{"id":160222,"date":"2018-12-10T06:30:15","date_gmt":"2018-12-09T22:30:15","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=160222"},"modified":"2018-12-10T12:33:47","modified_gmt":"2018-12-10T04:33:47","slug":"%e3%80%90%e6%a0%a1%e7%a8%bf%e4%b8%89%e6%ac%a1%e6%9c%aa%e5%9b%9e%e5%a4%8d%e3%80%91%e5%a4%8d%e6%97%a6%e5%a4%a7%e5%ad%a6%e9%99%88%e8%8c%82macromolecules%ef%bc%9a%e7%bb%93%e6%9e%84%e5%8f%af%e8%b0%83","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=160222","title":{"rendered":"\u590d\u65e6\u5927\u5b66\u9648\u8302Macromolecules\uff1a\u7ed3\u6784\u53ef\u8c03\u63a7\u3001\u5149\/\u7535\u6027\u80fd\u53ef\u8c03\u8282\u7684\u4ea4\u53c9\u5171\u8f6d\u805a\u5408\u7269\u7684\u5236\u5907\u7684\u65b0\u9014\u5f84"},"content":{"rendered":"<p>\u3010<strong>\u5f15\u8a00<\/strong>\u3011<\/p>\n<p>\u57fa\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u53cd\u5e94\u7684\u805a\u5408\u65b9\u6cd5\u7684\u53d1\u5c55\u6781\u5927\u5730\u4e30\u5bcc\u4e86\u9ad8\u5206\u5b50\u79d1\u5b66\u7684\u9886\u57df\uff0c\u4f7f\u6709\u6548\u5730\u5408\u6210\u590d\u6742\u7684\u3001\u591a\u6837\u7684\u529f\u80fd\u6750\u6599\u6210\u4e3a\u53ef\u80fd\u3002\u4ea4\u53c9\u5171\u8f6d\u805a\u5408\u7269\u4e3a\u6750\u6599\u5de5\u7a0b\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u4f1a\u3002\u8bf8\u5982\u91cf\u5b50\u5e72\u6d89\u3001\u975e\u7ebf\u6027\u5149\u5b66\u7684\u4e0d\u540c\u9886\u57df\u5df2\u7ecf\u5f00\u53d1\u4e86\u76f8\u5173\u7684\u6750\u6599\u3002\u7136\u800c\uff0c\u548c\u5e7f\u6cdb\u7814\u7a76\u7684\u5171\u8f6d\u805a\u5408\u7269\u76f8\u6bd4\uff0c\u5b83\u4eec\u7684\u5408\u6210\u65b9\u6cd5\u5f88\u5c11\u88ab\u62a5\u9053\u3002\u5b83\u4eec\u7684\u73b0\u6709\u7684\u5408\u6210\u65b9\u6cd5\u9700\u8981\u7528\u5230\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\uff0c\u8fd9\u9650\u5236\u4e86\u8fd9\u4e9b\u65b9\u6cd5\u7684\u4f7f\u7528\u548c\u5b83\u7684\u89c4\u6a21\u3002\u94af\u50ac\u5316\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u4e3aC\u2212C\u5076\u8054\u53cd\u5e94\u63d0\u4f9b\u4e86\u53e6\u4e00\u79cd\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u8fd9\u4e2a\u50ac\u5316\u53cd\u5e94\u8fd8\u6ca1\u5e94\u7528\u5728\u9ad8\u5206\u5b50\u5316\u5b66\u4e2d\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p>\u590d\u65e6\u5927\u5b66\u7684\u805a\u5408\u7269\u5206\u5b50\u5de5\u7a0b\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u548c\u4e91\u5357\u5927\u5b66\u7684\u81ea\u7136\u8d44\u6e90\u836f\u7269\u5316\u5b66\u6559\u80b2\u90e8\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u9996\u6b21\u7528\u5bf9\u7532\u82ef\u78fa\u9170\u8159\u548c\u5364\u4ee3\u82b3\u70c3\u901a\u8fc7\u94af\u50ac\u5316\u7684\u4ea4\u53c9\u5076\u8054\u805a\u5408\u53cd\u5e94\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u4ea4\u53c9\u5171\u8f6d\u805a\u5408\u7269\u3002\u5b83\u4eec\u7ed3\u6784\u89c4\u6574\u3001\u52a0\u5de5\u6027\u597d\u3001\u70ed\u7a33\u5b9a\u6027\u5f3a\u3001\u4ea7\u7387\u9ad8\u3002\u7531\u4e8e\u5b83\u4eec\u5177\u6709\u72ec\u7279\u7684\u4e59\u70ef\u57fa\u7ed3\u6784\uff0c\u56e0\u6b64\u5b83\u4eec\u5728\u540e\u805a\u5408\u8fc7\u7a0b\u4e2d\u5f88\u5bb9\u6613\u88ab\u6539\u6027\uff0c\u88ab\u8d4b\u4e88\u9ad8\u5ea6\u7684\u7ed3\u6784\u590d\u6742\u6027\u3002\u800c\u4e14\uff0c\u5b83\u4eec\u5177\u6709\u6709\u8da3\u7684\u3001\u53ef\u8c03\u8282\u7684\u5149\u5b66\u548c\u5bfc\u7535\u6027\u80fd\uff0c\u5728\u5f88\u591a\u5e94\u7528\u4e2d\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5b66\u672f\u671f\u520a<em>Macromolecules<\/em>\u00a0\u62a5\u9053\u4e86\u76f8\u5173\u6210\u679c\uff0c\u901a\u8baf\u4f5c\u8005\u662f\u590d\u65e6\u5927\u5b66\u7684\u9648\u8302\u7814\u7a76\u5458\u3002<\/p>\n<p>\u3010<strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p>Scheme 1. \u5171\u8f6d\u805a\u5408\u7269\u548c\u4ea4\u53c9\u5171\u8f6d\u805a\u5408\u7269\u7684\u5408\u6210<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160302\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u56fe\u724720181126114132.png\" alt=\"\" width=\"600\" height=\"424\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u56fe\u724720181126114132.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u56fe\u724720181126114132-300x212.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>Scheme 2.\u4ea4\u53c9\u5171\u8f6d\u805a\u5408\u7269P1\u7684\u5408\u6210\u7684\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160301\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u56fe\u724720181126114424.png\" alt=\"\" width=\"600\" height=\"625\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u56fe\u724720181126114424.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u56fe\u724720181126114424-288x300.png 288w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>Figure 1.P1\u7684\u7ed3\u6784\u7684\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160299\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126114506.jpg\" alt=\"\" width=\"600\" height=\"960\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126114506.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126114506-188x300.jpg 188w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a\u2212c)\u00a0Scheme 2\u4e2dentry 3\uff08a\uff09\u3001entry 4\uff08b\uff09\u3001entry 6\uff08c\uff09\u7684\u4ea7\u7269P1\u7684<sup>1<\/sup>H NMR\u56fe<\/p>\n<p>(d)entry 6\uff08c\uff09\u7684\u4ea7\u7269P1\u7684<sup>13<\/sup>C NMR\u56fe<\/p>\n<p>Scheme 2.\u4ea4\u53c9\u5171\u8f6d\u805a\u5408\u7269P1-P15\u7684\u5408\u6210<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160298\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126114539.jpg\" alt=\"\" width=\"600\" height=\"604\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126114539.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126114539-150x150.jpg 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126114539-298x300.jpg 298w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>Figure 2.P1-P15\u7684SEC\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160296\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126115621.jpg\" alt=\"\" width=\"600\" height=\"304\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126115621.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126115621-300x152.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>Scheme 4.P7\u7684\u540e\u4fee\u9970<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160308\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126134043.jpg\" alt=\"\" width=\"600\" height=\"460\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126134043.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126134043-300x230.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>Figure 3. \u5173\u4e8e\u5149\u5b66\u6027\u8d28\u548c\u5bfc\u7535\u6027\u8d28\u7684\u7814\u7a76<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160297\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126115138.jpg\" alt=\"\" width=\"600\" height=\"424\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126115138.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/11\/QQ\u622a\u56fe20181126115138-300x212.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a, b)\u4e0d\u540cM<sub>n<\/sub>\u7684P13\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\u548c\u8367\u5149\u5149\u8c31<\/p>\n<p>(c) \u7531M<sub>n<\/sub> = 36.3 kDa\u7684P13\u5236\u6210\u7684\u819c<\/p>\n<p>(d)P3\u3001P8\u3001P10\u7684\u5149\u53d1\u5c04<\/p>\n<p>(e)\u7531\u63ba\u6742\u4e86\u7898\u7684P13\u5236\u6210\u7684\u819c<\/p>\n<p>\u3010<strong>\u5c0f\u7ed3<\/strong>\u3011<\/p>\n<p>\u4f5c\u8005\u62a5\u9053\u4e86\u9996\u6b21\u901a\u8fc7\u94af\u50ac\u5316\u7684\u5bf9\u7532\u82ef\u78fa\u9170\u8159\u548c\u5364\u4ee3\u82b3\u70c3\u7684\u4ea4\u53c9\u5076\u8054\u805a\u5408\u53cd\u5e94\u6765\u5408\u6210\u4ea4\u53c9\u5171\u8f6d\u805a\u5408\u7269\u3002\u8fd9\u79cd\u65b9\u6cd5\u7684\u539f\u6750\u6599\u5bb9\u6613\u83b7\u53d6\uff0c\u4ea7\u7387\u9ad8\uff0c\u4ea7\u7269\u7ed3\u6784\u89c4\u6574\u3002\u800c\u4e14\uff0c\u8fd9\u4e9b\u805a\u5408\u7269\u8868\u73b0\u51fa\u4e0d\u9519\u7684\u52a0\u5de5\u6027\u548c\u70ed\u7a33\u5b9a\u6027\u3001\u7ed3\u6784\u53ef\u8c03\u63a7\u548c\u5149\u5b66\u3001\u5bfc\u7535\u6027\u80fd\u53ef\u8c03\u8282\uff0c\u5177\u6709\u591a\u79cd\u6f5c\u5728\u7684\u4f5c\u7528\u3002\u7531\u4e8e\u4ea4\u53c9\u5171\u8f6d\u7ed3\u6784\u5728\u5f88\u591a\u5e94\u7528\u4e2d\u5177\u6709\u6781\u5927\u7684\u6f5c\u529b\uff0c\u4f5c\u8005\u76f8\u4fe1\u8fd9\u79cd\u65b9\u6cd5\u4e3a\u6750\u6599\u5de5\u7a0b\u5f00\u8f9f\u4e86\u65b0\u7684\u9053\u8def\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<strong><a title=\"Palladium-Catalyzed Cross-Coupling Polymerization: A New Access to Cross-Conjugated Polymers with Modifiable Structure and Tunable Optical\/Conductive Properties\" href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/acs.macromol.8b02163\" target=\"_blank\" rel=\"noopener\">Palladium-Catalyzed Cross-Coupling Polymerization: A New Access to Cross-Conjugated Polymers with Modifiable Structure and Tunable Optical\/Conductive Properties<\/a><\/strong><\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8kv1004\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<u><\/u>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u57fa\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u53cd\u5e94\u7684\u805a\u5408\u65b9\u6cd5\u7684\u53d1\u5c55\u6781\u5927\u5730\u4e30\u5bcc\u4e86\u9ad8\u5206\u5b50\u79d1\u5b66\u7684\u9886\u57df\uff0c\u4f7f\u6709\u6548\u5730\u5408\u6210\u590d\u6742\u7684\u3001\u591a\u6837\u7684\u529f\u80fd\u6750\u6599\u6210\u4e3a\u53ef\u80fd\u3002\u4ea4\u53c9\u5171\u8f6d\u805a\u5408\u7269\u4e3a\u6750\u6599\u5de5\u7a0b\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u4f1a&#8230;<\/p>\n","protected":false},"author":1592,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-160222","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/160222"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1592"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=160222"}],"version-history":[{"count":8,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/160222\/revisions"}],"predecessor-version":[{"id":161503,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/160222\/revisions\/161503"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=160222"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=160222"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=160222"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}