{"id":157129,"date":"2018-10-24T08:00:57","date_gmt":"2018-10-24T00:00:57","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=157129"},"modified":"2018-10-23T19:03:18","modified_gmt":"2018-10-23T11:03:18","slug":"%e7%8e%8b%e9%87%91%e5%85%b0%e6%9d%9c%e7%88%b1%e5%86%9bj-am-chem-soc-%e7%94%a8%e4%ba%8e%e5%8f%af%e8%a7%81%e5%85%89%e5%82%ac%e5%8c%96%e5%9b%ba%e6%b0%ae%e7%9a%84%e9%9d%9e%e9%87%91%e5%b1%9e","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=157129","title":{"rendered":"\u738b\u91d1\u5170&\u675c\u7231\u519bJ. Am. Chem. Soc.: \u7528\u4e8e\u53ef\u89c1\u5149\u50ac\u5316\u56fa\u6c2e\u7684\u975e\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\n \u4f5c\u4e3a\u6c2e\u6c14\u7684\u8fd8\u539f\u4ea7\u7269\uff0cNH3<\/sub>\u4e0d\u4ec5\u662f\u4e00\u79cd\u91cd\u8981\u7684\u5316\u5b66\u54c1\uff0c\u800c\u4e14\u4e5f\u662f\u5f88\u6709\u524d\u666f\u7684\u50a8\u80fd\u4e2d\u95f4\u4f53\u3002\u5229\u7528\u5149(\u7535)\u50ac\u5316\u8fd8\u539f\u6c2e\u6c14\u6709\u671b\u5b9e\u73b0\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u7684\u53ef\u6301\u7eed\u56fa\u6c2e\u3002\u56e0\u6b64\uff0c\u5728\u8fc7\u53bb\u7684\u5341\u591a\u5e74\u4e2d\uff0c\u56fa\u6c2e\u53cd\u5e94(NRR)\u50ac\u5316\u5242\u7684\u7814\u7a76\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u76ee\u524d\u7684\u56fa\u6c2e\u50ac\u5316\u5242\u4e3b\u8981\u96c6\u4e2d\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u8fd9\u662f\u7531\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u4e00\u822c\u5177\u6709\u7a7a\u7684d\u8f68\u9053\u548c\u5360\u636e\u7684d\u7535\u5b50\u3002\u5176\u4e2d\u7a7a\u8f68\u9053\u53ef\u4ee5\u63a5\u53d7N2<\/sub>\u7684\u5b64\u7535\u5b50\u5bf9\uff0c\u800c\u5360\u636e\u7684d\u7535\u5b50\u53c8\u53ef\u4ee5\u53cd\u9988\u81f3N2<\/sub>\u7684\u53cd\u952e\u8f68\u9053\uff0c\u4ece\u800c\u8fbe\u5230N2<\/sub>\u7684\u6355\u83b7\u4e0e\u6d3b\u5316\u7684\u76ee\u7684\u3002\u5bf9\u4e8e\u975e\u91d1\u5c5e\u5143\u7d20\uff0c sp2<\/sup>\u548csp3<\/sup>\u6742\u5316\u7684\u787c\u539f\u5b50\u4e0e\u4e00\u4e9b\u8fc7\u6e21\u91d1\u5c5e\u7c7b\u4f3c\uff0c\u4e5f\u540c\u65f6\u5177\u6709\u5360\u636e\u8f68\u9053\u548c\u7a7a\u8f68\u9053\u3002\u5b9e\u9a8c\u4e0a\u5df2\u7ecf\u5408\u6210\u4e86\u4ee5sp2<\/sup>\u6742\u5316\u7684B\u539f\u5b50\u4e3a\u6d3b\u6027\u4e2d\u5fc3\u7684\u5206\u5b50\u50ac\u5316\u5242\uff0cN2<\/sub>\u53ef\u4ee5\u901a\u8fc7\u7aef\u70b9\u6a21\u5f0f\u4e0e\u4e24\u4e2a\u787c\u4f4d\u70b9\u76f8\u4e92\u4f5c\u7528\u5e76\u8fd8\u539f\u6210B2<\/sub>N2<\/sub>\u6216[B2<\/sub>N2<\/sub>]2-<\/sup>\u3002\u5b9e\u9645\u4e0a\uff0c\u7531\u4e8e\u8f68\u9053\u5bf9\u79f0\u6027\u7684\u5339\u914d\uff0csp3<\/sup>\u6742\u5316\u7684\u787c\u539f\u5b50\u53ef\u4ee5\u901a\u8fc7\u4fa7\u5411\u6a21\u5f0f\u4e0eN2<\/sub>\u7ed3\u5408\uff0c\u56e0\u6b64N2<\/sub>\u7684\u6d3b\u5316\u7a0b\u5ea6\u66f4\u9ad8\uff0c\u4ece\u800c\u53ef\u80fd\u4ea7\u751f\u8fd8\u539f\u7a0b\u5ea6\u66f4\u9ad8\u7684\u4ea7\u7269\uff0c\u5982NH3<\/sub>\u7b49\u3002\u56e0\u6b64\uff0c\u5c06sp3<\/sup>\u6742\u5316\u7684\u787c\u539f\u5b50\u4fee\u9970\u5230\u5177\u6709\u5149\u5b66\u6d3b\u6027\u7684\u975e\u91d1\u5c5e\u57fa\u5e95\u6750\u6599\u4e0a\u53ef\u4ee5\u5b9e\u73b0\u7531\u592a\u9633\u80fd\u9a71\u52a8\u7684\u975e\u91d1\u5c5e\u56fa\u6c2e\u3002\u7531\u4e8e\u77f3\u58a8\u76f8\u6c2e\u5316\u78b3(g-C3<\/sub>N4<\/sub>)\u662f\u4e00\u79cd\u826f\u597d\u7684\u975e\u91d1\u5c5e\u5149\u50ac\u5316\u5242\uff1b\u540c\u65f6\uff0c\u4e8c\u914d\u4f4d\u7684N\u539f\u5b50\u80fd\u591f\u4e0eB\u539f\u5b50\u7ed3\u5408\uff0c\u8fbe\u5230\u8d1f\u8f7dB\u539f\u5b50\u7684\u76ee\u7684\uff1b\u6b64\u5916\uff0c\u5468\u671f\u6027\u7684\u7a7a\u4f4d\u7ed9N2<\/sub>\u7684\u5438\u9644\u4ee5\u53ca\u8fd8\u539f\u63d0\u4f9b\u8db3\u591f\u7684\u7a7a\u95f4\uff0c\u56e0\u6b64g-C3<\/sub>N4<\/sub>\u662f\u7406\u60f3\u7684\u57fa\u5e95\u6750\u6599\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\n \u8fd1\u65e5\uff0c\u4e1c\u5357\u5927\u5b66\u738b\u91d1\u5170\u6559\u6388\u3001\u6fb3\u5927\u5229\u4e9a\u6606\u58eb\u5170\u79d1\u6280\u5927\u5b66\u675c\u7231\u519b\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u57fa\u4e8e\u7535\u5b50\u201c\u63a5\u53d7-\u4f9b\u7ed9\u201d\u7684\u6982\u5ff5\uff0c\u5229\u7528\u5e7f\u6cdb\u7684\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u8bbe\u8ba1\u4e86\u975e\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u5373\u787c(B)\u539f\u5b50\u4fee\u9970\u7684\u77f3\u58a8\u76f8\u6c2e\u5316\u78b3(B\/g-C3<\/sub>N4<\/sub>)\uff0c\u7528\u4e8e\u5149\u50ac\u5316\u56fa\u6c2e\u53cd\u5e94\uff0c\u5e76\u5728J. Am. Chem. Soc.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cMetal-Free Single Atom Catalyst for N2<\/sub> Fixation Driven by Visible Light<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u4e1c\u5357\u5927\u5b66\u548c\u6606\u58eb\u5170\u79d1\u6280\u5927\u5b66\u8054\u5408\u57f9\u517b\u535a\u58eb\u7814\u7a76\u751f\u51cc\u5d07\u76ca\u3002\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u6c2e\u6c14\u53ef\u4ee5\u901a\u8fc7\u9176\u4fc3\u673a\u7406\u5728B\/g-C3<\/sub>N4<\/sub>\u4e0a\u6709\u6548\u5730\u88ab\u8fd8\u539f\u4e3aNH3<\/sub>\uff0c\u5176\u5177\u6709\u521b\u7eaa\u5f55\u7684\u4f4e\u8d77\u59cb\u7535\u4f4d(0.20 V)\u3002\u6b64\u5916\uff0c\u787c\u4fee\u9970\u7684g-C3<\/sub>N4<\/sub>\u53ef\u4ee5\u663e\u8457\u589e\u5f3a\u53ef\u89c1\u5149\u5438\u6536\uff0c\u4f7f\u5176\u6210\u4e3a\u592a\u9633\u80fd\u9a71\u52a8\u56fa\u6c2e\u7684\u7406\u60f3\u9009\u62e9\u3002\u91cd\u8981\u7684\u662f\uff0cB\/g-C3<\/sub>N4<\/sub>\u5177\u6709\u5176\u6781\u9ad8\u7684\u7a33\u5b9a\u6027\uff0c\u5e76\u4e14\u5177\u6709\u5f88\u5927\u7684\u5408\u6210\u524d\u666f\u3002\u8fd9\u7bc7\u5de5\u4f5c\u9996\u6b21\u63d0\u51fa\u4e86\u975e\u91d1\u5c5e\u5355\u539f\u5b50\u5149\u50ac\u5316\u5242\u8fd9\u4e00\u6982\u5ff5\uff0c\u4e0d\u4ec5\u4e3a\u63a8\u8fdb\u53ef\u6301\u7eed\u56fa\u6c2e\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u9047\uff0c\u4e5f\u4e3a\u50ac\u5316\u5242\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u65b0\u7684\u65b9\u5411\u3002<\/p>\n

\n \u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u8fc7\u6e21\u91d1\u5c5e\u548c\u787c\u539f\u5b50\u7684\u6742\u5316\u8f68\u9053<\/strong><\/p>\n

\"\"<\/p>\n

a) \u6c2e\u6c14\u952e\u5408\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u7684\u7b80\u5316\u793a\u610f\u56fe\uff1b
\n b) \u5177\u6709sp3<\/sup>\u6742\u5316\u7684\u7eaf\u787c\u539f\u5b50\u548c\u787c\u539f\u5b50\u7684\u7535\u5b50\u6784\u578b\uff1b
\n c) \u6c2e\u6c14\u4e0e\u7a33\u5b9a\u4e8e\u57fa\u5e95\u4e0a\u787c\u539f\u5b50\u7684\u7ed3\u5408\u5f62\u5f0f\uff1b
\n d) B\/g-C3<\/sub>N4<\/sub>\u56fa\u6c2e\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u601d\u8def\uff0c\u7070\u8272\u3001\u84dd\u8272\u548c\u7c89\u8272\u7403\u5206\u522b\u4ee3\u8868\u78b3\u3001\u6c2e\u548c\u787c\u539f\u5b50\u3002<\/p>\n

\u56fe2 \u7528\u4e8e\u7406\u8bba\u8ba1\u7b97\u7684B\/g-C3<\/sub>N4<\/sub>\u7ed3\u6784\u548c\u7535\u8377\u5206\u5e03<\/strong><\/p>\n

\"\"<\/p>\n

a) B\/g-C3<\/sub>N4<\/sub>\u7ed3\u6784\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\uff0c\u7070\u8272\u3001\u84dd\u8272\u548c\u7c89\u7ea2\u8272\u7403\u5206\u522b\u4ee3\u8868\u78b3\u3001\u6c2e\u548c\u787c\u539f\u5b50(\u4e0b\u540c)\uff1b
\n b) B\/g-C3<\/sub>N4<\/sub>\u901a\u8fc7\u4fa7\u5411\u6a21\u5f0f\u5438\u9644\u6c2e\u6c14\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\uff1b
\n c) B\/g-C3<\/sub>N4<\/sub>\u901a\u8fc7\u7aef\u70b9\u6a21\u5f0f\u5438\u9644\u6c2e\u6c14\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\uff1b
\n d) B\/g-C3<\/sub>N4<\/sub>\u901a\u8fc7\u4fa7\u5411\u6a21\u5f0f\u5438\u9644\u6c2e\u6c14\u7684\u4e8c\u6b21\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\uff0c\u5176\u4e2d\u6b63\u3001\u8d1f\u7535\u8377\u5206\u522b\u663e\u793a\u4e3a\u9ec4\u8272\u548c\u9752\u8272(\u4e0b\u540c)\uff1b
\n e) B\/g-C3<\/sub>N4<\/sub>\u901a\u8fc7\u7aef\u70b9\u6a21\u5f0f\u5438\u9644\u6c2e\u6c14\u7684\u4e8c\u6b21\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe\u3002<\/p>\n

\u56fe3 B\/g-C3<\/sub>N4<\/sub>\u901a\u8fc7\u4e0d\u540c\u673a\u7406\u8fdb\u884c\u53cd\u5e94\u7684\u8def\u5f84\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

a) \u901a\u8fc7\u672b\u7aef\u3001\u4ea4\u66ff\u548c\u9176\u673a\u7406\u5c06\u6c2e\u6c14\u8fd8\u539f\u4e3aNH3<\/sub>\u7684\u53cd\u5e94\u8def\u5f84\u56fe\uff1b
\n b) B\/g-C3<\/sub>N4<\/sub>\u5728\u4e0d\u540c\u7535\u52bf\u4e0b\u901a\u8fc7\u672b\u7aef\u673a\u7406\u8fdb\u884c\u7684\u56fa\u6c2e\u81ea\u7531\u80fd\u56fe\uff1b
\n c) B\/g-C3<\/sub>N4<\/sub>\u5728\u4e0d\u540c\u7535\u52bf\u4e0b\u901a\u8fc7\u4ea4\u66ff\u673a\u7406\u8fdb\u884c\u7684\u56fa\u6c2e\u81ea\u7531\u80fd\u56fe\uff1b
\n d) B\/g-C3<\/sub>N4<\/sub>\u5728\u4e0d\u540c\u7535\u52bf\u4e0b\u901a\u8fc7\u9176\u673a\u7406\u8fdb\u884c\u7684\u56fa\u6c2e\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n

\u56fe4 \u7eafg-C3<\/sub>N4<\/sub>\u548cB\/g-C3<\/sub>N4<\/sub>\u7684\u5149\u5438\u6536\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

\u7eafg-C3<\/sub>N4<\/sub>\u548cB\/g-C3<\/sub>N4<\/sub>\u7684\u5149\u5438\u6536\u8c31\u56fe\uff0c\u5206\u522b\u7528\u9ed1\u7ebf\u548c\u7ea2\u7ebf\u8868\u793a\u3002<\/p>\n

\u56fe5 B\/g-C3<\/sub>N4<\/sub>\u5408\u6210\u53ef\u884c\u6027\u548c\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5728g-C3<\/sub>N4<\/sub>\u4e0d\u540c\u4f4d\u7f6e\u4e0a\u4fee\u9970\u787c\u539f\u5b50\u7684\u5f62\u6210\u80fd\uff0c\u53f3\u56fe\u4e3a\u4f18\u5316\u7ed3\u6784\uff0c\u56fe\u4e2d\u6240\u793a\u7684\u80fd\u91cf\u662f\u76f8\u5bf9\u4e8e\u56fe2a\u4e2d\u7ed3\u6784\u7684\u76f8\u5e94\u5f62\u6210\u80fd\uff1b
\n b) AIMD\u6a21\u62dfB\/g-C3<\/sub>N4<\/sub>\u7684\u6e29\u5ea6\u548c\u80fd\u91cf\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff0c\u63d2\u56fe\u4e3a\u7528\u4e8e\u6a21\u62df\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\uff0c\u6a21\u62df\u57281000 K\u4e0b\u8fd0\u884c10 ps\uff0c\u65f6\u95f4\u6b65\u957f\u4e3a2 fs\u3002<\/p>\n

\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u9996\u4f8b\u975e\u91d1\u5c5e\u5355\u539f\u5b50\u5149\u50ac\u5316\u5242B\/g-C3<\/sub>N4<\/sub>\uff0c\u5176\u5177\u6709\u4f18\u5f02\u7684\u56fa\u6c2e\u6d3b\u6027\u3002\u53cc\u5411\u7535\u8377\u8f6c\u79fb\u8bc1\u5b9e\u4e86\u6c2e\u6c14\u548cB\/g-C3<\/sub>N4<\/sub>\u4e4b\u95f4\u7684\u201c\u63a5\u53d7-\u4f9b\u7ed9\u201d\u8fc7\u7a0b\uff0c\u5176\u5728\u6c2e\u6c14\u7684\u6355\u83b7\u548c\u6d3b\u5316\u4e2d\u8d77\u5173\u952e\u4f5c\u7528\u3002\u5bf9\u4e8e\u968f\u540e\u7684\u6c2e\u6c14\u8fd8\u539f\u8fc7\u7a0b\uff0c\u901a\u8fc7\u9176\u673a\u7406\u8ba1\u7b97\u7684\u8d77\u59cb\u7535\u4f4d\u4ec5\u4e3a0.20 V\u3002\u6b64\u5916\uff0cg-C3<\/sub>N4<\/sub>\u4e0a\u787c\u7684\u4fee\u9970\u53ef\u4ee5\u5927\u5927\u589e\u5f3a\u53ef\u89c1\u5149\u548c\u7ea2\u5916\u5149\u7684\u5438\u6536\uff0c\u4f7f\u5f97\u5176\u6210\u4e3a\u53ef\u89c1\u5149\u56fa\u6c2e\u7684\u7406\u60f3\u9009\u62e9\u3002\u6b64\u5916\uff0c\u6240\u8bbe\u8ba1\u7684B\/g-C3<\/sub>N4<\/sub>\u6bd4\u5176\u4ed6\u787c\u4fee\u9970\u7684g-C3<\/sub>N4<\/sub>\u7ed3\u6784\u5177\u6709\u66f4\u4f4e\u7684\u5f62\u6210\u80fd\uff0c\u5728\u5b9e\u9a8c\u5408\u6210\u65b9\u9762\u5177\u6709\u663e\u8457\u4f18\u52bf\u3002\u6b64\u5916\uff0c\u8be5\u50ac\u5316\u5242\u57281000 K\u4ee5\u4e0a\u5177\u6709\u8f83\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u4f4e\u8d77\u59cb\u7535\u4f4d\u3001\u5bbd\u5149\u8c31\u5438\u6536\u3001\u5408\u6210\u7b80\u4fbf\u548c\u9ad8\u7a33\u5b9a\u6027\u7b49\u4f18\u52bf\u4f7f\u5f97B\/g-C3<\/sub>N4<\/sub>\u6709\u671b\u6210\u4e3a\u4e00\u79cd\u5341\u5206\u5f15\u4eba\u6ce8\u76ee\u7684\u56fa\u6c2e\u5149\u50ac\u5316\u5242\uff0c\u4e3a\u63a8\u52a8NH3<\/sub>\u7684\u53ef\u6301\u7eed\u751f\u4ea7\u94fa\u5e73\u9053\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aMetal-Free Single Atom Catalyst for N2<\/sub> Fixation Driven by Visible Light <\/a><\/strong>(J. Am. Chem. Soc.<\/strong>, 2018, DOI: 10.1021\/jacs.8b07472)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong>
\n \u738b\u91d1\u5170\u6559\u6388\u73b0\u4efb\u804c\u4e8e\u4e1c\u5357\u5927\u5b66\u7269\u7406\u5b66\u9662\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u83b7\u5f97\u8005(2015)\u3001\u6c5f\u82cf\u7701\u201c333\u9ad8\u5c42\u6b21\u4eba\u624d\u652f\u6301\u8ba1\u5212\u201d\u7b2c\u4e8c\u5c42\u6b21\u83b7\u5f97\u8005(2016)\u3001\u56fd\u52a1\u9662\u7279\u6b8a\u6d25\u8d34\u83b7\u5f97\u8005(2018)\u3002\u957f\u671f\u4ece\u4e8b\u4f4e\u7ef4\u6750\u6599\u591a\u5c3a\u5ea6\u6a21\u62df\u4e0e\u8bbe\u8ba1\u5de5\u4f5c\uff0c\u4e3b\u6301\u591a\u9879\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u4e0e\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u3002\u53d1\u8868SCI\u8bba\u6587180\u4f59\u7bc7\uff0c\u5f71\u54cd\u56e0\u5b5010\u4ee5\u4e0a\u8bba\u658730\u4f59\u7bc7\uff0c\u5176\u4e2dScience1\u7bc7\uff0cNat Commun 7\u7bc7\uff0cJ Am Chem Soc 6\u7bc7\uff0cAngew Chem Int Ed 5\u7bc7(\u5c01\u9762\u70ed\u70b9\u6587\u7ae01\u7bc7)\uff0cNano Lett\/ACS Nano\/Adv Mater. 14\u7bc7\u3002\u5f15\u7528\u8d85\u8fc76400\u6b21\uff0cH-index 42\uff0c\u8fde\u7eed\u56db\u5e74\u5165\u9009\u201cElsevier\u4e2d\u56fd\u9ad8\u88ab\u5f15\u5b66\u8005\u540d\u5355(2014-2017)\u201d\u3002
\n \u8bfe\u9898\u7ec4\u4e3b\u9875: http:\/\/hpc.seu.edu.cn\/jlwang\/index.html<\/a><\/strong><\/p>\n

\u3010\u56e2\u961f\u5728\u8be5\u9886\u57df\u4ee3\u8868\u6027\u5de5\u4f5c\u3011<\/strong>
\n (1) Z. Luo, Y. Ouyang, H. Zhang, M. Xiao, J. Ge, Z. Jiang, J. Wang, D. Tang, X. Cao, C. Liu, W. Xing. Chemically activating MoS2<\/sub> via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolution<\/strong><\/a>, Nat. Commun.<\/strong>, 2018, 9, 2120.
\n (2) C. Ling, Q. Li, A. Du, J. Wang. Computation-aided Design of Single Atom Catalyst for One-pot CO2<\/sub> Capture, Activation and Conversion<\/strong><\/a>, ACS Appl. Mater. Inter.<\/strong>, 2018, In press.
\n (3) Q. Li, X. Bai, C. Ling, Q. Zhou, S. Yuan, Q. Chen, J. Wang. Forming Atom\u2013Vacancy Interface on the MoS2<\/sub> Catalyst for Efficient Hydrodeoxygenation Reactions<\/a><\/strong>, Small Method<\/strong>, 2018, In press.
\n (4) Y. Ouyang, Q. Li, L. Shi, C. Ling, J. Wang. Molybdenum sulfide clusters immobilized on defective graphene: a stable catalyst for the hydrogen evolution reaction<\/strong><\/a>, J Mater. Chem. A<\/strong>, 2018, 6, 2289.
\n (5) C. Ling, L. Shi, Y. Ouyang, X.C. Zeng, J Wang. Nanosheet Supported Single-Metal Atom Bifunctional Catalyst for Overall Water Splitting<\/strong><\/a>, Nano Lett.<\/strong>, 2017, 17, 5133.
\n (6) C. Ling, Y. Ouyang, L. Shi, S. Yuan, Q. Chen, J. Wang. Template-Grown MoS2<\/sub> Nanowires Catalyze Hydrogen Evolution Reaction: Ultra-low Kinetic Barriers with High Active Site Density<\/strong><\/a>, ACS Catal.<\/strong>, 2017, 7, 5097.
\n (7) C. Ling, L. Shi, Y. Ouyang, Q. Chen, J. Wang. Transition metal-promoted V2<\/sub>CO2<\/sub> (MXenes): A New and Highly Active Catalyst for Hydrogen Evolution Reaction<\/a><\/strong>, Adv. Sci.<\/strong>, 2016, 3, 1600180.
\n (8) C. Ling, L. Shi, Y. Ouyang, J. Wang. Searching for Highly Active Catalysts for Hydrogen Evolution Reaction Based on O-terminated MXenes through A Simple Descriptor<\/a><\/strong>, Chem. Mater.<\/strong>, 2016, 28, 9026.
\n (9) Y. Ouyang, C. Ling, Q. Chen, Z. Wang, L. Shi, J. Wang. Activating inert basal planes of MoS2<\/sub> for hydrogen evolution reaction through the formation of different intrinsic defects<\/strong><\/a>, Chem. Mater.<\/strong>, 2016, 28, 4390.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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