>8<\/sub>\u58f3\u5305\u88f9\u3002\u540c\u65f6Ag<sub>3<\/sub>Cu<sub>12<\/sub>(SR)<sub>14<\/sub>(Dppm)<sub>6<\/sub>Br<sub>8<\/sub>\u00a0\u58f3\u53c8\u770b\u6210\u662f\u4e24\u4e2a\u5c0f\u7684Ag<sub>1<\/sub>Cu<sub>6<\/sub>(SR)<sub>7<\/sub>(Dppm)<sub>3<\/sub>Br<sub>4<\/sub>\u901a\u8fc7\u4e00\u4e2aAg\u539f\u5b50\u8fde\u63a5\u6784\u6210\uff0c\u9664\u6b64\u4e4b\u5916\uff0cAg<sub>1<\/sub>Cu<sub>6<\/sub>(SR)<sub>7<\/sub>(Dppm)<sub>3<\/sub>Br<sub>4<\/sub>\u53ef\u4ee5\u62c6\u5206\u6210Cu<sub>2<\/sub>(SR)<sub>3<\/sub>(Dppm)Br \u548cAgCu<sub>3<\/sub>(SR)<sub>4<\/sub>(Dppm)<sub>2<\/sub>Br<sub>3<\/sub>\u4e24\u4e2a\u5355\u5143\uff0c\u4ee5Cu\u539f\u5b50\u8fde\u63a5\u6784\u6210\u3002\u8be5\u5408\u91d1\u7eb3\u7c73\u56e2\u7c07\u4e2d\uff0cCu\u539f\u5b50\u9009\u62e9\u6027\u5730\u8d2f\u7a7f\u4e8e\u58f3\u4e2d\u3002\u8fd9\u4e2a\u7814\u7a76\u901a\u8fc7\u914d\u4f53\u548c\u91d1\u5c5e\u7684\u5408\u91d1\u5316\u6548\u5e94\u6765\u8c03\u63a7\u5408\u91d1\u7eb3\u7c73\u56e2\u7c07\u7684\u7ed3\u6784\u3002<\/p>\n<p>\u3010<strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p>\u56fe1. \u4e24\u79cd\u4e0d\u540c\u89d2\u5ea6\u7684[Ag<sub>20<\/sub>Cu<sub>12<\/sub>(SR)<sub>14<\/sub>(Dppm)<sub>6<\/sub>Br<sub>8<\/sub>]<sup>2+<\/sup>\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-154649 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72471-5.png\" alt=\"\" width=\"555\" height=\"218\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72471-5.png 555w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72471-5-300x118.png 300w\" sizes=\"(max-width: 555px) 100vw, 555px\" \/><\/p>\n<p>\u00a0\u989c\u8272\u5206\u7c7b\uff1a\u7eff\/\u7070=Ag\uff1b\u7ea2=S; \u54c1\u7ea2=P; \u7816\u7ea2=Cu\u3002<\/p>\n<p>\u56fe2. [Ag<sub>20<\/sub>Cu<sub>12<\/sub>(SR)<sub>14<\/sub>(Dppm)<sub>6<\/sub>Br<sub>8<\/sub>]<sup>2+<\/sup>\u7ed3\u6784\u7684\u62c6\u5206\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-154650 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72472-4.png\" alt=\"\" width=\"625\" height=\"677\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72472-4.png 625w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72472-4-277x300.png 277w\" sizes=\"(max-width: 625px) 100vw, 625px\" \/><\/p>\n<ul>\n<li>Ag<sub>17<\/sub>\u5185\u6838\u7ed3\u6784\uff1b<\/li>\n<li>Ag<sub>3<\/sub>Cu<sub>12<\/sub>(SR)<sub>14<\/sub>(Dppm)<sub>6<\/sub>Br<sub>8<\/sub>\u7684\u7acb\u4f53\u7ed3\u6784\u4ee5\u53ca\u914d\u4f53\u7684\u82ef\u73af\u4e4b\u95f4\u5b58\u5728\u7684\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\uff1b<\/li>\n<li>\u7acb\u4f53\u7684Ag<sub>1<\/sub>Cu<sub>6<\/sub>(SR)<sub>7<\/sub>(Dppm)<sub>3<\/sub>Br<sub>4<\/sub>\u7ed3\u6784\uff1b<\/li>\n<li>\u7acb\u4f53\u7ed3\u6784Ag1Cu6(SR)7(Dppm)3Br4\u7684\u5e73\u9762\u793a\u610f\u56fe<\/li>\n<li>\u4e24\u4e2a\u5c0f\u7684Cu<sub>2<\/sub>(SR)3(Dppm)Br \u548cAgCu<sub>3<\/sub>(SR)<sub>4<\/sub>(Dppm)<sub>2<\/sub>Br<sub>3<\/sub>\u5355\u5143\u3002<\/li>\n<\/ul>\n<p>\u56fe3. \u7cfb\u521732\u4e2a\u91d1\u5c5e\u539f\u5b50\u7c07\u5408\u7269\u7684\u7ed3\u6784\u5bf9\u6bd4<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-154651 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72473-4.png\" alt=\"\" width=\"654\" height=\"654\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72473-4.png 654w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72473-4-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72473-4-300x300.png 300w\" sizes=\"(max-width: 654px) 100vw, 654px\" \/><\/p>\n<ul>\n<li>[Ag<sub>32<\/sub>(DPPE)<sub>5<\/sub>(SC<sub>6<\/sub>H<sub>4<\/sub>CF<sub>3<\/sub>)<sub>24<\/sub>]<sup>2<\/sup><sup>\u2212<\/sup>\uff1b<\/li>\n<li>[Ag<sub>32<\/sub>(Dppm)<sub>5<\/sub>(SAdm)<sub>13<\/sub>Cl<sub>8<\/sub>]<sup>3+<\/sup>\uff1b<\/li>\n<li>[Ag<sub>20<\/sub>Cu<sub>12<\/sub>(SR)<sub>14<\/sub>(Dppm)<sub>6<\/sub>Br<sub>8<\/sub>]<sup>2+<\/sup>\u3002<\/li>\n<\/ul>\n<p>\u56fe4. [Ag<sub>20<\/sub>Cu<sub>12<\/sub>(SR)<sub>14<\/sub>(Dppm)<sub>6<\/sub>Br<sub>8<\/sub>]<sup>2+<\/sup>\u7684\u4e24\u4e2a\u5149\u8c31\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-154652 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72474-4.png\" alt=\"\" width=\"433\" height=\"601\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72474-4.png 433w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/09\/\u56fe\u72474-4-216x300.png 216w\" sizes=\"(max-width: 433px) 100vw, 433px\" \/><\/p>\n<ul>\n<li>\u7c97\u4ea7\u7269\u548c\u6676\u4f53\u7684\u7d2b\u5916\u5149\u8c31\uff1b<\/li>\n<li>\u5b9e\u9a8c\u548c\u7406\u8bba\u7684ESI\u5149\u8c31\u3002<\/li>\n<\/ul>\n<p><strong><b>\u3010\u603b\u7ed3\u3011<\/b><\/strong><\/p>\n<p>\u5408\u6210\u4e86\u4e00\u4e2a\u65b0\u7684AgCu\u5408\u91d1\u7eb3\u7c73\u56e2\u7c07\uff0c\u5e76\u901a\u8fc7X-\u5c04\u7ebf\u6676\u4f53\u884d\u5c04\u786e\u5b9a\u4e86\u5176\u7ed3\u6784\u548c\u5206\u5b50\u5f0f\u4e3a[Ag<sub>20<\/sub>Cu<sub>12<\/sub>(SR)<sub>14<\/sub>(Dppm)<sub>6<\/sub>Br<sub>8<\/sub>]<sup>2+<\/sup>\u3002\u4e0e\u4e4b\u524d\u62a5\u9053\u7684\u4e24\u4e2aAg<sub>32<\/sub>\u7eb3\u7c73\u56e2\u7c07\u76f8\u6bd4\u8f83\uff0c\u867d\u7136\u5177\u6709\u76f8\u540c\u7684\u91d1\u5c5e\u539f\u5b50\u6570\u76ee\uff0c\u4f46\u5b83\u4eec\u7684\u5185\u6838\u3001\u5916\u56f4\u58f3\u4ee5\u53ca\u81ea\u7531\u7535\u5b50\u6570\u90fd\u4e0d\u76f8\u540c\u3002\u540c\u65f6\uff0c\u5728\u8fd9\u4e2a\u5408\u91d1\u7eb3\u7c73\u56e2\u7c07\u7684\u58f3\u4e2d\uff0c\u7531\u4e8e\u914d\u4f53\u82ef\u73af\u4e4b\u95f4\u5b58\u5728\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\u4f7f\u5f97\u6574\u4f53\u7ed3\u6784\u6210\u4e3a\u4e00\u4e2a\u5c01\u95ed\u7684\u4f53\u7cfb\uff0c\u589e\u52a0\u4e86\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u79cd\u5229\u7528\u914d\u4f53\u548c\u5408\u91d1\u5316\u7684\u5171\u540c\u6548\u5e94\u6765\u8c03\u63a7\u7eb3\u7c73\u56e2\u7c07\u7684\u7535\u5b50\u7ed3\u6784\u548c\u6574\u4f53\u7ed3\u6784\u7684\u65b9\u6cd5\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<u>Tailoring the structure of 32-metal-atom nanoclusters by ligands and alloying<\/u>\uff0c<\/p>\n<p>(Nano Futures, 2018, DOI: <a href=\"http:\/\/iopscience.iop.org\/article\/10.1088\/2399-1984\/aadd21to\">http:\/\/iopscience.iop.org\/article\/10.1088\/2399-1984\/aadd21<\/a>)<\/p>\n<p>&nbsp;<\/p>\n<p>\u6750\u6599\u4eba\u4e0eIOP\u51fa\u7248\u793e\u8054\u5408\u63a8\u51fa\u3010IOP\u4e13\u680f\u3011\uff0c\u62a5\u9053IOP\u65d7\u4e0b\u671f\u520a\u7cbe\u5f69\u7814\u7a76\u8fdb\u5c55\u3002\u672c\u6587\u7cfb\u3010IOP\u4e13\u680f\u3011\u7b2c8\u7bc7\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\"><strong><b>\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/b><\/strong><\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong><b>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/b><\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong><u><b>\u6d4b\u8bd5\u8c37<\/b><\/u><\/strong><\/a><strong><b>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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