{"id":156194,"date":"2018-10-14T06:19:56","date_gmt":"2018-10-13T22:19:56","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=156194"},"modified":"2018-10-13T11:20:07","modified_gmt":"2018-10-13T03:20:07","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e6%9d%a8%e4%b8%8a%e5%b3%b0nature-commun-%e4%bb%a5c60%e4%bd%9c%e7%9b%be%e7%89%8c%e7%a8%b3%e5%ae%9a%e9%bb%91%e7%a3%b7%e7%ba%b3%e7%b1%b3%e7%89%87","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=156194","title":{"rendered":"\u4e2d\u79d1\u5927\u6768\u4e0a\u5cf0Nature Commun.: \u4ee5C60\u4f5c\u76fe\u724c\u7a33\u5b9a\u9ed1\u78f7\u7eb3\u7c73\u7247"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u7684\u6768\u4e0a\u5cf0\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u62a5\u9053\u4e86\u901a\u8fc7\u5c06\u5bcc\u52d2\u70efC60<\/sub>\u5206\u5b50\u9009\u62e9\u6027\u5730\u5171\u4ef7\u8fde\u63a5\u5728\u9ed1\u78f7\u7eb3\u7c73\u7247\u8fb9\u7f18\u5f62\u6210\u9ed1\u78f7-C60<\/sub>\u6742\u5316\u6750\u6599\uff0c\u5229\u7528\u5bcc\u52d2\u70ef\u7684\u9ad8\u7a33\u5b9a\u6027\u5c06\u5176\u7528\u4f5c\u4fdd\u62a4\u76fe\u724c\uff0c\u663e\u8457\u63d0\u9ad8\u4e86BP\u7eb3\u7c73\u7247\u5728\u6c34\u4e2d\u7684\u7a33\u5b9a\u6027\u3002\u7531\u4e8e\u758f\u6c34\u6027C60<\/sub>\u5206\u5b50\u7684\u9ad8\u7a33\u5b9a\u6027\uff0cC60<\/sub>\u8d77\u5230\u727a\u7272\u76fe\u724c\u7684\u4f5c\u7528\uff0c\u4ece\u800c\u6709\u6548\u5730\u4fdd\u62a4BP\u7eb3\u7c73\u7247\u5728\u81ea\u7136\u6761\u4ef6\u4e0b\u4e0d\u88ab\u6c27\u5316\u3002\u6b64\u5916\uff0c\u7531\u4e8eC60<\/sub>\u5177\u6709\u5f3a\u7684\u63a5\u53d7\u7535\u5b50\u7684\u80fd\u529b\uff0c\u5f62\u6210\u9ed1\u78f7-C60<\/sub>\u6742\u5316\u6750\u6599\u540e\u53ef\u4ee5\u53d1\u751f\u9ed1\u78f7\u5230C60<\/sub>\u7684\u5149\u8bf1\u5bfc\u7535\u5b50\u8f6c\u79fb\uff0c\u4ece\u800c\u663e\u8457\u5730\u63d0\u5347\u4e86\u5c11\u5c42\u9ed1\u78f7\u7eb3\u7c73\u7247\u7684\u5149\u7535\u6d41\u54cd\u5e94\u548c\u5149\u50ac\u5316\u6d3b\u6027\u3002\u901a\u8fc7\u727a\u7272C60<\/sub>\u5206\u5b50\u9009\u62e9\u6027\u6765\u949d\u5316BP\u7eb3\u7c73\u7247\u7684\u8fb9\u7f18\u4f4d\u70b9\u4e3aBP\u5728\u81ea\u7136\u6761\u4ef6\u4e0b\u7684\u5904\u7406\u548c\u5e94\u7528\u94fa\u5e73\u4e86\u9053\u8def\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cStabilizing black phosphorus nanosheets via edge-selective bonding of sacrificial C60<\/sub> molecules\u201d<\/strong>\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNat. Commun.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u5fae\u89c2\u7ed3\u6784\u8868\u5f81\"\"<\/strong>
\n \uff08a\uff09 BP-C60<\/sub>\u6742\u5316\u6750\u6599\u7684\u5236\u5907\u65b9\u6cd5\u548c\u7ed3\u6784\u65b9\u6848\uff1b<\/p>\n

\uff08b\uff09 \u5355\u72ec\u7403\u78e8BP\uff08BP-BM\uff09\u7684HRTEM\uff08\u6bd4\u4f8b\u5c3a\uff1a5 nm\uff09\u548c\u4f4e\u500d\u7387TEM\uff08\u63d2\u56fe\uff0c\u6bd4\u4f8b\u5c3a\uff1a100 nm\uff09\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09 BP-C60<\/sub>\u6742\u5316\u6750\u6599\u7684HRTEM\uff08\u6bd4\u4f8b\u5c3a\uff1a5 nm\uff09\u548c\u4f4e\u653e\u5927\u7387TEM\uff08\u63d2\u56fe\uff0c\u6bd4\u4f8b\u5c3a\uff1a100 nm\uff09\u56fe\u50cf\uff1b<\/p>\n

\uff08d-g\uff09BP-C60<\/sub>\u6742\u5316\u6750\u6599\u7684STEM\u548cEDX\u5143\u7d20\u5206\u6790\uff08P\u548cC\uff09\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e8c\u3001\u5149\u8c31\u7279\u5f81<\/strong>
\n \"\"\uff08a\uff09 \u539f\u59cb\u7684C60<\/sub>\u3001C60<\/sub>-BM\u3001BP\/C60<\/sub>\u6df7\u5408\u7269\u548cBP-C60<\/sub>\u6742\u5316\u6750\u6599\u7684FTIR\u5149\u8c31\uff1b<\/p>\n

\uff08b\uff09 \u5757\u4f53BP\u3001BP-C60<\/sub>\u6742\u5316\u6750\u6599\u3001BP\/C60<\/sub>\u6df7\u5408\u7269\u548c\u539f\u59cb\u7684C60<\/sub>\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n

\uff08c\uff09 \u5757\u4f53BP\u548cBP-C60<\/sub>\u6742\u5316\u6750\u6599\u7684P\u5143\u7d20K\u8fb9XAS\u5149\u8c31\uff1b<\/p>\n

\uff08d\uff09 \u5757\u4f53BP\u3001BP\/C60<\/sub>\u6df7\u5408\u7269\u548cBP-C60<\/sub>\u6742\u5316\u6750\u6599\u7684P\u5143\u7d20 L\u8fb9XAS\u5149\u8c31\uff1b<\/p>\n

\uff08e\uff09 \u5757\u4f53BP\u7684\u9ad8\u5206\u8fa8P2p XPS\u5149\u8c31\uff1b<\/p>\n

\uff08f\uff09 BP-C60\u6742\u5316\u6750\u6599\u7684\u9ad8\u5206\u8fa8P2p XPS\u5149\u8c31\u3002<\/p>\n

\u56fe\u4e09\u3001BP-C60<\/sub>\u6742\u5316\u6750\u6599\u548cBP-BM\u5728\u6c34\u4e2d\u7684\u5206\u6563\u6db2\u7684\u7a33\u5b9a\u6027<\/strong>
\n \"\"\uff08a\uff09BP-C60<\/sub>\u6742\u5316\u6750\u6599\u5728\u6c34\u4e2d\u7684\u5206\u6563\u6db2\u5728\u9759\u7f6e\u4e0d\u540c\u65f6\u95f4\u540e\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

\uff08b\uff09BP-BM\u5728\u6c34\u4e2d\u7684\u5206\u6563\u6db2\u5728\u9759\u7f6e\u4e0d\u540c\u65f6\u95f4\u540e\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

\uff08c\uff09 \u4e0d\u540c\u65f6\u95f4\u7684BP-C60<\/sub>\u548cBP-BM\u5206\u6563\u6db2\u5728550 nm\u7684\u5438\u6536\u6bd4\uff08A\/A0<\/sub>\uff09\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe\u56db\u3001\u5149\u7535\u6d41\u54cd\u5e94\u548c\u5149\u50ac\u5316\u6d3b\u6027\"\" <\/strong><\/p>\n

\uff08a\uff09 BP-C60<\/sub>\u6742\u5316\u6750\u6599\u3001BP\/C60<\/sub>\u6df7\u5408\u7269\u3001BP-BM\u548cC60<\/sub>-BM\u7684\u5149\u7535\u6d41-\u65f6\u95f4\u4f9d\u8d56\u6027\uff1b<\/p>\n

\uff08b\uff09 \u53ef\u89c1\u5149\u4e0bBP-C60<\/sub>\u6742\u5316\u6750\u6599\u3001BP\/C60<\/sub>\u6df7\u5408\u7269\u3001BP-BM\u3001C60<\/sub>-BM\u3001\u539f\u59cb\u7684C60<\/sub>\u548c\u5757\u4f53BP\u7c89\u672b\u5bf9RhB\u7684\u5149\u50ac\u5316\u964d\u89e3\uff1b<\/p>\n

\uff08c\uff09 \u4e0d\u540c\u6837\u54c1\u4e2dRhB\u964d\u89e3\u7684\u51c6\u4e00\u7ea7\u52a8\u529b\u5b66\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09 \u5b9e\u9a8c\u786e\u5b9a\u7684BP-C60<\/sub>\u6742\u5316\u6750\u6599\u548cBP-BM\u7684\u80fd\u7ea7\u56fe\u4ee5\u53caBP-C60<\/sub>\u6742\u5316\u6750\u6599\u7684\u5149\u50ac\u5316\u964d\u89e3\u67d3\u6599\u673a\u7406\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aStabilizing black phosphorus nanosheets via edge-selective bonding of sacrificial<\/a>\u00a0C60 molecules<\/strong>\uff08Nat. Commun., 2018<\/strong>, DOI: 10.1038\/s41467-018-06437-1\uff09<\/p>\n

\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6768\u4e0a\u5cf0\uff0c<\/strong>\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u6267\u884c\u4e3b\u4efb\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u201c\u767e\u4eba\u8ba1\u5212\u201d\u5165\u9009\u8005\u5e76\u83b7\u7ed3\u9898\u8bc4\u4f30\u201c\u4f18\u79c0\u201d\u30022003\u5e74\u5728\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u83b7\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\u30022004\u5e742\u6708\u81f32007\u5e7412\u6708\u83b7\u5f97\u6d2a\u5821\u57fa\u91d1\u4f1a\u7684\u8d44\u52a9\u5728\u5fb7\u56fd\u83b1\u5e03\u5c3c\u5179\u56fa\u4f53\u6750\u6599\u7814\u7a76\u6240\u5de5\u4f5c\uff0c\u540e\u62c5\u4efbguest scientist\uff0c\u4ee3\u7406\u8bfe\u9898\u7ec4\u7ec4\u957f\u30022007\u5e7412\u6708\u52a0\u5165\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u548c\u5408\u80a5\u5fae\u5c3a\u5ea6\u7269\u8d28\u79d1\u5b66\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u4efb\u53cc\u8058\u6559\u6388\u30022008\u5e74\u5165\u9009\u4e2d\u56fd\u79d1\u5b66\u9662\u201c\u767e\u4eba\u8ba1\u5212\u201d\uff0c2009\u5e745\u6708\u83b7\u62e9\u4f18\u652f\u6301\uff0c2013\u5e74\u7ed3\u9898\u88ab\u8bc4\u4e3a\u201c\u4f18\u79c0\u201d\u30022014\u5e7410\u6708\u8d77\u4efb\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u6267\u884c\u4e3b\u4efb\uff0c2015\u5e7410\u6708\u8d77\u4efb\u4e2d\u56fd\u79d1\u5b66\u9662\u80fd\u91cf\u8f6c\u6362\u6750\u6599\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u526f\u4e3b\u4efb\u3002\u76ee\u524d\u7684\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u662f\u65b0\u578b\u78b3\u7eb3\u7c73\u6750\u6599\u7684\u5408\u6210\u53ca\u5728\u6709\u673a\/\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u3002\u8fc4\u4eca\u4e3a\u6b62\u5df2\u5728\u5305\u62ecNature Commun., Adv. Mater., Angew. Chem. Int. Ed., J. Am. Chem. Soc., Chem. Rev., Chem. Soc. Rev.\u7b49\u56fd\u9645\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587200\u4f59\u7bc7\uff0c\u8bba\u6587\u88abSCI\u4ed6\u5f153400\u4f59\u6b21\u3002\u83b7\u5f97\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6821\u53cb\u57fa\u91d1\u4f1a\u201c\u4f18\u79c0\u9752\u5e74\u6559\u5e08\u5956\u201d\uff082010\u5e74\uff09\u30022011\u5e74\u5165\u9009\u5b89\u5fbd\u7701\u9996\u6279\u201c\u767e\u4eba\u8ba1\u5212\u201d\uff0c\u83b7\u201c\u5b89\u5fbd\u7279\u8058\u4e13\u5bb6\u201d\u79f0\u53f7\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u201c\u4f18\u79c0\u5bfc\u5e08\u5956\u201d\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u201c\u6731\u674e\u6708\u534e\u4f18\u79c0\u6559\u5e08\u5956\u201d\uff082016 \u5e74\u30012017 \u5e74\uff09\u3002<\/p>\n

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