{"id":155638,"date":"2018-10-14T06:30:11","date_gmt":"2018-10-13T22:30:11","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=155638"},"modified":"2018-10-13T21:00:48","modified_gmt":"2018-10-13T13:00:48","slug":"%e4%b8%8a%e6%b5%b7%e4%ba%a4%e9%80%9a%e5%a4%a7%e5%ad%a6%e4%bf%9e%e7%82%9cmacromolecules-%e5%9c%a8%e5%8a%a8%e6%80%81%e4%b8%8d%e5%af%b9%e7%a7%b0%e8%81%9a%e5%b7%b1%e5%86%85%e9%85%af-%e8%8b%af%e4%b9%99","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=155638","title":{"rendered":"\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u4fde\u709cMacromolecules: \u5728\u52a8\u6001\u4e0d\u5bf9\u79f0\u805a\u5df1\u5185\u916f\/\u82ef\u4e59\u70ef\u4e19\u70ef\u8148\u5d4c\u6bb5\u5171\u805a\u7269\u4e2d\u7684\u94fe\u6bb5\u548c\u672b\u7aef\u7684\u5f1b\u8c6b\u51cf\u901f"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u7406\u89e3\u805a\u5408\u7269\u5171\u6df7\u7269\u4e2d\u7684\u5206\u5b50\u52a8\u529b\u5b66\u5728\u9ad8\u5206\u5b50\u7269\u7406\u7814\u7a76\u4e2d\u5177\u6709\u5341\u5206\u91cd\u8981\u7684\u610f\u4e49\u3002\u6df1\u5165\u7684\u5b9e\u9a8c\u548c\u6a21\u62df\u7814\u7a76\u8bc1\u5b9e\u4e86\u52a8\u6001\u591a\u76f8\u6027\u5728\u805a\u5408\u7269\u5171\u6df7\u7269\u4e2d\u7684\u5b58\u5728\uff0c\u4f53\u73b0\u4e3a\u73bb\u7483\u5316\u8f6c\u53d8\u7684\u62d3\u5bbd\u3001\u94fe\u6bb5\u5f1b\u8c6b\u6a21\u5f0f\u7684\u5e7f\u6cdb\u5206\u5e03\uff0c\u4ee5\u53ca\u70ed\u6d41\u53d8\u7684\u590d\u6742\u6027\u3002<\/p>\n

\u5c40\u90e8\u7684\u5206\u5b50\u52a8\u529b\u5b66\u5728\u94fe\u6bb5\u5c3a\u5ea6\u4e0a\u5bf9\u73bb\u7483\u5316\u8f6c\u53d8\u6709\u5f88\u5927\u7684\u5f71\u54cd\u3002\u5b9e\u9a8c\u53d1\u73b0\uff0c\u5e7f\u6cdb\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u4e3b\u8981\u6765\u6e90\u4e8e\u4e24\u4e2a\u65b9\u9762\uff0c\u4e00\u4e2a\u662f\u6bcf\u4e00\u79cd\u7ec4\u4efd\u7684\u94fe\u6bb5\u8fd0\u52a8\u901f\u7387\u7684\u5e7f\u6cdb\u5206\u5e03\uff0c\u53e6\u4e00\u4e2a\u662f\u4e0d\u540c\u7ec4\u4efd\u8fd0\u52a8\u901f\u7387\u7684\u672c\u8d28\u533a\u522b\u3002\u57fa\u4e8e\u5c40\u90e8\u73af\u5883\u7684\u7406\u8bba\u6a21\u578b\u88ab\u63d0\u51fa\u6765\u7528\u6765\u89e3\u91ca\u94fe\u6bb5\u52a8\u529b\u5b66\u3002\u70ed\u9a71\u52a8\u5bfc\u81f4\u7684\u6d53\u5ea6\u6ce2\u52a8\u88ab\u8ba4\u4e3a\u662f\u7279\u5b9a\u94fe\u6bb5\u5468\u56f4\u7684\u5206\u5b50\u95f4\u7ec4\u4efd\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u8fd9\u4e2a\u53ef\u4ee5\u7528\u6765\u89e3\u91ca\u5b9e\u9a8c\u4e2d\u6240\u89c2\u5bdf\u5230\u7684\u975e\u5e38\u660e\u663e\u7684\u5f1b\u8c6b\u6269\u5927\u73b0\u8c61\u3002\u5206\u5b50\u5185\u94fe\u8fde\u63a5\u4f5c\u4e3a\u81ea\u6d53\u5ea6\u6a21\u578b\u7684\u6838\u5fc3\uff0c\u53ef\u4ee5\u7528\u6765\u89e3\u91ca\u5171\u6df7\u7269\u6240\u5177\u6709\u7684\u4e0d\u540c\u52a8\u6001\u6027\u8d28\u3002\u70ed\u6d53\u5ea6\u6ce2\u52a8\u548c\u94fe\u8fde\u63a5\u53ef\u4ee5\u88ab\u7528\u6765\u7814\u7a76\u94fe\u6bb5\u52a8\u529b\u5b66\u95ee\u9898\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u4fde\u709c<\/strong>\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5229\u7528\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\u3001\u5bbd\u9891\u4ecb\u7535\u8c31\u548c\u6d41\u53d8\u6d4b\u8bd5\u6765\u7814\u7a76SAN\u548cPCL\u805a\u5408\u7269\u5171\u6df7\u7269\u4e2d\u7684\u5206\u5b50\u5f1b\u8c6b\u884c\u4e3a\u3002\u5f53\u6e29\u5ea6\u964d\u4f4e\u65f6\uff0c\u94fe\u6bb5\u5c3a\u5ea6\u548c\u5206\u5b50\u94fe\u5c3a\u5ea6\u7684\u5f1b\u8c6b\u6b21\u6570\u548c\u5f1b\u8c6b\u8c31\u56fe\u5bbd\u5ea6\u90fd\u4f1a\u589e\u52a0\u3002\u4e24\u79cd\u4e0d\u540c\u957f\u5ea6\u5c3a\u5ea6\u7684\u5f1b\u8c6b\u6b21\u6570\u662f\u7ebf\u6027\u76f8\u5173\u7684\u3002\u540c\u65f6\uff0c\u7814\u7a76\u53d1\u73b0\u5f53\u6e29\u5ea6\u4e0e\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u76f8\u8fd1\u65f6\uff0c\u672b\u7aef\u5f1b\u8c6b\u5bbd\u5ea6\u4f1a\u5927\u4e8e\u94fe\u6bb5\u5f1b\u8c6b\u5bbd\u5ea6\u3002\u7531\u6b64\u8bf4\u660e\u7531\u4e8ePCL\u548cSAN\u4e4b\u95f4\u7684\u7279\u5b9a\u4f5c\u7528\uff0c\u5728\u6709\u6548\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u4e0b\u7684\u94fe\u6bb5\u5f1b\u8c6b\u65f6\u95f4\u662f\u4f9d\u8d56\u4e8e\u7ec4\u4efd\u7684\u3002\u901a\u8fc7\u7ed3\u5408\u65f6\u95f4\u4f9d\u8d56\u7684\u53cc\u91cd\u722c\u884c\u6a21\u578b(TDD-DR)\u3001\u81ea\u6d53\u5ea6\u548c\u6d53\u5ea6\u6ce2\u52a8\u6a21\u578b(SCCF)\u548c\u6709\u6548\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u4e0b\u7684\u94fe\u6bb5\u5f1b\u8c6b\u65f6\u95f4\uff0c\u6211\u4eec\u53ef\u4ee5\u9884\u6d4bSAN\/PCL\u7684\u7c98\u5f39\u6027\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Simultaneous Slowdown of Segmental and Terminal Relaxation of Both Components in Dynamically Asymmetric Poly(<\/strong>\u2107<\/em><\/strong>-caprolactone)\/Poly(styrene-<\/strong>co<\/em><\/strong>-acrylonitrile) Blends<\/strong>“\u53d1\u8868\u5728Macromolecules<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

Figure <\/strong>1<\/strong>.<\/strong>SAN<\/strong>\u3001<\/strong>PCL\u53ca\u5176\u5171\u6df7\u7269\u7684\u8868\u5f81<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

(a).SAN\u3001PCL\u53ca\u5176\u5171\u6df7\u7269\u7684\u70ed\u5bb9<\/p>\n

(b).SAN\u3001PCL\u53ca\u5176\u5171\u6df7\u7269\u7684\u793a\u5dee\u66f2\u7ebf<\/p>\n

(c).\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u968f\u7ec4\u4efd\u7684\u53d8\u5316<\/p>\n

Figure <\/strong>2<\/strong>.<\/strong>\u4e0d\u540c\u7ec4\u4efd\u5171\u6df7\u7269\u7684\u4ecb\u7535\u635f\u8017<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

(ab).\u7eafSAN\u548cSAN\/PCL=70\/30\u5171\u6df7\u7269\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u4ecb\u7535\u635f\u8017<\/p>\n

(cd).\u5f52\u4e00\u5316\u540e\u7684\u76f8\u5173\u6570\u636e<\/p>\n

\u56fe<\/strong>3<\/strong>.<\/strong>\u94fe\u6bb5\u5f1b\u8c6b\u65f6\u95f4\u7684\u6e29\u5ea6\u4f9d\u8d56\u548c\u6e29\u5ea6\u5dee\u4f9d\u8d56<\/strong><\/p>\n

\"\"<\/p>\n

(a).\u94fe\u6bb5\u5f1b\u8c6b\u65f6\u95f4\u7684\u6e29\u5ea6\u4f9d\u8d56<\/p>\n

(b).\u00a0<\/strong>\u94fe\u6bb5\u5f1b\u8c6b\u65f6\u95f4\u7684\u6e29\u5ea6\u5dee\u4f9d\u8d56<\/p>\n

\u56fe<\/strong>4<\/strong>.<\/strong>SAN\/PCL\u5171\u6df7\u7269\u7684\u4ecb\u7535\u5f1b\u8c6b\u5bbd\u5ea6\u7684\u6e29\u5ea6\u4f9d\u8d56\u548c\u6e29\u5ea6\u5dee\u4f9d\u8d56<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

(a).SAN\/PCL\u5171\u6df7\u7269\u7684\u4ecb\u7535\u5f1b\u8c6b\u5bbd\u5ea6\u7684\u6e29\u5ea6\u4f9d\u8d56<\/p>\n

(b).SAN\/PCL\u5171\u6df7\u7269\u7684\u4ecb\u7535\u5f1b\u8c6b\u5bbd\u5ea6\u7684\u6e29\u5ea6\u5dee\u4f9d\u8d56<\/p>\n

\u56fe<\/strong>5<\/strong>.<\/strong>SAN\u548cSAN\/PCL\u5728\u4e0d\u540c\u6e29\u5ea6\u65f6\u7684\u52a8\u6001\u7c98\u5ea6<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

(a).SAN\u5728\u4e0d\u540c\u6e29\u5ea6\u65f6\u7684\u52a8\u6001\u7c98\u5ea6<\/p>\n

(b).SAN\/PCL\u5728\u4e0d\u540c\u6e29\u5ea6\u65f6\u7684\u52a8\u6001\u7c98\u5ea6<\/p>\n

\u56fe<\/strong>6<\/strong>.<\/strong>SAN\u3001PCL\u548cSAN\/PCL\u5171\u6df7\u7269\u5728\u4e0d\u540c\u6e29\u5ea6\u548c\u76f8\u5bf9\u6e29\u5ea6\u4e0b\u7684\u94fe\u5f1b\u8c6b\u65f6\u95f4<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

(a).SAN\u3001PCL\u548cSAN\/PCL\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u94fe\u5f1b\u8c6b\u65f6\u95f4<\/p>\n

(b).SAN\u3001PCL\u548cSAN\/PCL\u5728\u4e0d\u540c\u76f8\u5bf9\u6e29\u5ea6\u4e0b\u7684\u94fe\u5f1b\u8c6b\u65f6\u95f4<\/p>\n

\u56fe<\/strong>7<\/strong>.<\/strong>SAN\u3001PCL\u548cSAN\/PCL\u5171\u6df7\u7269\u672b\u7aef\u5f1b\u8c6b\u5bbd\u5ea6\u7cfb\u6570\u5728\u4e0d\u540c\u6e29\u5ea6\u548c\u76f8\u5bf9\u6e29\u5ea6\u4e0b\u7684\u94fe\u5f1b\u8c6b\u65f6\u95f4<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>8<\/strong>.<\/strong>SAN\u548cSAN\/PCL\u5171\u6df7\u7269\u94fe\u5f1b\u8c6b\u65f6\u95f4\u548c\u94fe\u6bb5\u5f1b\u8c6b\u65f6\u95f4\u7684\u6bd4\u8f83<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>9<\/strong>.<\/strong>SAN\u548cSAN\/PCL\u5171\u6df7\u7269\u94fe\u5f1b\u8c6b\u5bbd\u5ea6\u7cfb\u6570\u548c\u94fe\u6bb5\u5f1b\u8c6b\u5bbd\u5ea6\u7cfb\u6570\u7684\u6bd4\u8f83<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>10<\/strong>.<\/strong>\u76f8\u5bf9\u94fe\u6bb5\u5f1b\u8c6b\u65f6\u95f4\u7684\u76f8\u5bf9\u65f6\u95f4\u4f9d\u8d56<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>11<\/strong>.<\/strong>SAN\u548cPCL\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u7ebf\u6027\u7c98\u5f39\u6027<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>12<\/strong>.<\/strong>TDD-DR-SCCF\u6a21\u578b\u9884\u6d4b\u548c\u5b9e\u9a8c\u6570\u636e\u7684\u6bd4\u8f83<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u5229\u7528\u5229\u7528\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\u3001\u5bbd\u9891\u4ecb\u7535\u8c31\u548c\u6d41\u53d8\u6d4b\u8bd5\u6765\u7814\u7a76SAN\u548cPCL\u805a\u5408\u7269\u5171\u6df7\u7269\u4e2d\u7684\u5206\u5b50\u5f1b\u8c6b\u884c\u4e3a\u3002\u5f53\u6e29\u5ea6\u964d\u4f4e\u65f6\uff0c\u94fe\u6bb5\u5c3a\u5ea6\u548c\u5206\u5b50\u94fe\u5c3a\u5ea6\u7684\u5f1b\u8c6b\u6b21\u6570\u548c\u5f1b\u8c6b\u8c31\u56fe\u5bbd\u5ea6\u90fd\u4f1a\u589e\u52a0\u3002\u4e24\u79cd\u4e0d\u540c\u957f\u5ea6\u5c3a\u5ea6\u7684\u5f1b\u8c6b\u6b21\u6570\u662f\u7ebf\u6027\u76f8\u5173\u7684\u3002\u540c\u65f6\uff0c\u7814\u7a76\u53d1\u73b0\u5f53\u6e29\u5ea6\u4e0e\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u76f8\u8fd1\u65f6\uff0c\u672b\u7aef\u5f1b\u8c6b\u5bbd\u5ea6\u4f1a\u5927\u4e8e\u94fe\u6bb5\u5f1b\u8c6b\u5bbd\u5ea6\u3002\u7531\u6b64\u8bf4\u660e\u7531\u4e8ePCL\u548cSAN\u4e4b\u95f4\u7684\u7279\u5b9a\u4f5c\u7528\uff0c\u5728\u6709\u6548\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u4e0b\u7684\u94fe\u6bb5\u5f1b\u8c6b\u65f6\u95f4\u662f\u4f9d\u8d56\u4e8e\u7ec4\u4efd\u7684\u3002\u901a\u8fc7\u7ed3\u5408\u65f6\u95f4\u4f9d\u8d56\u7684\u53cc\u91cd\u722c\u884c\u6a21\u578b(TDD-DR)\u3001\u81ea\u6d53\u5ea6\u548c\u6d53\u5ea6\u6ce2\u52a8\u6a21\u578b(SCCF)\u548c\u6709\u6548\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u4e0b\u7684\u94fe\u6bb5\u5f1b\u8c6b\u65f6\u95f4\uff0c\u6211\u4eec\u53ef\u4ee5\u9884\u6d4bSAN\/PCL\u7684\u7c98\u5f39\u6027\u3002\u3002<\/p>\n

Simultaneous Slowdown of Segmental and Terminal Relaxation of Both Components in Dynamically Asymmetric Poly(\u2107<\/em>-caprolactone)\/Poly(styrene-co<\/em>-acrylonitrile) Blends.<\/a><\/p>\n

(Macromolecules, 2018, DOI: 10.1021\/acs.macromol.8b01214)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0<\/p>\n

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