{"id":155117,"date":"2018-10-01T06:07:01","date_gmt":"2018-09-30T22:07:01","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=155117"},"modified":"2018-09-30T14:08:26","modified_gmt":"2018-09-30T06:08:26","slug":"%e6%96%b0%e5%8a%a0%e5%9d%a1%e5%9b%bd%e7%ab%8b%e5%a4%a7%e5%ad%a6%e6%9b%be%e5%8d%8e%e6%b7%b3adv-mater-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e4%b8%ad%e7%a9%ba%e5%82%ac%e5%8c%96%e8%a3%85%e7%bd%ae%e7%9a%84%e7%bb%93","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=155117","title":{"rendered":"\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u66fe\u534e\u6df3Adv. Mater.\u7efc\u8ff0\uff1a\u4e2d\u7a7a\u50ac\u5316\u88c5\u7f6e\u7684\u7ed3\u6784\u4e0e\u5236\u5907"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66<\/b><\/strong>\u66fe\u534e\u6df3<\/b><\/strong>\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u56e2\u961f\u7b80\u8981\u6982\u8ff0\u4e2d\u7a7a\u6750\u6599\u7684\u8bbe\u8ba1\uff0c\u5408\u6210\u548c\u529f\u80fd\u5316\u7684\u6700\u65b0\u53d1\u5c55\uff0c\u4ee5\u7528\u4e8e\u5176\u5728\u591a\u76f8\u50ac\u5316\u9886\u57df\u4e2d\u7684\u5e94\u7528\u3002\u9996\u5148\u5c06\u8fd9\u4e9b\u50ac\u5316\u7a7a\u5fc3\u6750\u6599\u7684\u5408\u6210\u65b9\u6cd5\u5206\u7c7b\u4e3a\u4e09\u4e2a\u4e3b\u8981\u7c7b\u522b\uff0c\u6a21\u677f\u6cd5\uff0c\u65e0\u6a21\u677f\u548c\u7ec4\u5408\u65b9\u6cd5\u3002\u53e6\u5916\uff0c\u5177\u6709\u6216\u4e0d\u5177\u6709\u529f\u80fd\u5316\u7684\u4e2d\u7a7a\u6750\u6599\u5c06\u8fdb\u4e00\u6b65\u5206\u7c7b\u4e3a\u4e0d\u540c\u7c7b\u578b\u7684\u6784\u578b\uff0c\u800c\u5c06\u5206\u522b\u5f15\u5165\u7528\u4e8e\u6bcf\u79cd\u7c7b\u578b\u6784\u578b\u7684\u5236\u9020\u6280\u672f\u3002\u56e2\u961f\u8fd8\u4e13\u6ce8\u4e8e\u5c06\u5f00\u53d1\u6784\u578b\u7684\u7ed3\u6784\u4f18\u70b9\u4e0e\u5176\u6539\u8fdb\u7684\u50ac\u5316\u6027\u80fd\u76f8\u5173\u8054\u3002\u5728\u5c06\u7eaf\u7406\u8bba\u7814\u7a76\u4e0e\u5de5\u4e1a\u5e94\u7528\u76f8\u7ed3\u5408\u7684\u8fc7\u7a0b\u4e2d\uff0c\u5206\u6790\u5404\u6784\u578b\u5728\u591a\u76f8\u50ac\u5316\u4e2d\u7684\u4f18\u7f3a\u70b9\u3002\u6700\u540e\uff0c\u57fa\u4e8e\u4f5c\u8005\u7684\u4e2a\u4eba\u89c2\u70b9\uff0c\u5e76\u5c31\u4e2d\u7a7a\u50ac\u5316\u88c5\u7f6e\u7684\u672a\u6765\u53d1\u5c55\u548c\u524d\u666f\u63d0\u51fa\u4e00\u4e9b\u4e2a\u4eba\u89c2\u70b9\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cArchitecture and Preparation of Hollow Catalytic Devices<\/b><\/strong>\u201d\u53d1\u8868\u5728Adv. Mater.<\/b><\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>1<\/b><\/strong>\u00a0\u786c\u6a21\u677f<\/b><\/strong>\u6cd5\u5408\u6210<\/b><\/strong>\u5185\u6838\u4e0e\u6d82\u5c42\u58f3<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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b\uff09MoVI<\/sup>\u6ce8\u5165\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

c\uff09\u901a\u8fc7\u8f6f\u6a21\u677f\u65b9\u6cd5\u5408\u6210\u548c\u6574\u5408Fe-soc-MOF\u7acb\u65b9\u4f53\u5230\u7a7a\u5fc3\u80f6\u4f53\u4e2d\u7684\u793a\u610f\u56fe\uff1b\u00a0<\/p>\n

d\uff09Fe-soc-MOF\u7a7a\u5fc3\u7403\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/b><\/strong>2<\/b><\/strong>\u00a0\u53d6\u5411\u8fde\u63a5<\/b><\/strong>\u6cd5\u5408\u6210\u4e2d\u7a7a\u6750\u6599<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a) \u8bf4\u660e\u901a\u8fc7\u53d6\u5411\u8fde\u63a5\u4ece\u96f6\u7ef4SnO2<\/sub>\u5fae\u6676\u7ec4\u88c5\u52302D\u4e09\u89d2\u5f62\u548c3D\u7a7a\u5fc3\u516b\u9762\u4f53\u7684\u65b9\u6848\uff1b<\/p>\n

b\uff09\u4ee5\u4e0d\u540c\u503e\u659c\u89d2\u5ea6\u62cd\u6444\u7684SnO2<\/sub>\u4e2d\u7a7a\u516b\u9762\u4f53\u7684\u8fde\u7eedTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/b><\/strong>3<\/b><\/strong>\u00a0<\/b><\/strong>Ostwald<\/b><\/strong>\u719f\u5316\u6cd5\u5408\u6210\u4e2d\u7a7a\u6750\u6599<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09Ostwald\u719f\u5316\u8fc7\u7a0b\u548cTiO2<\/sub>\u7a7a\u5fc3\u7403\u5f62\u6210\u7684\u65b9\u6848\uff1b\u00a0<\/p>\n

b\uff09\u663e\u793a\u53cd\u5e942\u300120\u548c50\u5c0f\u65f6\u540eTiO2<\/sub>\u7eb3\u7c73\u7403\u7684\u6f14\u53d8\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

c\uff09TiO2<\/sub>\u7a7a\u5fc3\u7403\u5728\u4e0eHF\u6eb6\u6db2\u53cd\u5e94\u4e4b\u524d\u548c\u4e4b\u540e\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

d\uff09CuO\u7eb3\u7c73\u6676\u5411\u7a7a\u5fc3Cu2<\/sub>O\u7eb3\u7c73\u7403\u5f62\u6210\u548c\u8fd8\u539f\u8f6c\u5316\u7684\u5408\u6210\u6d41\u7a0b\u56fe\uff1b<\/p>\n

e\uff09\u901a\u8fc7\u53cd\u5e94\u8026\u5408Ostwald\u719f\u5316\u7684Cu2<\/sub>O\u7eb3\u7c73\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\u548cSAED\u56fe\u50cf\uff1b<\/p>\n

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g\uff09\u53cd\u5e94\u4e0d\u540c\u65f6\u95f4\u540e\u5177\u6709\u5bf9\u79f0Ostwald\u719f\u5316\u7684ZnS\u86cb\u9ec4-\u58f3\u7403\u7684\u6f14\u5316\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

h\uff09TEM\u548cSAED \u901a\u8fc7\u4e0d\u5bf9\u79f0Ostwald\u719f\u5316\u7814\u7a76\u534a\u7a7a\u5fc3Co3<\/sub>O4<\/sub>\u7403\u7684\u5f62\u6210\u8fc7\u7a0b\u3002<\/p>\n

\u56fe<\/b><\/strong>4<\/b><\/strong>\u00a0\u901a\u8fc7Kirkendall<\/b><\/strong>\u6548\u5e94<\/b><\/strong>\u5236\u9020\u4e2d\u7a7a\u6750\u6599<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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b\uff09\u5236\u5907\u7684ZnO\u84b2\u516c\u82f1\u5f62\u72b6\u7684SEM\u548cTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0<\/b><\/strong>\u5229<\/b><\/strong>\u7528<\/b><\/strong>Ostwald\u719f\u5316<\/b><\/strong>\u5408\u6210\u5408\u6210Au@TiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u86cb\u9ec4-\u58f3\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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b\uff09Au@TiO2<\/sub>\u86cb\u9ec4-\u58f3\u7eb3\u7c73\u7403\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

c\uff09\u901a\u8fc7\u5728\u6838\u5fc3\u548c\u6838-\u58f3\u754c\u9762\u540c\u65f6\u8fdb\u884cOstwald\u719f\u5316\u6765\u8bf4\u660e\u7ec6\u83cc\u6837\u53cc\u58f3CaCO3<\/sub>\u5fae\u80f6\u56ca\u5f62\u6210\u8fc7\u7a0b\u7684\u5de5\u827a\u6d41\u7a0b\u56fe\uff1b\u00a0<\/p>\n

d\uff09\u5408\u6210\u7684CaCO3<\/sub>\u53cc\u58f3\u7a7a\u5fc3\u7403\u7684SEM\uff0cTEM\u548cSAED\u56fe\u50cf\uff1b\u00a0<\/p>\n

e\uff09\u901a\u8fc7Ostwald\u719f\u5316\u548cKirkendall\u8fc7\u7a0b\u7684\u91cd\u590d\u79bb\u5b50\u4ea4\u6362\u548c\u7a7a\u5fc3\u5316\uff0c\u5f62\u6210\u591a\u5c42Cu2<\/sub>S\u7a7a\u5fc3\u7403\u7684\u5f62\u6210\u8fc7\u7a0b\uff1b\u00a0<\/p>\n

f\uff09\u53cc\u58f3\u548c\u4e09\u58f3Cu2<\/sub>S\u7a7a\u5fc3\u7403\u7684 TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/b><\/strong>6<\/b><\/strong>\u00a0<\/b><\/strong>\u901a\u8fc7\u53d6\u5411\u8fde\u63a5\u548c<\/b><\/strong>Kirkendall<\/b><\/strong>\u6548\u5e94<\/b><\/strong>\u7ec4\u5408<\/b><\/strong>\u5408\u6210\u7eb3\u7c73<\/b><\/strong>\u7a7a\u5fc3<\/b><\/strong>\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u901a\u8fc7\u56fa\u4f53\u7eb3\u7c73\u7acb\u65b9\u4f53\u76843D\u53d6\u5411\u8fde\u63a5\u548c\u901a\u8fc7Ostwald\u719f\u5316\u4ea7\u751f\u5185\u90e8\u4e2d\u7a7a\u7684Cu2<\/sub>O\u4e2d\u7a7a\u7eb3\u7c73\u7acb\u65b9\u4f53\u7684\u5408\u6210\u65b9\u6848\uff1b\u00a0<\/p>\n

b\uff0cc\uff09\u5236\u5907\u7684Cu2<\/sub>O\u4e2d\u7a7a\u7eb3\u7c73\u7acb\u65b9\u4f53\u7684SEM\u548cTEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

c\uff09\u901a\u8fc7CO2<\/sub>\u6c14\u6ce1\u6a21\u677f\u548cSiO2<\/sub>\u73e0\u786c\u6a21\u677f\u7684\u53cc\u6a21\u677f\u5408\u6210\u5fae\u6ce1\u7ed3\u6784\u7684\u7845\u9178\u9530\u7eb3\u7c73\u6c14\u6ce1\u7684\u793a\u610f\u56fe\uff1b\u00a0<\/p>\n

e\uff09SiO2<\/sub>\u73e0\u524d\u4f53\u548cMn\u7845\u9178\u76d0\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

f\uff09\u901a\u8fc7\u5c06\u7eb3\u7c73\u68d2\u53d6\u5411\u8fde\u63a5\u5230\u4e2d\u5fc3\u830e\u4e2d\u5e76\u968f\u540e\u6a21\u677f\u5316\u751f\u957f\u548c\u5f62\u6210\u6700\u7ec8\u7a7a\u5fc3\u7403\u7684\u56ca\u72b6\u6a21\u677f\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u5f62\u6210\u7684ZnO\u591a\u811a\u72b6\u5355\u5143\u7684\u6676\u4f53\u53d6\u5411\uff1b\u00a0<\/p>\n

g\uff09\u5355\u4e2aZnO\u7ed3\u6784\u5355\u5143\u548cZnO\u7a7a\u5fc3\u7403\u5185\u8868\u9762\u7684SEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

h\uff09ZnO\u7a7a\u5fc3\u7403\u53ca\u5176\u8db3\u7403\u72b6\u201c\u7247\u533a\u201d\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/b><\/strong>7<\/b><\/strong>\u00a0<\/b><\/strong>\u901a<\/b><\/strong>\u8fc7\u5316\u5b66\u8f6c\u5316<\/b><\/strong>\u4ee5<\/b><\/strong>CuS\u4e2d\u7a7a\u7403\u7684\u6bcd\u4f53\u524d\u4f53\u5236\u5907Ag<\/b><\/strong>2<\/b><\/sub><\/strong>S\u4e2d\u7a7a\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u901a\u8fc7CuS\u4e0eAg+<\/sup>\u7684\u9633\u79bb\u5b50\u4ea4\u6362\u5f62\u6210\u7684Ag2<\/sub>S\u7a7a\u5fc3\u7403\u7684\u793a\u610f\u56fe\uff1b\u00a0<\/p>\n

b\uff09\u4ee5\u4e0d\u540cAgNO3<\/sub>\u4e0eCuS\u6469\u5c14\u6bd4\u5236\u5907\u7684Ag2<\/sub>S\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

c\uff09\u4f7f\u7528CTAB\u56ca\u6ce1\u8f6f\u6a21\u677f\u5408\u6210ZIF-67\u7a7a\u5fc3\u7403\u7684\u5de5\u827a\u6d41\u7a0b\u56fe\uff1b\u00a0<\/p>\n

d\uff09ZIF-67\u7a7a\u5fc3\u7403\u53ca\u5176\u884d\u751f\u7269Co3<\/sub>O4<\/sub>\u5728\u6c29\u6c14\u548c\u7a7a\u6c14\u4e2d\u8fdb\u4e00\u6b65\u7145\u70e7\u540e\u7684\u7a7a\u5fc3\u7403\u7684 SEM\u548cTEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

e\uff09ZnO\u4e2d\u7a7a\u7ed3\u6784\u4ece\u73af\u72b6\u516d\u8fb9\u5f62\u57fa\u5e95\u5230\u6700\u7ec8\u5b50\u5f39\u5934\u72b6\u7ed3\u6784\u7684\u53d6\u5411\u8fde\u63a5\u5f62\u6210\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

f\uff09\u4e0d\u540c\u53cd\u5e94\u65f6\u95f4\u540eZnO\u7a7a\u5fc3\u7403\u5f62\u6210\u8fc7\u7a0b\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

g\uff09\u968f\u540e\u7684LaMer\u578b\u751f\u957f\u548cOstwald\u719f\u5316\u540e\u7684ZnO\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

h\uff09\u6765\u81eaSiO2<\/sub>\u73e0\u524d\u4f53\u7684PDA\u6d82\u8986\u7684\u8fc7\u6e21\u91d1\u5c5e\u7845\u9178\u76d0\u7684\u4e24\u79cd\u5408\u6210\u8def\u7ebf\u53ca\u5176\u7ed3\u6784\u884d\u751f\u7269\uff1b\u00a0<\/p>\n

i\uff09\u4ee5\u4e24\u79cd\u4e0d\u540c\u7684\u653e\u5927\u500d\u6570\u62cd\u6444\u7684TMSi@PDA\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u00a0<\/b><\/strong>\u56fe<\/b><\/strong>8<\/b><\/strong>\u00a0\u65e0\u6a21\u677f\u5408\u6210\u03b2-Ni(OH)<\/b><\/strong>2<\/b><\/sub><\/strong>\u7a7a\u5fc3\u7403\u7684\u793a\u610f\u6d41\u7a0b\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u65e0\u6a21\u677f\u5408\u6210\u03b2-Ni(OH)2<\/sub>\u7a7a\u5fc3\u7403\u7684\u793a\u610f\u6d41\u7a0b\u56fe\uff0c\u8be5\u7a7a\u5fc3\u7403\u7531\u7eb3\u7c73\u6a21\u5757\u7684\u81ea\u7ec4\u88c5\u548c\u5728\u5404\u79cd\u5904\u7406\u8fc7\u7a0b\u540e\u5f62\u6210\u5176\u884d\u751f\u7269\u7ed3\u6784\u5236\u5907\u800c\u6210\uff1b<\/p>\n

b-e\uff09b\uff09\u03b2-Ni(OH)2<\/sub>\uff0cc\uff09NiO\uff0cd\uff09\u91d1\u5c5eNi\uff0c\u548ce\uff09Ni\/\u03b2-NiNi(OH)2<\/sub>\u4e2d\u7a7a\u7ed3\u6784\u7684SEM\u548cTEM\u56fe\u50cf\u3002<\/p>\n

\u00a0<\/b><\/strong>\u56fe<\/b><\/strong>9<\/b><\/strong>\u00a0\u7c7b\u4f3c\u4e8e\u55b7\u96fe\u5408\u6210\u7684\u7145\u70e7\u7b56\u7565\u6765\u5236\u5907\u591a\u5c42\u7a7a\u5fc3\u7403<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u5236\u5907am<\/sub>ZIF-90\u7eb3\u7c73\u68d2\uff0c\u84b2\u516c\u82f1\u72b6am<\/sub>ZIF-90\u7ec4\u5408\uff0cam<\/sub>ZIF-90\u652f\u6491\u7684\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\uff0c\u591a\u5c42CuO\/ZnO\u7a7a\u5fc3\u7403\u793a\u610f\u56fe\uff1b\u00a0<\/p>\n

b\uff09\u5feb\u901f\u7145\u70e7\u540e\u5408\u6210\u7684ZnO\/CuO\u591a\u5c42\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\u548cEDX\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n

\u56fe<\/b><\/strong>10<\/b><\/strong>\u00a0\u4ece\u539f\u59cb\u7a7a\u5fc3\u7403\u884d\u751f\u7684\u4e0d\u540c\u4e2d\u7a7a\u50ac\u5316\u88c5\u7f6e\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/b><\/strong>11<\/b><\/strong>\u00a0\u901a\u8fc7Au\u6a21\u677f\u548c<\/b><\/strong>\u5176<\/b><\/strong>\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u4e4b\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u5f62\u6210Au<\/b><\/strong>x<\/b><\/sub><\/strong>M<\/b><\/strong>y<\/b><\/sub><\/strong>\u5408\u91d1<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a)\u901a\u8fc7Au\u7eb3\u7c73\u56e2\u7c07\uff08AuNC\uff09\u548c\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u4e4b\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u5236\u5907\u7684Au\u5408\u91d1\u4e2d\u7a7a\u7eb3\u7c73\u68d2\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

b\uff09\u539f\u59cbAuNC\u7ec4\u5408\u548c\u4e0eCu(NO3<\/sub>)2<\/sub>\u53cd\u5e94\u540e\u5f62\u6210\u7684\u5178\u578b\u7ba1\u72b6\u7ed3\u6784\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/b><\/strong>12<\/b><\/strong>\u00a0\u4f7f\u7528Zn\u63ba\u6742\u7684SiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7a7a\u5fc3\u7403\u4f5c\u4e3a\u8f7d\u4f53\u5408\u6210\u4e86\u4e00\u7cfb\u5217Ru\/ZnO\/Zn-SiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7eb3\u7c73\u50ac\u5316\u5242<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u7531SiO2<\/sub>\u524d\u4f53\u5f62\u6210\u677f\u4ea4\u9519\u7684Zn\u63ba\u6742\u7684SiO2<\/sub>\uff0c\u968f\u540e\u9010\u6b65\u6c89\u79efZnO\u548cRu\u7eb3\u7c73\u9897\u7c92\u7684\u5408\u6210\u6d41\u7a0b\u56fe\uff1b\u00a0<\/p>\n

b\uff09\u6240\u5236\u5907\u7684\u591a\u5b54Zn-SiO2<\/sub>\u7a7a\u5fc3\u7403\u548cRu\/ZnO\/Zn-SiO2<\/sub>\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

c\uff09\u8fc7\u6e21\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u58f3\u6c89\u79ef\u5230AuNC\u7684\u7ec4\u5408\u7269\u4e0a\u7684\u793a\u610f\u56fe\uff0c\u6240\u8ff0AuNCs\u6765\u81ea\u5438\u9644\u6709MDBS\u590d\u5408\u7269\u7684\u77ac\u6001AuNCs\uff1b\u00a0<\/p>\n

d\uff09\u5236\u5907\u7684AuNCs@Co(OH)2<\/sub>\u548cAuNCs@Ni(OH)2<\/sub>\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/b><\/strong>13<\/b><\/strong>\u00a0\u4ece\u5177\u6709\u4e24\u4e2a\u4e0d\u540c\u6d82\u5c42\u58f3\u7684\u6838<\/b><\/strong>–<\/b><\/strong>\u58f3\u524d\u4f53\u83b7\u5f97<\/b><\/strong>\u86cb\u9ec4\u6838\u58f3\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u793a\u610f\u56fe\uff1ai\uff09\u7531NP@SiO2<\/sub>\u6838-\u58f3\u7ed3\u6784\u5408\u6210\u7684NP@MS \uff0cii\uff09\u7531CNT@NPs@SiO2<\/sub>\u7ed3\u6784\u5236\u5907\u7684CNT @NNs@MS\u7ed3\u6784\uff0c\u5176\u4e2dNPs\u5d4c\u5165\u5728CNT\u548cSiO2<\/sub>\u58f3\u4e4b\u95f4\uff0c\u4e24\u79cd\u60c5\u51b5\u4e0bSiO2<\/sub>\u90fd\u8d77\u5230\u727a\u7272\u6a21\u677f\u7684\u4f5c\u7528\uff1b\u00a0<\/p>\n

b\uff09Au@SiO2<\/sub>\u6838-\u58f3\u548cAu@MS\u86cb\u9ec4-\u58f3\u7ed3\u6784\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

c\uff09CNT@Au-Pd@SiO2<\/sub>\u6838-\u58f3\u548cCNT@Au-Pd@MS\u86cb\u9ec4\u56fa\u5b9a\u7ed3\u6784\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

d\uff09\u7531\u4ecb\u5b54SiO2<\/sub>\u7a7a\u5fc3\u7403\u5236\u5907\u7684NPs@mSiO2<\/sub>\u86cb\u9ec4-\u58f3\u548c\u6447\u52a8\u578b\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u5176\u4e2di\uff09\u901a\u8fc7Ostwald\u719f\u5316\u548c\u5185\u90e8\u7eb3\u7c73\u9897\u7c92\u7684\u540e\u7ec4\u88c5\u4ea7\u751f\u5185\u90e8\u7a7a\u95f4\uff0cii\uff09\u5c06\u7eb3\u7c73\u9897\u7c92\u5305\u542b\u5728\u4e2d\u5fc3\u7a7a\u95f4\u4e2d\uff0c\u540c\u65f6\u4ece\u8def\u7ebf\uff08i\uff09\u5408\u6210SiO2<\/sub>\u7a7a\u5fc3\u7403\uff0ciii\uff09\u901a\u8fc7\u8f6f\u6a21\u677f\u65b9\u6cd5\u5236\u5907SiO2<\/sub>\u7a7a\u5fc3\u7403\uff0c\u5c06\u7eb3\u7c73\u7c92\u5b50\u5305\u5c01\u5230\u8f6f\u6a21\u677f\u4e2d\uff1b\u00a0<\/p>\n

e\uff09\u7531\u8def\u7ebf\uff08i\uff09\u5236\u5907\u7684\u5177\u6709\u7c97\u7cd9\u5185\u90e8\u7684\u4ecb\u5b54SiO2<\/sub>\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\uff1b\u00a0<\/p>\n

f\uff09\u901a\u8fc7\u8def\u7ebfi\uff09\u5236\u5907\u7684Au@SiO2<\/sub>\u86cb\u9ec4-\u58f3\u7ed3\u6784\u548c\u901a\u8fc7\u8def\u7ebfii\uff09\u548c\u8def\u7ebfiii\uff09\u5236\u5907\u7684Co3<\/sub>O4<\/sub>\u00a0@SiO2<\/sub>\u62e8\u6d6a\u9f13\u578b\u7ed3\u6784\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/b><\/strong>14<\/b><\/strong>\u00a0MoO<\/b><\/strong>2<\/b><\/sub><\/strong>@SiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u7ed3\u6784\u7684\u5408\u6210<\/b><\/strong>\u6d41\u7a0b\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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b\uff09MoO2<\/sub>@SiO2<\/sub>\u62e8\u6d6a\u9f13\u578b\u7684SEM\u548cTEM\u56fe\u50cf\uff1b<\/p>\n

c\uff09\u5206\u6b65\u5408\u6210\u7684Al2<\/sub>O3<\/sub>@mAl-\u7845\u9178\u76d0\u548c\u8fdb\u4e00\u6b65\u7684NP\u6c89\u79ef\u4ea7\u751f\u7684NPs@Al2<\/sub>O3<\/sub>@mAl-\u7845\u9178\u76d0\u7684\u793a\u610f\u6027\u6d41\u7a0b\u56fe\uff1b<\/p>\n

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\u56fe<\/b><\/strong>15<\/b><\/strong>\u00a0<\/b><\/strong>\u7531<\/b><\/strong>TiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u5f00\u53d1TiO<\/b><\/strong>2<\/b><\/sub><\/strong>@PAN\u7684\u5408\u6210\u7eb3\u7c73\u9897\u7c92\u5206\u6563\u5728\u805a\u82ef\u80fa\u58f3\u7684\u5185\u8868\u9762<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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b\uff09TiO2<\/sub>\u7403\uff0cTiO2<\/sub>\u7eb3\u7c73\u7c92\u5b50\u548c\u8d1f\u8f7d\u4e8c\u6c27\u5316\u7845\u7403TiO2<\/sub>\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

c\uff09TiO2<\/sub>@PAN\u5185\u90e8\u56fa\u5b9a\u7a7a\u5fc3\u7403\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u3010\u7ed3\u8bba\u4e0e\u5c55\u671b\u3011<\/b><\/strong><\/p>\n

\u5728\u8fc7\u53bb\u7684\u4e8c\u5341\u5e74\u4e2d\uff0c\u7a7a\u5fc3\u50ac\u5316\u88c5\u7f6e\u5728\u591a\u76f8\u50ac\u5316\u9886\u57df\u5df2\u7ecf\u4ea7\u751f\u4e86\u6839\u672c\u6027\u7684\u5f71\u54cd\uff0c\u5b83\u4eec\u5728\u53cd\u5e94\u6d3b\u6027\uff0c\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\u65b9\u9762\u7684\u72ec\u7279\u4f18\u52bf\u662f\u4f20\u7edf\u50ac\u5316\u5242\u6240\u4e0d\u5177\u5907\u7684\u3002\u5728\u672c\u62a5\u544a\u4e2d\uff0c\u8be5\u56e2\u961f\u603b\u7ed3\u4e86\u7528\u4e8e\u5236\u5907\u5177\u6709\u590d\u6742\u7ec4\u6210\u548c\u5f62\u6001\u7684\u6d3b\u6027\u4e2d\u7a7a\u50ac\u5316\u88c5\u7f6e\u7684\u4ee3\u8868\u6027\u8bbe\u8ba1\uff0c\u5408\u6210\u548c\u529f\u80fd\u5316\u65b9\u6cd5\u3002\u6839\u636e\u76ee\u6807\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u7ed3\u6784\u8bbe\u8ba1\uff0c\u6240\u6709\u65b9\u6cd5\u53ef\u4ee5\u4ee5\u591a\u79cd\u65b9\u5f0f\u8fdb\u4e00\u6b65\u7ec4\u5408\u4ee5\u4ea7\u751f\u5177\u6709\u66f4\u591a\u7ec4\u6210\u548c\u5f62\u6001\u590d\u6742\u6027\u7684\u4e2d\u7a7a\u6750\u6599\u3002\u4f46\u662f\uff0c\u5236\u9020\u590d\u6742\u7684\u4e2d\u7a7a\u50ac\u5316\u88c5\u7f6e\u9700\u8981\u540c\u65f6\u63a7\u5236\u5c3a\u5bf8\uff0c\u5f62\u6001\uff0c\u7ec4\u6210\u548c\u5b54\u9699\u7387\uff0c\u8fd9\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n

\u6587\u732e\u8fde\u63a5\uff1a<\/b><\/strong>Architecture and Preparation of Hollow Catalytic Devices<\/b><\/u><\/strong><\/a>\uff08<\/b><\/strong>Adv. Mater.<\/b><\/strong>, 2018, DOI: 10.1002\/adma.201801104\uff09<\/b><\/strong><\/p>\n

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