{"id":161068,"date":"2018-12-05T06:30:20","date_gmt":"2018-12-04T22:30:20","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=161068"},"modified":"2018-12-06T12:40:11","modified_gmt":"2018-12-06T04:40:11","slug":"khalil-amine%e3%80%81gerbrand-ceder%e3%80%81%e5%a4%8f%e5%ae%9a%e5%9b%bd%e7%ad%89%e5%9c%a8%e5%af%8c%e9%94%82%e9%94%b0%e5%9f%ba%e6%9d%90%e6%96%99%e6%96%b9%e5%90%91%e7%9a%84%e6%9c%80%e6%96%b0%e8%bf%9b","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=161068","title":{"rendered":"Bryan Mccloskey\u3001\u590f\u5b9a\u56fd\u3001\u90ed\u7389\u56fd\u7b49\u5728\u5bcc\u9502\u9530\u57fa\u6750\u6599\u65b9\u5411\u7684\u6700\u65b0\u8fdb\u5c55"},"content":{"rendered":"

1.<\/b><\/strong>Bryan Mccloskey<\/b><\/strong>\uff08\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\uff09<\/b><\/strong><\/p>\n

\u4eba\u7269\u7b80\u4ecb\uff1a<\/b><\/strong>Bryan Mccloskey, 2009\u5e74\u4e8e\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c2014\u5e74\u52a0\u5165\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u3002\u4ed6\u7684\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u662f\u7535\u5316\u5b66\u50a8\u80fd\uff0c\u7535\u5316\u5b66\u50ac\u5316\u548c\u805a\u5408\u7269\u7684\u5206\u5b50\u548c\u79bb\u5b50\u8f93\u8fd0\u3002\u8fc4\u4eca\u53d1\u8868\u6587\u7ae0\u8fbe100\u4f59\u7bc7\u3002<\/p>\n

\u7814\u7a76\u52a8\u6001\uff1a<\/b><\/strong>\u4f5c\u8005\u7814\u7a76\u4e86\u5bcc\u9502\u91d1\u5c5e\u6c27\u5316\u7269Li1.2<\/sub>Ni0.2<\/sub>TM0.6<\/sub>O2<\/sub>(TM=Mn\uff0cRu)\u663e\u793a\u51fa\u9ad8\u7684\u7535\u5316\u5b66\u5bb9\u91cf\uff0c\u4f46\u662f\u63d0\u4f9b\u8fd9\u79cd\u5bb9\u91cf\u7684\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u5728\u6bcf\u4e2a\u6750\u6599\u4e2d\u660e\u663e\u4e0d\u540c\uff0c\u5373\u4f7f\u6bcf\u4e2a\u6750\u6599\u7684\u7ed3\u6784\u76f8\u4f3c\u3002\u5229\u7528X\u5c04\u7ebf\u80fd\u8c31\u6280\u672f\uff0c\u9610\u660e\u4e86\u4e24\u79cd\u5316\u5408\u7269\u4e2d\u8fc7\u6e21\u91d1\u5c5e\u7684\u7535\u8377\u8865\u507f\u673a\u5236\uff0c\u5e76\u9a8c\u8bc1\u4e86LNMO\u4e2dNi\u548cO\u4ee5\u53caLNRO\u4e2dNi\u548cRu\u7684\u7535\u5316\u5b66\u6d3b\u6027\u3002\u901a\u8fc7LNMO\u7684RIXS\u884d\u5c04\u76f4\u63a5\u89c2\u5bdf\u5230\u9634\u79bb\u5b50\u6c27\u6c27\u5316\u8fd8\u539f\u7684\u7279\u5f81\uff0c\u800cLNRO\u4e2d\u6ca1\u6709\u8fd9\u79cd\u7279\u5f81\uff0c\u8868\u660eLNRO\u4e2d\u6ca1\u6709\u8fd9\u79cd\u6c27\u6c27\u5316\u8fd8\u539f\u7684\u6d3b\u6027\u3002\u901a\u8fc7\u6bd4\u8f83\u5177\u6709\u76f8\u4f3c\u7ed3\u6784\u7684\u6750\u6599\uff0c\u8bc1\u660e\u4e86\u8fc7\u6e21\u91d1\u5c5e\u5bf9\u5bcc\u9502\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u6c27\u6d3b\u5316\u7684\u6f5c\u5728\u5f71\u54cd\u3002<\/p>\n

\u56fe1 \u00a0LRMO\u548cLNRO\u7684RIXS\u56fe<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Elucidating anionic oxygen activity in lithium-rich layered oxides<\/b><\/strong>. <\/b><\/strong>(Nature Communications<\/i><\/em>. <\/i><\/em>2018, 947. DOI:10.1038\/s41467-018-03403-9)<\/p>\n

2.<\/b><\/strong>Gerbrand Ceder<\/b><\/strong>(<\/b><\/strong>\u52a0\u5229\u798f\u5c3c\u4e9a\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821<\/b><\/strong>)<\/b><\/strong><\/p>\n

\u4eba\u7269\u7b80\u4ecb\uff1a<\/b><\/strong>Gerbrand Ceder\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u662f\u57fa\u4e8e\u7b2c\u4e00\u6027\u539f\u7406\u548c\u9009\u62e9\u6027\u8bd5\u9a8c\u8fdb\u884c\u6750\u6599\u8bbe\u8ba1\u3002\u540c\u65f6\u7814\u7a76\u80fd\u6e90\u6750\u6599\uff0c\u5305\u62ec\u80fd\u91cf\u50a8\u5b58\uff0c\u592a\u9633\u80fd\u548c\u70ed\u70b9\u8f6c\u6362\u4ee5\u53ca\u6750\u6599\u57fa\u56e0\u548c\u9ad8\u901a\u91cf\u8ba1\u7b97\u3001\u6750\u6599\u79d1\u5b66\u65b9\u9762\u7684\u6570\u636e\u6316\u6398\u548c\u7edf\u8ba1\u5b66\u4e60\u3002\u6750\u6599\u53ca\u5176\u4e9a\u7a33\u6001\u7684\u5f62\u6838\u548c\u6210\u578b\u3002\u8fc4\u4eca\u53d1\u5e03\u6587\u7ae0\u8fbe320\u591a\u7bc7\uff0c\u8d85\u8fc720\u9879\u4e13\u5229\u3002<\/p>\n

\u7814\u7a76\u52a8\u6001\uff1a<\/b><\/strong>Gerbrand Ceder\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u4e0eJinhyuk Lee\u5408\u4f5c\u63d0\u51fa\u4e86\u5728\u65e0\u5e8f\u5ca9\u76d0\u7ed3\u6784\u4e2d\u7ed3\u5408\u9ad8\u4ef7\u9633\u79bb\u5b50\u548c\u6c1f\u90e8\u5206\u53d6\u4ee3\u6c27\u7684\u7b56\u7565\uff0c\u4ee5\u5c06\u53ef\u9006Mn2+<\/sup>\/Mn4+<\/sup>\u53cc\u6c27\u5316\u8fd8\u539f\u5076\u7ed3\u5408\u5230\u5bcc\u9502\u9530\u57fa\u6750\u6599\u4e2d\uff0c\u83b7\u5f97\u9ad8\u5bb9\u91cf\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3002Mn2+<\/sup>\/Mn4+<\/sup>\u6c27\u5316\u8fd8\u539f\u7684\u4f7f\u7528\u964d\u4f4e\u4e86\u6c27\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\uff0c\u4ece\u800c\u7a33\u5b9a\u4e86\u6750\u6599\u3002<\/p>\n

\u56fe2 \u00a0<\/b><\/strong>Li<\/b><\/strong>2<\/b><\/sub><\/strong>Mn<\/b><\/strong>2\/3<\/b><\/sub><\/strong>Nb<\/b><\/strong>1\/3<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>F<\/b><\/strong>\u8bbe\u8ba1\u548c\u7ed3\u6784\u7279\u70b9<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Reversible Mn2+\/Mn4+\u00a0double redox in lithium-excess cathode<\/b><\/strong>\u00a0<\/b><\/strong>materials<\/b><\/strong>. <\/b><\/strong>(Nature<\/i><\/em>.<\/i><\/em>2018,\u00a0556,\u00a0185\u2013190.DOI:\u00a010.1038\/s41586-018-0015-4\uff09<\/p>\n

3.Doron Aurbach<\/b><\/strong>\uff08<\/b><\/strong>\u4ee5\u8272\u5217\u5df4\u4f0a\u5170\u5927\u5b66<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

\u4eba\u7269\u7b80\u4ecb\uff1a<\/b><\/strong>Doron Aurbach\uff0c\u5df4\u4f0a\u5170\u7eb3\u7c73\u6280\u672f\u4e0e\u5148\u8fdb\u6750\u6599\u7814\u7a76\u6240\u6e05\u6d01\u6280\u672f\u4e2d\u5fc3\u4e3b\u4efb\u3001\u4ee5\u8272\u5217\u5b9e\u9a8c\u5ba4\u8bc4\u5ba1\u673a\u6784\u4e3b\u5e2d\u3002\u5728\u56fd\u9645\u77e5\u540d\u79d1\u5b66\u671f\u520a\u4e0a\u53d1\u8868\u4e86570\u4f59\u7bc7\u6587\u7ae0\uff0c\u5f15\u7528\u6b21\u6570\u603b\u8ba1\u8d85\u8fc724000\u6b21\uff0cH\u56e0\u5b5091\uff0c\u83b7\u5f9725\u9879\u53d1\u660e\u4e13\u5229\uff0c\u4e3b\u7f16\u548c\u53c2\u4e0e\u7f16\u8457\u4e8612\u672c\u56fd\u9645\u79d1\u5b66\u4e13\u8457\u3002<\/p>\n

\u7814\u7a76\u52a8\u6001\uff1a<\/b><\/strong>\u5bcc\u9502\u9530\u57fa\u6750\u6599\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff08\u8d85\u8fc7250mAh g-1<\/sup>\uff09\uff0c\u7136\u800c\u6750\u6599\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5b58\u5728\u5927\u7684\u9996\u5708\u5faa\u73af\u4e0d\u53ef\u9006\u5bb9\u91cf\u3001\u5bb9\u91cf\u8870\u51cf\u3001\u4f4e\u500d\u7387\u5bb9\u91cf\u3001\u3001\u5927\u5e73\u5747\u653e\u7535\u7535\u538b\u8870\u51cf\u7b49\u95ee\u9898\u3002\u4f5c\u8005\u7efc\u8ff0\u4e86\u91c7\u7528\u7528\u94a0\u3001\u9541\u3001\u94dd\u3001\u94c1\u3001\u94b4\u3001\u948c\u7b49\u63ba\u6742\u5bcc\u9502\u9530\u57fa\u6750\u6599\uff0c\u6709\u5229\u4e8e\u7a33\u5b9a\u7535\u6781\u7684\u5bb9\u91cf\uff0c\u6291\u5236\u653e\u7535\u7535\u538b\u8870\u51cf\uff1b\u901a\u8fc7Al2<\/sub>O3<\/sub>\u3001V2<\/sub>O5<\/sub>\u3001AlF3<\/sub>\u3001AlPO4<\/sub>\u7b49\u5305\u8986\u6216\u901a\u8fc7\u6c14\u4f53\u5904\u7406(\u4f8b\u5982\u901a\u8fc7NH3<\/sub>)\u8fdb\u884c\u8868\u9762\u6539\u6027\uff0c\u8fd8\u53ef\u4ee5\u589e\u5f3a\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u7535\u538b\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe3 \u00a0LiMO<\/b><\/strong>2<\/b><\/sub><\/strong>\u548cLi<\/b><\/strong>2<\/b><\/sub><\/strong>MnO<\/b><\/strong>3<\/b><\/sub><\/strong>\u7ed3\u6784\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1aReview on Challenges and Recent Advances in the Electrochemical Performance of High Capacity Li<\/b><\/strong>\u2010<\/b><\/strong>\u00a0and Mn<\/b><\/strong>\u2010<\/b><\/strong>Rich Cathode Materials for Li<\/b><\/strong>\u2010<\/b><\/strong>Ion Batteries<\/b><\/strong>.<\/b><\/strong>\u00a0<\/b><\/strong>(Adv. Energy Mater<\/i><\/em>.\u00a02018,1702397. DOI:10.1002\/aenm.201702397)<\/p>\n

4.\u590f\u5b9a\u56fd\uff08\u5317\u4eac\u5927\u5b66\uff09<\/b><\/strong><\/p>\n

\u4eba\u7269\u7b80\u4ecb\uff1a<\/b><\/strong>\u590f\u5b9a\u56fd\uff0c\u5317\u4eac\u5927\u5b66\u5de5\u5b66\u9662\u80fd\u6e90\u4e0e\u8d44\u6e90\u5de5\u7a0b\u7cfb&\u5148\u8fdb\u6750\u6599\u4e0e\u7eb3\u7c73\u6280\u672f\u7cfb\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u5317\u4eac\u5927\u5b66\u5de5\u5b66\u9662\u80fd\u6e90\u4e0e\u8d44\u6e90\u5de5\u7a0b\u7cfb\u526f\u4e3b\u4efb\u3002\u5148\u8fdb\u7535\u6c60\u6750\u6599\u7406\u8bba\u4e0e\u6280\u672f\u5317\u4eac\u5e02\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\u3002\u7814\u7a76\u9886\u57df\u4e3b\u8981\u5305\u62ec\u50ac\u5316\u5242\u3001\u9502\u63d2\u5165\u5316\u5408\u7269\u548c\u6750\u6599\u6a21\u62df\u8ba1\u7b97\u3002<\/p>\n

\u7814\u7a76\u52a8\u6001\uff1a<\/b><\/strong><\/p>\n

(1)\u4f20\u7edf\u7684O3\u578b\u5bcc\u9502\u9530\u57fa\u6750\u6599\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u5177\u6709\u7535\u538b\u548c\u5bb9\u91cf\u8870\u51cf\u7684\u7f3a\u70b9\uff0c\u590f\u5b9a\u56fd\uff08\u901a\u8baf\u4f5c\u8005\uff09\u62a5\u9053\u4e86O2\u578b\u5355\u5c42Li2<\/sub>MnO3<\/sub>\u8d85\u7ed3\u6784\u7684\u5bcc\u9502\u9530\u57fa\u6750\u6599\uff0c\u653e\u70b9\u6bd4\u5bb9\u91cf\u8fbe\u5230400mAh g-1<\/sup>\uff08\u80fd\u91cf\u5bc6\u5ea6\u4e3a1360Wh kg-1<\/sup>\uff09\uff0c\u5e76\u89e3\u6790\u4e86\u6750\u6599\u7684\u9ad8\u5bb9\u91cf\u6765\u81ea\u4e8e\u6750\u6599\u5185\u7a33\u5b9a\u7684\u9634\u79bb\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002<\/p>\n

\u56fe4 \u00a0<\/b><\/strong>Li<\/b><\/strong>1.25<\/b><\/sub><\/strong>Co<\/b><\/strong>0.25<\/b><\/sub><\/strong>Mn<\/b><\/strong>0.50<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u6750\u6599\u7684HAADF\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>A High-Capacity O2-Type Li-Rich Cathode Material<\/b><\/strong>\u00a0with a Single-Layer Li2MnO3 Superstructure<\/b><\/strong>. <\/b><\/strong>(Adv. Mater. <\/i><\/em>2018, 1707255.\u00a0DOI: 10.1002\/adma.201707255)<\/p>\n

(2)\u4f5c\u8005\u62a5\u9053\u4e86\u91c7\u7528Fe3+<\/sup>\u63ba\u6742\u8fdb\u5165\u7acb\u65b9\u578bLi2<\/sub>TiO3<\/sub>\u4e2d\uff0c\u63d0\u4f9b\u4e86\u7a33\u5b9a\u7684\u9634\u79bb\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u7ed3\u5408\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\uff0c\u7535\u5b50\u8f6c\u79fb\u4e3b\u8981\u53d1\u751f\u5728\u88abFe3+<\/sup>\u5305\u56f4\u7684\u6c27\u539f\u5b50\u4e0a\uff0c\u800c\u4e0d\u662fTi4+<\/sup>,\u00a0Fe3+<\/sup>\u4f5c\u4e3a\u50ac\u5316\u5242\u5f15\u5165\u5230\u6750\u6599\u4e2d\u4fc3\u8fdb\u4e86\u7a33\u5b9a\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u5c06Co3+<\/sup>\u63ba\u6742\u5165Li2<\/sub>TiS3<\/sub>\u5c55\u793a\u51fa\u4e86\u76f8\u4f3c\u7684\u7ed3\u679c\u3002<\/p>\n

\u56fe5 \u00a0<\/b><\/strong>Li<\/b><\/strong>2<\/b><\/sub><\/strong>TiO<\/b><\/strong>3<\/b><\/sub><\/strong>\u00a0and Li<\/b><\/strong>1.2<\/b><\/sub><\/strong>Ti<\/b><\/strong>0.4<\/b><\/sub><\/strong>Fe<\/b><\/strong>0.4<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u5145\u7535\u8f6c\u79fb\u8fc7\u7a0b\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Thermodynamic Activation of Charge Transfer in Anionic<\/b><\/strong>
\n <\/b><\/strong>Redox Process for Li-Ion Batteries<\/b><\/strong>. (<\/b><\/strong>Adv. Funct. Mater. <\/i><\/em>2018, 28<\/i><\/em>, 1704864.\u00a0DOI: 10.1002\/adfm.201704864)<\/p>\n

5.\u90ed\u7389\u56fd\uff08\u4e2d\u79d1\u9662\u5316\u5b66\u6240\uff09<\/b><\/strong><\/p>\n

\u4eba\u7269\u7b80\u4ecb\uff1a<\/b><\/strong>\u90ed\u7389\u56fd\uff0c 1978\u5e74\u51fa\u751f\u30022004\u5e74\u4e8e\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u83b7\u535a\u58eb\u5b66\u4f4d\u30022004-2006\u5e74\u5728\u5fb7\u56fd\u9a6c\u666e\u56fa\u4f53\u7814\u7a76\u6240\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\u30022006-2007\u5e74\u88ab\u8058\u4e3a\u9a6c\u666e\u56fa\u4f53\u7814\u7a76\u6240Staff Scientist\u30022007\u5e74\u5165\u9009\u5316\u5b66\u6240\u201c\u5f15\u8fdb\u56fd\u5916\u6770\u51fa\u9752\u5e74\u4eba\u624d\u8ba1\u5212\u201d\uff0c\u52a0\u5165\u4e2d\u79d1\u9662\u5206\u5b50\u7eb3\u7c73\u7ed3\u6784\u4e0e\u7eb3\u7c73\u6280\u672f\u9662\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4efb\u7814\u7a76\u5458\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u3001\u8bfe\u9898\u7ec4\u957f\u30022012\u5e74\u83b7\u5f97\u201c\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u201d\u652f\u6301\uff0c\u5e76\u5165\u9009\u4e2d\u592e\u7ec4\u7ec7\u90e8\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u9996\u6279\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u3002<\/p>\n

\u7814\u7a76\u5de5\u4f5c\u4e3b\u8981\u96c6\u4e2d\u5728\u9502\u79bb\u5b50\u7535\u6c60\u3001\u9502\u786b\u7535\u6c60\u7b49\u80fd\u91cf\u8f6c\u5316\u4e0e\u50a8\u5b58\u5668\u4ef6\u4e2d\u529f\u80fd\u7eb3\u7c73\u7ed3\u6784\u6750\u6599\u7684\u8bbe\u8ba1\u3001\u5236\u5907\u3001\u7ec4\u88c5\u3001\u7ed3\u6784\u548c\u6027\u80fd\u5173\u7cfb\u7684\u57fa\u7840\u79d1\u5b66\u7814\u7a76\u548c\u5e94\u7528\u63a2\u7d22\u3002\u5728Nature Mater.<\/i><\/em>\uff081\u7bc7\uff09\u3001Acc. Chem. Res.<\/i><\/em>\uff081\u7bc7\uff09\u3001J. Am. Chem. Soc.<\/i><\/em>\uff088\u7bc7\uff09\u3001Angew. Chem. Int. Ed.<\/i><\/em>\u00a0(4\u7bc7)\u3001Adv. Mater.<\/i><\/em>\uff0818\u7bc7\uff09\u3001Adv. Energy Mater.<\/i><\/em>\uff083\u7bc7\uff09\u3001Adv. Funct. Mater.<\/i><\/em>\uff084\u7bc7\uff09\u3001NPG Asia Mater.<\/i><\/em>\uff082\u7bc7\uff09\u3001Energy Environ. Sci.<\/i><\/em>\uff084\u7bc7\uff09\u7b49\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u6587140\u4f59\u7bc7\u3002\u53d1\u8868\u8bba\u6587\u88ab\u4ed6\u4ebaSCI\u5f15\u75287600\u591a\u6b21\u3002<\/p>\n

\u7814\u7a76\u52a8\u6001\uff1a<\/b><\/strong>\u4f5c\u8005\u62a5\u9053\u4e86\u63d0\u9ad8\u5bcc\u9502\u9530\u57fa\u6750\u6599\u4e2dNi\u5143\u7d20\u542b\u91cf\u548c\u91cd\u590d\u9000\u706b\u7684\u7b56\u7565\uff0c\u5c06\u6750\u6599\u7684\u7535\u538b\u5e73\u53f0\u75313.5V\u63d0\u9ad8\u52303.8V\uff0c\u80fd\u91cf\u5bc6\u5ea6\u7531912Wh kg-1<\/sup>\u63d0\u9ad8\u52301033Wh kg-1<\/sup>\u3002\u63d0\u5347\u7684\u673a\u7406\u6765\u6e90\u4e8e\u66f4\u4f4e\u7684Li2<\/sub>MnO3<\/sub>\u542b\u91cf\u3002<\/p>\n

\u56fe6 \u5bcc\u9502\u9530\u57fa\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>High<\/b><\/strong>\u2010<\/b><\/strong>Capacity Cathode Material with High Voltage for Li<\/b><\/strong>\u2010<\/b><\/strong>Ion Batteries<\/b><\/strong>.<\/b><\/strong>(Adv. Mater.<\/i><\/em>\u00a02018,<\/i><\/em>1705575.\u00a0<\/b><\/strong>DOI:10.1002\/adma.201705575)<\/p>\n

6.\u738b\u5146\u7fd4(\u4e2d\u79d1\u9662\u7269\u7406\u6240)<\/b><\/strong><\/p>\n

\u4eba\u7269\u7b80\u4ecb\uff1a<\/b><\/strong>\u738b\u5146\u7fd4\uff0c1963\u5e744\u6708\u51fa\u751f\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30021992\u5e74\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u5149\u5b66\u4e13\u4e1a\u83b7\u5f97\u7855\u58eb\u5b66\u4f4d\u5e76\u7559\u6240\u5de5\u4f5c\uff0c1998\u5e74\u5728\u4e2d\u79d1\u9662\u7269\u7406\u6240\u51dd\u805a\u6001\u7269\u7406\u4e13\u4e1a\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\u5e76\u83b7\u5f97\u7559\u6240\u5de5\u4f5c\u8d44\u683c\u30021998\u5e746\u6708\u81f32000\u5e747\u6708\u5148\u540e\u5728\u65e5\u672c\u4e09\u91cd(Mie)\u5927\u5b66\u3001\u82f1\u56fdUniversity of St. Andrews\u548c\u7f8e\u56fdUniversity of Michigan\u505a\u535a\u58eb\u540e\u7814\u7a76\u3002<\/p>\n

\u7814\u7a76\u52a8\u6001\uff1a<\/b><\/strong>\u7531\u4e8e\u5bcc\u9502\u9530\u57fa\u6750\u6599\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\uff08TMs\uff09\u4f1a\u4e0d\u53ef\u63a7\u8fc1\u79fb\u5bfc\u81f4\u6750\u6599\u7535\u538b\u5e73\u53f0\u964d\u4f4e\u548c\u5bb9\u91cf\u4e0b\u964d\uff0c\u56e0\u800c\u4f5c\u8005\u62a5\u9053\u4e86Li1.2<\/sub>Mo0.6<\/sub>Fe0.2<\/sub>O2<\/sub>\u9884\u5148\u5145\u7535\uff0c\u4fc3\u8fdb\u6750\u6599\u53ef\u63a7\u5f62\u6210\u5ca9\u76d0\u76f8\uff0c\u8fdb\u800c\u6291\u5236\u6750\u6599\u7684\u7535\u538b\u5e73\u53f0\u964d\u4f4e\u548c\u5bb9\u91cf\u4e0b\u964d\u3002<\/p>\n

\u56fe7 \u6750\u6599\u7ed3\u6784\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Another Strategy, Detouring Potential Decay by Fast Completion of Cation Mixing<\/b><\/strong>.<\/b><\/strong>\u00a0<\/i><\/b><\/em><\/strong>(Adv. Energy Mater<\/i><\/em>.\u00a02018, 1703092. DOI:10.1002\/aenm.201703092)<\/p>\n

7.\u5218\u5146\u5e73(\u5b81\u6ce2\u6750\u6599\u6240)<\/b><\/strong><\/p>\n

\u4eba\u7269\u7b80\u4ecb\uff1a<\/b><\/strong>\u5218\u5146\u5e73\uff0c\u535a\u58eb\uff0c\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u5165\u9009\u4e2d\u79d1\u9662\u767e\u4eba\u8ba1\u5212\u3001\u79d1\u6280\u90e8\u521b\u65b0\u4eba\u624d\u63a8\u8fdb\u8ba1\u5212\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\u3002\u7814\u7a76\u65b9\u5411\u4e3a\u77f3\u58a8\u70ef\u548c\u52a8\u529b\u9502\u79bb\u5b50\u7535\u6c60\u53ca\u5176\u6750\u6599\u6280\u672f\u3002\u5df2\u5728J. Am. Chem. Soc., Angew. Chem., Adv. Mater.\u7b49\u8457\u540d\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587120\u4f59\u7bc7\uff0c\u83b7\u4ed6\u4eba\u5f15\u7528\u8fd15000\u6b21\uff1b\u7533\u8bf7\u56fd\u5bb6\u53d1\u660e\u4e13\u5229160\u4f59\u9879\uff0cPCT\u4e13\u52296\u9879\uff1b\u5e26\u9886\u56e2\u961f\u5b9e\u73b0\u78f7\u9178\u94c1\u9502\u3001\u77f3\u58a8\u70ef\u3001\u9530\u9178\u9502\u7b49\u6750\u6599\u4ea7\u4e1a\u5316\u6280\u672f\u548c\u8f6c\u79fb\u8f6c\u5316\u3002\u4e3b\u6301\u627f\u62c5\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u4e2d\u79d1\u9662\u91cd\u70b9\u90e8\u7f72\u9879\u76ee\uff0c\u4e2d\u79d1\u9662\u9662\u5730\u5408\u4f5c\u9879\u76ee\u3001\u5b81\u6ce2\u5e02\u79d1\u6280\u521b\u65b0\u56e2\u961f\u9879\u76ee\u4ee5\u53ca\u4f01\u4e1a\u5408\u4f5c\u7b49\u79d1\u6280\u9879\u76ee30\u4f59\u9879\u3002<\/p>\n

\u7814\u7a76\u52a8\u6001\uff1a<\/b><\/strong>\u4f5c\u8005\u91c7\u7528\u9ad8\u6d53\u5ea6\u786b\u9178\u4f5c\u4e3a\u5a92\u4ecb\u9884\u8131\u9502\u5904\u7406\u5bcc\u9502\u9530\u57fa\u6750\u6599\uff0c\u5728\u6750\u6599\u4e2d\u521b\u9020\u51fa\u6c27\u7a7a\u4f4d\u548c\u9502\u7a7a\u4f4d\uff0c\u83b7\u5f97\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\u5e76\u6709\u6548\u6291\u5236\u7535\u538b\u8870\u51cf\uff0c\u7535\u538b\u964d\u4e3a\u6bcf\u57080.281mV\u3002\u63d0\u5347\u7684\u673a\u7406\u662f\u56e0\u4e3a\u6750\u6599\u7684\u7ed3\u6784\u7531\u5c42\u72b6\u7ed3\u6784\u6f14\u53d8\u4e3a\u90e8\u5206\u5c16\u6676\u77f3\u7ed3\u6784\u3002<\/p>\n

\u56fe8 \u6750\u6599\u7ed3\u6784\u6f14\u53d8\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Abundant nanoscale defects to eliminate voltage decay in Li-rich cathode materials<\/b><\/strong>. <\/b><\/strong>(Energy Storage Materials<\/i><\/em>, 2019, 220-227. DOI:\u00a0<\/b><\/strong>10.1016\/j.ensm.2018.05.022)<\/p>\n

8.<\/b><\/strong>\u5c09\u6d77\u519b<\/b><\/strong>(\u5317\u4eac\u5de5\u4e1a\u5927\u5b66)<\/b><\/strong><\/p>\n

\u4eba\u7269\u7b80\u4ecb\uff1a<\/b><\/strong>\u5c09\u6d77\u519b\uff0c\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u3002<\/b><\/strong>2007\u5e74\u83b7\u4e1c\u5317\u5927\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u5148\u540e\u5728\u5317\u4eac\u6709\u8272\u91d1\u5c5e\u7814\u7a76\u603b\u9662\uff082007-2010\uff09\u548c\u65e5\u672c\u56fd\u7acb\u4ea7\u4e1a\u6280\u672f\u7efc\u5408\u7814\u7a76\u6240\uff082010-2015\uff09\u4ece\u4e8b\u7535\u6c60\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\uff0c2015\u5e74\u8d77\u5728\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u5de5\u4f5c\u3002\u5728Angew. Chem. Int. Ed.\u3001Energy & Environ. Sci.\u3001Nano.Lett.\u7b49\u56fd\u9645\u77e5\u540d\u80fd\u6e90\u5316\u5b66\u671f\u520a\u4e0a\u53d1\u8868\u5b66\u672f\u8bba\u658765\u7bc7\uff0cSCI\u4ed6\u5f152000\u4f59\u6b21\uff0c\u7533\u8bf7\u4e13\u522925\u9879\uff0c\u5df2\u6388\u67434\u9879\u3002\u76ee\u524d\uff0c\u91cd\u70b9\u7814\u7a76\u52a8\u529b\u7535\u6c60\u548c\u50a8\u80fd\u7535\u6c60\u7b49\uff08\u5982\u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\u3001\u56fa\u6001\u79bb\u5b50\u7535\u6c60\u3001\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u7b49\uff09\u9886\u57df\u7684\u5173\u952e\u6750\u6599\u4e0e\u5668\u4ef6\uff0c\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u5982\u4e0b\uff1a1.\u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\u6750\u6599\u4e0e\u6280\u672f\u7814\u7a76\uff1b2.\u56fa\u6001\u79bb\u5b50\u7535\u6c60\u6750\u6599\u4e0e\u5668\u4ef6\u7814\u7a76\uff1b3.\u65b0\u578b\u7535\u5316\u5b66\u50a8\u80fd\u4f53\u7cfb\u57fa\u7840\u7814\u7a76\u3002<\/p>\n

\u7814\u7a76\u52a8\u6001\uff1a<\/b><\/strong>\u4f5c\u8005\u62a5\u9053\u4e86\u5bcc\u9502\u9530\u57fa\u6750\u6599\u539f\u59cb\u7ed3\u6784\u4e3aLiTMO2<\/sub>\u76f8\u548cLi2<\/sub>MnO3<\/sub>\u76f8\u5171\u540c\u4e3b\u5bfc\uff0c\u7ecf\u8fc7\u5145\u653e\u7535\u5faa\u73af\u540e\uff0c\u53d8\u5316\u4e3a\u4ee5LiTMO2<\/sub>\u76f8\u4e3a\u5185\u6838\u3001\u4ee5\u5c16\u6676\u77f3\u76f8\u548c\u5ca9\u76d0\u76f8\u4e3a\u5916\u6838\u6784\u6210\u7684\u6838\u58f3\u7ed3\u6784\u3002\u800c\u4e14\u8fd9\u79cd\u53d8\u5316\u5bf9\u4e8e\u6e29\u5ea6\u5f88\u654f\u611f\uff0c\u5728\u9ad8\u6e29\u4e0b\u66f4\u5bb9\u6613\u4ea7\u751f\u7ed3\u6784\u53d8\u5316\u3002\u53d8\u5316\u7684\u673a\u7406\u662f\u5145\u653e\u7535\u5faa\u73af\u65f6\u6750\u6599\u4e2d\u5c42\u72b6\u6c27\u9038\u51fa\uff0c\u5bfc\u81f4\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u5411\u6750\u6599\u8868\u9762\u805a\u96c6\u3002\u8be5\u9879\u7814\u7a76\u9610\u660e\u4e86\u5bcc\u9502\u9530\u57fa\u5c42\u72b6\u6c27\u5316\u7269\u6b63\u6781\u7684\u7ed3\u6784\u6f14\u53d8\u673a\u7406\u5e76\u4e3a\u7c7b\u4f3c\u9ad8\u6bd4\u80fd\u91cf\u6750\u6599\u7684\u7ed3\u6784\u8bbe\u8ba1\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n

\u56fe9 \u7ed3\u6784\u53d8\u5316\u8fc7\u7a0b\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Temperature-Sensitive Structure Evolution of Lithium\u2013Manganese-Rich Layered Oxides for Lithium-Ion Batteries<\/b><\/strong>.<\/b><\/strong>(J. Am. Chem. Soc.<\/i><\/em>,\u00a02018,\u00a0140<\/i><\/em>\u00a0(45), 15279\u201315289. DOI:\u00a0<\/b><\/strong>10.1021\/jacs.8b07858)<\/p>\n

\u6ce8\uff1a\u4ee5\u4e0a\u4ec5\u4ecb\u7ecd\u4e86\u51e0\u4e2a\u5177\u6709\u4ee3\u8868\u6027\u7684\u7814\u7a76\u56e2\u961f\uff0c\u8fd8\u6709\u5f88\u591a\u5176\u4ed6\u4f18\u79c0\u7684\u56e2\u961f\u540c\u6837\u6709\u5f88\u591a\u4f18\u79c0\u7684\u5de5\u4f5c\uff0c\u4f46\u662f\u7531\u4e8e\u7bc7\u5e45\u7684\u5173\u7cfb\uff0c\u6211\u4eec\u5728\u8fd9\u91cc\u5c31\u4e0d\u80fd\u4e00\u4e00\u5217\u4e3e\u4e86\u3002<\/b><\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u79d1\u6280\u987e\u95ee\u535a\u95fb<\/strong>\u4f9b\u7a3f\uff0c\u7f16\u8f91\u90e8\u7f16\u8f91\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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