{"id":157446,"date":"2018-11-06T06:30:27","date_gmt":"2018-11-05T22:30:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=157446"},"modified":"2018-11-05T12:31:43","modified_gmt":"2018-11-05T04:31:43","slug":"%e5%b1%b1%e8%a5%bf%e7%85%a4%e5%8c%96%e6%89%80%e5%8c%97%e4%ba%ac%e5%a4%a7%e5%ad%a6chem%e6%b0%a7%e4%bf%ae%e9%a5%b0fe5c2%e5%82%ac%e5%8c%96%e5%89%82%e5%85%89%e9%a9%b1%e5%8a%a8%e5%90%88%e6%88%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=157446","title":{"rendered":"\u5c71\u897f\u7164\u5316\u6240&amp;\u5317\u4eac\u5927\u5b66Chem:\u6c27\u4fee\u9970Fe5C2\u50ac\u5316\u5242\u5149\u9a71\u52a8\u5408\u6210\u6c14\u8f6c\u5316\u4e3a\u4f4e\u78b3\u70ef\u70c3"},"content":{"rendered":"<p><strong>\u3010\u524d\u8a00\u3011<\/strong><\/p>\n<p>\u4f4e\u78b3\u6570\u70ef\u70c3(C<sub>2\u20134<\/sub>=)\u4f5c\u4e3a\u5173\u952e\u7684\u7ed3\u6784\u5355\u5143\u5316\u5b66\u54c1\uff0c\u662f\u5408\u6210\u805a\u5408\u7269\u548c\u533b\u836f\u4ea7\u54c1\u7684\u5173\u952e\u3002\u901a\u5e38\uff0c\u4f4e\u78b3\u6570\u70ef\u70c3\u53ef\u4ee5\u4ece\u6cb9\u88c2\u89e3\u548c\u7532\u9187\u5236\u70ef\u70c3\u5de5\u827a\u4e2d\u83b7\u5f97\u3002\u968f\u7740\u539f\u6cb9\u7684\u67af\u7aed\uff0c\u7279\u522b\u662f\u5bf9\u4f4e\u78b3\u70ef\u70c3\u7684\u9700\u6c42\u65e5\u76ca\u589e\u957f\uff0c\u901a\u8fc7\u8d39\u6258\u5408\u6210(FTS)\u5de5\u827a\u5c06\u5408\u6210\u6c14\u76f4\u63a5\u8f6c\u5316\u4e3a\u4f4e\u78b3\u70ef\u70c3\u662f\u77f3\u6cb9\u8def\u7ebf\u7684\u4e00\u79cd\u6709\u524d\u9014\u7684\u66ff\u4ee3\u65b9\u6848\u3002\u636e\u62a5\u9053\uff0cK-\u548cS-\u4fc3\u8fdb\u7684\u94c1\u50ac\u5316\u5242\u6216Na -\u548cZn -\u4fc3\u8fdb\u7684Fe<sub>5<\/sub>C<sub>2<\/sub>\u50ac\u5316\u5242\u5bf9\u70ef\u70c3\u751f\u4ea7\u5177\u6709\u9ad8\u5ea6\u9009\u62e9\u6027\u3002\u6700\u8fd1\uff0c\u636e\u62a5\u9053\uff0cMn\u6539\u6027\u7684\u78b3\u5316\u94b4\u50ac\u5316\u5242\u80fd\u591f\u5c06\u5408\u6210\u6c14\u8f6c\u5316\u4e3a\u4f4e\u78b3\u70ef\u70c3\uff0c\u521b\u4e0b\u70ef\u70c3\/\u77f3\u8721\u6bd430-50\u7684\u65b0\u7eaa\u5f55\u3002\u7136\u800c\uff0c\u53cd\u5e94\u6761\u4ef6\u6240\u9700\u7684\u5927\u91cf\u70ed\u80fd\uff0c\u56e0\u6b64\u5de5\u4e1a\u9700\u8981\u66f4\u7eff\u8272\u548c\u53ef\u6301\u7eed\u7684\u9014\u5f84\u6765\u884d\u751f\u7684\u4e0a\u8ff0FTO\u5de5\u827a\u3002<\/p>\n<p>\u4e0e\u70ed\u80fd\u9a71\u52a8\u7684\u53cd\u5e94\u76f8\u6bd4\uff0c\u5149\u9a71\u52a8\u7684CO\u6216CO<sub>2<\/sub>\u5229\u7528\u53cd\u5e94\u662f\u53ef\u6301\u7eed\u7684\u9014\u5f84\uff0c\u901a\u8fc7\u5b83\u53ef\u4ee5\u6536\u83b7\u5730\u7403\u4e0a\u6700\u4e30\u5bcc\u7684\u80fd\u91cf\u5f62\u5f0f\uff0c\u5e76\u751f\u4ea7\u51fa\u6240\u9700\u7684\u71c3\u6599\u548c\u5316\u5b66\u54c1\u3002\u6700\u8fd1\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u6539\u6027\u7684Ni\u50ac\u5316\u5242\u53ef\u4ee5\u5728\u53ef\u89c1\u5149\u6216\u7d2b\u5916-\u53ef\u89c1(UV &#8211; 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49 %\u3002\u5bf9CO<sub>2<\/sub>\u7684\u9009\u62e9\u6027\u4f4e\u81f318.9 %\uff0c\u786e\u4fdd\u4e86\u9ad8\u7684\u78b3\u8d44\u6e90\u5229\u7528\u6548\u7387\uff0c\u50ac\u5316\u5242\u663e\u793a\u51fa\u826f\u597d\u7684\u7a33\u5b9a\u6027\u3002\u5728\u5149\u7167\u5c04\u6761\u4ef6\u4e0b\uff0cFe<sub>5<\/sub>C<sub>2<\/sub>\u50ac\u5316\u5242\u7684\u8868\u9762\u88ab\u539f\u4f4d\u5f62\u6210\u7684O\u539f\u5b50\u81ea\u53d1\u4fee\u9970\uff0c\u5bfc\u81f4\u5bf9\u70ef\u70c3\u7684\u9ad8\u9009\u62e9\u6027\uff0c\u8fd9\u4f7f\u5f97\u5b83\u6210\u4e3a\u5149\u9a71\u52a8FTO\u53cd\u5e94\u7684\u4f18\u79c0\u50ac\u5316\u5242\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u56fe 1. \u50ac\u5316\u5242\u8868\u5f81\u4e0e\u53cd\u5e94\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-157447\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/1-35.jpg\" alt=\"\" width=\"600\" height=\"477\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/1-35.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/1-35-300x239.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(A) Fe<sub>5<\/sub>C<sub>2<\/sub>\u548c\u76f8\u5173\u50ac\u5316\u5242\u7684XRD\u56fe\uff1b<\/p>\n<p>(B) Fe<sub>5<\/sub>C<sub>2<\/sub> \u50ac\u5316\u5242\u5728\u5149\u7167\u4e0b\u7684\u5e8a\u6e29\u6d4b\u5b9a\uff1b<\/p>\n<p>(C) Fe<sub>5<\/sub>C<sub>2<\/sub>\u548c\u76f8\u5173\u50ac\u5316\u5242\u7684UV-vis\uff1b<\/p>\n<p>(D) Fe<sub>5<\/sub>C<sub>2<\/sub> \u50ac\u5316\u5242\u5faa\u73af\u6027\uff1b<\/p>\n<p>\u56fe 2. \u4e0d\u540c\u50ac\u5316\u5242\u7684XPS\u56fe\u548cX\u5c04\u7ebf\u5438\u6536\u8c31<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-157448\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/2-36.jpg\" alt=\"\" width=\"600\" height=\"457\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/2-36.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/2-36-300x229.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(A) Fe<sub>5<\/sub>C<sub>2<\/sub>\u50ac\u5316\u5242\u5728\u4e0d\u540c\u5904\u7406\u6761\u4ef6\u4e0b\u7684\u539f\u4f4dXPS\uff1b<\/p>\n<p>(B) \u65b0\u9c9c\u548c\u4f7f\u7528\u540e\u7684Fe<sub>5<\/sub>C<sub>2<\/sub> \u50ac\u5316\u5242\u7684O1s\u56fe\uff1b<\/p>\n<p>(C) Fe<sub>5<\/sub>C<sub>2<\/sub>\u5728\u4e0d\u540c\u53cd\u5e94\u65f6\u95f4\u4e0b\u7684Fe K\u8fb9XANES\u56fe\uff1b<\/p>\n<p>(D) Fe<sub>5<\/sub>C<sub>2<\/sub>\u5728\u4e0d\u540c\u53cd\u5e94\u65f6\u95f4\u4e0b\u7684\u539f\u4f4dEXAFS\u56fe\uff1b<\/p>\n<p>\u56fe 3. \u4e24\u4e2aCH<sub>2<\/sub> \u8026\u5408\u548c\u5728Fe<sub>5<\/sub>C<sub>2<\/sub>(111)\u548cFe<sub>5<\/sub>C<sub>2<\/sub>(111)-4O<sub>ads<\/sub>\u4e0a\u52a0\u6c22\u5f62\u6210C<sub>2<\/sub>H<sub>6<\/sub>\u7684\u80fd\u7ea7\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-157449\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/3-36.jpg\" alt=\"\" width=\"600\" height=\"462\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/3-36.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/3-36-300x231.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>Fe, C, O \u548cH \u539f\u5b50\u5206\u522b\u4e3a\u84dd\u8272\uff0c\u68d5\u8272\uff0c\u7ea2\u8272\u4ee5\u53ca\u767d\u8272<\/p>\n<p>\u56fe 4. C<sub>2<\/sub>H<sub>4<\/sub>\u5438\u9644\u548c\u5728Fe<sub>5<\/sub>C<sub>2<\/sub>(111)\u548cFe<sub>5<\/sub>C<sub>2<\/sub>(111)-4O<sub>ads<\/sub>\u8868\u9762\u4e0a\u901a\u8fc7\u70ed\u9a71\u52a8\uff08\u57fa\u6001\uff09\u548c\u5149\u9a71\u52a8\uff08\u6fc0\u53d1\u6001\uff09\u52a0\u6c22\u5f62\u6210C<sub>2<\/sub>H<sub>4<\/sub>\u7684\u80fd\u7ea7\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-157450\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/4-32.jpg\" alt=\"\" width=\"600\" height=\"512\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/4-32.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/10\/4-32-300x256.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>Fe, C, O, \u548cH\u539f\u5b50\u5206\u522b\u4e3a\u84dd\u8272\uff0c\u68d5\u8272\uff0c\u7ea2\u8272\u4ee5\u53ca\u767d\u8272<\/p>\n<p><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n<p>\u8be5\u56e2\u961f\u7814\u7a76\u7684\u5149\u9a71\u52a8FTO\u5de5\u827a\u53ef\u4ee5\u663e\u8457\u6539\u53d8Fe<sub>5<\/sub>C<sub>2<\/sub>\u50ac\u5316\u5242\u4e0a\u7684\u4ea7\u7269\u9009\u62e9\u6027\uff0c\u5bfc\u81f4\u70ef\u70c3\/\u77f3\u8721\u6bd4\u4e3a10.9\uff0cCO\u8f6c\u5316\u7387&gt; 49 %\u3002\u5bf9CO<sub>2<\/sub>\u7684\u9009\u62e9\u6027\u4f4e\u81f318.9 %\uff0c\u786e\u4fdd\u4e86\u9ad8\u7684\u78b3\u8d44\u6e90\u5229\u7528\u6548\u7387\uff0c\u50ac\u5316\u5242\u663e\u793a\u51fa\u826f\u597d\u7684\u7a33\u5b9a\u6027\u3002\u5728\u5149\u7167\u5c04\u6761\u4ef6\u4e0b\uff0cFe<sub>5<\/sub>C<sub>2<\/sub>\u50ac\u5316\u5242\u7684\u8868\u9762\u88ab\u539f\u4f4d\u5f62\u6210\u7684O\u539f\u5b50\u81ea\u53d1\u4fee\u9970\uff0c\u5bfc\u81f4\u5bf9\u70ef\u70c3\u7684\u9ad8\u9009\u62e9\u6027\uff0c\u8fd9\u4f7f\u5f97\u5b83\u6210\u4e3a\u5149\u9a71\u52a8FTO\u53cd\u5e94\u7684\u4f18\u79c0\u50ac\u5316\u5242\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2451929418304376#!\" target=\"_blank\" rel=\"noopener\">Photo-Driven Syngas Conversion to Lower Olefins over Oxygen-Decorated Fe<sub>5<\/sub>C<sub>2<\/sub> Catalyst<\/a>, (Chem, 2018, DOI: 10.1016\/j.chempr.2018.09.017)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7eb3\u7c73\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com\u3002<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u524d\u8a00\u3011 \u4f4e\u78b3\u6570\u70ef\u70c3(C2\u20134=)\u4f5c\u4e3a\u5173\u952e\u7684\u7ed3\u6784\u5355\u5143\u5316\u5b66\u54c1\uff0c\u662f\u5408\u6210\u805a\u5408\u7269\u548c\u533b\u836f\u4ea7\u54c1\u7684\u5173\u952e\u3002\u901a\u5e38\uff0c\u4f4e\u78b3\u6570\u70ef\u70c3\u53ef\u4ee5\u4ece\u6cb9\u88c2\u89e3\u548c\u7532\u9187\u5236\u70ef\u70c3\u5de5\u827a\u4e2d\u83b7\u5f97\u3002\u968f\u7740\u539f\u6cb9\u7684\u67af\u7aed\uff0c\u7279&#8230;<\/p>\n","protected":false},"author":3029,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-157446","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/157446"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/3029"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=157446"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/157446\/revisions"}],"predecessor-version":[{"id":158229,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/157446\/revisions\/158229"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=157446"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=157446"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=157446"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}