{"id":161168,"date":"2018-12-09T06:44:51","date_gmt":"2018-12-08T22:44:51","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=161168"},"modified":"2018-12-08T20:45:25","modified_gmt":"2018-12-08T12:45:25","slug":"%e4%b8%9c%e5%8c%97%e5%b8%88%e5%a4%a7%e7%8e%8b%e6%81%a9%e6%b3%a2%e5%9b%a2%e9%98%9fchem-soc-rev%ef%bc%9a%e5%a4%9a%e9%87%91%e5%b1%9e%e6%b0%a7%e9%85%b8%e7%9b%90poms%e5%9c%a8%e6%9f%93%e6%96%99%e6%95%8f","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=161168","title":{"rendered":"\u4e1c\u5317\u5e08\u5927\u738b\u6069\u6ce2\u56e2\u961fChem Soc Rev\uff1a\u591a\u91d1\u5c5e\u6c27\u9178\u76d0(POMs)\u5728\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60(\u82f1\u6587\u7b80\u5199\u4e3aDSSC)\u662f\u7531Gr\u00e4tzel\u548cO\u2019Regan\u53d1\u5c55\u7684\u7b2c\u4e09\u4ee3\u5149\u4f0f\u7535\u6c60\uff0c\u5b83\u5177\u6709\u8f83\u4f4e\u7684\u6210\u672c\uff0c\u5236\u5907\u7b80\u5355\uff0c\u53ef\u8c03\u53d8\u7684\u5149\u7535\u6027\u8d28\uff0c\u66f4\u9ad8\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387(PCE)\u3002\u968f\u7740\u80fd\u6e90\u5371\u673a\u7684\u65e5\u76ca\u4e25\u91cd\uff0c\u5f00\u53d1\u9ad8\u6548\uff0c\u73af\u5883\u53cb\u597d\uff0c\u8282\u80fd\u7684\u7535\u6c60\u6750\u6599\u8feb\u5728\u7709\u776b\u3002\u591a\u9178\u4f5c\u4e3a\u4e00\u79cd\u5206\u5b50\u65e0\u673a\u7c7b\u534a\u5bfc\u4f53\u6750\u6599\uff0c\u7531\u4e8e\u5b83\u4eec\u62e5\u6709\u51fa\u8272\u7684\u5149\u654f\u6027\u8d28\uff0c\u6c27\u5316\u8fd8\u539f\uff0c\u50ac\u5316\u6d3b\u6027\u4ee5\u53ca\u76f8\u5bf9\u7a33\u5b9a\u6027\u662fDSSC\u7684\u4f18\u79c0\u5019\u9009\u4f53\u3002\u8be5\u7efc\u8ff0\u9996\u5148\u5bf9DSSC\u7684\u53d1\u5c55\u4ee5\u53ca\u591a\u9178\u5728DSSC\u9886\u57df\u7684\u6f5c\u5728\u5e94\u7528\u4ef7\u503c\u505a\u4e86\u9610\u8ff0\uff0c\u7136\u540e\u4ee5\u591a\u9178\u7684\u80fd\u7ea7\u8c03\u63a7\u4f5c\u4e3a\u7406\u8bba\u57fa\u7840\u6765\u603b\u7ed3\u591a\u9178\u5728DSSC\u9886\u57df\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u8be5\u7efc\u8ff0\u9610\u8ff0\u4e86\u591a\u9178\u7684\u5149\u654f\u6027\u3001\u53ef\u4f5c\u4e3a\u7535\u5b50\u53d7\u4f53\u3001\u50ac\u5316\u3001\u6c27\u5316\u8fd8\u539f\u6027\u80fd\u5728DSSC\u9886\u57df\u7684\u91cd\u8981\u5e94\u7528\uff0c\u800c\u8fd9\u4e9b\u6027\u80fd\u4e3b\u8981\u662f\u7531\u591a\u9178\u7535\u5b50\u7ed3\u6784\u7684\u591a\u6837\u6027\u6765\u51b3\u5b9a\u7684\uff0c\u4f5c\u8005\u5728\u7efc\u8ff0\u4e2d\u6df1\u5165\u63a2\u8ba8\u4e86\u5176\u7ed3\u6784\u4e0e\u6027\u80fd\u7684\u5173\u7cfb\u3002\u6700\u540e\u4f5c\u8005\u5bf9\u591a\u9178\u5728DSSC\u9886\u57df\u7684\u53d1\u5c55\u524d\u666f\u8fdb\u884c\u4e86\u603b\u7ed3\u548c\u5c55\u671b\u3002\u8fd9\u7bc7\u7efc\u8ff0\u53ef\u80fd\u4e3a\u81f4\u529b\u4e8e\u8bbe\u8ba1\u5177\u6709\u7279\u5b9a\u7ed3\u6784\u7684POM\u7684\u5408\u6210\u5316\u5b66\u5bb6\uff0c\u4ee5\u53ca\u4ece\u4e8b\u5c06POM\u6269\u5c55\u5230\u5149\u7535\u6750\u6599\u7b49\u4ea4\u53c9\u5b66\u79d1\u7684\u7814\u7a76\u4eba\u5458\u63d0\u4f9b\u65b0\u601d\u8def\u3002<\/p>\n

\u3010\u7efc\u8ff0\u5bfc\u89c8\u56fe\u3011<\/strong><\/p>\n

\"\"<\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u3010\u6210\u679c\u901f\u9012\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e1c\u5317\u5e08\u8303\u5927\u5b66\u5316\u5b66\u5b66\u9662\u591a\u9178\u79d1\u5b66\u6559\u80b2\u90e8\u91cd\u70b9\u5b9e\u9a8c\u5ba4<\/strong>2015<\/strong>\u7ea7\u535a\u58eb<\/strong>\u751f\u9648\u9ece<\/strong>(\u7b2c\u4e00\u4f5c\u8005)\u7b49\u5728\u9648\u7ef4\u6797\u526f\u6559\u6388\u3001\u738b\u65b0\u9f99\u6559\u6388\u548c\u738b\u6069\u6ce2\u6559\u6388<\/strong>(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7684\u6307\u5bfc\u4e0b\uff0c\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aChem. Soc. Rev.<\/em><\/strong>\u4e0a\u53d1\u8868\u4e86\u6587\u7ae0\uff1aPolyoxometalates in dye-sensitized solar cells<\/strong>\u3002<\/strong>\u8fd9\u7bc7\u7efc\u8ff0\u4ee5\u8be5\u7814\u7a76\u56e2\u961f\u5728\u591a\u9178\u57fa\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\u8fd1\u5341\u5e74\u7684\u7814\u7a76\u5de5\u4f5c\u548c\u540c\u884c\u4e13\u5bb6\u7684\u76f8\u5173\u5de5\u4f5c\u4e3a\u57fa\u7840\uff0c\u5bf9\u591a\u9178\u5728DSSCs\u9886\u57df\u7684\u91cd\u8981\u5e94\u7528\u8fdb\u884c\u4e86\u7efc\u8ff0\uff0c\u5e76\u6df1\u5165\u63a2\u8ba8\u4e86\u591a\u9178\u7684\u7535\u5b50\u7ed3\u6784\u4e0e\u6027\u80fd\u7684\u91cd\u8981\u89c4\u5f8b\u548c\u5173\u7cfb\u3002\u8be5\u7efc\u8ff0\u7684\u53d1\u8868\u6807\u5fd7\u7740\u6211\u6821\u591a\u9178\u57fa\u592a\u9633\u80fd\u7535\u6c60\u7684\u7814\u7a76\u5de5\u4f5c\u83b7\u5f97\u4e86\u56fd\u9645\u540c\u884c\u7684\u5e7f\u6cdb\u5173\u6ce8\u548c\u8ba4\u53ef\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u53d7\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u91cd\u70b9\u9879\u76ee\u548c\u9762\u4e0a\u9879\u76ee\u7b49\u591a\u9879\u57fa\u91d1\u652f\u6301\u3002<\/p>\n

\u4e1c\u5317\u5e08\u8303\u5927\u5b66<\/strong>\u5316\u5b66\u5b66\u9662\u738b\u6069\u6ce2\u6559\u6388<\/strong>\u4e0e\u9648\u7ef4\u6797\u526f\u6559\u6388<\/strong>\u591a\u5e74\u6765\u4e00\u76f4\u4ece\u4e8b\u591a\u9178\u57fa\u5149\u7535\u6750\u6599\u7684\u5408\u6210\u53ca\u5176\u5728\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\u7684\u5e94\u7528\u7b49\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\uff0c\u7814\u7a76\u56e2\u961f\u8fd1\u4e94\u5e74\u5728Angew. Chem. Int. Ed.\u3001J. Mater. Chem. A\u3001Chem. Commun.\u3001ACS Appl. Mater. Interfaces\u3001Chemsuchem\u3001J. Power Sources\u7b49\u56fd\u9645\u671f\u520a\u53d1\u8868SCI\u8bba\u658740\u4f59\u7bc7\uff0c\u7814\u7a76\u5de5\u4f5c\u53d7\u5230\u540c\u884c\u6743\u5a01\u4e13\u5bb6\u7684\u9ad8\u5ea6\u8ba4\u53ef\u3002<\/p>\n

\u56fe<\/strong>1. <\/strong>\u672c\u6587\u4f5c\u8005<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u00a0<\/strong>\u56fe<\/strong>2. DSSC<\/strong>\u7684\u7ed3\u6784\u548c\u5de5\u4f5c\u539f\u7406\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u7eff\u8272\u5b9e\u7ebf\u8868\u793a\u7535\u5b50\u7684\u4f20\u8f93\u8def\u5f84\uff0c\u7ea2\u8272\u865a\u7ebf\u8868\u793a\u7535\u5b50\u7684\u91cd\u7ec4\u8def\u5f84\u3002\u6700\u5927\u7535\u538b<\/strong>(Voc)<\/strong>\u7531<\/strong>TiO2<\/sub><\/strong>\u7684\u8d39\u7c73\u80fd\u7ea7<\/strong>(E<\/em>F<\/sub>)<\/strong>\u548c\u7535\u89e3\u8d28\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d<\/strong>(I3<\/sub>–<\/sup> \/I–<\/sup>)<\/strong>\u51b3\u5b9a\u3002<\/strong><\/p>\n

\u56fe<\/strong>3. [PMo12<\/sub>O40<\/sub>]3-<\/sup><\/strong>\u53ca\u5176\u8fd8\u539f\u6001<\/strong>[PMo12<\/sub>O40<\/sub>]27-<\/sup><\/strong>\u53ef\u9006\u7684\u5206\u5b50\u548c\u7535\u5b50\u7ed3\u6784\u53d8\u5316\u793a\u610f\u56fe\u3002<\/strong>(QM<\/strong>\uff1a\u91cf\u5b50\u529b\u5b66<\/strong>; MD<\/strong>\uff1a\u5206\u5b50\u52a8\u529b\u5b66<\/strong>)<\/strong>\u3002<\/strong><\/p>\n

\"\"<\/p>\n

POMs<\/strong>\u7684\u80fd\u7ea7\u8c03\u8282\uff1a<\/strong><\/p>\n

\u56fe<\/strong>4. <\/strong>\u4e09\u79cd\u4e0d\u540c\u7684\u8ba1\u7b97<\/strong>POMs<\/strong>\u80fd\u7ea7\u7684\u65b9\u6cd5\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5. p-type DSSCs<\/strong>\u4e2d\u67d3\u6599\u7684\u524d\u7ebf\u5206\u5b50\u8f68\u9053\u548c\u80fd\u7ea7\u5206\u5e03\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u6709\u673a\u57fa\u56e2\u7cfb\u7edf1-6\u7684\u5206\u5b50\u7ed3\u6784;(b)\u6709\u673a\u57fa\u56e2\u7cfb\u7edf1-6\u7684\u524d\u6cbf\u5206\u5b50\u8f68\u9053\u80fd\u7ea7\u56fe\u3002<\/p>\n

\u56fe<\/strong>6. DSSC<\/strong>\u4e2d\u5177\u6709\u4e0d\u540c\u80fd\u7ea7\u7684<\/strong>POMs<\/strong>\u7684\u7535\u5b50\u4f20\u8f93\u673a\u5236<\/strong>(CB<\/strong>\uff1a<\/strong>TiO2<\/sub><\/strong>\u7684\u5bfc\u5e26<\/strong>; VB<\/strong>\uff1a<\/strong>TiO2<\/sub><\/strong>\u7684\u4ef7\u5e26<\/strong>)<\/strong>\u3002<\/strong><\/p>\n

\"\"<\/p>\n

POMs<\/strong>\u7684\u5149\u7535\u54cd\u5e94\u6027\u80fd\u7814\u7a76\uff1a<\/strong>\u00a0<\/strong><\/p>\n

\u56fe<\/strong>7. <\/strong>\u6750\u6599\u7684\u77ac\u6001\u5149\u7535\u6d41\u56fe\u4ee5\u53ca\u7535\u5b50\u4f20\u9012\u673a\u7406\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

(a)(PSS\/TiO2<\/sub>)2<\/sub>\u819c[\u9ed1\u7ebf]\u3001(P2<\/sub>W18<\/sub>\/TiO2<\/sub>)2<\/sub>\u819c[\u7ea2\u7ebf]\u3001(P2<\/sub>W18<\/sub>\/TiO2<\/sub>\/P2<\/sub>W18<\/sub>\/Au)2<\/sub>\u819c[\u84dd\u7ebf]\u548c(PSS\/TiO2<\/sub>\/PSS\/Au)2<\/sub>\u819c[\u7eff\u7ebf]\u57280.1M Na2<\/sub>SO4<\/sub>\u7535\u89e3\u6db2\u4e2d\u7684\u5149\u7535\u6d41\u54cd\u5e94;(b)\u6bcf\u79cd\u7269\u8d28\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u548c\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>8. <\/strong>\u6750\u6599\u7684\u77ac\u6001\u5149\u7535\u6d41\u56fe\u4ee5\u53ca\u7535\u5b50\u4f20\u9012\u673a\u7406\u56fe\u3002<\/strong>\"\"(a)\u5728100mW cm-2<\/sup>\u7684\u6a21\u62dfAM1.5\u7167\u5c04\u4e0b\uff0c\u5149\u7535\u6d41\u54cd\u5e94;(b)TiO2<\/sub>(\u84dd\u7ebf)\u548c{Mo132<\/sub>}(\u7ea2\u7ebf)\u7684\u80fd\u7ea7\u3002\u7bad\u5934\u8868\u793a\u7535\u5b50\u7684\u4f20\u9012\u65b9\u5411\u3002<\/p>\n

\u56fe<\/strong>9. <\/strong>\u6750\u6599\u7684\u77ac\u6001\u5149\u7535\u6d41\u56fe\u4ee5\u53ca\u7535\u5b50\u4f20\u9012\u673a\u7406\u56fe\u3002<\/strong>\"\"<\/p>\n

(a)P2\u548c{W72<\/sub>V30<\/sub>}\u7684\u80fd\u7ea7\u4ee5\u53ca\u7535\u5b50\u4f20\u9012\u8fc7\u7a0b\u56fe;(b)\u5f00-\u5173Xe\u5f27\u5149\u706f\u7684\u5149\u7167\u5c04\u4e0b(W72<\/sub>V30<\/sub>\/P2)10<\/sub>\u8584\u819c(\u7eff\u8272\u66f2\u7ebf)\u548c(PSS\/P2<\/sub>)10<\/sub>\u8584\u819c(\u7ea2\u8272\u66f2\u7ebf)\u7684\u5149\u7535\u5316\u5b66\u54cd\u5e94\u3002<\/p>\n

POMs<\/strong>\u4f5c\u4e3a<\/strong>DSSCs<\/strong>\u4e2d\u7684\u7535\u5b50\u53d7\u4f53\uff1a<\/strong><\/p>\n

\u56fe<\/strong>10. <\/strong>\u819c\u7535\u6781\u7684\u5236\u5907\u8fc7\u7a0b\u4ee5\u53ca\u6027\u80fd\u8868\u5f81\u56fe\u3002<\/strong>\"\"<\/p>\n

(a)(PW12<\/sub>\/TiO2<\/sub>)3<\/sub>\u754c\u9762\u5c42\u5149\u7535\u9633\u6781\u7684\u5236\u5907;(b)\u77f3\u82f1\u57fa\u677f\u4e0a\u591a\u5c42\u819c(PW12<\/sub>\/TiO2<\/sub>)n\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31(n=1-5);(c)(PW12<\/sub>\/TiO2<\/sub>)3<\/sub>\u754c\u9762\u5c42\u7684AFM\u56fe\u50cf;(d)\u5728AM1.5\u7167\u5c04(100mW cm 2)\u4e0b\u7684TiCl4<\/sub>\u5904\u7406\u4e0e\u672a\u5904\u7406(PW12<\/sub>\/TiO2<\/sub>)n(n=1-5)\u819c\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong>11. <\/strong>\u6750\u6599\u7684\u7d2b\u5916<\/strong>–<\/strong>\u53ef\u89c1\u5149\u8c31\u4e0e\u67d3\u6599\u654f\u5316\u5149\u4f0f\u7535\u6c60\u7684\u793a\u610f\u56fe\u3002<\/strong>\"\"<\/p>\n

(a)SiW11<\/sub>Co\u3001\u5e02\u552eP25\u548cTiO2<\/sub>@SiW11<\/sub>Co\u7684\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31;(b)\u67d3\u6599\u654f\u5316\u5149\u4f0f\u7535\u6c60\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>12. <\/strong>\u9ad8\u8d1f\u8f7d\u91cf\u7684\u7eb3\u7c73<\/strong>POMs<\/strong>\u7c07\u7684\u5236\u5907\u65b9\u6cd5\u53ca\u7535\u6c60\u6027\u80fd\u6d4b\u8bd5\u3002<\/strong>\"\"(a)\u9ad8\u8d1f\u8f7d\u91cf\u7eb3\u7c73POMs\u7c07\u7684\u5236\u5907\u65b9\u6cd5;(b)AM1.5(100 mW cm-2<\/sup>)\u8f90\u5c04\u4e0b\u4e0d\u540cDSSCs\u7684J-V\u66f2\u7ebf;(c)\u6697\u7535\u6d41\u66f2\u7ebf\u3002<\/p>\n

POMs<\/strong>\u7684\u5149\u654f\u6027\u7814\u7a76\uff1a<\/strong><\/p>\n

\u56fe<\/strong>13. POMs<\/strong>\u7684\u5149\u8c31\uff1a\u7d2b\u5916<\/strong>–<\/strong>\u53ef\u89c1\u5438\u6536\u5149\u8c31\u3002<\/strong>\"\"N719\u4e59\u9187\u6eb6\u6db2\uff0cB2<\/sub>P8<\/sub>MoV<\/sup>5<\/sub>MoVI<\/sup>7<\/sub>\u548c{SiW9<\/sub>Co3<\/sub>}\u6c34\u6eb6\u6db2\u7684UV-\u53ef\u89c1\u5149\u8c31\u3002(\u5206\u522b\u5c065mg N719\uff0cB2<\/sub>P8<\/sub>MoV<\/sup>5<\/sub>MoVI<\/sup>7<\/sub>\u548c{SiW9<\/sub>Co3<\/sub>}\u6eb6\u89e3\u572820mL\u4e59\u9187\u6216\u6c34\u4e2d)\u3002<\/p>\n

\u56fe<\/strong>14. POMs<\/strong>\u7684\u80fd\u7ea7\uff1a\u4f9b\u4f53<\/strong>–<\/strong>\u53d7\u4f53\u53d6\u4ee3<\/strong>Wells-Dawson<\/strong>\u591a\u9762\u4f53\u7ed3\u6784\u56fe\u3002<\/strong>\"\"<\/p>\n

\u56fe<\/strong>15. POMs<\/strong>\u7684\u7535\u5b50\u4f20\u9012\u7814\u7a76\uff1a<\/strong>POMs<\/strong>\u590d\u5408\u6750\u6599\u7684\u8868\u9762\u5149\u7535\u538b<\/strong>(SPV)<\/strong>\u8c31\u56fe\u4ee5\u53ca\u8367\u5149\u8c31\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

(a)PW11<\/sub>Rh-COOH(\u7ea2\u7ebf)\u4ee5\u53caTiO2<\/sub>\u4e0ePW11<\/sub>Rh-COOH\u590d\u5408\u7269(\u84dd\u7ebf)\u7684SPV\u5149\u8c31\uff0c\u63d2\u56fe\u662fPW11<\/sub>Rh-COOH\u9634\u79bb\u5b50\u7684\u591a\u9762\u4f53\u7ed3\u6784\u3002(b)TiO2<\/sub>\u5bf9\u6d53\u5ea6\u4e3a5\u00d710-6<\/sup> mol L-1<\/sup>(GeW9<\/sub>-Mn-SnCOOH)2<\/sub>\u6c34\u6eb6\u6db2\u7684\u8367\u5149\u53d1\u5c04\u5149\u8c31\u7684\u5f71\u54cd(\u7ea2\u7ebf\u4ee3\u8868\u4e0d\u5b58\u5728TiO2<\/sub>; \u84dd\u7ebf\u4ee3\u8868[TiO2<\/sub>]=0.25g L-1<\/sup>)\u3002<\/p>\n

POMs<\/strong>\u4f5c\u4e3a\u5149\u654f\u5242\u548c\u5171\u654f\u5242\u5728<\/strong>DSSCs<\/strong>\u4e2d\u7684\u5e94\u7528\uff1a<\/strong><\/p>\n

\u56fe<\/strong>16. POM<\/strong>\u4e0e<\/strong>TiO2<\/sub><\/strong>\u7684\u80fd\u7ea7\u56fe\u4ee5\u53ca\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u8868\u5f81\u3002<\/strong><\/p>\n

\"\"<\/p>\n

(a)POM\u548cTiO2<\/sub>\u7684\u80fd\u7ea7\u56fe;(b)\u5728AM1.5\u6a21\u62df\u5149\u4e0b(\u5b9e\u7ebf\u3001\u865a\u7ebf)POMs\u654f\u5316(\u7ea2\u7ebf)\u548c\u7a7a\u767dTiO2<\/sub>(\u9ed1\u7ebf)\u592a\u9633\u80fd\u7535\u6c60\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong>17. POMs<\/strong>\u4f5c\u4e3a\u5171\u654f\u5316\u5242\u539f\u7406\u4e0e\u6027\u80fd\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

(a)POMs\u4f5c\u4e3a\u5171\u654f\u5316\u5242\u793a\u610f\u56fe\uff1b(b)POMs\u548cTiO2<\/sub>\u7684\u80fd\u7ea7\u793a\u610f\u56fe;(c)GeW9-Mn-SnR\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf;(d)\u5355\u72ecN719(\u9ed1\u7ebf)\u548cGeW9-Mn-SnR\/N719(\u7ea2\u7ebf)\u654f\u5316DSSCs\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf(\u865a\u7ebf\u4e3a\u6697\u7535\u6d41)\u3002<\/p>\n

\u56fe<\/strong>18. <\/strong>\u6742\u591a\u84dd\u8584\u819c\u5236\u5907\u793a\u610f\u56fe\u4ee5\u53ca\u5149\u54cd\u5e94\u6027\u80fd\u6d4b\u8bd5\u3002<\/strong>\"\"<\/p>\n

(a)FTO\u4e0a\u7684\u8584\u819c\u7ed3\u6784\u548c\u771f\u7a7a\u70ed\u84b8\u53d1\u56fa\u6001\u8fd8\u539fPOMs\u7684\u793a\u610f\u56fe;(b)\u5728\u53ef\u89c1\u5149(\u03bb>420nm)\u4e0bTiO2<\/sub>\/PW12<\/sub>-Al(HPB)\u8584\u819c\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u54cd\u5e94;(c)\u5728\u5404\u79cd\u529f\u7387\u5149\u5f3a\u5ea6\u4e0b{TiO2<\/sub>}5<\/sub>\/{PW12<\/sub>}6<\/sub>-Al(HPB)\u8584\u819c\u7684\u5149\u7535\u6d41\u5bc6\u5ea6;(d)\u8be5\u7535\u6781\u4e2d\u7535\u5b50\u8f6c\u79fb\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>19. POMs<\/strong>\u57fa\u5149\u654f\u5242\u7684\u7406\u8bba\u8ba1\u7b97\uff1a<\/strong>POMs<\/strong>\u5171\u8f6d<\/strong>Zn(II)-<\/strong>\u535f\u5549\u67d3\u6599\u3002<\/strong>\"\"<\/p>\n

(a)\u67d3\u65991-6\u7684\u7ed3\u6784;(b)\u67d3\u65992-6\u7684\u7535\u5b50\u5bc6\u5ea6\u5dee\u5f02\u56fe\u3002<\/p>\n

\u56fe<\/strong>20. DSSC<\/strong>\u7684\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/strong>\u00a0<\/strong>\"\"<\/p>\n

\u56fe<\/strong>21. POMs<\/strong>\u5728<\/strong>DSSCs<\/strong>\u7535\u89e3\u8d28\u6750\u6599\u4e2d\u7684\u5e94\u7528\u3002<\/strong>\"\"<\/p>\n

(a)\u57fa\u4e8ePOM1-Cu-phen\uff0cPOM2-Cu-phen\u548cCu-phen\u6c27\u5316\u8fd8\u539f\u5bf9\u7535\u89e3\u8d28\u7684DSSCs\u7684\u5149\u7535\u6d41\u5bc6\u5ea6-\u7535\u538b\u66f2\u7ebf;(b)\u5177\u6709POM1\/POM2-Cuphen\u6c27\u5316\u8fd8\u539f\u5bf9\u7684\u7535\u89e3\u8d28\u7684DSSCs\u5185\u90e8\u5de5\u4f5c\u539f\u7406\u793a\u610f\u56fe\u3002 (\u9ed1\u8272\u7bad\u5934\u8868\u793a\u7535\u5b50\u8f6c\u79fb;\u7ea2\u8272\u865a\u7ebf\u8868\u793a\u5171\u4ef7\u952e;\u9ec4\u8272\u7ebf\u8868\u793a\u7535\u5b50\u8f6c\u79fb;\u7ea2\u8272\u7bad\u5934\u8868\u793aCuI\/II<\/sup>\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u7684\u8f6c\u79fb)\u3002<\/p>\n

POMs<\/strong>\u5728<\/strong>DSSCs<\/strong>\u5bf9\u7535\u6781<\/strong>(CE)<\/strong>\u6750\u6599\u4e2d\u7684\u5e94\u7528\uff1a<\/strong><\/p>\n

\u56fe<\/strong>22. POMs<\/strong>\u548c<\/strong>Pt<\/strong>\u590d\u5408\u6750\u6599\u4f5c\u4e3a<\/strong>DSSCs<\/strong>\u4e2d\u7684<\/strong>CE<\/strong>\u3002<\/strong>\"\"<\/p>\n

(a)\u7531\u4e00\u5c42SiW11Cu\u548c\u4e24\u5c42\u5e38\u89c4Pt\u7eb3\u7c73\u9897\u7c92\u7ec4\u6210\u7684CE; (b)Pt\u548cSiW11Cu \/ Pt CEs\u57280.01M LiI\uff0c0.001M I2\u548c0.1M LiClO4\u4e59\u8148\u6eb6\u6db2\u4e2d\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\uff0c\u626b\u63cf\u901f\u7387\u4e3a50mV \/ s; (c)Cu \/ Pt\u548cPt CE\u7684Tafel\u6781\u5316\u66f2\u7ebf\u3002\u00a0<\/strong><\/p>\n

\u56fe<\/strong>23. POMs<\/strong>\u63ba\u6742\u7684\u5bfc\u7535\u805a\u5408\u7269<\/strong>PEDOT<\/strong>\u8584\u819c\u4f5c\u4e3a<\/strong>DSSCs<\/strong>\u4e2d\u7684<\/strong>CE<\/strong>\u3002<\/strong>\"\"(a)\u7535\u805a\u5408POM-doped PEDOT\u8584\u819c\u4f5c\u4e3aDSSCs\u4e2d\u7684CE;(b)\u4ee5APS-SiW11-PEDOT\uff0cAPS-PEDOT\uff0cSiW11-PEDOT\uff0cPEDOT\u548cPt \u4e3aCE\u7684DSSC\u7684\u5149\u7535\u6d41-\u7535\u538b\u66f2\u7ebf;(c)\u4e0d\u540cCE\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31(EIS)\u3002\u7814\u7a76\u7684\u9891\u7387\u8303\u56f4\u4e3a0.01 Hz\u81f3105<\/sup> Hz\uff0c\u4ea4\u6d41\u632f\u5e45\u4e3a10 mV\u3002\u4e24\u4e2a\u5bf9\u79f0CE\u4e4b\u95f4\u65bd\u52a0\u7684\u504f\u538b\u4e3a0V\u3002<\/p>\n

\u56fe<\/strong>24. POMs<\/strong>\u590d\u5408\u78b3\u6750\u6599\u4f5c\u4e3a<\/strong>DSSCs<\/strong>\u4e2d\u7684<\/strong>CE<\/strong>\u3002<\/strong>\"\"<\/p>\n

(a)\u7fa7\u57fa\u9521\u4fee\u9970\u7684\u5939\u5c42\u9517\u94a8\u9178\u76d0\u4fee\u9970\u7684\u78b3\u7eb3\u7c73\u7ba1\u4f5c\u4e3aDSSCs\u4e2d\u7684CE;(b)\u4f7f\u7528\u4e0d\u540cCE\u7684DSSCs\u7684J-V\u66f2\u7ebf;(c)SWNT\/GeW9<\/sub>-Cu-SnR\u7684HRTEM\u56fe\u50cf;(d)SWNT\/GeW9-Cu-SnR\u7684EDS\u3002\u00a0<\/strong><\/p>\n

\u56fe<\/strong>25. POMs<\/strong>\u884d\u751f\u5bf9\u7535\u6781\u6750\u6599<\/strong>Co3<\/sub>O4<\/sub>-WC-CN\/rGO<\/strong>\u5728<\/strong>DSSCs<\/strong>\u4e2d\u7684\u5e94\u7528\u3002<\/strong>\"\"(a)Co3<\/sub>O4<\/sub>-WC-CN\/rGO\u7684\u5236\u5907\u793a\u610f\u56fe;(b)\u4f7f\u7528\u4e0d\u540cCE\u6750\u6599\u7684Tafel\u6781\u5316\u66f2\u7ebf;(c)\u4f7f\u7528\u4e0d\u540cCE\u6750\u6599\u7684DSSCs\u7684J-V\u66f2\u7ebf\u3002<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u81ea\u4ecePope\u548cM\u00fcller\u4e8e1991\u5e74\u5bf9POM\u8fdb\u884c\u91cd\u65b0\u7814\u7a76\u4ee5\u6765\uff0cPOM\u5316\u5b66\u7ecf\u5386\u4e86\u7206\u70b8\u5f0f\u589e\u957f\u3002\u7531\u4e8e\u5176\u65e0\u4e0e\u4f26\u6bd4\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\uff0cPOM\u7684\u5f00\u53d1\u5df2\u4ece\u5355\u4e00\u7684\u5408\u6210\u5316\u5b66\u8f6c\u53d8\u4e3a\u591a\u529f\u80fd\u5e94\u7528\u5316\u5b66\u3002\u5c06POM\u5e94\u7528\u4e8eDSSC\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u4ee4\u4eba\u632f\u594b\u7684\u65b0\u53d1\u73b0\uff0c\u663e\u793a\u4e86\u5b83\u4eec\u5728\u89e3\u51b3\u672a\u6765\u80fd\u6e90\u95ee\u9898\u65b9\u9762\u7684\u524d\u666f\u3002\u672c\u7efc\u8ff0\u603b\u7ed3\u4e86\u57fa\u4e8e\u6211\u4eec\u548c\u5176\u4ed6\u8bfe\u9898\u7ec4POM\u5728DSSC\u9886\u57df\u5e94\u7528\u7684\u91cd\u8981\u5de5\u4f5c\u3002POM\u53ef\u4f5c\u4e3aDSSC\u7684\u5149\u654f\u5242\u548c\u5171\u654f\u5242\uff0c\u5b83\u4eec\u65e2\u80fd\u63a5\u53d7\u7535\u5b50\uff0c\u53c8\u80fd\u63d0\u4f9b\u7535\u5b50\u800c\u7528\u4f5c\u5149\u9633\u6781\u3002\u6b64\u5916\uff0c\u5b83\u4eec\u4f18\u5f02\u7684\u6c27\u5316\u8fd8\u539f\u6027\u80fd\u4f7f\u5b83\u4eec\u53ef\u7528\u4f5cDSSC\u5bf9\u7535\u6781\u548c\u7535\u89e3\u8d28\u7684\u50ac\u5316\u5242\u3002\u603b\u4e4b\uff0cPOM\u8f83\u5f3a\u7684\u7535\u5b50\u53d7\u4f53\u6027\u8d28\uff0c\u53ef\u8c03\u8282\u7684\u80fd\u5e26\u7ed3\u6784\uff0c\u5bbd\u7684\u5149\u8c31\u5438\u6536\uff0c\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u4f4e\u6210\u672c\uff0c\u4f18\u5f02\u7684\u5149\u7535\u50ac\u5316\u6d3b\u6027\u548c\u5176\u4ed6\u7279\u6027\u610f\u5473\u7740\u5b83\u4eec\u53ef\u4ee5\u7528\u4e8eDSSC\u7684\u4e0d\u540c\u90e8\u5206\u4ee5\u4f18\u5316\u7535\u6c60\u7684\u6027\u80fd\u3002\u6211\u4eec\u7684\u6700\u65b0\u7814\u7a76\u8868\u660e\uff0cPOM\u53ef\u4ee5\u901a\u8fc7\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u4e0e\u96e8\u6ef4\u9633\u79bb\u5b50(the cations of raindrops)\u5f62\u6210\u53cc\u7535\u5c42\uff0c\u4ece\u800c\u4ea7\u751f\u7535\u4fe1\u53f7\u3002\u968f\u7740\u96e8\u6ef4\u7684\u6301\u7eed\u6ef4\u843d\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u83b7\u5f97\u6301\u7eed\u7535\u6d41\u3002\u6211\u4eec\u8fd8\u53d1\u73b0POM\u53ef\u7528\u4e8e\u5177\u6709DSSC\u7684p-n\u5f02\u8d28\u7ed3\u538b\u7535\u5668\u4ef6\u4e2d\uff0c\u4ee5\u5236\u9020\u900f\u660e\u538b\u7535\u53cc\u529f\u80fd\u592a\u9633\u80fd\u7535\u6c60\uff0c\u8fd9\u4e24\u4e2a\u5de5\u4f5c\u4e5f\u5373\u5c06\u53d1\u8868\u3002\u5c3d\u7ba1\u591a\u9178\u5728DSSC\u4e2d\u6709\u91cd\u8981\u5e94\u7528\uff0c\u4f46\u4ecd\u6709\u4e00\u4e9b\u95ee\u9898\u9700\u8981\u89e3\u51b3\uff1a<\/p>\n

    \n
  1. \u57fa\u4e8ePOM\u7684DSSC\u7684\u7535\u5b50\u4f20\u8f93\u673a\u5236\u662f\u4ec0\u4e48\uff1f<\/li>\n
  2. POM\u4f5c\u4e3a\u65e0\u673a\u5149\u654f\u5242\u6216\u5171\u654f\u5242\u5f00\u53d1\u7684\u74f6\u9888\u662f\u4ec0\u4e48\uff1f<\/li>\n
  3. \u5982\u4f55\u5c06POM\u548c\u534a\u5bfc\u4f53\u4ee5\u5171\u4ef7\u952e\u6216\u914d\u4f4d\u952e\u5f62\u5f0f\u7ed3\u5408\uff1f<\/li>\n
  4. POM\u7684\u5f62\u6001\u548c\u5c3a\u5bf8\u5bf9DSSC\u7684\u5f71\u54cd\u662f\u4ec0\u4e48\uff1f<\/li>\n<\/ol>\n

    \u00a0<\/strong>\u6587\u7ae0\u94fe\u63a5\uff1a<\/strong>Polyoxometalates in dye-sensitized solar cells.<\/strong><\/a> (Chem. Soc. Rev.<\/em><\/strong>,<\/em> DOI: 10.1039\/c8cs00559a)<\/p>\n

    \u00a0<\/strong>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u8ba1\u7b97\u6750\u6599\u5b66\u672f\u7ec4\u827e\u8d85<\/strong>\u4f9b\u7a3f\uff0c\u738b\u6069\u6ce2\u6559\u6388\u7814\u7a76\u56e2\u961f\u6821\u7a3f<\/strong>\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

    \u540c\u5b66\u4eec\uff0c\u5982\u679c\u4f60\u5bf9\u591a\u9178\u57fa<\/strong>DSSC<\/strong>\u7684\u7814\u7a76\u611f\u5174\u8da3\u6b22\u8fce\u5927\u5bb6\u52a0\u5165\u8be5\u7814\u7a76\u56e2\u961f\uff01<\/strong><\/p>\n

    \u56e2\u961f\u4ecb\u7ecd<\/strong><\/p>\n

    \u738b\u6069\u6ce2\u6559\u6388<\/strong> \u4e2a\u4eba\u7b80\u5386<\/strong><\/p>\n

    \u738b\u6069\u6ce2\uff0c\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u4e1c\u5317\u5e08\u8303\u5927\u5b66\u8363\u8a89\u6559\u6388\u3002\u56fd\u5bb6\u7ea7\u6709\u7a81\u51fa\u8d21\u732e\u4e13\u5bb6\uff0c\u5409\u6797\u7701\u6709\u7a81\u51fa\u8d21\u732e\u4e13\u5bb6\uff0c\u5409\u6797\u7701\u201c\u7701\u7ba1\u4f18\u79c0\u4e13\u5bb6\u201d\uff0c\u201c\u957f\u6625\u77e5\u540d\u6559\u6388\u201d\uff0c\u5409\u6797\u7701\u4f18\u79c0\u6559\u5e08, \u56fd\u5bb6\u6559\u59d4\uff0c\u56fd\u5bb6\u79d1\u59d4\u66fe\u8054\u5408\u6388\u4e88\u201c\u5168\u56fd\u9ad8\u7b49\u5b66\u6821\u5148\u8fdb\u79d1\u6280\u5de5\u4f5c\u8005\u201d\u79f0\u53f7\uff0c\u5168\u56fd\u5e08\u5fb7\u6807\u5175\u3002\u66fe\u83b7\u5409\u6797\u7701\u4eba\u6c11\u653f\u5e9c\u9881\u53d1\u7684\u201c\u5409\u6797\u82f1\u624d\u201d\u5956\u7ae0\uff0c\u8363\u83b7\u56fd\u52a1\u9662\u9881\u53d1\u7684\u653f\u5e9c\u7279\u6b8a\u6d25\u8d34\u30022014-2017\u5e74\u8fde\u7eed\u5165\u9009\u4e2d\u56fd\u9ad8\u88ab\u5f15\u5b66\u8005\u5316\u5b66\u699c\u5355\u30022016\u5e74\uff0c\u5165\u9009\u4e16\u754c\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u9ad8\u88ab\u5f15\u5b66\u8005\u699c\u5355\u3002<\/p>\n

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    \u5148\u540e\u627f\u62c5\u4e86\u56fd\u5bb6\u201c\u516b\u4e94\u201d\u91cd\u5927\u653b\u5173\u9879\u76ee\uff0c\u56fd\u5bb6\u201c\u4e5d\u4e94\u201d\u91cd\u70b9\u79d1\u6280\u653b\u5173\u9879\u76ee\uff0c\u56fd\u5bb6863\u9879\u76ee\uff0c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u91cd\u70b9\u9879\u76ee\u53ca\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\uff0c\u56fd\u5bb6\u6559\u80b2\u90e8\u91cd\u5927\u9879\u76ee\u3001\u91cd\u70b9\u9879\u76ee\uff0c\u56fd\u5bb6\u7ea7\u706b\u70ac\u9879\u76ee\uff0c\u5409\u6797\u7701\u79d1\u59d4\u3001\u7701\u8ba1\u59d4\u91cd\u70b9\u9879\u76ee\u53ca\u9762\u4e0a\u9879\u76ee\u7b49\u591a\u9879\u3002<\/p>\n

    \u51fa\u7248\u300a\u591a\u9178\u5316\u5b66\u300b\u3001\u300a\u591a\u9178\u5316\u5b66\u6982\u8bba\u300b\u3001\u300a\u591a\u9178\u5316\u5b66\u5bfc\u8bba\u300b\u3001\u300a\u540c\u591a\u3001\u6742\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\u300b\u7b49\u591a\u9178\u5316\u5b66\u7cfb\u5217\u8457\u4f5c\uff0c\u5e76\u51fa\u7248\u300a\u73b0\u4ee3\u65e0\u673a\u5316\u5b66\u6982\u8bba\u300b\u3001\u53c2\u4e0e\u64b0\u5199\u82f1\u56fdJohn Wiley& Sons, Ltd\u6742\u5fd7\u793e\u7684\u300a\u65e0\u673a\u5316\u5b66\u5927\u767e\u79d1\u5168\u4e66\u300b\u3001\u300a\u9ad8\u901f\u53d1\u5c55\u7684\u4e2d\u56fd\u5316\u5b66(1982-2012)\u300b\u3001\u300a\u5168\u56fd\u65e0\u673a\u5316\u5b66\u4e1b\u4e66\u7b2c13\u5377\uff1a\u65e0\u673a\u53cd\u5e94\u52a8\u529b\u5b66\u300b\u3001\u300a\u914d\u4f4d\u5316\u5b66\u8fdb\u5c55\u300b\u3001\u300a\u4e2d\u56fd\u56fa\u4f53\u5316\u5b66\u5341\u5e74\u8fdb\u5c55\u300b\u7b49\u65e0\u673a\u7cfb\u5217\u4e66\u7c4d\u3002<\/p>\n

    \u9648\u7ef4\u6797<\/strong> \u526f\u6559\u6388<\/strong> \u4e2a\u4eba\u7b80\u5386<\/strong><\/p>\n

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    \u738b\u65b0\u9f99\uff0c\u535a\u58eb\uff0c\u4e1c\u5317\u5e08\u8303\u5927\u5b66\u5316\u5b66\u5b66\u9662\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u4e3b\u8981\u4ece\u4e8b\u914d\u4f4d\u5316\u5b66\u4e0e\u591a\u91d1\u5c5e\u6c27\u7c07\u5316\u5b66\u9886\u57df\u7684\u7814\u7a76\uff0c\u5728\u529f\u80fd\u914d\u5408\u7269\u6216\u91d1\u5c5e-\u6709\u673a\u7f51\u7edc\u5316\u5408\u7269\u7684\u65b0\u7ed3\u6784\u63a2\u7d22\u5408\u6210\u3001\u57fa\u4e8e\u91d1\u5c5e\u6c27\u7c07\u7684\u7ec4\u88c5\u89c4\u5f8b\u7814\u7a76\u3001\u7ed3\u6784\u8c03\u63a7\u4e0e\u529f\u80fd\u6027\u8d28\u7814\u7a76\u7b49\u65b9\u9762\u53d6\u5f97\u7cfb\u5217\u521b\u65b0\u6027\u6210\u679c\u3002\u83b7\u5f972009\u5e74\u5168\u56fd\u4f18\u79c0\u535a\u58eb\u5b66\u4f4d\u8bba\u6587\u5956\uff0c2009\u5e74\u5165\u9009\u6559\u80b2\u90e8\u65b0\u4e16\u7eaa\u4f18\u79c0\u4eba\u624d\u652f\u6301\u8ba1\u5212\uff0c2013\u5e74\u5165\u9009\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u9996\u6279\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\uff0c2014\u5e74\u83b7\u5f97\u9996\u6279\u5409\u6797\u7701\u201c\u957f\u767d\u5c71\u5b66\u8005\u201d\u7279\u8058\u6559\u6388\uff0c\u5409\u6797\u7701\u7b2c\u5341\u4e8c\u6279\u6709\u7a81\u51fa\u8d21\u732e\u4e2d\u9752\u5e74\u4e13\u5bb6\uff0c\u957f\u6625\u5e02\u7b2c\u4e94\u6279\u6709\u7a81\u51fa\u8d21\u732e\u4e2d\u9752\u5e74\u4e13\u5bb6\u3002\u5165\u90092014\uff0c2015\u5e74\u4e2d\u56fd\u9ad8\u88ab\u5f15\u5b66\u8005\u699c\u5355\u5316\u5b66\u5b66\u79d1\u699c\u5355\uff08\u7814\u7a76\u6570\u636e\u6765\u81ea\u7231\u601d\u552f\u5c14\u65d7\u4e0b\u7684Scopus\u6570\u636e\u5e93\uff09\uff0c\u53c2\u4e0e\u83b7\u5f972014\u5e74\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\uff08\u7b2c\u4e09\u5b8c\u6210\u4eba\uff09\uff0c2012\u6559\u80b2\u90e8\u9ad8\u7b49\u5b66\u6821\u81ea\u7136\u79d1\u5b66\u5956\u4e00\u7b49\u5956\uff08\u7b2c\u4e09\u5b8c\u6210\u4eba\uff09\u3002\u5728Nat. Commun.\u3001Angew. Chem. Int. Ed.\u3001J. Am. Chem. Soc.\u3001Adv. Mater.\u3001Chem. Eur. J.\u3001Chem. Commun.\u7b49\u671f\u520a\u4e0a\u53d1\u886880\u4f59\u7bc7\u7814\u7a76\u8bba\u6587\uff0c\u8bba\u6587\u4ed6\u5f154000\u4f59\u6b21\u3002<\/p>\n

    \u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u6c47\u603b<\/strong><\/p>\n

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