{"id":156487,"date":"2018-10-17T06:10:09","date_gmt":"2018-10-16T22:10:09","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=156487"},"modified":"2018-10-16T22:10:47","modified_gmt":"2018-10-16T14:10:47","slug":"%e9%83%ad%e9%9b%aa%e5%b3%b0%e6%9d%a8%e9%87%91%e9%be%99angew-chem-int-ed-%e9%80%9a%e8%bf%87%e7%a6%bb%e5%ad%90%e6%b6%b2%e4%bd%93%e6%a0%85%e6%9e%81%e5%ae%9e%e7%8e%b0%e4%ba%86%e8%8a%b3%e7%8e%af","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=156487","title":{"rendered":"\u90ed\u96ea\u5cf0&\u6768\u91d1\u9f99Angew. Chem. Int. Ed. : \u901a\u8fc7\u79bb\u5b50\u6db2\u4f53\u6805\u6781\u5b9e\u73b0\u4e86\u82b3\u73af\u5355\u5206\u5b50\u7ed3\u4e2d\u7535\u8377\u4f20\u8f93\u7684\u8c03\u63a7"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u53d7\u6700\u521d\u63d0\u51fa\u7684\u5355\u5206\u5b50\u53ef\u4f5c\u4e3a\u7535\u5b50\u5668\u4ef6\u7535\u8def\u4e2d\u7684\u529f\u80fd\u5355\u5143\u7684\u542f\u53d1\uff0c\u7814\u7a76\u4eba\u5458\u4e00\u76f4\u52aa\u529b\u5728\u5355\u5206\u5b50\u6c34\u5e73\u5b9e\u73b0\u5404\u79cd\u529f\u80fd\uff0c\u4ee5\u53ca\u5728\u539f\u5b50\/\u5206\u5b50\u5c3a\u5ea6\u4e0a\u63a2\u6d4b\u548c\u7406\u89e3\u6750\u6599\u7684\u56fa\u6709\u7279\u6027\u3002\u5355\u5206\u5b50\u6676\u4f53\u7ba1\uff0c\u5373\u5355\u4e2a\u5206\u5b50\u5939\u5728\u4e24\u4e2a\u7eb3\u7c73\u7ea7\u95f4\u9699\u7535\u6781\u4e4b\u95f4\uff0c\u800c\u6240\u5f97\u5206\u5b50\u6865\u7684\u80fd\u7ea7\u7531\u7b2c\u4e09\u4e2a\u8fd1\u7aef\u7535\u6781\u63a7\u5236\uff0c\u8fdb\u800c\u4f5c\u4e3a\u6784\u6210\u5206\u5b50\u7eb3\u7c73\u7535\u8def\u7684\u57fa\u672c\u5143\u4ef6\u4e4b\u4e00\uff0c\u5438\u5f15\u4e86\u4f17\u591a\u7814\u7a76\u5174\u8da3\u3002\u7531\u4e8e\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u7684\u56fa\u6709\u7279\u6027\u662f\u5f71\u54cd\u5206\u5b50\u7ed3\u4e2d\u7535\u8377\u4f20\u8f93\u7684\u6700\u5173\u952e\u56e0\u7d20\u4e4b\u4e00\uff0c\u8fd9\u79cd\u4e09\u7aef\u5668\u4ef6\u7ed3\u6784\u4e5f\u4e3a\u63a2\u7d22\u91cf\u5b50\u4f20\u8f93\u548c\u5355\u5206\u5b50\u65b0\u7269\u7406\u73b0\u8c61\u63d0\u4f9b\u4e86\u666e\u9002\u6027\u7b56\u7565\u3002\u76ee\u524d\u7814\u7a76\u4eba\u5458\u5df2\u5f00\u53d1\u4e86\u51e0\u79cd\u65b9\u6cd5\u6765\u5236\u9020\u5177\u6709\u6676\u4f53\u7ba1\u914d\u7f6e\u7684\u6805\u7535\u6781\u7684\u5206\u5b50\u7ed3\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u6709\u4e24\u79cd\u4e3b\u8981\u7c7b\u578b\uff1a\u4e00\u79cd\u662f\u80cc\u6805\uff0c\u53ef\u7528\u4e8e\u7535\u8fc1\u79fb\u5206\u5b50\u7ed3\u548c\u673a\u68b0\u53ef\u63a7\u65ad\u88c2\u7ed3(MCBJ)\uff1b\u53e6\u4e00\u79cd\u662f\u7535\u5316\u5b66\u6805\uff0c\u5e7f\u6cdb\u7528\u4e8e\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c(STM)\u65ad\u88c2\u7ed3\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u5728\u524d\u671f\u5de5\u4f5c\u4e2d\uff0c\u5317\u4eac\u5927\u5b66\u90ed\u96ea\u5cf0\u6559\u6388\u3001\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6768\u91d1\u9f99\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5b9e\u73b0\u4e86\u5728\u5355\u5206\u5b50\u6c34\u5e73\u4e0a\u5bf9\u6c22\u952e\u52a8\u6001\u8fc7\u7a0b\u7684\u539f\u4f4d\u76f4\u63a5\u89c2\u6d4b(Nature Commun. 2018, 9, 807)\u3002\u8fd1\u65e5\u4ed6\u4eec\u8fdb\u4e00\u6b65\u5408\u4f5c\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8e\u79bb\u5b50\u6db2\u4f53\u6805\u6781\u7684\u77f3\u58a8\u70ef-\u5206\u5b50-\u77f3\u58a8\u70ef\u5355\u5206\u5b50\u7ed3\u7684\u65b0\u578b\u82b3\u73af\u5206\u5b50\u7eb3\u7c73\u6676\u4f53\u7ba1\uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cTuning Charge Transport in Aromatic-Ring Single-Molecule Junctions via Ionic-Liquid Gating<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u5b9e\u9a8c\u73b0\u8c61\u548c\u7406\u8bba\u8ba1\u7b97\u8bc1\u5b9e\uff0c\u8be5\u79bb\u5b50\u6db2\u4f53\u6805\u6781\u53ef\u4ee5\u6709\u6548\u5730\u8c03\u8282\u5206\u5b50\u524d\u7ebf\u8f68\u9053\u4e0e\u77f3\u58a8\u70ef\u7535\u6781\u7684\u8d39\u7c73\u80fd\u7ea7\u4e4b\u95f4\u7684\u5339\u914d\u5173\u7cfb\uff0c\u4ece\u800c\u8c03\u8282\u5206\u5b50\u7ed3\u7684\u7535\u8377\u4f20\u8f93\u7279\u6027\u3002\u6b64\u5916\uff0c\u5229\u7528\u5c0f\u7684\u6805\u6781\u7535\u538b(|VG<\/sub>|\u22641.5V)\uff0c\u5b9e\u73b0\u4e86\u7535\u5316\u5b66\u60f0\u6027\u5206\u5b50\u4f53\u7cfb(EG<\/sub>> 3.5eV)\u4e2d\u7684\u53cc\u6781\u7535\u8377\u4f20\u8f93\u3002\u4e0a\u8ff0\u7ed3\u679c\u4e3a\u6784\u5efa\u9ad8\u6027\u80fd\u7684\u5355\u5206\u5b50\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u548c\u7814\u7a76\u4e0e\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u76f8\u5173\u7684\u91cf\u5b50\u8f93\u8fd0\u6548\u5e94\u63d0\u4f9b\u4e86\u53ef\u9760\u5e73\u53f0\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u5177\u6709\u79bb\u5b50\u6db2\u4f53\u6805\u6781\u4ecb\u7535\u5c42\u7684\u77f3\u58a8\u70ef-\u5206\u5b50-\u77f3\u58a8\u70ef\u5355\u5206\u5b50\u7ed3<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u5355\u5206\u5b50\u6676\u4f53\u7ba1\u793a\u610f\u56fe\u4ee5\u53caDEME+<\/sup>\u548cTFSI–<\/sup>\u7684\u5206\u5b50\u7ed3\u6784\uff1b
\n c) \u4ee5\u80fa\u57fa\u4e3a\u952e\u5408\u57fa\u56e2\u7684\u8054\u82ef\u3001\u4e09\u82ef\u57fa\u548c\u516d\u82ef\u57fa\u5206\u5b50\u7684\u7ed3\u6784\uff1b
\n d) GMG-SMJs\u9635\u5217\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 \u8054\u82ef\u3001\u4e09\u82ef\u57fa\u548c\u516d\u82ef\u57fa\u5355\u5206\u5b50\u7ed3\u7684\u7535\u8377\u4f20\u8f93\u6027\u8d28\u548c\u80fd\u7ea7<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5728\u4e8c\u7532\u57fa\u7532\u9170\u80fa\u4e2d\u6d4b\u8bd5\u7684\u4e09\u79cd\u5206\u5b50\u7684\u5f52\u4e00\u5316UV\/Vis\u5438\u6536\u5149\u8c31\uff1b
\n b) \u8ba1\u7b97\u6240\u5f97\u7684\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\uff0c\u77f3\u58a8\u70ef\u8d39\u7c73\u80fd\u7ea7\u7531\u5b9e\u9a8c\u7ed3\u679c\u63a8\u5bfc\u6240\u5f97\uff1b
\n c) \u5728\u5ba4\u6e29\u4e0b\u3001VG<\/sub> = 0V\u4e0b\u6d4b\u8bd5\u7684\u8054\u82ef\/\u4e09\u82ef\u57fa\/\u516d\u82ef\u57fa\u91cd\u8054\u5206\u5b50\u7ed3\u7684I-V\u66f2\u7ebf\uff1b
\n d) \u672a\u65bd\u52a0\u6805\u6781\u7535\u538b\u65f6\uff0c\u8ba1\u7b97\u6240\u5f97\u7684\u4e09\u79cd\u5206\u5b50\u7ed3\u7684\u96f6\u504f\u900f\u5c04\u8c31\u3002<\/p>\n

\u56fe3 \u5355\u5206\u5b50\u6676\u4f53\u7ba1\u4e2d\u7684\u6805\u6781\u53ef\u63a7\u7535\u8377\u4f20\u8f93<\/strong><\/p>\n

\"\"<\/p>\n

a) \u8054\u82ef\u5206\u5b50\u5728VD<\/sub>=\u20130.5 V\u7684\u4f20\u8f93\u7279\u6027\u66f2\u7ebf\uff1b
\n b) \u8054\u82ef\u5206\u5b50dI\/dV \u5bf9VG<\/sub>\u548cVD<\/sub>\u7684\u4e8c\u7ef4\u53ef\u89c6\u5316\u56fe\u50cf\uff1b
\n c) \u4e09\u82ef\u57fa\u5206\u5b50\u5728VD<\/sub>=\u20130.5 V\u7684\u4f20\u8f93\u7279\u6027\u66f2\u7ebf\uff1b
\n d) \u4e09\u82ef\u57fa\u5206\u5b50dI\/dV \u5bf9VG<\/sub>\u548cVD<\/sub>\u7684\u4e8c\u7ef4\u53ef\u89c6\u5316\u56fe\u50cf\uff1b
\n e) \u516d\u82ef\u57fa\u5206\u5b50\u5728VD<\/sub>=\u20130.5 V\u7684\u4f20\u8f93\u7279\u6027\u66f2\u7ebf\uff1b
\n f) \u516d\u82ef\u57fa\u5206\u5b50dI\/dV \u5bf9VG<\/sub>\u548cVD<\/sub>\u7684\u4e8c\u7ef4\u53ef\u89c6\u5316\u56fe\u50cf\u3002<\/p>\n

\u56fe4 \u77f3\u58a8\u70ef-\u5206\u5b50-\u77f3\u58a8\u70ef\u5355\u5206\u5b50\u6676\u4f53\u7ba1\u7684\u5de5\u4f5c\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

a) \u4e09\u82ef\u57fa\u5206\u5b50\u5355\u5206\u5b50\u7ed3\u5728\u20131.5 V\u2264VG<\/sub>\u22641.5 V\u6805\u6781\u504f\u538b\u4e0b\u7684\u900f\u5c04\u8c31(\u6e90\u6f0f\u504f\u538b\u4e3a\u96f6)\uff1b
\n b) \u516d\u82ef\u57fa\u5206\u5b50\u5355\u5206\u5b50\u7ed3\u5728\u20131.5 V\u2264VG<\/sub>\u22641.5 V\u6805\u6781\u504f\u538b\u4e0b\u7684\u900f\u5c04\u8c31(\u6e90\u6f0f\u504f\u538b\u4e3a\u96f6)\uff1b
\n c) \u5728\u4e0d\u540c\u6805\u6781\u7535\u538b\u4e0b\u4e09\u82ef\u57fa\u548c\u516d\u82ef\u57fa\u5355\u5206\u5b50\u6676\u4f53\u7ba1\u4e2d\u5206\u5b50\u8f68\u9053\u76f8\u5bf9\u4e8e\u77f3\u58a8\u70ef\u8d39\u7c73\u80fd\u7ea7\u5339\u914d\u7684\u80fd\u7ea7\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u5728GMG-SMJ\u5e73\u53f0\u57fa\u7840\u4e0a\uff0c\u4f5c\u8005\u5c55\u793a\u4e86\u4e00\u79cd\u901a\u8fc7\u4f7f\u7528\u79bb\u5b50\u6db2\u4f53\u4f5c\u4e3a\u6805\u6781\u4ecb\u7535\u5c42\u6765\u8c03\u5236\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u548c\u77f3\u58a8\u70ef\u7535\u6781\u7684\u8d39\u7c73\u80fd\u7ea7\u7684\u6709\u6548\u65b9\u6cd5\uff0c\u4ece\u800c\u5b9e\u73b0\u6805\u6781\u53ef\u63a7\u7535\u8377\u4f20\u8f93\u3002\u6240\u6709\u4e09\u79cd\u7535\u5316\u5b66\u60f0\u6027\u7684\u82b3\u65cf\u94fe\u5355\u5206\u5b50\u7ed3\u90fd\u8868\u73b0\u51fa\u6805\u6781\u63a7\u5236\u7684\u7535\u5bfc\u884c\u4e3a\uff0c\u5176\u4e2d\u53d1\u73b0\u6805\u6781\u6548\u7387\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u5206\u5b50\u957f\u5ea6\u548cEDL\u539a\u5ea6\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u4e09\u82ef\u57fa\u548c\u516d\u82ef\u57fa\u5206\u5b50\u7ed3\u5747\u8868\u73b0\u51fa\u53cc\u6781\u6027\u7535\u8377\u4f20\u8f93\u7279\u6027\uff0c\u8fd9\u662f\u7531\u4e8e\u5f53\u6805\u6781\u7535\u538b\u4ece\u8d1f\u53d8\u4e3a\u6b63\u65f6\u4e3b\u5bfc\u7535\u5b50\u8f68\u9053\u4eceHOMO\u53d8\u4e3aLUMO\u6240\u81f4\u3002\u56e0\u6b64\uff0c\u8be5\u5668\u4ef6\u67b6\u6784\u4e3a\u8c03\u8282\u7535\u8377\u4f20\u8f93\u63d0\u4f9b\u4e86\u53ef\u9760\u7684\u7b56\u7565\uff0c\u662f\u671d\u5411\u5b9e\u7528\u5355\u5206\u5b50\u6676\u4f53\u7ba1\u8fc8\u51fa\u7684\u91cd\u8981\u4e00\u6b65\u3002\u7531\u4e8e\u79bb\u5b50\u6db2\u4f53\u53ef\u4ee5\u4fdd\u6301\u5176EDL\u4e0d\u4f4e\u4e8e\u5176\u51dd\u56fa\u70b9\uff0c\u56e0\u6b64\u8fd9\u79cd\u5355\u5206\u5b50\u6676\u4f53\u7ba1\u53ef\u4ee5\u8fdb\u4e00\u6b65\u7528\u4e8e\u63a2\u7d22\u4e0e\u6805\u6781\u6709\u5173\u7684\u91cf\u5b50\u4f20\u8f93\u548c\u4f4e\u6e29\u4e0b\u5355\u5206\u5b50\u7684\u65b0\u7269\u7406\u73b0\u8c61\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aTuning Charge Transport in Aromatic-Ring Single-Molecule Junctions via Ionic-Liquid Gating<\/a><\/strong>\u00a0(Angew. Chem. Int. Ed.<\/strong>, 2018, DOI: 10.1002\/anie.201807465)<\/p>\n

\u3010\u901a\u8baf\u4f5c\u8005\u56e2\u961f\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u90ed\u96ea\u5cf0\u6559\u6388\u548c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6768\u91d1\u9f99\u6559\u6388\u4e3a\u8be5\u5de5\u4f5c\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>\uff0c\u6587\u7ae0\u7684\u5e76\u5217\u7b2c\u4e00\u4f5c\u8005\u4e3a\u8f9b\u5a1c\u535a\u58eb\u3001\u674e\u661f\u661f\u535a\u58eb\u548c\u8d3e\u4f20\u6210\u535a\u58eb\u3002\u8be5\u5de5\u4f5c\u5f97\u5230\u4e86\u6765\u81ea\u79d1\u6280\u90e8\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u3001\u5317\u4eac\u5e02\u79d1\u59d4\u548c\u5317\u4eac\u5927\u5b66\u7b49\u9879\u76ee\u7684\u652f\u6301\u3002<\/p>\n

\u5317\u4eac\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\u90ed\u96ea\u5cf0\u8bfe\u9898\u7ec4<\/strong>\u957f\u671f\u4ece\u4e8b\u5206\u5b50\u6750\u6599\u548c\u5668\u4ef6\u7684\u7814\u7a76\uff0c\u53d1\u5c55\u4e86\u5236\u5907\u78b3\u57fa\u7535\u6781\u7684\u7a33\u5b9a\u5355\u5206\u5b50\u5668\u4ef6\u7684\u7a81\u7834\u6027\u65b9\u6cd5\uff0c\u6784\u5efa\u4e86\u56fd\u9645\u9996\u4f8b\u7a33\u5b9a\u53ef\u63a7\u7684\u5355\u5206\u5b50\u7535\u5b50\u5f00\u5173\u5668\u4ef6\uff0c\u9996\u6b21\u5b9a\u91cf\u786e\u5b9a\u4e86DNA\u5206\u5b50\u7684\u5bfc\u7535\u6027\uff0c\u53d1\u5c55\u4e86\u5355\u5206\u5b50\u7535\u5b66\u68c0\u6d4b\u7684\u5173\u952e\u6027\u6838\u5fc3\u65b0\u6280\u672f\uff0c\u5f00\u62d3\u4e86\u5355\u5206\u5b50\u79d1\u5b66\u4e0e\u6280\u672f\u7814\u7a76\u7684\u65b0\u9886\u57df\u3002\u7279\u522b\u662f\u5728\u6700\u8fd1\u4e24\u5e74\uff0c\u4ed6\u4eec\u4e0e\u5408\u4f5c\u8005\u57fa\u4e8e\u5176\u5b9e\u9a8c\u5ba4\u524d\u671f\u5f00\u53d1\u7684\u78b3\u57fa\u5355\u5206\u5b50\u5668\u4ef6\u5e73\u53f0(Science <\/em>2006<\/strong>,\u00a0311<\/em>, 356\uff1bAcc. Chem. Res<\/em>.\u00a02008<\/strong>,\u00a041<\/em>, 1731\uff1bAcc. Chem. Res.<\/em>\u00a02015,\u00a048<\/em>, 2565)\u7814\u5236\u4e86\u5355\u5206\u5b50\u5149\u5f00\u5173\u7b49\u529f\u80fd\u5668\u4ef6(Science<\/em><\/strong>\u00a02016,\u00a0352<\/em><\/strong>, 1443;\u00a0J. Phys. Chem. Lett.<\/em><\/strong>\u00a02017,\u00a08<\/em><\/strong>, 2849)\uff0c\u63a2\u7d22\u4e86\u5355\u5206\u5b50\u5c3a\u5ea6\u7684\u7acb\u4f53\u7535\u5b50\u6548\u5e94(Nano Lett.<\/em><\/strong>\u00a02017,\u00a017<\/em><\/strong>, 856)\u548c\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u5185\u5728\u673a\u7406(Science Advances<\/em><\/strong>\u00a02016,\u00a02<\/em><\/strong>, e1601113\uff1bSmall Methods<\/em>, 2017, 1700071; Science Advances<\/em>\u00a02018,\u00a0<\/strong>4<\/em>, eaar2177\uff1bNature Commun.<\/em> 2018, 9<\/em>, 807; Nano Lett.<\/em> 2018, 18<\/em>, 4156)\u3002\u5e94\u9080\u64b0\u5199\u4e86\u4e24\u7bc7\u7cfb\u7edf\u6027\u7684\u6743\u5a01\u7efc\u8ff0(Chem. Rev.<\/em>\u00a02016<\/strong>,\u00a0116<\/em>, 4318\uff1bChem<\/em>\u00a02017<\/strong>,\u00a03<\/em>, 373)\uff0c\u6380\u8d77\u4e86\u5355\u5206\u5b50\u7535\u5b50\u5b66\u9886\u57df\u7684\u590d\u5174\u548c\u7814\u7a76\u70ed\u6f6e\u3002<\/p>\n

\u90ed\u96ea\u5cf0\u8bfe\u9898\u7ec4\u4e3b\u9875\u94fe\u63a5\uff1ahttp:\/\/www.chem.pku.edu.cn\/guoxf\/index.htm<\/a><\/strong><\/p>\n

\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\u6768\u91d1\u9f99\u8bfe\u9898\u7ec4<\/strong>\u957f\u671f\u4ece\u4e8b\u7406\u8bba\u4e0e\u8ba1\u7b97\u5316\u5b66\u9886\u57df\u7814\u7a76\uff0c\u5728\u65b0\u578b\u529f\u80fd\u6750\u6599\u7684\u7406\u8bba\u8bbe\u8ba1\u4e0e\u6a21\u62df\u3001\u8868\u9762\u5355\u5206\u5b50\u91cf\u5b50\u884c\u4e3a\u7684\u8868\u5f81\u4e0e\u8c03\u63a7\u7b49\u65b9\u9762\u53d6\u5f97\u4e86\u539f\u521b\u6027\u548c\u7cfb\u7edf\u6027\u6210\u679c\uff0c\u5728\u56fd\u5185\u5916\u4ea7\u751f\u4e86\u91cd\u8981\u5f71\u54cd\u3002\u5728\u6982\u5ff5\u4e0a\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u81ea\u65cb\u7535\u5b50\u5b66\u6750\u6599\uff0c\u5373\u53cc\u6781\u78c1\u6027\u534a\u5bfc\u4f53(Nanoscale 2012,4,5680;JACS 2014,136,11065), \u53d1\u5c55\u4e86\u7cfb\u5217\u5178\u578b\u534a\u91d1\u5c5e\u78c1\u6027\u6750\u6599(JACS 2006,128,2310\uff1bJACS 2008,130,4224\uff1bJACS 2014,136,5664)\uff0c\u63d0\u51fa\u4e86\u7ea2\u5916\u5149\u5149\u89e3\u6c34\u5236\u6c22\u673a\u5236(PRL 2014,112,018301), \u63d0\u51fa\u4e86\u8ba4\u5b9a\u7535\u5b50\u9634\u79bb\u5b50\u5316\u5408\u7269\u7684\u7406\u8bba\u5224\u636e(Angew.Chem.Int.Ed.2004,43,6479), \u53d1\u5c55\u4e86\u4e00\u5957\u5148\u8fdb\u7684\u7406\u8bba\u6a21\u62df\u65b9\u6cd5\uff0c\u5982\u7ebf\u6027\u6807\u5ea6\u7535\u5b50\u7ed3\u6784\u8ba1\u7b97(PRL 2006,97,266402)\uff0c\u4e0e\u5b9e\u9a8c\u7814\u7a76\u8005\u7d27\u5bc6\u5408\u4f5c\uff0c\u7cfb\u7edf\u7814\u7a76\u8868\u9762\u5355\u5206\u5b50\u7279\u6027\uff0c\u5982\u5229\u7528\u5355\u5206\u5b50\u9009\u952e\u5316\u5b66\u5b9e\u73b0\u4e86\u5355\u5206\u5b50\u78c1\u6027\u81ea\u65cb\u6001\u63a7\u5236(Science 2005,309,1542)\uff0c\u5229\u7528\u5355\u5206\u5b50\u624b\u672f\u548c\u5355\u5206\u5b50\u6ce2\u51fd\u6570\u5de5\u7a0b\u8bbe\u8ba1\u5e76\u5b9e\u73b0\u4e86\u540c\u65f6\u5177\u6709\u6574\u6d41\u6548\u5e94\u548c\u5f00\u5173\u6548\u5e94\u7684\u53cc\u529f\u80fd\u65b0\u578b\u5355\u5206\u5b50\u5668\u4ef6(PNAS 2009\uff0c106,15259)\u3002<\/p>\n

\u6768\u91d1\u9f99\u8bfe\u9898\u7ec4\u4e3b\u9875\u94fe\u63a5\uff1ahttp:\/\/staff.ustc.edu.cn\/~jlyang\/<\/a><\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/strong><\/p>\n

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