{"id":159278,"date":"2018-11-22T06:30:32","date_gmt":"2018-11-21T22:30:32","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=159278"},"modified":"2018-11-21T18:57:11","modified_gmt":"2018-11-21T10:57:11","slug":"%e6%a0%a1%e7%a8%bf%e6%9c%aa%e5%9b%9e%e5%a4%8d%e4%b8%ad%e7%a7%91%e5%a4%a7%e8%b0%a2%e6%af%85%e5%90%b4%e9%95%bf%e5%be%81acc-chem-res-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e7%94%a8%e4%ba%8e%e7%94%b5%e5%82%ac","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=159278","title":{"rendered":"\u4e2d\u79d1\u5927\u8c22\u6bc5\u5434\u957f\u5f81Acc. Chem. Res.\u7efc\u8ff0\uff1a\u7528\u4e8e\u7535\u50ac\u5316\u7684\u65e0\u673a\u4f4e\u7ef4\u7535\u6781\u6750\u6599\u7684\u8868\u754c\u9762\u5de5\u7a0b"},"content":{"rendered":"

\u3010\u524d\u8a00\u3011<\/strong><\/p>\n

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\u3010\u7efc\u8ff0\u5bfc\u89c8\u56fe\u3011<\/strong><\/p>\n

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1.1 \u63d0\u9ad8\u7535\u5bfc\u7387<\/strong><\/p>\n

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\u56fe2. \u63d0\u9ad8\u7535\u5bfc\u7387\u3002<\/p>\n

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\u56fe3. \u63d0\u9ad8\u7535\u5bfc\u7387\u3002<\/p>\n

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1.2 <\/strong>\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9<\/strong><\/p>\n

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\u56fe4. \u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u3002<\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540cCV\u6d4b\u8bd5\u540e\u539f\u59cbCo4<\/sub>N\u548cCo4<\/sub>N\u7684\u6781\u5316\u66f2\u7ebf\u3002\uff08b\uff091000\u6b21CV\u6d4b\u8bd5\u540eCo4<\/sub>N\u6837\u54c1\u7684HRTEM\u56fe\u50cf\u3002\uff08c\uff09\u5728OER\u8fc7\u7a0b\u4e4b\u540eCo2<\/sub>P\u548cCo2<\/sub>P\u7eb3\u7c73\u9897\u7c92\u7684Co K\u8fb9\u7f18\u5904\u7684FT-EXAFS\u5149\u8c31\u3002\uff08d\uff09\u4e2d\u6027OER\u8fc7\u7a0b\u540eCo2<\/sub>P\u7684HRTEM\u56fe\u50cf\u3002\uff08e\uff09OER\u8fc7\u7a0b\u4e2d\u7535\u5b50\u4f20\u8f93\u7684\u793a\u610f\u56fe\u3002\uff08f\uff091000CV\u5faa\u73af\u540eNi3<\/sub>C\/C\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe5. \u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u3002<\/p>\n

\"\"\uff08a\uff09DFT\u8ba1\u7b97\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53d8\u5316\uff0c\u7528\u4e8e\u5f62\u6210\u5404\u79cd\u7a7a\u4f4d\u3002\uff08b\uff09\u7535\u6d41\u5bc6\u5ea6\u4e0e\u626b\u63cf\u901f\u7387\u7684\u5173\u7cfb\u56fe\u3002\uff08c\uff09\u6c27\u6c14\u7ed3\u5408\u540eNi2<\/sub>P\u7684\u539f\u5b50\u7ed3\u6784\u6a21\u578b\uff0c\u4ee5\u53ca\u7535\u6d41\u5bc6\u5ea6\u53d8\u5316\u4e0e\u626b\u63cf\u901f\u7387\u7684\u5dee\u5f02\u3002\uff08d\uff09\u5177\u6709\u589e\u52a0\u7684Fe\u542b\u91cf\u7684\u6df7\u5408Ni-Fe\u50ac\u5316\u5242\u7684OER\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

1.3 \u4f18\u5316\u5438\u9644<\/strong>\/<\/strong>\u89e3\u5438\u80fd\u91cf\u969c\u788d<\/strong><\/p>\n

\u53cd\u5e94\u80fd\u5792\u4e0e\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u5438\u9644\/\u89e3\u5438\u76f4\u63a5\u76f8\u5173\uff0c\u5e76\u4e14\u88ab\u8ba4\u4e3a\u662f\u8bc4\u4ef7\u7535\u50ac\u5316\u6d3b\u6027\u7684\u56fa\u6709\u53c2\u6570\u3002\u7535\u6781\u6750\u6599\u7684\u8868\u9762\u7279\u6027\u662f\u4e2d\u95f4\u7269\u8d28\u5438\u9644\/\u89e3\u5438\u884c\u4e3a\u7684\u5173\u952e\u3002<\/p>\n

\u56fe6. \u4f18\u5316\u5438\u9644\/\u89e3\u5438\u80fd\u91cf\u969c\u788d\u3002<\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728Ni\uff08OH\uff092<\/sub>\u7eb3\u7c73\u7247\u8868\u9762\u4e0aCO2<\/sub>\u89e3\u5438\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\u3002\uff08b\uff09\u8ba1\u7b97N-CoS2<\/sub>\u50ac\u5316\u5242\u4e0aCo\u4f4d\u70b9\u7684HER\u81ea\u7531\u80fd\u56fe\u3002\uff08c\uff09\u8fc7\u7535\u4f4d\u548c\u5854\u83f2\u5c14\u659c\u7387\u7684\u6bd4\u8f83\u3002\uff08d\uff09\u7528\u4e8eORR\u7684MnO@FLC\u548cSdMC\u50ac\u5316\u5242\u7684\u81ea\u7531\u80fd\u53d8\u5316\u3002\uff08e\uff09\u7535\u50ac\u5316\u5242\u7684ORR\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n

\u56fe7. \u4f18\u5316\u5438\u9644\/\u89e3\u5438\u80fd\u91cf\u969c\u788d\u3002<\/p>\n

\"\"\uff08a\uff09CoO\u6837\u54c1\u7684\u8ba1\u7b97OER\/ORR\u81ea\u7531\u80fd\u56fe\u3002\uff08b\uff09CoO\u50ac\u5316\u5242\u7684\u53cc\u529f\u80fd\u6d3b\u6027\u7684\u793a\u610f\u56fe\u3002\uff08c\uff0cd\uff09OER\/ORR\u5bf9\u4e0d\u540c\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u7684\u6bd4\u8f83\u3002<\/p>\n

1.4 \u8bbe\u8ba1\u7535\u5b50\u81ea\u65cb\u914d\u7f6e<\/strong><\/p>\n

\u76ee\u524d\uff0c\u5b9e\u9a8c\u539f\u7406\u5f3a\u8c03\u5f53eg<\/sub>\u7535\u5b50\u586b\u5145\u72b6\u6001\u63a5\u8fd1\u4e8e1\u65f6\uff0ceg<\/sub>\u8f68\u9053\u4e2d\u7684\u7535\u5b50\u66f4\u6709\u6548\u5730\u4e0e\u542b\u6c27\u5438\u9644\u7269\u76f8\u4e92\u4f5c\u7528\uff0c\u5bfc\u81f4\u66f4\u9ad8\u7684OER\/ORR\u6d3b\u6027\u3002\u8868\u9762\u7f3a\u9677\u5de5\u7a0b\uff0ceg<\/sub>\u53ef\u4ee5\u5f15\u8d77\u91d1\u5c5e\u79bb\u5b50\u7684\u4ef7\u6001\u8f6c\u53d8\u7684\u6c27\u7a7a\u4f4d\uff0c\u53ef\u7528\u4e8e\u8c03\u5236\u56fa\u6709\u7535\u5b50\u914d\u7f6e\u548c\u4f18\u5316eg<\/sub>\u7535\u5b50\u586b\u5145\u72b6\u6001\u3002<\/p>\n

\u56fe8. \u8bbe\u8ba1\u7535\u5b50\u81ea\u65cb\u914d\u7f6e\u3002<\/p>\n

\"\"\uff08a\uff09\u5e73\u5747\u4f8b\u5982\u4e0e\u4e0d\u540cH2<\/sub>\u5904\u7406\u6e29\u5ea6\u76f8\u5173\u7684\u7535\u5b50\u586b\u5145\u3002\u63d2\u56fe\uff1aMn 3d\u8f68\u9053\u56fe\u3002\uff08b\uff09\u4e0d\u540cCa0.9<\/sub>Yb0.1<\/sub>MnO3-\u03b4<\/sub>\u50ac\u5316\u5242\u7684OER\u6781\u5316\u66f2\u7ebf\u3002\uff08c\uff09\u81ea\u65cb\u6001\u8dc3\u8fc1\u4ee5\u53ca\u7535\u5b50\u4ecet2g\u8df3\u8dc3\u5230\u4f8b\u5982\u8f68\u9053\u7684\u793a\u610f\u56fe\u3002\uff08d\uff09LaCoO3<\/sub>\u8584\u819c\u7684O K\u8fb9\u7f18XANES\u5149\u8c31\u3002\uff08e\uff09OER\u50ac\u5316\u6027\u80fd\u7684\u6bd4\u8f83\u3002<\/p>\n

\u56fe9. \u8bbe\u8ba1\u7535\u5b50\u81ea\u65cb\u914d\u7f6e\u3002<\/p>\n

\"\"\uff08a\uff092D NiSe2<\/sub>\u7eb3\u7c73\u7247\u4e2d\u79bb\u57df\u81ea\u65cb\u6001\u7684\u793a\u610f\u56fe\u3002\uff08b\uff09CoSe2<\/sub>\uff0cMn0.03<\/sub>Co0.97<\/sub>Se2<\/sub>\u548cMn0.05<\/sub>Co0.95<\/sub>Se2<\/sub>\u7eb3\u7c73\u7247\u7684M-H\u66f2\u7ebf\u3002\uff08c\uff09\u5982\u4f55\u7ed3\u5408\u5f02\u8d28\u81ea\u65cb\u6001\u5f71\u54cd\u539f\u5b50\u6392\u5217\u7684\u7ec6\u5fae\u53d8\u5f62\u7684\u793a\u610f\u56fe\u3002\uff08d\uff09Mn0.05<\/sub>Co0.95<\/sub>Se2<\/sub>\u7eb3\u7c73\u7247\u7684HRTEM\u56fe\u50cf\u548cFFT\u56fe\u6848\u3002\uff08e\uff09\u4e0d\u540c\u7535\u50ac\u5316\u5242\u7684HER\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n

\u3010\u8868<\/strong>\/<\/strong>\u754c\u9762\u5de5\u7a0b\u4f4e\u7ef4\u7535\u6781\u6750\u6599\u7684\u5e94\u7528<\/strong>\u3011<\/p>\n

2.1 <\/strong>\u5168\u89e3\u6c34<\/strong><\/p>\n

\u7535\u5316\u5b66\u6c34\u5206\u89e3\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6e05\u6d01\u9ad8\u6548\u7684\u6280\u672f\uff0c\u53ef\u4ee5\u751f\u4ea7\u9ad8\u7eaf\u5ea6H2<\/sub>\uff0c\u4ee5\u7f13\u89e3\u65e5\u76ca\u4e25\u91cd\u7684\u80fd\u6e90\u5371\u673a\u3002\u6c34\u5168\u5206\u89e3\u7531\u4e24\u4e2a\u534a\u53cd\u5e94\u7ec4\u6210\uff1a\u9633\u6781OER\uff08H2<\/sub>O\u21921\/2O2<\/sub>+2H+<\/sup>+2e–<\/sup>\uff09\u548c\u9634\u6781HER\uff082H+ <\/sup>+ 2e–<\/sup>\u2192H2<\/sub>\uff09\u3002\u7406\u8bba\u4e0a\uff0cOER\u548cHER\u7684\u6c27\u5316\u548c\u8fd8\u539f\u7535\u4f4d\u5206\u522b\u5728\u6807\u51c6\u6761\u4ef6\u4e0b\u4e3a1.23\u548c0V\u3002\u7136\u800c\uff0c\u5546\u4e1a\u7535\u89e3\u69fd\u7684\u5b9e\u9645\u64cd\u4f5c\u7535\u538b\u8fdc\u9ad8\u4e8e\u7406\u8bba\u503c\uff0c\u8fd9\u53ef\u5f52\u56e0\u4e8e\u7535\u50ac\u5316\u5242\u4e2d\u7684\u963b\u788d\u56e0\u7d20\uff0c\u4f8b\u5982\u7535\u5b50\u8f6c\u79fb\u3001\u6d3b\u6027\u4f4d\u70b9\u3001\u7535\u89e3\u8d28\u6269\u6563\u548c\u6c14\u6ce1\u89e3\u5438\u3002\u4e3a\u89e3\u51b3\u4e0a\u8ff0\u6838\u5fc3\u95ee\u9898\uff0c\u8868\/\u754c\u9762\u8c03\u8282\u7b56\u7565\u5c06\u662f\u63d0\u9ad8\u7535\u5316\u5b66\u6c34\u5206\u89e3\u6574\u4f53\u6548\u7387\u7684\u6709\u6548\u65b9\u6cd5\u3002<\/p>\n

\u56fe10. \u5168\u89e3\u6c34\u3002\"\"\uff08a\uff09\u4f7f\u7528N-Ni3<\/sub>S2<\/sub>\/NF\u7535\u50ac\u5316\u5242\u7684\u6c34\u7535\u89e3\u7684\u6781\u5316\u66f2\u7ebf\u3002\uff08b\uff09N-Ni3<\/sub>S2<\/sub>\/NF\u7684\u8ba1\u65f6\u7535\u4f4d\u66f2\u7ebf\u3002\uff08c\uff09\u57fa\u4e8eNi2<\/sub>P\u7535\u6781\u7684\u78b1\u6027\u7535\u89e3\u69fd\u7684I-V\u54cd\u5e94\u3002\u63d2\u56fe\uff1aOER\u540eNi2<\/sub>P\u7684\u6052\u7535\u6d41\u7535\u89e3\u548cHRTEM\u56fe\u50cf\u3002\uff08d\uff09\u57fa\u4e8eNiS2<\/sub>\/CoS2<\/sub>-O NWs\u7684\u6c34\u5206\u79bb\u88c5\u7f6e\u7684\u7535\u538b-\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

2.2 <\/strong>\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60<\/strong><\/p>\n

\u53ef\u518d\u5145\u7535\u7684\u950c\u7a7a\u6c14\u7535\u6c60\u56e0\u5176\u4f4e\u6210\u672c\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u800c\u6210\u4e3a\u672a\u6765\u7535\u52a8\u6c7d\u8f66\u52a8\u529b\u7535\u6c60\u7684\u6709\u5e0c\u671b\u7684\u5019\u9009\u8005\u3002\u7a7a\u6c14\u9634\u6781\u7684\u4e3b\u8981\u6311\u6218\u662f\u7531\u4e8e\u53cd\u5e94\u52a8\u529b\u5b66\u8fc7\u7a0b\u7f13\u6162\u5f15\u8d77\u7684\u9ad8\u8fc7\u7535\u4f4d\u548c\u4f4eO2<\/sub>\u53ef\u9006\u6027\u3002\u5982\u4e0a\u6240\u8ff0\uff0c\u901a\u8fc7\u5229\u7528\u8868\/\u754c\u9762\u5316\u5b66\u6539\u6027\uff0c\u53ef\u4ee5\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u8c03\u63a7\u7535\u6781\u6750\u6599\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\u56fe11. \u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u3002\"\"\uff08a\uff09\u5904\u4e8e\u5145\u7535\u72b6\u6001\u7684\u542b\u6c34\u950c\u7a7a\u6c14\u7535\u6c60\uff08ZAB\uff09\u7684\u793a\u610f\u56fe\u3002\uff08b\uff09SN-Fe\/N\/C-CNT\u6750\u6599\u7684\u5145\u7535\u548c\u653e\u7535\u6781\u5316\u66f2\u7ebf\u3002\uff08c\uff09\u4f7f\u7528S-C2NA\u4f5c\u4e3a\u7535\u50ac\u5316\u5242\u7684\u67d4\u6027ZAB\u7684\u5178\u578b\u6bd4\u5bb9\u91cf\u3002<\/p>\n

2.3 <\/strong>\u71c3\u6599\u7535\u6c60<\/strong><\/p>\n

\u71c3\u6599\u7535\u6c60\u662f\u4e00\u79cd\u53ef\u4ee5\u5c06\u71c3\u6599\u7684\u5316\u5b66\u80fd\u76f4\u63a5\u8f6c\u5316\u4e3a\u7535\u80fd\u7684\u5316\u5b66\u88c5\u7f6e\uff0c\u957f\u671f\u4ee5\u6765\u4e00\u76f4\u88ab\u89c6\u4e3a\u89e3\u51b3\u65e5\u76ca\u52a0\u6df1\u7684\u80fd\u6e90\u5371\u673a\u7684\u5019\u9009\u8005\u3002\u7531\u4e8e\u591a\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u4e2d\u7684\u52a8\u529b\u5b66\u8fdf\u7f13\uff0c\u7535\u6781\u6750\u6599\u5728\u9633\u6781\u6216\u9634\u6781\u4e0a\u7684\u50ac\u5316\u6d3b\u6027\u5dee\u662f\u71c3\u6599\u7535\u6c60\u6539\u5584\u7684\u4e3b\u8981\u9650\u5236\u56e0\u7d20\u3002\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u754c\u9762\u8c03\u5236\u6216\u8868\u9762\u7f3a\u9677\u5de5\u7a0b\u5c06\u662f\u63a8\u52a8\u71c3\u6599\u7535\u6c60\u9ad8\u6d3b\u6027\u7535\u50ac\u5316\u5242\u53d1\u5c55\u7684\u6709\u6548\u9014\u5f84\u3002<\/p>\n

\u56fe12. \u71c3\u6599\u7535\u6c60\u3002\"\"\uff08a\uff09\u71c3\u6599\u7535\u6c60\u7684\u793a\u610f\u56fe\u3002\uff08b\uff09NiMoO4-x<\/sub>\/NF\u7684CV\u66f2\u7ebf\u3002\u63d2\u56fe\uff1aNiMoO4<\/sub>\u4e2d\u6c27\u7a7a\u4f4d\u7684\u793a\u610f\u56fe\u3002\uff08c\uff09\u76f4\u63a5\u5c3f\u7d20\u71c3\u6599\u7535\u6c60\u7684\u6781\u5316\u66f2\u7ebf\u3002\uff08d\uff09\u9650\u5236\u5728\u7ea4\u7ef4\u72b6\u78b3\u4e2d\u7684Fe\u539f\u5b50\u7684HAADF-STEM\u56fe\u50cf\u3002\uff08e\uff09\uff08CM+PANI\uff09-Fe-C\u7535\u50ac\u5316\u5242\u7684ORR\u6d3b\u6027\u3002\uff08f\uff09\uff08CM+PANI\uff09-Fe-C\u7684H2<\/sub>-\u7a7a\u6c14\u71c3\u6599\u7535\u6c60\u6781\u5316\u56fe\u3002<\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

\u7535\u5316\u5b66\u80fd\u6e90\u76f8\u5173\u6280\u672f\u5728\u4e0b\u4e00\u4ee3\u6e05\u6d01\u80fd\u6e90\u8bbe\u5907\u4e2d\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002\u6700\u8fd1\u7684\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728\u7cbe\u5fc3\u5229\u7528\u53ef\u63a7\u6750\u6599\u8bbe\u8ba1\u548c\u8868\/\u754c\u9762\u79d1\u5b66\u539f\u7406\uff0c\u4ee5\u5f00\u53d1\u5177\u6709\u8ff7\u4eba\u534f\u540c\u4f18\u52bf\u7684\u9ad8\u6027\u80fd\u7535\u6781\u6750\u6599\u3002\u4f4e\u7ef4\u7eb3\u7c73\u6750\u6599\u7684\u5feb\u901f\u53d1\u5c55\u4fc3\u8fdb\u4e86\u8be5\u9886\u57df\u7684\u7e41\u8363\uff0c\u5e76\u6709\u63d0\u4f9b\u66f4\u591a\u673a\u4f1a\u6765\u8bbe\u8ba1\u9ad8\u6548\u7535\u6781\u6750\u6599\u3002\u5728\u672c\u6587\u4e2d\uff0c\u7814\u7a76\u8005\u4eec\u6982\u8ff0\u4e86\u65b0\u7684\u5c3a\u5bf8\u9650\u5236\uff0c\u7ed3\u5408\uff0c\u8868\u9762\u91cd\u5efa\uff0c\u754c\u9762\u8c03\u5236\u548c\u7f3a\u9677\u5de5\u7a0b\u7684\u8868\/\u754c\u9762\u8c03\u8282\u7b56\u7565\uff0c\u901a\u8fc7\u8bbe\u8ba1\u5173\u952e\u9650\u5236\u53c2\u6570\uff08\u5982\u7535\u6c14\uff09\u6709\u6548\u4f18\u5316\u4f4e\u7ef4\u7535\u6781\u6750\u6599\u7684\u7535\u50ac\u5316\u6d3b\u6027\u3001\u7535\u5bfc\u7387\u3001\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u66b4\u9732\u3001\u53cd\u5e94\u80fd\u5792\u548c\u7535\u5b50\u81ea\u65cb\u914d\u7f6e\u3002<\/p>\n

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\u6587\u7ae0\u94fe\u63a5\uff1a<\/strong>Surface\/Interfacial Engineering of Inorganic Low-Dimensional Electrode Materials for Electrocatalysis<\/strong>.<\/a> (DOI:10.1021\/acs.accounts.8b00266)<\/p>\n

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