{"id":163885,"date":"2019-01-07T06:23:27","date_gmt":"2019-01-06T22:23:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=163885"},"modified":"2019-01-07T09:48:02","modified_gmt":"2019-01-07T01:48:02","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e5%85%b0%e5%b7%9e%e5%a4%a7%e5%ad%a6%e5%b8%ad%e8%81%98%e8%b4%a4%e5%9b%a2%e9%98%9f%e5%b8%83%e6%9c%97%e5%a4%a7%e5%ad%a6%e5%ad%99%e5%ae%88%e6%81%92nano-e","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=163885","title":{"rendered":"\u5170\u5dde\u5927\u5b66\u5e2d\u8058\u8d24\u56e2\u961f&\u5e03\u6717\u5927\u5b66\u5b59\u5b88\u6052Nano Energy\uff1a\u7528Co\u66ff\u4ee3\u53ef\u63a7\u8c03\u8282Fe-N\u7eb3\u7c73\u7247\u589e\u5f3a\u6790\u6c27\u53cd\u5e94"},"content":{"rendered":"

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\u56fe2<\/b><\/strong>\u00a0<\/b><\/strong>Co<\/b><\/strong>0.15<\/b><\/sub><\/strong>Fe<\/b><\/strong>0.85<\/b><\/sub><\/strong>N<\/b><\/strong>0.5<\/b><\/sub><\/strong>\u00a0NSs<\/b><\/strong>\u7684<\/b><\/strong>XPS\u5149\u8c31<\/b><\/strong>\u548c<\/b><\/strong>EXAFS\u5149\u8c31<\/b><\/strong>\u8868\u5f81<\/b><\/strong>\"\"<\/p>\n

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\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0<\/b><\/strong>OER<\/b><\/strong>\u8fc7\u7a0b\u4e2d\u4e0d\u540c<\/b><\/strong>\u6d3b\u6027\u4f4d\u70b9<\/b><\/strong>\u7684\u7406\u8bba\u8ba1\u7b97<\/b><\/strong>\"\"<\/p>\n

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\uff08c\uff09DFT\u8ba1\u7b97Fe-Fe\uff0cCo-Fe\u548cCo-Co\u6a21\u578b\u7684\u8fc7\u7535\u4f4d\u3002\u63d2\u56fe\uff1aFe-Fe\uff0cCo-Fe\u548cCo-Co\u6a21\u578b\u7684OER\u6d3b\u6027\u4f4d\u70b9\u6570\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n

\u603b\u4e4b\uff0c\u5f00\u53d1\u57fa\u4e8eTMNs\u7ed3\u6784\u7684\u65b0\u578b\u53cc\u529f\u80fd\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u56e2\u961f\u901a\u8fc7\u6eb6\u6db2\u76f8\u5265\u79bb\u65b9\u6cd5\u5408\u6210\u539f\u5b50\u7ea7\u8584\uff081.1nm\uff09Co-Fe-N NSs\u3002\u8d85\u8584\u6027\u4fdd\u8bc1\u4e86Co\/Fe\u6700\u5927\u7a0b\u5ea6\u5730\u66b4\u9732\u4e8e\u53cd\u5e94\u73af\u5883\uff0c\u5e76\u80fd\u8be6\u7ec6\u7814\u7a76Co\u5728\u6539\u53d8Fe-N\u7ed3\u6784\u4e2d\u7684\u4f5c\u7528\uff0c\u4ee5\u663e\u793a\u53cc\u529f\u80fdORR\/OER\u50ac\u5316\u3002\u7814\u7a76\u8868\u660e\uff0c\u5728Co-Fe-N\u7ed3\u6784\u4e2d\uff0cCo\u7684\u5b58\u5728\u524a\u5f31\u4e86Fe-N\/Fe-Fe\u952e\u5e76\u589e\u52a0\u4e86\u6574\u4f53\u91d1\u5c5e\u6c27\u5316\u6001\uff0c\u6539\u53d8\u4e86\u7535\u5b50\u7ed3\u6784\u5e76\u6539\u5584\u4e86Fe\u7684\u50ac\u5316\u6027\u80fd\u3002\u7ed3\u679c\uff0cCo0.15<\/sub>Fe0.85<\/sub>N0.5<\/sub>\u00a0NSs\u572810mA cm-2<\/sup>\u5904\u663e\u793a\u51fa\u6700\u4f4e\u7684\u03b7\u4e3a266 mV\uff0c\u6700\u5c0f\u7684Tafel\u659c\u7387\u4e3a~30mV dec-1<\/sup>\u5e76\u4e14\u5177\u6709\u6700\u9ad8\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0cDFT\u8ba1\u7b97\u8868\u660eCo0.15<\/sub>Fe0.85<\/sub>N0.5<\/sub>\u00a0NSs\u7ed3\u6784\u4e2d\u7684Co-Fe\u4f4d\u70b9\u88ab\u4f18\u5316\uff0c\u4fc3\u8fdbOH\u204e\u5411O\u204e\u8f6c\u5316\uff0cO\u204e-O\u204e\u8026\u5408\u548cO2<\/sub>\u5f62\u6210\uff0c\u8868\u660eCo-Fe\u4f4d\u70b9\u5728\u589e\u5f3aOER\u50ac\u5316\u65b9\u9762\u786e\u5b9e\u8868\u73b0\u51fa\u975e\u5e38\u7406\u60f3\u7684\u534f\u540c\u4f5c\u7528\u3002\u8be5\u7814\u7a76\u7684\u5408\u6210\u65b9\u6cd5\u4e0d\u4ec5\u9650\u4e8eCo-Fe-N\u7684\u5236\u5907\uff0c\u8fd8\u53ef\u4ee5\u63a8\u5e7f\u5230Mx<\/sub>M1-x<\/sub>Ny<\/sub>\uff0c\u4e3a\u5236\u5907\u91cd\u8981\u7535\u5316\u5b66\u53cd\u5e94\u7684\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u53cc\u91d1\u5c5e\u6c2e\u5316\u7269\u63d0\u4f9b\u4e86\u4e00\u79cd\u901a\u7528\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Controllable Tuning of Fe-N Nanosheets by Co Substitution for Enhanced Oxygen Evolution Reaction<\/u><\/a>\uff08Nano Energy, 2018, DOI:10.1016\/j.nanoen.2018.12.094\uff09<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd<\/b><\/strong>\u3011<\/p>\n

\u7814\u7a76\u56e2\u961f\u76f8\u5173\u53c2\u8003\u6587\u732e\uff1a<\/p>\n

    \n
  1. Heterostructure-Promoted Oxygen Electrocatalysis Enables Rechargeable Zinc-Air Battery with Neutral Aqueous Electrolyte, J. Am. Chem. Soc. 2018, 140, 17624.<\/li>\n
  2. Ni-C-N Nanosheets as Catalyst for Hydrogen Evolution Reaction, J. Am. Chem. Soc. 2016, 138,14546.<\/li>\n
  3. Oxygen Vacancies Dominated NiS2<\/sub>\/CoS2<\/sub>Interface Porous Nanowires for Portable Zn-Air Batteries Driven Water Splitting Devices, Adv. Mater. 2017, 29, 1704681.<\/li>\n
  4. 4. Epitaxial Heterogeneous Interfaces on N-NiMoO4<\/sub>\/NiS2<\/sub>Nanowires\/Nanosheets to Boost Hydrogen and OxygenProduction for Overall Water Splitting, Adv. Funct. Mater. 2019, 29, 1805298<\/li>\n
  5. Atomic-level Coupled Interface and Lattice Distortion on Cu-Ni-S Nanocrystals Boost Oxygen Catalysis for Flexible Zn-Air Batteries, Adv. Funct. Mater. 2017, 27, 1703779.<\/li>\n
  6. NiO\/CoN Porous Nanowires as Efficient Bifunctional Catalysts for Zn-Air Batteries, ACS. Nano. 2017, 11, 2275.<\/li>\n
  7. FeS2<\/sub>\/CoS2<\/sub>Interface Nanosheets as Efficient Bifunctional Electrocatalyst for Overall Water Splitting, Small 2018, 14, 1801070.<\/li>\n
  8. Activation of defective nickel molybdate nanowires for enhanced alkaline electrochemical hydrogen evolution, Nanoscale, 2018, 10, 16539.<\/li>\n
  9. High-Index Faceted CuFeS2 <\/sub>Nanosheets with Enhanced Behavior for Boosting Hydrogen Evolution Reaction, Nanoscale, 2017, 9, 9230.<\/li>\n
  10. Self-supported nanoporous NiCo2<\/sub>O4 <\/sub>nanowires with cobalt-nickel layered oxide nanosheets for overall water splitting, Nanoscale, 2016, 8, 1390.<\/li>\n
  11. A Self-Standing High-Performance Hydrogen Evolution Electrode with Nanostructured NiCo2<\/sub>O4<\/sub>\/CuS Heterostructures, Adv. Funct. Mater., 2015, 25, 6814.<\/li>\n
  12. Phase Transformation Fabrication of a Cu2<\/sub>S Nanoplate as an Efficient Catalyst for Water Oxidation with Glycine, Inorg. Chem.,2015, 54, 3281.<\/li>\n
  13. High-Quality Copper Sulfide Nanocrystals with Diverse Shapes and Their Catalysis for Electrochemical Reduction of H2<\/sub>O2<\/sub>, Part. Part. Syst. Charact. 2015, 32, 536.<\/li>\n
  14. Ultrafast Hole Trapping and Relaxation Dynamics in p-Type CuS Nanodisks, J. Phys. Chem. Lett. 2015, 6, 2671.<\/li>\n
  15. Self-supported nanoporous NiCo2<\/sub>O4<\/sub>nanowires with cobalt-nickel layered oxide nanosheets for overall water splitting. Nanoscale, 2016, 8, 1390.<\/li>\n<\/ol>\n

    \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u5170\u5dde\u5927\u5b66\u5e2d\u8058\u8d24\u6559\u6388<\/strong>\u4fee\u6b63\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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