{"id":156089,"date":"2018-10-12T06:30:22","date_gmt":"2018-10-11T22:30:22","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=156089"},"modified":"2018-10-11T19:35:23","modified_gmt":"2018-10-11T11:35:23","slug":"%e6%b0%94%e4%bd%93%e5%88%86%e7%a6%bbscience%e5%ad%90%e5%88%8a%ef%bc%9a%e5%a4%9a%e5%ad%94%e6%9c%89%e6%9c%ba%e9%aa%a8%e6%9e%b6%e8%96%84%e8%86%9c%e7%94%a8%e4%ba%8e%e7%87%83%e7%83%a7%e5%89%8d%e6%8d%95","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=156089","title":{"rendered":"\u6c14\u4f53\u5206\u79bbScience\u5b50\u520a\uff1a\u591a\u5b54\u6709\u673a\u9aa8\u67b6\u8584\u819c\u7528\u4e8e\u71c3\u70e7\u524d\u6355\u96c6\u4e8c\u6c27\u5316\u78b3"},"content":{"rendered":"<p>\u3010<strong>\u6982\u8ff0<\/strong>\u3011<\/p>\n<p>\u5316\u77f3\u71c3\u6599\u7684\u4e00\u5927\u7f3a\u70b9\u5c31\u662f\u5728\u71c3\u70e7\u8fc7\u7a0b\u4f1a\u4ea7\u751f\u5927\u91cf\u4e8c\u6c27\u5316\u78b3\u7b49\u6e29\u5ba4\u6c14\u4f53\uff0c\u4ece\u800c\u52a0\u5267\u6e29\u5ba4\u6548\u5e94\u662f\u5f97\u6c14\u5019\u73af\u5883\u8fdb\u4e00\u6b65\u6076\u5316\u3002\u7136\u800c\u9664\u975e\u53ef\u518d\u751f\u80fd\u6e90\u5728\u6210\u672c\u4e0a\u80fd\u591f\u5408\u7406\u5316\uff0c\u5728\u6b64\u4e4b\u524d\u5316\u77f3\u80fd\u6e90\u4f9d\u7136\u662f\u4eba\u7c7b\u4e0d\u53ef\u6216\u7f3a\u7684\u80fd\u91cf\u6765\u6e90\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u9ad8\u6548\u6355\u96c6\u4e8c\u6c27\u5316\u78b3\u5c31\u662f\u4f18\u5316\u5316\u77f3\u80fd\u6e90\u4f7f\u7528\u7684\u5f53\u52a1\u4e4b\u6025\u3002\u4f20\u7edf\u5de5\u4e1a\u7684\u65b9\u6cd5\u8f83\u5e38\u7528\u80fa\u6eb6\u6db2\u7684\u6d17\u8131\u6280\u672f\u6765\u5b9e\u73b0\u5e9f\u6c14\u4e2d\u4e8c\u6c27\u5316\u78b3\u7684\u6d88\u9664\uff0c\u8fd9\u4e00\u65b9\u6cd5\u80fd\u91cf\u6d88\u8017\u5de8\u5927\uff0c\u8bbe\u5907\u6210\u672c\u9ad8\uff0c\u4e9f\u9700\u6548\u7387\u66f4\u9ad8\u3001\u66f4\u73af\u4fdd\u7684\u65b9\u6cd5\u8fdb\u884c\u66ff\u4ee3\u3002\u591a\u5b54\u6750\u6599\u4ee5\u5176\u8f83\u9ad8\u7684\u6c14\u4f53\u5438\u9644\u91cf\u3001\u6613\u8131\u9644\u4ee5\u53ca\u9ad8\u9009\u62e9\u6027\u7b49\u7279\u70b9\u6210\u4e3a\u4e86\u7814\u7a76\u4eba\u5458\u5bfb\u6c42\u66ff\u4ee3\u65b9\u6848\u7684\u4e3b\u8981\u65b9\u5411\u3002<\/p>\n<p>\u5229\u7528\u57fa\u4e8e\u591a\u5b54\u6750\u6599\u7684\u8584\u819c\u6765\u5438\u9644\u5206\u79bb\u4e8c\u6c27\u5316\u78b3\u5177\u6709\u64cd\u4f5c\u7b80\u4fbf\u3001\u9ad8\u6548\u73af\u4fdd\u7684\u7279\u70b9\uff0c\u7136\u800c\u819c\u6750\u6599\u81ea\u8eab\u5438\u9644\u9009\u62e9\u6027\u5dee\u3001\u6613\u8001\u5316\u7b49\u95ee\u9898\u4e00\u76f4\u963b\u788d\u7740\u76f8\u5173\u5de5\u4e1a\u6280\u672f\u7684\u53d1\u5c55\u3002\u4ee5\u591a\u5b54\u6709\u673a\u9aa8\u67b6\uff08POFs\uff09\u819c\u4e3a\u4f8b\uff0cPOFs\u7684\u5b54\u5f84\u76f8\u5bf9\u8f83\u5927\uff0c\u5e76\u4e14\u76ee\u524d\u5236\u5907\u8fde\u7eed\u65e0\u7f3a\u9677\u819c\u7684\u6280\u672f\u4f9d\u7136\u4e0d\u6210\u719f\uff0c\u81f4\u4f7fPOF\u57fa\u819c\u6750\u6599\u7684\u6c14\u4f53\u5206\u79bb\u6027\u80fd\u5927\u6253\u6298\u6263\u3002\u9488\u5bf9\u5927\u5b54\u7684\u95ee\u9898\uff0c\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u4e86\u82ef\u5e76\u54aa\u5511\u5355\u5143\u8fde\u63a5\u7684\u6709\u673a\u591a\u5b54\u805a\u5408\u7269\uff08BILPs\uff09\uff0c\u8fd9\u7c7bPOFs\u7684\u5b54\u5f84\u76f8\u5bf9\u72ed\u5c0f\uff0c\u4e0d\u4ec5\u66f4\u6613\u4e8e\u5438\u6536\u4e8c\u6c27\u5316\u78b3\uff0c\u800c\u4e14\u70ed\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u4e5f\u975e\u5e38\u597d\u3002\u4f46\u662fBILPs\u4e0d\u6eb6\u4e8e\u5927\u591a\u6570\u6eb6\u5242\uff0c\u4f7f\u5f97\u5236\u5907BILPs\u57fa\u8584\u819c\u53d8\u5f97\u6781\u5177\u6311\u6218\u6027\u3002<strong>\u8377\u5170\u4ee3\u5c14\u592b\u7279\u7406\u5de5\u5927\u5b66\u7684<\/strong><strong>Jorge Gascon<\/strong>\u8bfe\u9898\u7ec4\u5229\u7528\u5ba4\u6e29\u754c\u9762\u805a\u5408\uff08IP\uff09\u7684\u65b9\u6cd5\u6210\u529f\u5236\u5907\u4e86\u65e0\u7f3a\u9677\u7684BILPs\u8584\u819c\uff08BILP-101x\uff09\uff0c\u5e76\u4e14\u8fd9\u4e00\u8584\u819c\u5728\u6c22\u6c14\/\u4e8c\u6c27\u5316\u78b3\u5206\u79bb\u65b9\u9762\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u30022018\u5e749\u670821\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Facile manufacture of porous organic framework membranes for precombustion CO2 capture<\/strong>\u201d\u5728\u7ebf\u53d1\u8868\u5728<strong>Science Advances<\/strong>\u4e0a\u3002<\/p>\n<p>\u3010<strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-156090\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe1.jpg\" alt=\"\" width=\"600\" height=\"433\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe1.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe1-300x217.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>1 BILP-101<\/strong><strong>\uff08<\/strong><strong>Chem. Commun. 51, 13393\u201313396 (2015)<\/strong><strong>\uff09<\/strong><\/p>\n<p>BILP-101\u8fd9\u4e00\u5438\u9644\u5242\u6700\u65e9\u4e8e2015\u5e74\u7531\u7f8e\u56fd\u56fd\u5bb6\u80fd\u6e90\u6280\u672f\u5b9e\u9a8c\u5ba4\u7684\u7814\u7a76\u4eba\u5458\uff08Chem. Commun. 51, 13393\u201313396 (2015)\uff09\u5f00\u53d1\u800c\u6765\u3002\u8fd9\u4e00\u5438\u9644\u5242\u4e3b\u8981\u5177\u6709\u76f8\u5bf9\u8f83\u5c0f\u7684\u5b54\u5f84\u3001\u8f83\u9ad8\u7684\u5fae\u5b54\u7387\u4ee5\u53ca\u4f18\u5f02\u7684\u7269\u7406\u5316\u5b66\u7a33\u5b9a\u6027\u80fd\u7684\u7279\u70b9\u3002\u5728\u65e9\u5148\u7684\u7814\u7a76\u4e2d\uff0c\u5df2\u7ecf\u8bc1\u660e\u5176\u4e8c\u6c27\u5316\u78b3\u5438\u6536\u6548\u7387\u53ef\u8fbe\u52301 mmol g\u22121\uff084 wt%, 0.15 bar\/298 K\uff09\uff0cCO<sub>2<\/sub>\/N<sub>2<\/sub>\u7684\u9009\u62e9\u5438\u9644\u6027\u80fd\u4e5f\u6bd4\u8f83\u826f\u597d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-156091\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe2.jpg\" alt=\"\" width=\"600\" height=\"320\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe2.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe2-300x160.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>2 BILP-101x<\/strong><strong>\u8584\u819c\u7684\u754c\u9762\u805a\u5408\u8fc7\u7a0b\u4ee5\u53ca\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n<p>\u4ee5\u6b64\u4e3a\u57fa\u7840\uff0cGason\u8bfe\u9898\u7ec4\u7684\u7814\u7a76\u4eba\u5458\u5728\u03b1-Al<sub>2<\/sub>O<sub>3<\/sub>\u591a\u5b54\u57fa\u8d28\u76f4\u63a5\u5236\u5907\u4e86BILP-101x\u8584\u819c\u3002\u5982\u56fe2\u6240\u793a\uff0c\u03b1-Al<sub>2<\/sub>O<sub>3<\/sub>\u5177\u6709\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u9876\u90e8\u7684\u03b3-Al<sub>2<\/sub>O<sub>3<\/sub>\u5219\u62e5\u6709\u4eb2\u6c34\u5c0f\u5b54\u53ef\u4f9b\u754c\u9762\u805a\u5408\u8fc7\u7a0b\u3002\u8fd9\u4e00\u591a\u5b54\u57fa\u8d28\u5148\u540e\u6d78\u6ca1\u5728BTA\u6c34\u6eb6\u6db2\u548cTFB\u7684\u82ef\u6eb6\u6db2\u4e2d\uff0cBTA\u5355\u4f53\u7684\u6c28\u57fa\u4e0eTFB\u7684\u82ef\u6eb6\u6db2\u63a5\u89e6\uff0c\u5728\u82ef\/\u6c34\u754c\u9762\u4e0e\u919b\u8fc5\u901f\u53cd\u5e94\u5f62\u6210\u8584\u5c42\u3002\u8584\u5c42\u8fdb\u800c\u751f\u957f\u6210\u819c\uff0c\u5e76\u963b\u6321\u5355\u4f53\u4e4b\u95f4\u7684\u63a5\u89e6\u9a71\u4f7f\u53cd\u5e94\u5728\u4ecd\u5b58\u5728\u7684\u7f3a\u9677\u4e2d\u8fdb\u884c\uff0c\u6700\u7ec8\u5728\u57fa\u8d28\u8868\u9762\u4e0a\u5f62\u6210\u8fde\u7eed\u65e0\u7f3a\u9677\u8584\u819c\u5c42\u3002\u56fe2\u7684SEM\u7b49\u8868\u5f81\u663e\u793a\u8fd9\u4e00\u8584\u819c\u7684\u539a\u5ea6\u5728400nm\u5de6\u53f3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-156092\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe3.jpg\" alt=\"\" width=\"600\" height=\"449\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe3.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe3-300x225.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>3 BILP-101x<\/strong><strong>\u8584\u819c\u7684\u8c31\u5b66\u8868\u5f81\u53ca\u5176\u6c14\u4f53\u5438\u9644\u68c0\u6d4b<\/strong><\/p>\n<p>\u56fe3\u7684\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u548c\u6838\u78c1\u8c31\u63ed\u793a\u4e86\u8584\u819c\u4e2d\u82ef\u5e76\u54aa\u5511\u73af\u7684\u5f62\u6210\u4ee5\u53ca\u90e8\u5206\u919b\u57fa\u56e2\u6b8b\u7559\uff0c\u8bc1\u660e\u4e86TFB\u548cBTA\u6784\u5efa\u6a21\u5757\u6210\u529f\u53d1\u751f\u4e86\u7f29\u805a\u53cd\u5e94\u3002\u6c2e\u6c14\u5438\u9644\u66f2\u7ebf\u8868\u660e\u4e86\u8584\u819c\u7531\u4e00\u5c0f\u90e8\u5206\u5fae\u5b54\uff0817m<sup>2<\/sup> g<sup>\u22121<\/sup>\uff09\u4ee5\u53ca\u6bd4\u8868\u9762\u79ef\u4e3a70m<sup>2<\/sup> g<sup>\u22121<\/sup>\u7684\u5916\u8868\u9762\u7ec4\u6210\u3002\u800c\u4e8c\u6c27\u5316\u78b3\u7684\u5438\u9644\u66f2\u7ebf\u5374\u8868\u660e\uff0c\u8584\u819c\u5bf9\u4e8c\u6c27\u5316\u78b3\u7684\u5438\u9644\u91cf\u7ea6\u4e3a22m<sup>3<\/sup> g<sup>\u22121<\/sup>\uff081bar\uff0c298K\uff09\uff0c\u8fdc\u4f4e\u4e8eBILP-101\u5438\u9644\u5242\u3002\u7814\u7a76\u4eba\u5458\u8ba4\u4e3a\uff0c\u4e4b\u6240\u4ee5\u51fa\u73b0\u8fd9\u6837\u7684\u6027\u80fd\u5dee\u522b\u4e3b\u8981\u662f\u56e0\u4e3a\u8584\u819c\u7ed3\u6784\u4e2d\u805a\u5408\u7269\u7684\u76f8\u4e92\u8d2f\u7a7f\u7a0b\u5ea6\u66f4\u9ad8\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-156093\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe4.jpg\" alt=\"\" width=\"600\" height=\"218\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe4.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/\u56fe4-300x109.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe<\/strong><strong>4 BILP-101x<\/strong><strong>\u8584\u819c\u7684\u6027\u80fd\u68c0\u6d4b<\/strong><\/p>\n<p>\u5236\u5907\u7684BILP-101x\u8584\u819c\u968f\u540e\u88ab\u5b89\u88c5\u5728Wicke-Kallenbach 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href=\"http:\/\/advances.sciencemag.org\/content\/4\/9\/eaau1698.short\" target=\"_blank\" rel=\"noopener\">Facile manufacture of porous organic framework membranes for precombustion CO2 capture<\/a>\uff08Sci. Adv., 2018, DOI: 10.1126\/sciadv.aau1698\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4NanoCJ\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c<a href=\"mailto:\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\">\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6982\u8ff0\u3011 \u5316\u77f3\u71c3\u6599\u7684\u4e00\u5927\u7f3a\u70b9\u5c31\u662f\u5728\u71c3\u70e7\u8fc7\u7a0b\u4f1a\u4ea7\u751f\u5927\u91cf\u4e8c\u6c27\u5316\u78b3\u7b49\u6e29\u5ba4\u6c14\u4f53\uff0c\u4ece\u800c\u52a0\u5267\u6e29\u5ba4\u6548\u5e94\u662f\u5f97\u6c14\u5019\u73af\u5883\u8fdb\u4e00\u6b65\u6076\u5316\u3002\u7136\u800c\u9664\u975e\u53ef\u518d\u751f\u80fd\u6e90\u5728\u6210\u672c\u4e0a\u80fd\u591f\u5408\u7406\u5316\uff0c\u5728\u6b64\u4e4b\u524d\u5316&#8230;<\/p>\n","protected":false},"author":1076,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-156089","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/156089"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1076"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=156089"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/156089\/revisions"}],"predecessor-version":[{"id":156098,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/156089\/revisions\/156098"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=156089"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=156089"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=156089"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}