{"id":16242,"date":"2016-05-30T09:00:06","date_gmt":"2016-05-30T01:00:06","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=16242"},"modified":"2016-07-10T23:16:00","modified_gmt":"2016-07-10T15:16:00","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81angew%e7%ad%89%e9%94%82%e7%a9%ba%e7%94%b5%e6%b1%a0%e5%8f%8a%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e8%bf%91%e6%9c%9f%e5%ad%a6%e6%9c%af%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=16242","title":{"rendered":"\u9876\u520a\u52a8\u6001|Angew\u7b49\u9502\u7a7a\u7535\u6c60\u53ca\u94a0\u79bb\u5b50\u7535\u6c60\u8fd1\u671f\u5b66\u672f\u8fdb\u5c55\u6c47\u603b\u3010\u65b0\u80fd\u6e90\u5468\u62a5160530\u671f\u3011"},"content":{"rendered":"

\u9502\u7a7a\u6c14\u7535\u6c60\u548c\u94a0\u79bb\u5b50\u7535\u6c60\u4f5c\u4e3a\u65b0\u4e00\u4ee3\u5927\u5bb9\u91cf\u7535\u6c60\u5907\u53d7\u77a9\u76ee\uff0c\u4f46\u76ee\u524d\u8981\u5b9e\u73b0\u5927\u89c4\u6a21\u5e94\u7528\uff0c\u8fd8\u5b58\u5728\u4e0d\u5c11\u95ee\u9898\u3002\u4e0b\u9762\u662f\u76ee\u524d\u5bf9\u9502\u7a7a\u6c14\u7535\u6c60\u548c\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6027\u80fd\u6539\u5584\u7814\u7a76\u7684\u53d1\u5c55\u52a8\u6001\u6c47\u603b\u3002<\/strong><\/p>\n

1. Angewandte Chemie International Edition: <\/strong>\u975e\u8d28\u5b50\u9502\u6c27\u7535\u6c60\u7684\u6d3b\u6027\u4f4d\u70b9\u4e0e\u4f20\u8f93\u9650\u5236\u7684\u7814\u7a76<\/strong><\/p>\n

\"fig1-1\"<\/p>\n

\u9502\u6c27\u7535\u6c60\u56e0\u5176\u8d85\u9ad8\u7684\u6bd4\u80fd\u91cf\u5f15\u8d77\u4eba\u4eec\u7684\u5173\u6ce8\u3002\u5bf9\u4e8e\u975e\u8d28\u5b50\u9502\u6c27\u7535\u6c60\u6765\u8bf4\uff0c\u6b63\u6781\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u4ea7\u751f\u56fa\u4f53Li2<\/sub>O2<\/sub>\uff0c\u5728\u4e00\u4e2a\u8f83\u5e73\u7a33\u7684\u653e\u7535\u7535\u538b\u5e73\u53f0\u540e\uff0c\u6709\u7535\u538b\u6025\u5267\u4e0b\u964d\u73b0\u8c61\uff08\u4e5f\u79f0\u201c\u731d\u6b7b\u201d\uff09\uff0c\u8fd9\u4f7f\u5f97\u9502\u6c27\u7535\u6c60\u7684\u5b9e\u9645\u5bb9\u91cf\u4f4e\u4e8e\u7406\u8bba\u5bb9\u91cf\u3002<\/p>\n

\u4e3a\u4e86\u66f4\u6df1\u5165\u5730\u7406\u89e3\u9502\u6c27\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u5c40\u9650\u6027\uff0c\u957f\u6625\u5e94\u5316\u6240JiaWei Wang\u7b49\u4eba\u5bf9Au \/Li2<\/sub>O2<\/sub>\/Li+<\/sup>\/\u4e8c\u7532\u57fa\u4e9a\u781c\u7684\u7535\u6781\u4f53\u7cfb\u8fdb\u884c\u7535\u5bfc\u7387\u6d4b\u8bd5\u548c\u539f\u4f4d\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u5149\u8c31\u5206\u6790\u3002\u5728\u8fd9\u4e2a\u7535\u6781\u4f53\u7cfb\u4e2d\uff0c\u7528\u6052\u7535\u6d41\u653e\u7535\u6cd5\u4f7fAu\u7535\u6781\u8868\u9762\u8986\u76d63.8 nm\u7684\u8d85\u8584Li2<\/sub>O2<\/sub>\u8584\u819c\uff0c\u7535\u6781\u9884\u5148\u949d\u5316\uff0c\u653e\u7535\u5230\u7535\u538b\u6025\u5267\u4e0b\u964d\u72b6\u6001\uff0c\u5e76\u6d4b\u5f97\u6b64\u65f6Au\/Li2<\/sub>O2<\/sub>\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u7535\u5b50\u7535\u5bfc\u7387\u5206\u522b\u4e3a2.2\u00d710-13<\/sup>\u548c3.1\u00d710-12<\/sup> S cm-1<\/sup>\u3002\u5728\u539f\u4f4d\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u5149\u8c31\u5206\u6790\u4e2d\u7684ORR\u53cd\u5e94\u65f6\uff0c\u9884\u5148\u949d\u5316\u4e2d\u4f7f\u752818<\/sup>O2<\/sub>\uff0c\u800c\u540e\u7eed\u653e\u7535\u4e2d\u4f7f\u752816<\/sup>O2<\/sub>\uff0c\u7ed3\u679c\u53d1\u73b0\uff0c\u4e8b\u5148\u6c89\u79ef\u7684Li2<\/sub>18<\/sup>O2<\/sub>\u9010\u6e10\u88ab\u540e\u6765\u751f\u6210\u7684Li2<\/sub>16<\/sup>O2<\/sub>\u4ee3\u66ff\uff0c\u8bc1\u660eORR\u53cd\u5e94\u53d1\u751f\u5728Au\/Li2<\/sub>O2<\/sub>\u754c\u9762\u4e14\u53d7\u7535\u5b50\u4f20\u9012\u7684\u9650\u5236\uff0c\u800c\u975eLi+<\/sub>\u6216\u8005O2<\/sub>\u7684\u4f20\u8f93\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aIdentifying Reactive Sites and Transport Limitations of Oxygen Reactions in Aprotic Lithium-O2<\/sub> Batteries at the Stage of Sudden Death<\/a><\/p>\n

2. \u00a0Angewandte Chemie International Edition: <\/strong>\u9502\u6c27\u7535\u6c60\u5145\u7535\u8fc7\u7a0b\u5355\u7ebf\u6001\u6c27\u7684\u751f\u6210<\/strong><\/p>\n

\"fig2-1\"<\/p>\n

\u63d0\u9ad8\u9502\u6c27\u7535\u6c60\u53cd\u5e94\u7684\u53ef\u9006\u6027\u7684\u4e00\u4e2a\u6838\u5fc3\u95ee\u9898\u662f\uff0c\u5982\u4f55\u6291\u5236\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5f15\u8d77\u78b3\u7535\u6781\u8150\u8680\u548c\u7535\u89e3\u6db2\u5206\u89e3\u7684\u526f\u53cd\u5e94\uff0c\u56e0\u4e3a\u6b63\u662f\u8fd9\u4e9b\u53cd\u5e94\u5219\u5bfc\u81f4\u4e86\u7535\u6c60\u7684\u5931\u6548\u3002\u5927\u591a\u6570\u4eba\u4e00\u822c\u91c7\u7528e–<\/sup>\/O2<\/sub>\u7684\u6bd4\u7387\u6765\u8861\u91cf\u53d1\u751f\u7684\u526f\u53cd\u5e94\u7684\u7a0b\u5ea6\uff0c\u6b63\u5e38\u6765\u8bf4\uff0ce–<\/sup>\/O2<\/sub>\u7ea6\u7b49\u4e8e2.00\u3002\u7136\u800c\u6709\u4e9b\u7814\u7a76\u53d1\u73b0\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\uff0ce–<\/sup>\/O2<\/sub>\u4e4b\u6bd4\u5374\u504f\u79bb\u4e862.00\u6b63\u5e38\u8303\u56f4\uff0c\u5e76\u63d0\u51fa\u5047\u8bbe\uff0c\u57283.5 V\u5de6\u53f3\u6709\u67d0\u79cd\u4e2d\u95f4\u4ea7\u7269\u751f\u6210\u3002<\/p>\n

\u5fb7\u56fd\u5316\u5b66\u4e0e\u50ac\u5316\u7814\u7a76\u4e2d\u5fc3J.Wandt\u7b49\u4eba\u5047\u8bbe\u8fd9\u79cd\u6d3b\u6027\u4e2d\u95f4\u4ea7\u7269\u662f\u5355\u7ebf\u6001\u6c271<\/sup>O2<\/sub>\uff08\u4e00\u79cd\u5904\u4e8e\u6fc0\u53d1\u6001\u7684\u5206\u5b50\u6c27\uff09\u3002\u5355\u7ebf\u6001\u6c27\u6709\u5f88\u5f3a\u7684\u6c27\u5316\u6027\uff0c\u80fd\u5f62\u6210Li2<\/sub>O2<\/sub>\u3001Na2<\/sub>O2<\/sub>\u7b49\u4e00\u7cfb\u5217\u6709\u673a\u8fc7\u6c27\u5316\u7269\uff0c\u7535\u89e3\u6c27\u5316Li2<\/sub>O2<\/sub>\u8fc7\u7a0b\u4e2d\uff0c\u751f\u62101<\/sup>O2<\/sub>\u7684\u70ed\u529b\u5b66\u53ef\u9006\u7535\u52bf\u4f30\u8ba1\u57283.45~3.5 V\uff08\u4ec5\u6bd4\u4e09\u7ebf\u6001\u6c27\u7684\u70ed\u529b\u5b66\u53ef\u9006\u7535\u52bf\u9ad80.5 V\uff09\u3002\u75282,2,6,6-\u56db\u7532\u57fa-\u54cc\u5576\u916e\u548c\u7535\u5b50\u987a\u78c1\u5171\u632f\u6ce2\u8c31\u6765\u68c0\u6d4b\u5206\u6790\u5355\u7ebf\u6001\u6c27\u7684\u751f\u6210\uff0c\u5e76\u7528\u539f\u4f4d\u7535\u5316\u5b66\u8d28\u8c31\u6d4b\u5b9a\u6cd5\u9a8c\u8bc1\u3002\u7ed3\u679c\u8868\u660e\uff0c\u57283.5 V\u5de6\u53f3\uff0cLi2<\/sub>O2<\/sub>\u7684\u6c27\u5316\u53cd\u5e94\u4e2d\uff0c\u53cd\u5e94\u4ea7\u7269\u4e2d\u7684\u6c27\u81f3\u5c11\u67090.5%\u7684\u5355\u7ebf\u6001\u6c27\uff0c\u5e76\u663e\u793a\u51fa\u5355\u7ebf\u6001\u6c27\u5728\u9502\u6c27\u7535\u6c60\u7684\u4e0d\u53ef\u9006\u526f\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u8d77\u4e86\u91cd\u8981\u4f5c\u7528\u3002\u8fd9\u4e2a\u5b9e\u9a8c\u4ec5\u4ec5\u7c97\u7565\u4f30\u8ba1\u4e86\u5355\u7ebf\u6001\u6c27\u7684\u542b\u91cf\u4e0e\u4f5c\u7528\uff0c\u4e0b\u4e00\u6b65\u8ba1\u5212\u7814\u7a76\u5355\u7ebf\u6001\u6c27\u5728\u5404\u4e2a\u53cd\u5e94\u4e2d\u7684\u542b\u91cf\uff0c\u5e76\u51cf\u5c11\u526f\u53cd\u5e94\uff0c\u6539\u5584\u9502\u6c27\u7535\u6c60\u7684\u5faa\u73af\u53ef\u9006\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSinglet Oxygen Formation during the Charging Process of an Aprotic Lithium\u2013Oxygen Battery<\/a><\/p>\n

3. \u00a0Angewandte Chemie International Edition<\/strong>\uff1a\u9541\u63ba\u6742\u6291\u5236Na0.67<\/sub>Mn0.67<\/sub>Ni0.33<\/sub>O2<\/sub><\/strong>\u6b63\u6781\u6750\u6599\u4e2dP2<\/sub>-O2<\/sub><\/strong>\u76f8\u6001\u8f6c\u53d8\u6539\u5584\u94a0\u79bb\u5b50\u7535\u6c60\u6027\u80fd<\/strong><\/p>\n

\"fig3-1
\n\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u5c42\u72b6\u6c27\u5316\u7269Nax<\/sub>TMO2<\/sub>\uff08TM=\u8fc7\u6e21\u91d1\u5c5e\uff0c\u5c42\u72b6\u6c27\u5316\u7269\u6750\u6599\u53ef\u4ee5\u5206\u4e3a\u4e24\u5927\u7c7b\uff1aP2<\/sub>\u578b\u548cO2<\/sub>\u578b\uff09\u4f5c\u4e3a\u9ad8\u5bb9\u91cf\u6b63\u6781\u6750\u6599\u6709\u5f88\u597d\u7684\u524d\u666f\u4f18\u52bf\u3002\u76f8\u6bd4\u4e8eO2<\/sub>\u578b\u6750\u6599\uff0cP2<\/sub>\u591a\u5143\u578b\u6750\u6599\u7684\u7ed3\u6784\u6846\u67b6\uff0c\u5982Na0.5<\/sub>[Ni0.23<\/sub>Fe0.13<\/sub>Mn0.63<\/sub>]O2<\/sub>\uff0c\u6709\u83f1\u5f62\u7684\u94a0\u79bb\u5b50\u6269\u6563\u901a\u9053\uff0c\u6269\u6563\u963b\u529b\u5c0f\uff0c\u4f7fP2<\/sub>\u578b\u6750\u6599\u6709\u9ad8\u5bb9\u91cf\u548c\u5faa\u73af\u6027\u80fd\u826f\u597d\u7b49\u4f18\u52bf\u3002<\/p>\n

\u800c\u5728P2<\/sub>-Na2\/3<\/sub>Ni1\/3<\/sub>Mn2\/3<\/sub>O2<\/sub>\u6750\u6599\u4e2d\uff0c\u901a\u8fc7Ni2+<\/sup>\/Ni4+<\/sup>\u57282.0 V~4.5 V\u4e4b\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u6765\u5b9e\u73b0\u94a0\u79bb\u5b50\u7684\u8fd0\u8f93\uff0c\u8fbe\u5230160 mAh\/g\u7684\u5bb9\u91cf\uff083.7 V vs. Na+<\/sup>\/Na\uff09\u3002\u5f53\u5145\u7535\u52304.22 V\u65f6\uff0cP2<\/sub>-Na+<\/sup>2\/3<\/sub>[Ni2+<\/sup>1\/3<\/sub>Mn4+<\/sup>2\/3<\/sub>]O2-<\/sup>2<\/sub>\u4e2d\u6c27\u6c14\u6846\u67b6\u7684\u8f6c\u79fb\u81f4\u4f7f\u6b63\u6781\u6750\u6599\u53d1\u751fP2<\/sub>-O2<\/sub> \u8f6c\u53d8\uff0c\u4f53\u79ef\u4e5f\u6709\u4e00\u5b9a\u53d8\u5316\uff0c\u57284.35 V\u65f6\u5bb9\u91cf\u6025\u5267\u4e0b\u964d\uff0c\u4ec5\u526980 mAh\/g\u3002<\/p>\n

\u5bf9\u4e8eP2<\/sub>-Na2\/3<\/sub>Ni1\/3<\/sub>Mn2\/3<\/sub>O2<\/sub>\u6750\u6599\uff0c\u4e2d\u79d1\u9662Peng-Fei Wang\u7b49\u4eba\u8003\u8651\u5230Mg2+<\/sup> (0.072 nm) \u548c Ni2+ <\/sup>(0.069 nm)\u7684\u76f8\u4f3c\u6027\uff0c\u5c06\u4e00\u90e8\u5206Mg2+<\/sup>\u4ee3\u66ffNi2+<\/sup>\uff0c\u901a\u8fc7\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u5408\u6210P2<\/sub>-Na0.67<\/sub>Mn0.67<\/sub>Ni0.33-x<\/sub>Mgx<\/sub>O2<\/sub>\u65b0\u578b\u6b63\u6781\u6750\u6599\uff0c\u5bb9\u91cf\u8fbe\u5230123 mAh\/g\uff083.7 V vs Na+<\/sup>\/Na\uff09\uff0c\u6bd4\u80fd\u91cf\u4e3a455 Wh\/Kg\u3002\u5728TM\u5c42\u5185\uff0c\u6d3b\u6027\u4f4e\u7684\u9541\u79bb\u5b50\u4f7f\u83f1\u5f62\u901a\u9053\u80fd\u591f\u50a8\u5b58\u66f4\u591a\u7684\u94a0\u79bb\u5b50\uff0c\u51cf\u5c0f\u4e86\u5145\u653e\u7535\u8fc7\u7a0b\u6b63\u6781\u7684\u4f53\u79ef\u53d8\u5316\uff0c\u63d0\u9ad8\u4e86\u6b63\u6781\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u5728\u8fc7\u6e21\u91d1\u5c5e\u5c42\u72b6\u6c27\u5316\u7269\u6750\u6599\u4e2d\u6dfb\u52a0\u4e0d\u6d3b\u6cfc\u7684\u91d1\u5c5e\u79bb\u5b50\uff0c\u662f\u4e00\u79cd\u63d0\u9ad8P2<\/sub>\u578b\u5c42\u72b6\u6c27\u5316\u7269\u6b63\u6781\u6750\u6599\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u7684\u6709\u6548\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSuppressing the P2<\/sub>\u2013O2 <\/sub>Phase Transition of Na0.67<\/sub>Mn0.67<\/sub>Ni0.33<\/sub>O2<\/sub> by Magnesium Substitution for Improved Sodium-Ion Batteries<\/a><\/p>\n

4. AEM:<\/strong>\u77f3\u58a8\u70ef\u5305\u88f9\u591a\u5b54<\/strong>Li4<\/sub>Ti5<\/sub>O12<\/sub><\/strong>\u7eb3\u7c73\u7ea4\u7ef4\u590d\u5408\u6c14\u51dd\u80f6\u5728\u754c\u9762\u4e0a\u50a8\u94a0\u7684\u7814\u7a76<\/strong><\/p>\n

\"fig4-1\"<\/p>\n

\u6700\u8fd1\u5173\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u7814\u7a76\u96c6\u4e2d\u5728Nax<\/sub>CoO2<\/sub>\u3001 Na3<\/sub>V2<\/sub>(PO4<\/sub>)3<\/sub>\u3001Na2<\/sub>FePO4<\/sub>F\u7b49\u7b49\uff0c\u800c\u8d1f\u6781\u6750\u6599\u591a\u6570\u4e3a\u542b\u78b3\u6750\u6599\u3002\u5c3d\u7ba1Na+<\/sup>\u5728\u52a8\u529b\u5b66\u548c\u70ed\u529b\u5b66\u4e0a\u4e0d\u80fd\u591f\u63d2\u5165\u672a\u4fee\u9970\u7684\u78b3\u6750\u6599\u4e2d\uff0c\u786c\u78b3\u7684\u65e0\u5e8f\u7ed3\u6784\u5374\u6709\u52a9\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u63d0\u5347\u5bb9\u91cf\u548c\u6539\u5584\u5faa\u73af\u6027\u80fd\u3002\uff0c\u7136\u800c\uff0c\u786c\u78b3\u6750\u6599\u5374\u4f7f\u7535\u6c60\u7684\u5f00\u8def\u7535\u538b\u5f88\u4f4e\uff08\u51e0\u4e4e\u4e3a\u96f6vs Na+<\/sup>\/Na\uff09\u3002\u7814\u7a76\u8868\u660e\uff0c\u542b\u949b\u5316\u5408\u7269\u7684\u7535\u6781\u6750\u6599\u80fd\u63d0\u9ad8\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u7535\u538b\u3002\u4e5f\u6709\u4e00\u4e9b\u5de5\u4f5c\u8868\u660e\uff0c\u5728\u7535\u6c60\u7cfb\u7edf\u4e2d\uff0c\u56fa\u2014\u56fa\u3001\u56fa\u2014\u6db2\u754c\u9762\u6784\u5efa\u591a\u5b54\u6216\u6df7\u5408\u76f8\u7ed3\u6784\uff0c\u754c\u9762\u4e0a\u7684\u50a8\u9502\u6216\u94a0\u662f\u53ef\u884c\u7684\u3002<\/p>\n

\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u7684Chaoji Chen\u7b49\u4eba\u7814\u7a76\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u591a\u5b54\u7ed3\u6784\u96c6\u6210\u590d\u5408\u6c14\u51dd\u80f6\u6df7\u5408\u76f8\u5316\u5408\u7269\uff0c\u662f\u5c06\u591a\u5b54\u7684Li4<\/sub>Ti5<\/sub>O12<\/sub>\uff08PLTO\uff09\u7eb3\u7c73\u7ea4\u7ef4\u4e0e\u9ad8\u5bfc\u7535\u6027\u76843D\u77f3\u58a8\u70ef\u9aa8\u67b6\u7ed3\u5408\uff08G\u2014PLTO\uff09\u3002\u8fd9\u79cd\u7ed3\u6784\u6709\u7740\u77ed\u7684\u79bb\u5b50\u901a\u9053\uff0c\u4e0d\u4ec5\u6709\u5229\u4e8eNa+<\/sup>\u7684\u6269\u6563\uff0c\u4e5f\u63d0\u4f9b\u4e86\u5927\u91cf\u7684Na+<\/sup>\u5b58\u50a8\u7684\u754c\u9762\u4f4d\u70b9\u3002\u8fd9\u79cd\u7279\u6027\u4f7f\u5f97\u57280.2 C\u653e\u7535\u65f6\uff0c\u7535\u6c60\u4ecd\u6709195 mAh\/g\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u8d85\u8fc7\u4e86LTO\uff08Li4<\/sub>Ti5<\/sub>O12<\/sub><\/strong>\uff09\u7684\u7406\u8bba\u503c\uff01\u53e6\u5916\uff0c\u8fd9\u79cd\u7ed3\u6784\u5177\u6709\u5f88\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u6709\u5229\u4e8eSEI\u819c\u5728\u56fa\u4f53\u7535\u6781\u4e0a\u7684\u5f62\u6210\u3002\u56e0\u6b64\uff0c\u6d4b\u8bd5G-PLTO\u670912000\u6b21\u7684\u5faa\u73af\u5bff\u547d\u3002\u8fd9\u4e9b\u53d1\u73b0\u6709\u671b\u63a8\u8350\u9ad8\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u5927\u89c4\u6a21\u50a8\u80fd\u7684\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aIntegrated Intercalation-Based and Interfacial Sodium Storage in Graphene-Wrapped Porous Li4<\/sub>Ti5<\/sub>O12<\/sub> Nanofibers Composite Aerogel<\/a><\/p>\n

5. Nano Energy: <\/strong>\u5305\u88f9\u94a0\u8d85\u79bb\u5b50\u5bfc\u4f53- Fe2<\/sub>(MoO4<\/sub>)3<\/sub><\/strong>\u7eb3\u7c73\u9897\u7c92\u7684\u77f3\u58a8\u70ef\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599<\/strong><\/p>\n

\"fig5\"<\/p>\n

\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\uff0c\u94a0\u8d85\u79bb\u5b50\u5bfc\u4f53\u6709\u7740\u7406\u60f3\u7684\u4e09\u7ef4\u94a0\u79bb\u5b50\u8fd0\u8f93\u901a\u9053\uff0c\u53ea\u6709\u90e8\u5206\u6709\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u94bc\u9178\u94c1\u76d0\uff08Fe2<\/sub>(MoO4<\/sub>)3<\/sub>\uff09\u5c31\u662f\u5176\u4e2d\u7684\u4e00\u79cd\u3002Fe2<\/sub>(MoO4<\/sub>)3<\/sub>\u6ca1\u6709\u6bd2\u6027\uff0c\u57282.6 V\u5904\u6709\u4e00\u4e2a\u653e\u7535\u5e73\u53f0\u3002\u7136\u800c\uff0cFe2<\/sub>(MoO4<\/sub>)3<\/sub>\u7684\u53d1\u5c55\u53d7\u5230\u4f4e\u7535\u5b50\u5bfc\u7535\u6027\u548c\u8f83\u957f\u7684\u94a0\u79bb\u5b50\u901a\u9053\u5f15\u8d77\u7684\u7535\u5316\u5b66\u52a8\u529b\u5b66\u4e0a\u7684\u8fdf\u7f13\u6027\u9650\u5236\u3002<\/p>\n

\u6b66\u6c49\u7406\u5de5\u5927\u5b66Jinzhi Shen\u7b49\u4eba\u901a\u8fc7\u5fae\u4e73\u6db2\u6cd5\u5408\u6210\u4e86\u5305\u88f9Fe2<\/sub>(MoO4<\/sub>)3<\/sub>\u7eb3\u7c73\u7c92\u5b50\u7684\u77f3\u58a8\u70ef\uff0c\u6d4b\u5f97\u5728100 C\u653e\u7535\u65f6\u5bb9\u91cf\u4e3a64.1 mAh\/g\uff0c10 C\u653e\u7535\u5faa\u73af100\u6b21\u540e\u8fd8\u670976%\u7684\u5bb9\u91cf\uff0c\u8bf4\u660e\u9ad8\u500d\u7387\u653e\u7535\u65f6\u4ecd\u6709\u5f88\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u7535\u5316\u5b66\u6027\u80fd\u7684\u6539\u5584\u53ef\u5f52\u56e0\u4e8eFe2<\/sub>(MoO4<\/sub>)3<\/sub>\u7eb3\u7c73\u7c92\u5b50\u548c\u9ad8\u5bfc\u7535\u7684\u77f3\u58a8\u70ef\uff0c\u4e0d\u4ec5\u7f29\u77ed\u4e86\u94a0\u79bb\u5b50\u901a\u9053\u8fd8\u589e\u52a0\u4e86\u4f20\u5bfc\u7535\u5b50\u7684\u80fd\u529b\u3002\u6700\u540e\uff0c\u4f5c\u8005\u8fd8\u8be6\u7ec6\u4ecb\u7ecd\u4e86\u94a0\u79bb\u5b50\u8fd0\u8f93\u548c\u5b58\u50a8\u7684\u673a\u7406\u3002\u8fd9\u79cd\u5305\u88f9\u4e86Fe2<\/sub>(MoO4<\/sub>)3<\/sub>\u7eb3\u7c73\u7c92\u5b50\u7684\u77f3\u58a8\u70ef\u6750\u6599\u5728\u9ad8\u500d\u7387\u7684\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u6709\u5f88\u597d\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aGraphene wrapped NASICON-type Fe2(MoO4)3 nanoparticles as a ultra-high rate cathode for sodium ion batteries<\/a><\/p>\n

\u8be5\u6587\u732e\u6c47\u603b\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u5c0f\u7ec4\u00a0 \u5218\u82b3\u00a0\u00a0 \u4f9b\u7a3f\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\uff0c\u82e5\u60f3\u53c2\u4e0e\u65b0\u80fd\u6e90\u6587\u732e\u89e3\u8bfb\u548c\u6587\u732e\u6c47\u603b\u3001\u65b0\u80fd\u6e90\u77e5\u8bc6\u79d1\u666e\u548c\u6df1\u5ea6\u6316\u6398\u65b0\u80fd\u6e90\u5b66\u672f\u4ea7\u4e1a\u4fe1\u606f\uff0c\u8bf7\u52a0qq 2728811768\u3002<\/p>\n

\u6b22\u8fce\u5404\u5927\u8bfe\u9898\u7ec4\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/p>\n","protected":false},"excerpt":{"rendered":"

\u9502\u7a7a\u6c14\u7535\u6c60\u548c\u94a0\u79bb\u5b50\u7535\u6c60\u4f5c\u4e3a\u65b0\u4e00\u4ee3\u5927\u5bb9\u91cf\u7535\u6c60\u5907\u53d7\u77a9\u76ee\uff0c\u4f46\u76ee\u524d\u8981\u5b9e\u73b0\u5927\u89c4\u6a21\u5e94\u7528\uff0c\u8fd8\u5b58\u5728\u4e0d\u5c11\u95ee\u9898\u3002\u4e0b\u9762\u662f\u76ee\u524d\u5bf9\u9502\u7a7a\u6c14\u7535\u6c60\u548c\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6027\u80fd\u6539\u5584\u7814\u7a76\u7684\u53d1\u5c55\u52a8\u6001\u6c47\u603b\u3002 1…<\/p>\n","protected":false},"author":90,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[67],"tags":[],"class_list":["post-16242","post","type-post","status-publish","format-standard","hentry","category-zhoubao"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/16242"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/90"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=16242"}],"version-history":[{"count":10,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/16242\/revisions"}],"predecessor-version":[{"id":26161,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/16242\/revisions\/26161"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=16242"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=16242"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=16242"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}