{"id":164287,"date":"2019-01-10T06:30:24","date_gmt":"2019-01-09T22:30:24","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=164287"},"modified":"2019-01-09T16:00:47","modified_gmt":"2019-01-09T08:00:47","slug":"%e6%9a%a8%e5%8d%97%e5%a4%a7%e5%ad%a6%e5%94%90%e7%be%a4%e5%a7%94%e5%9b%a2%e9%98%9fsolar-rrl%ef%bc%9a%e5%85%a8%e6%97%a0%e6%9c%bacspbbr3%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=164287","title":{"rendered":"\u66a8\u5357\u5927\u5b66\u5510\u7fa4\u59d4\u56e2\u961fSolar RRL\uff1a\u5168\u65e0\u673aCsPbBr3\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u83b7\u5f9710.6%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u548c1.61V\u7684\u5f00\u8def\u7535\u538b"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u5168\u65e0\u673aCsPbBr3<\/sub>\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u56e0\u5728\u9ad8\u6e29\u3001\u9ad8\u6e7f\u3001\u7d2b\u5916\u5149\u7167\u73af\u5883\u4e0b\u5177\u6709\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u800c\u6210\u4e3a\u592a\u9633\u80fd\u5149\u4f0f\u53d1\u7535\u9886\u57df\u7684\u524d\u6cbf\u6280\u672f\uff0c\u4f46\u5176\u5149\u7535\u8f6c\u6362\u6548\u7387\u4ecd\u7136\u8f83\u4f4e\u3002\u7a76\u5176\u539f\u56e0\uff0cCsPbBr3<\/sub>\u7684\u7a84\u5149\u8c31\u5438\u6536\u3001\u4ecb\u5b54TiO2<\/sub>\u7684\u4f4e\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u4ee5\u53ca\u754c\u9762\u7535\u8377\u590d\u5408\u7b49\u90fd\u5df2\u6210\u4e3a\u9650\u5236\u5149\u4f0f\u6027\u80fd\u8fdb\u4e00\u6b65\u63d0\u5347\u7684\u91cd\u8981\u56e0\u7d20\u3002\u56e0\u6b64\uff0c\u62d3\u5bbd\u5149\u8c31\u54cd\u5e94\u8303\u56f4\u3001\u5f00\u53d1\u9ad8\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u7684\u7535\u5b50\u4f20\u8f93\u5c42\u3001\u901a\u8fc7\u754c\u9762\u5de5\u7a0b\u52a0\u5feb\u754c\u9762\u7535\u8377\u63d0\u53d6\u662f\u672c\u9886\u57df\u4e9f\u9700\u89e3\u51b3\u7684\u5173\u952e\u79d1\u5b66\u95ee\u9898\u3002\u66a8\u5357\u5927\u5b66\u65b0\u80fd\u6e90\u6280\u672f\u7814\u7a76\u9662\u5510\u7fa4\u59d4\u6559\u6388\u56e2\u961f\u56f4\u7ed5\u4ee5\u4e0a\u95ee\u9898\u5f00\u5c55\u4e86CsPbBr3<\/sub>\u7684\u591a\u6b65\u6db2\u76f8\u5236\u5907\u3001\u754c\u9762\u5de5\u7a0b\u3001\u7ec4\u5206\u5de5\u7a0b\u3001\u5149\u8c31\u5de5\u7a0b\u7b49\u7cfb\u7edf\u7814\u7a76\uff0c\u76f8\u5173\u6210\u679c\u5df2\u53d1\u8868\u5728Angewandte Chemie International Edition\u00a0(2018, 57, 3787-3791; 2018, 57, 5746-5749)\u3001Advanced Energy Materials (2018, 8, 1802346)\u3001Small\u00a0(2018, 14, 1704443)\u7b49\u520a\u7269\u4e0a\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u8be5\u56e2\u961f\u53c8\u5728Solar RRL\u6742\u5fd7\u53d1\u8868 \u201cUsing SnO2<\/sub>\u00a0QDs and CsMBr3<\/sub>\u00a0(M=Sn, Bi, Cu) QDs as Charge-Transporting Materials for 10.6%-Efficiency All-Inorganic CsPbBr3<\/sub>\u00a0Perovskite Solar Cells with an Ultrahigh Open-Circuit Voltage of 1.610 V\u201d\u7684\u8bba\u6587\u3002\u8d75\u5a9b\u5a9b\u535a\u58eb\u4e3a\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u5510\u7fa4\u59d4\u6559\u6388\u4e3a\u8bba\u6587\u7684\u552f\u4e00\u901a\u8baf\u4f5c\u8005\u3002<\/strong><\/p>\n

\u8be5\u5de5\u4f5c\u91c7\u7528\u4f4e\u6e29\u6eb6\u6db2\u6cd5\u5408\u6210\u4e86SnO2<\/sub>\u00a0QDs\u6eb6\u6db2\uff0c\u5e76\u901a\u8fc7\u63a7\u5236\u53cd\u5e94\u65f6\u95f4\u8c03\u63a7\u91cf\u5b50\u70b9\u7684\u80fd\u5e26\u7ed3\u6784\u3002\u91c7\u7528SnO2<\/sub>\u00a0QDs\u4f5c\u4e3a\u7535\u5b50\u4f20\u8f93\u6750\u6599\u4e0d\u4ec5\u6539\u5584\u4e86\u7535\u5b50\u63d0\u53d6\u548c\u8fc1\u79fb\u6027\u80fd\uff0c\u53c8\u8d4b\u4e88\u7535\u5b50\u4f20\u8f93\u5c42\uff08ETL\uff09\u589e\u900f\u6548\u5e94\uff0c\u63d0\u9ad8\u4e86CsPbBr3<\/sub>\u5c42\u7684\u5149\u7167\u5f3a\u5ea6\u3002\u540c\u65f6\u8be5\u5de5\u4f5c\u8fd8\u901a\u8fc7\u70ed\u6ce8\u5165\u6cd5\u5236\u5907\u4e86\u80fd\u7ea7\u5339\u914d\u7684CsMBr3<\/sub>\u00a0(M = Sn\u3001Bi\u3001Cu) QDs\u7528\u4f5c\u754c\u9762\u4fee\u9970\u6750\u6599\uff0c\u6709\u6548\u5730\u63d0\u9ad8\u4e86\u7a7a\u7a74\u63d0\u53d6\u80fd\u529b\uff0c\u6291\u5236\u4e86\u7535\u8377\u590d\u5408\u3002\u8be5\u5de5\u4f5c\u5236\u5907\u7684FTO\/SnO2<\/sub>\u00a0QDs\/CsPbBr3<\/sub>\/CsMBr3<\/sub>\u00a0QDs\/carbon\u5668\u4ef6\u5728\u6807\u51c6\u592a\u9633\u5149\u7167\u4e0b\u83b7\u5f97\u4e8610.60%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u548c1.610 V\u7684\u5f00\u8def\u7535\u538b\uff0c\u8fd9\u662f\u76ee\u524dCsPbBr3<\/sub>\u57fa\u5168\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u516c\u5f00\u62a5\u9053\u6700\u9ad8\u7684\u6548\u7387\u548c\u7535\u538b\u8bb0\u5f55\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u56fe\u4e00 SnO<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0<\/b><\/strong>QDs\u53ca\u8584\u819c\u7684\u76f8\u5173\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09FTO\/ETL\u7684\u900f\u5149\u5149\u8c31\u66f2\u7ebf\uff1b\u00a0<\/p>\n

\uff08B\uff09SnO2<\/sub>\u00a0QDs ETL\u7684\u8868\u9762SEM\u56fe\uff1b\u00a0<\/p>\n

\uff08C\uff09SnO2<\/sub>\u00a0QDs ETL\u7684\u65ad\u9762SEM\u56fe\uff1b<\/p>\n

\uff08D\uff09SnO2<\/sub>\u00a0QDs\u7684HRTEM\u56fe\uff1b<\/p>\n

\u56fe\u4e8c \u57fa\u4e8e<\/b><\/strong>SnO<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0QD<\/b><\/strong>s<\/b><\/strong>\u7684<\/b><\/strong>\u5168<\/b><\/strong>\u65e0\u673a<\/b><\/strong>CsPbBr<\/b><\/strong>3<\/b><\/sub><\/strong>\u9499\u949b\u77ff<\/b><\/strong>\u592a\u9633<\/b><\/strong>\u7535\u6c60\u7684\u5149\u4f0f\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09\u5168\u65e0\u673aCsPbBr3<\/sub>\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u7ed3\u6784\u65ad\u9762\u56fe\u3002<\/p>\n

\uff08B\uff09\u5168\u65e0\u673aCsPbBr3<\/sub>\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u80fd\u7ea7\u7ed3\u6784\u548c\u7535\u8377\u4f20\u8f93\u3002<\/p>\n

\uff08C\uff09\u5168\u65e0\u673aCsPbBr3<\/sub>\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684J-V\u66f2\u7ebf\u3002<\/p>\n

\uff08D\uff09\u5168\u65e0\u673aCsPbBr3<\/sub>\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684IPCE\u66f2\u7ebf\u3002<\/p>\n

\uff08E\uff09\u5168\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684PL\u56fe\u8c31<\/p>\n

\uff08F\uff09\u5168\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u77ac\u6001\u8367\u5149\u5149\u8c31\u3002<\/p>\n

\u56fe\u4e09 CsMBr<\/b><\/strong>3<\/b><\/sub><\/strong>\u00a0(M = Sn\u3001Bi\u3001Cu) QDs\u7684\u76f8\u5173\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

(A) CsSnBr3<\/sub>, (F) CsBi2\/3<\/sub>Br3<\/sub>, (K) CsCuBr3<\/sub>\u00a0QDs\u6eb6\u6db2\u7684\u6570\u7801\u7167\u7247\u3002<\/p>\n

(B) CsSnBr3<\/sub>, (G) CsBi2\/3<\/sub>Br3<\/sub>, (L) CsCuBr3<\/sub>\u00a0QDs\u6eb6\u6db2\u7684\u53d1\u5149\u7279\u6027\u3002<\/p>\n

(C-E) CsSnBr3<\/sub>, (H-J) CsBi2\/3<\/sub>Br3<\/sub>, (M-O) CsCuBr3<\/sub>\u00a0QDs\u7684TEM\u53caHRTEM\u56fe\u3002<\/p>\n

(P)\u00a0CsPbBr3<\/sub>\/CsSnBr3<\/sub>,\u00a0(Q) CsPbBr3<\/sub>\/CsBi2\/3<\/sub>Br3<\/sub>, (R) CsPbBr3<\/sub>\/CsCuBr3<\/sub>\u8584\u819c\u7684\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n

(S) FTO\/SQE36\/CsPbBr3<\/sub>\/CsMBr3<\/sub>\u00a0(M = Sn, Bi, Cu) QDs\u7684XRD\u56fe\u8c31\u3002<\/p>\n

\u56fe\u56db \u57fa\u4e8eSnO<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0QDs\u548c<\/b><\/strong>CsMBr<\/b><\/strong>3<\/b><\/sub><\/strong>\u00a0(M = Sn\u3001Bi\u3001Cu) QDs\u7684<\/b><\/strong>\u5168<\/b><\/strong>\u65e0\u673a\u9499\u949b\u77ff<\/b><\/strong>\u592a\u9633<\/b><\/strong>\u7535\u6c60<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

\uff08A\uff09CsSnBr3<\/sub>, CsBi2\/3<\/sub>Br3<\/sub>\u00a0and CsCuBr3<\/sub>\u00a0QDs\u7684PL\u53d1\u5c04\u8c31\u3002<\/p>\n

\uff08B\uff09\u5168\u65e0\u673aCsPbBr3<\/sub>\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684J<\/i><\/em>–V<\/i><\/em>\u00a0\u66f2\u7ebf\u3002<\/p>\n

\uff08C\uff09\u5168\u65e0\u673aCsPbBr3<\/sub>\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u80fd\u7ea7\u7ed3\u6784\u548c\u7535\u8377\u4f20\u8f93\u3002<\/p>\n

\uff08D\uff09\u5168\u65e0\u673aCsPbBr3<\/sub>\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u7a33\u6001\u8f93\u51fa\u3002<\/p>\n

\uff08E\uff09\u5668\u4ef6\u5728RH = 80%\uff0cT = 25 o<\/sup>C\u4e0b\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\uff08F\uff09\u5668\u4ef6\u5728RH = 0%\uff0cT = 80 o<\/sup>C\u4e0b\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u76f8\u5173\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/solr.201800284<\/p>\n

\u672c\u6587\u7531\u66a8\u5357\u5927\u5b66\u5510\u7fa4\u59d4\u56e2\u961f\u4f9b\u7a3f<\/b><\/strong>\uff0c\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5168\u65e0\u673aCsPbBr3\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u56e0\u5728\u9ad8\u6e29\u3001\u9ad8\u6e7f\u3001\u7d2b\u5916\u5149\u7167\u73af\u5883\u4e0b\u5177\u6709\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u800c\u6210\u4e3a\u592a\u9633\u80fd\u5149\u4f0f\u53d1\u7535\u9886\u57df\u7684\u524d\u6cbf\u6280\u672f\uff0c\u4f46\u5176\u5149\u7535\u8f6c\u6362\u6548\u7387\u4ecd\u7136\u8f83…<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-164287","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/164287"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=164287"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/164287\/revisions"}],"predecessor-version":[{"id":164305,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/164287\/revisions\/164305"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=164287"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=164287"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=164287"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}