{"id":165142,"date":"2019-01-23T06:30:33","date_gmt":"2019-01-22T22:30:33","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=165142"},"modified":"2019-01-22T18:12:49","modified_gmt":"2019-01-22T10:12:49","slug":"%e5%a4%a9%e6%b4%a5%e5%a4%a7%e5%ad%a6%e5%b7%a9%e9%87%91%e9%be%99%e5%9b%a2%e9%98%9fchem-soc-rev-%e5%9f%ba%e4%ba%8e%e7%a1%85%e7%9a%84%e5%8d%95%e6%99%b6%e7%94%b5%e6%9e%81%e7%94%a8%e4%ba%8e%e5%a4%aa","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=165142","title":{"rendered":"\u5929\u6d25\u5927\u5b66\u5de9\u91d1\u9f99\u56e2\u961fChem. Soc. Rev.:\u57fa\u4e8e\u7845\u7684\u5355\u6676\u7535\u6781\u7528\u4e8e\u592a\u9633\u80fd\u7535\u89e3\u6c34\u7684\u73b0\u72b6\u4e0e\u53d1\u5c55"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u592a\u9633\u80fd\u662f\u4e00\u79cd\u4e30\u5bcc\u4e14\u53d6\u4e4b\u4e0d\u5c3d\u7684\u81ea\u7136\u8d44\u6e90\uff0c\u662f\u4f20\u7edf\u5316\u77f3\u71c3\u6599\u7684\u7406\u60f3\u66ff\u4ee3\u54c1\uff0c\u53ef\u4ee5\u7f13\u89e3\u5168\u7403\u6240\u9762\u4e34\u7684\u80fd\u6e90\u5371\u673a\u3002\u81ea\u4ece1972\u5e74Honda\u548cFujishima\u5229\u7528TiO2<\/sub>\u7535\u6781\u8fdb\u884c\u6c34\u7535\u89e3\u6765\u4ea7\u751f\u6c27\u6c14\u4ee5\u6765\uff0c\u5229\u7528\u534a\u5bfc\u4f53\u7535\u89e3\u6c34\u4ea7\u751f\u6c22\u6c14\u5df2\u7ecf\u6210\u4e3a\u4e00\u79cd\u7814\u7a76\u8d8b\u52bf\u3002\u534a\u5bfc\u4f53\u5149\u50ac\u5316\u5242\u53ef\u4ee5\u5c06\u592a\u9633\u80fd\u50a8\u5b58\u5230\u5316\u5b66\u952e\uff08H2<\/sub>\uff09\u4e2d\uff0c\u8fd9\u4e5f\u662f\u4e00\u79cd\u89e3\u51b3\u592a\u9633\u80fd\u5b63\u8282\u6027\u53d8\u5316\u7684\u7406\u60f3\u65b9\u6cd5\u3002<\/p>\n

\u592a\u9633\u80fd\u6c34\u5206\u89e3\u8fc7\u7a0b\u662f\u7531\u4e24\u4e2a\u534a\u53cd\u5e94\u7ec4\u6210\u7684\uff0c\u5305\u62ec\u9633\u6781\u4e0a\u7684\u6c34\u6c27\u5316\u548c\u9634\u6781\u4e0a\u7684\u6c34\u8fd8\u539f\u3002\u7406\u8bba\u800c\u8a00\uff0c\u9633\u6781\u7531n\u578b\u534a\u5bfc\u4f53\u5236\u6210\uff0c\u800c\u9634\u6781\u5219\u7531p\u578b\u534a\u5bfc\u4f53\u5236\u6210\u3002\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u76ee\u6807\u662f\u5efa\u7acb\u4e00\u4e2a\u7531\u9633\u6781\u548c\u9634\u6781\u7ec4\u6210\u7684\u592a\u9633\u80fd\u6c34\u7535\u89e3\u5355\u5143\uff0c\u9a71\u52a8\u6c34\u6c27\u5316\u548c\u6c22\u6c14\u4ea7\u751f\u3002\u867d\u7136\u5df2\u7ecf\u6709\u5f88\u591a\u79cd\u534a\u5bfc\u4f53\u6750\u6599\u4f5c\u4e3a\u7535\u6781\u8fdb\u884c\u6c34\u7684\u6c27\u5316\u548c\u8fd8\u539f\uff0c\u6ca1\u6709\u4e00\u79cd\u534a\u5bfc\u4f53\u6750\u6599\u53ef\u4ee5\u6ee1\u8db3\u7528\u4e8e\u5236\u9020\u5b9e\u7528\u7535\u6781\u7684\u6240\u6709\u57fa\u672c\u8981\u6c42\uff0c\u6bd4\u5982\u4f4e\u6210\u672c\u3001\u9ad8\u6548\u7387\u548c\u9ad8\u7a33\u5b9a\u6027\u3002\u6839\u636e\u521d\u6b65\u8ba1\u7b97\uff0c\u8986\u76d6\u9762\u79ef\u4e3a\u5730\u7403\u4e0a1%\u7684\u571f\u5730\uff0c\u6548\u7387\u4ec5\u4e3a10%\u7684\u592a\u9633\u80fd\u6c34\u89e3\u7535\u6c60\u6240\u4ea7\u751f\u7684\u6c22\u71c3\u6599\u53ef\u4ee5\u6ee1\u8db3\u5168\u7403\u80fd\u6e90\u9700\u6c42\u3002\u7845\u6750\u6599\uff0c\u4f5c\u4e3a\u5728\u7535\u5b50\u548c\u5149\u4f0f\u9886\u57df\u6240\u5e7f\u6cdb\u4f7f\u7528\u7684\u534a\u5bfc\u4f53\u6750\u6599\uff0c\u5177\u6709\u9002\u7528\u4e8e\u5b9e\u9645\u6c34\u5206\u89e3\u6240\u8981\u6c42\u7684\u6027\u8d28\u3002\u901a\u8fc7\u9002\u5f53\u7684\u63ba\u6742\uff0c\u7845\u6750\u6599\u53ef\u4ee5\u540c\u65f6\u7528\u4f5c\u9634\u6781\u548c\u9633\u6781\u3002\u7845\u6750\u6599\u5de8\u5927\u7684\u8d44\u6e90\u50a8\u5b58\u91cf\u3001\u5f3a\u5927\u7684\u53ef\u89c1\u5149\u5438\u6536\u548c\u53ef\u5728\u5de5\u4e1a\u4e2d\u5927\u89c4\u6a21\u751f\u4ea7\u7684\u7279\u70b9\uff0c\u4f7f\u5176\u5728\u592a\u9633\u80fd\u6c34\u5206\u89e3\u9886\u57df\u62e5\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u901a\u5e38\u60c5\u51b5\u4e0b\uff0c\u8f83\u4f4e\u7684\u8fc7\u7535\u4f4d\u548c\u8f83\u5927\u7684\u5149\u7535\u6d41\u5bc6\u5ea6\u662f\u83b7\u5f97\u9ad8STH\u8f6c\u6362\u6548\u7387\u7684\u4e24\u4e2a\u5173\u952e\u53c2\u6570\u3002\u867d\u7136\u5df2\u7ecf\u6709\u5f88\u591a\u91d1\u5c5e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u5177\u6709\u6781\u4f4e\u7684\u8fc7\u7535\u4f4d\uff0c\u4f46\u5176\u9971\u548c\u5149\u7535\u6d41\u5bc6\u5ea6\u4f4e\u4e8e\u5355\u6676\u7845\u57fa\u7535\u6781\uff0c\u56e0\u800c\u9650\u5236\u4e86\u5176STH\u6548\u7387\u3002\u6700\u8fd1\uff0c\u5f88\u591a\u7814\u7a76\u62a5\u5bfc\u4e86\u57fa\u4e8e\u5355\u6676\u7845\u7684\u7535\u6781\u5b9e\u73b0\u4e86\u9ad8\u4e8e10%\u7684STH\u6548\u7387\u3002\u56e0\u6b64\uff0c\u53ef\u4ee5\u4e50\u89c2\u5730\u8ba4\u4e3a\u57fa\u4e8e\u7845\u57fa\u7535\u6781\u7684\u592a\u9633\u80fd\u6c34\u7535\u89e3\u53ef\u4ee5\u5728\u4e0d\u8fdc\u7684\u5c06\u6765\u5b9e\u73b0\u4ea7\u4e1a\u5316\u7684\u6c22\u6c14\u751f\u4ea7\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u5929\u6d25\u5927\u5b66\u5de9\u91d1\u9f99\u6559\u6388\u56e2\u961f<\/strong>\u5728Chem. Soc. Rev.<\/strong>\u4e0a\uff0c\u53d1\u8868\u4e86\u9898\u4e3a”Single-crystal silicon-based electrodes for unbiased solar water splitting: current status and prospects<\/strong>“\u7684\u7efc\u8ff0\u3002\u6587\u7ae0\u4ecb\u7ecd\u4e86\u5355\u6676\u7845\u57fa\u5149\u7535\u6781\u5728\u5149\u7535\u5316\u5b66\u6c34\u5206\u89e3\u5236\u6c22\u4e2d\u5e94\u7528\u7684\u73b0\u72b6\u548c\u524d\u666f\u3002\u4f5c\u8005\u9996\u5148\u91cd\u70b9\u4ecb\u7ecd\u4e86\u5355\u6676\u7845\u57fa\u9634\u6781\u548c\u9633\u6781\u5728\u5149\u7535\u5316\u5b66\u6c34\u7535\u89e3\u4e0a\u6240\u53d6\u5f97\u7684\u6210\u5c31\uff1b\u7136\u540e\u8ba8\u8bba\u4e86\u4f7f\u7528\u5355\u6676\u7845\u57fa\u5149\u7535\u6781\u8bbe\u8ba1\u548c\u5236\u9020\u592a\u9633\u80fd\u6c34\u89e3\u7535\u6c60\u7684\u6700\u65b0\u8fdb\u5c55\uff1b\u6700\u540e\uff0c\u63d0\u4f9b\u4e86\u5355\u6676\u7845\u57fa\u7535\u6781\u4f18\u5316\u7684\u6982\u8ff0\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

Figure <\/strong>1.n<\/strong>\u578b\u548c<\/strong>p<\/strong>\u578b\u7845\u6750\u6599\u5149\u7535\u6781\u80fd\u5e26\u5f2f\u66f2\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

Figure <\/strong>2.<\/strong>\u7845\u57fa\u5149\u7535\u6781\u7684\u4e0d\u540c\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

(a).pn+<\/sup>-Si\u7ebf\u9635\u7684SEM\u8868\u5f81<\/p>\n

(b).\u7845\u7eb3\u7c73\u67f1\u9635\u5217\u7684SEM\u8868\u5f81<\/p>\n

(c).p-Si\u91d1\u5b57\u5854\u7ed3\u6784\u6a2a\u622a\u9762\u7684SEM\u8868\u5f81<\/p>\n

(d).\u7eb3\u7c73\u7ec7\u6001\u7845\u7684SEM\u8868\u5f81<\/p>\n

Figure 3<\/strong>.p-Si<\/strong>\u548c<\/strong>n+<\/sup>p-Si<\/strong>\u5149\u7535\u6781\u7684\u80fd\u7ea7\u548c\u5149\u7535\u538b\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a,b).p-Si\u548cn+<\/sup>p-Si\u5149\u7535\u6781\u4e0eH+<\/sup>\/H2<\/sub>\u63a5\u89e6\u540e\u7684\u80fd\u7ea7\u5f2f\u66f2\u793a\u610f\u56fe<\/p>\n

(c,d).p-Si\u548cn+<\/sup>p-Si\u5149\u7535\u6781\u7684J-V\u884c\u4e3a<\/p>\n

\u56fe<\/strong>4.TiO2<\/sub><\/strong>\u4fdd\u62a4\u7684\u7845\u7535\u6781<\/strong><\/p>\n

\"\"<\/p>\n

(a).\u5bf9\u672a\u9000\u706b\u548c\u771f\u7a7a\u9000\u706b\u7684100\u7eb3\u7c73ALD TiO2<\/sub>\u4fdd\u62a4\u7684\u7535\u6781\u8fdb\u884c24\u5c0f\u65f6\u7a33\u5b9a\u6027\u8bc4\u4f30<\/p>\n

(b).\u5bf9\u771f\u7a7a\u9000\u706b\u7684100\u7eb3\u7c73ALD TiO2<\/sub>\u4fdd\u62a4\u7684\u7535\u6781\u8fdb\u884c\u4e24\u5468\u7684\u7a33\u5b9a\u6027\u8bc4\u4f30<\/p>\n

(c).SrTiO3<\/sub>\u4fdd\u62a4\u7684\u7845\u57fa\u5149\u7535\u6781\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

(d).\u7a33\u6001\u5149\u7535\u6d41\u8868\u5f81<\/p>\n

\u56fe<\/strong>5.<\/strong>\u91d1\u5c5e\u6c27\u5316\u7269\u4fdd\u62a4\u7684\u7845\u57fa\u5149\u7535\u6781\u8868\u5f81<\/strong>\u00a0\"\"<\/strong><\/p>\n

(a).\u5177\u6709\u548c\u4e0d\u5177\u67092 nm Al2<\/sub>O3<\/sub>\u5c42\u7684np+<\/sup>\u548cn+<\/sup>p\u5149\u7535\u9634\u6781\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5<\/p>\n

(b).MoS2<\/sub>\/Mo\/n+<\/sup>p-Si, MoSx<\/sub>\/MoS2<\/sub>\/Mo\/n+<\/sup>p-Si\u548cMoS2<\/sub>\/Mo\/n+<\/sup>p-Si\u7535\u6781\u7684\u8ba1\u65f6\u7535\u6d41\u5206\u6790<\/p>\n

\u56fe<\/strong>6.<\/strong>\u91d1\u5c5e\u4fdd\u62a4\u7684\u7845\u57fa\u5149\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).2 nm IrOx<\/sub>\/Ir\/p+<\/sup>n-Si\u5728\u4e0d\u540c\u9000\u706b\u6761\u4ef6\u4e0b\u7684\u8ba1\u65f6\u7535\u6d41\u6d4b\u8bd5<\/p>\n

(b).np+<\/sup>-Si\/SiOx<\/sub>\/NiFe\u5149\u7535\u6781\u7684\u8ba1\u65f6\u7535\u6d41\u6d4b\u8bd5J-t\u66f2\u7ebf\u56fe<\/p>\n

(c).2 nm Ni\u4fdd\u62a4\u7684n-Si\u7535\u6781\u7a33\u5b9a\u6027\u6d4b\u8bd5<\/p>\n

\u56fe<\/strong>7.<\/strong>\u91d1\u5c5e\u590d\u5408\u7269\u4fdd\u62a4\u7684\u7845\u57fa\u5149\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).Ir\/TiO2<\/sub>\/p+<\/sup>-Si\u548cIr\/p+<\/sup>-Si\u9634\u6781\u7684\u6052\u5b9a\u7535\u538b\u5bff\u547d\u6d4b\u8bd5<\/p>\n

(b).p+<\/sup>n-Si\/Co3<\/sub>O4<\/sub>\/Co(OH)2<\/sub>\u5149\u7535\u6781\u7684\u5149\u7535\u6d41<\/p>\n

(c).\u8986\u76d644 nm TiO2<\/sub>\u8584\u819c\u548cNi\u7684np+<\/sup>Si\u5149\u9634\u6781\u7684\u8ba1\u65f6\u7535\u6d41\u5206\u6790<\/p>\n

(d).n-Si\/SiOx<\/sub>\u548cRCA\/CoOx<\/sub>\u5149\u9634\u6781\u7684\u8ba1\u65f6\u7535\u6d41\u5206\u6790<\/p>\n

\u56fe<\/strong>8.<\/strong>\u91d1\u5c5e\u590d\u5408\u7269\u4fdd\u62a4\u7684\u7845\u57fa\u5149\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).p+<\/sup>-SiNiOx<\/sub>\u572850 mM Fe(CN)6<\/sub>3-<\/sup>\u548c350 mM Fe(CN)6<\/sub>4-<\/sup>\u7684Mott-Schottky\u56fe<\/p>\n

(b).np+<\/sup>-SiNiOx<\/sub>\u548cn-SiNiOx<\/sub>\u7535\u6781\u7684\u8ba1\u65f6\u7535\u6d41\u5206\u6790<\/p>\n

\u56fe<\/strong>9.<\/strong>\u754c\u9762\u4fee\u9970\u7684\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).\u4f18\u5316\u768420\/30 nm Pt\/Ti\u96c6\u7535\u6781\u6c89\u79ef\u57282 nm RTO SiO2<\/sub>\u2160p-Si\u8868\u9762\u7684\u6a2a\u622a\u9762TEM\u8868\u5f81<\/p>\n

(b).\u591a\u79cd\u6837\u54c1\u7684J-V\u66f2\u7ebf<\/p>\n

(c).n-Si\/SiOx,RCA<\/sub>\/Al2<\/sub>O3<\/sub>\/Pt\/Ni\u7684\u80fd\u5e26\u56fe<\/p>\n

(d).\u4e0d\u540c\u754c\u9762\u5c42\u7684MIS\u5149\u9634\u6781\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/p>\n

\u56fe<\/strong>10.<\/strong>\u754c\u9762\u4fee\u9970\u7684\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).n-Si\/SiOx,RCA<\/sub>\/CoOx<\/sub>\/NiOx<\/sub>\u7684\u6a2a\u622a\u9762TEM\u56fe<\/p>\n

(b).n-Si\/SiOx,RCA<\/sub>\/CoOx<\/sub>\/NiOx<\/sub>\u548cn-Si\/SiOx,RCA<\/sub>\/NiOx<\/sub>\u5149\u9634\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

(c).n-Si\/TiOx<\/sub>\/ITO\/NiOOH\u7684\u80fd\u5e26\u56fe<\/p>\n

(d).n-Si\/TiOx<\/sub>\/ITO, n-Si\/TiOx<\/sub>\/ITO\/NiOOH\u548cp++<\/sup>-Si\/TiOx<\/sub>\/ITO\/NiOOH\u5149\u7535\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

\u56fe<\/strong>11.<\/strong>\u91d1\u5c5e\u6750\u6599\u7528\u4e8e\u52a0\u901f\u8868\u9762\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

(a).\u4e0d\u540c\u539a\u5ea6Pt\u505aHER\u50ac\u5316\u5242\u7684SiHJ\u5149\u9633\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

(b).Pt2<\/sub>\/n+<\/sup>p-Si\u548cTiO2<\/sub>\/Pt2<\/sub>\/n+<\/sup>p-Si\u5149\u7535\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

(c).Ni-Mo\u6d82\u8986\u7684n+<\/sup>p-Si\u5fae\u7ebf\u9635\u7535\u6781\u7684J-V\u6570\u636e<\/p>\n

(d).\u5177\u6709\u548c\u4e0d\u5177\u6709MoS2\u5c42\u7684n+<\/sup>p-Si\u7535\u6781\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u56fe<\/p>\n

(e).67 nm MoS2<\/sub>\/Al2<\/sub>O3<\/sub>\/n+<\/sup>p-Si\u7535\u6781\u7684PEC\u7a33\u5b9a\u6027\u6d4b\u8bd5<\/p>\n

(f).CoP-n+<\/sup>p-Si\u5149\u7535\u6781\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u56fe<\/p>\n

\u56fe<\/strong>12.<\/strong>\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).n-Si\/TiO2<\/sub>\/Ir\u7535\u6781\u5728\u4e0d\u540cpH\u6eb6\u6db2\u4e2d\u7684\u6c34\u7535\u89e3<\/p>\n

(b).\u4e0d\u540c\u539a\u5ea6IrOx<\/sub>\u7684IrOx<\/sub>\/Ir\/p+<\/sup>n-Si\u7684J-V\u66f2\u7ebf<\/p>\n

\u56fe<\/strong>13.<\/strong>\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).\u4e0d\u540c\u539a\u5ea6Ni\u6d82\u8986\u7684n-Si\u9634\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

(b).ITO\u2160Au\u2160ITO\u2160NiOx<\/sub>\u5728\u4e0d\u540c\u57fa\u5e95\u4e0a\u7684J-V\u66f2\u7ebf<\/p>\n

(c).p+<\/sup>-Si\u2160NiOx<\/sub>\u548cnp+<\/sup>-Si\u2160NiOx<\/sub>\u7684PEC\u884c\u4e3a<\/p>\n

(d).n-Si\/SiOx,RCA<\/sub>\/CoOx<\/sub>\u5149\u9634\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

\u56fe<\/strong>14.<\/strong>\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).p+<\/sup>-Si\/SiOx<\/sub>\/Co\/CoOOH\u548cn-Si\/SiOx<\/sub>\/Co\/CoOOH\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u66f2\u7ebf<\/p>\n

(b).Ni\/NiOx<\/sub>\/NiFe-LDH, Ni\/NiOx<\/sub>, Ni\u6d82\u8986\u7684n+<\/sup>p-Si\/SiOx<\/sub>\u9634\u6781\u548cNi\/NiOx<\/sub>\/NiFe-LDH, Ni\/NiOx<\/sub>\u6d82\u8986\u7684p++<\/sup>-Si\u7535\u6781\u7684J-V\u884c\u4e3a<\/p>\n

\u56fe<\/strong>15.<\/strong>\u7535\u6c60\u7ed3\u6784\u548c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).\u7535\u6c60\u7ed3\u6784\u793a\u610f\u56fe\u548cJ-V\u66f2\u7ebf<\/p>\n

(b).\u4e0d\u540c\u8d64\u94c1\u77ff\u5149\u7535\u6781\u7684\u7a33\u6001J-V\u884c\u4e3a<\/p>\n

(c).\u5149\u7535\u6d41\u5206\u6790<\/p>\n

\u56fe<\/strong>16.<\/strong>\u7528\u4e8e\u6c34\u7535\u89e3\u7684\u7535\u6c60\u673a\u7406\u3001\u7ed3\u6784\u4e0e\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).WO3<\/sub>\/W-Pt\/Si PEC\u7535\u6c60\u7684\u80fd\u7ea7\u56fe<\/p>\n

(b).\u975e\u6676\u4f53\u96c6\u6210\u5149\u7535\u6781\u7ec4\u4ef6\u7684\u6a2a\u622a\u9762\u793a\u610f\u56fe<\/p>\n

(c).\u7528\u4e8e\u6c34\u5206\u89e3\u7684BiVO4<\/sub>\/Si\u7eb3\u7c73\u9635\u5217\u4e32\u8054\u7535\u6c60\u7684\u7b80\u5316\u7535\u5b50\u80fd\u7ea7\u56fe<\/p>\n

(d).\u4e24\u79cd\u7c7b\u578b\u7535\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

\u56fe<\/strong>17.TiO2<\/sub><\/strong>\u4fdd\u62a4\u7684\u65e0\u5b9a\u578b\u7845\u5149\u7535\u6781\u7684\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).Pt\u4f5c\u4e3a\u50ac\u5316\u5242\u7684a-Si\u5149\u7535\u9634\u6781\u7684\u6a2a\u622a\u9762SEM\u56fe<\/p>\n

(b).a-Si\u5149\u9633\u6781\u7684J-V\u56fe<\/p>\n

(c).TiO2<\/sub>(15 nm)\/Ga2<\/sub>O3<\/sub>(20 nm)\/Cu2<\/sub>O\u6a2a\u622a\u9762TEM\u56fe<\/p>\n

(d).\u4e0d\u540cTiO2<\/sub>\u6c89\u79ef\u6e29\u5ea6Pt\/TiO2<\/sub>\/Ga2<\/sub>O3<\/sub>\/Cu2<\/sub>O\u7684J-V\u66f2\u7ebf<\/p>\n

\u56fe<\/strong>18.<\/strong>\u57fa\u4e8e\u94dc\u6c27\u5316\u7269\u7684\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).CuBi2<\/sub>O4<\/sub>\u5149\u7535\u9634\u6781\u7684SEM\u56fe\u50cf<\/p>\n

(b).CuBi2<\/sub>O4<\/sub>\u548cCuBi2<\/sub>O4<\/sub>\/Pt\u5149\u7535\u9634\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

(c).\u901a\u8fc7\u9634\u6781\u7535\u6c89\u79ef\u5236\u5907\u7684CuBi2<\/sub>O4<\/sub>\u7684SEM\u8868\u5f81<\/p>\n

(d).\u751f\u957f\u5728FTO\u548cFTO\/Au\u57fa\u5e95\u4e0a\u7684CuBi2<\/sub>O4<\/sub>\u8584\u819c<\/p>\n

(e).\u901a\u8fc7\u7535\u5316\u5b66\u5408\u6210\u7684Ag\u63ba\u6742\u7684CuBi2<\/sub>O4<\/sub>\u8584\u819c\u7684SEM\u8868\u5f81<\/p>\n

(f).CuBi2<\/sub>O4<\/sub>\u548cCuBi2<\/sub>O4<\/sub>\/Ag- CuBi2<\/sub>O4<\/sub>\u5149\u9634\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

\u56fe<\/strong>19.<\/strong>\u57fa\u4e8e\u94c1\u6c27\u5316\u7269\u7684\u7535\u6781\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a).\u901a\u8fc7\u7535\u6c89\u79ef\u5236\u5907\u7684p\u578bCuFeO2<\/sub>\u819c\u7684SEM\u8868\u5f81<\/p>\n

(b).CuFeO2<\/sub>\u7535\u6781\u7684J-V\u66f2\u7ebf<\/p>\n

(c).\u901a\u8fc7\u5fae\u6ce2\u9000\u706b\u7684CuFeO2<\/sub>\u819c\u7684\u8868\u9762\u5f62\u8c8c<\/p>\n

(d).HMA, HMA-NiFe\u548cHMA-NiFe\/RGO\u7684J-V\u66f2\u7ebf<\/p>\n

\u56fe<\/strong>20.<\/strong>\u7528\u4e8e\u4e32\u8054\u7cfb\u7edf\u7684\u5149\u9633\u6781\u548c\u5149\u7535\u9634\u6781\u7684\u5019\u9009\u6750\u6599\u7684\u7406\u8bba\u4e0a\u53ef\u8fbe\u5230\u7684\u6548\u7387\u7684\u603b\u7ed3<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u9ad8\u6548\u7387\u548c\u9ad8\u7a33\u5b9a\u6027\u7684\u5149\u7535\u6781\u662f\u5b9e\u73b0\u592a\u9633\u80fd\u6c34\u5206\u89e3\u5236\u6c22\u5fc5\u4e0d\u53ef\u5c11\u7684\u91cd\u8981\u90e8\u4ef6\u3002\u5355\u6676\u7845\u5177\u6709\u5730\u7403\u50a8\u5b58\u4e30\u5bcc\u3001\u5e26\u9699\u8f83\u7a84\u7684\u4f18\u70b9\uff0c\u88ab\u516c\u8ba4\u4e3a\u6781\u5177\u5438\u5f15\u529b\u7684\u80fd\u7528\u4e8e\u592a\u9633\u80fd\u6c34\u5206\u89e3\u7684\u5149\u7535\u6781\u6750\u6599\u3002\u5728\u8fd9\u7bc7\u6587\u7ae0\u4e2d\uff0c\u4f5c\u8005\u7b80\u8981\u4ecb\u7ecd\u4e86\u89e3\u51b3\u7845\u52a8\u529b\u5b66\u548c\u70ed\u529b\u5b66\u95ee\u9898\u7684\u7b56\u7565\uff0c\u4f7f\u5176\u80fd\u5b9e\u73b0\u5728\u592a\u9633\u80fd\u6c34\u89e3\u4e2d\u7684\u5e94\u7528\u3002\u6784\u5efa\u6709\u6548\u7684\u5355\u6676\u7845\u57fa\u4e32\u8054\u7535\u6c60\u7528\u4e8e\u592a\u9633\u80fd\u6c34\u5206\u89e3\uff0c\u6240\u5b58\u5728\u7684\u4e3b\u8981\u95ee\u9898\u662f\u5149\u7535\u9634\u6781\u548c\u5149\u7535\u9633\u6781\u7684\u8026\u5408\u80fd\u591f\u4ea7\u751f\u7528\u4e8e\u9a71\u52a8\u6c34\u7684\u5149\u7535\u89e3\u7684\u5149\u4f0f\u7535\u538b\u3002\u7531\u4e8e\u5e26\u9699\u76f8\u5bf9\u8f83\u5c0f\uff0c\u56e0\u6b64\u5355\u6676\u7845\u57fa\u5149\u7535\u6781\u7684\u5149\u7535\u538b\u8f83\u5c0f\uff0c\u56e0\u6b64\u603b\u662f\u9700\u8981\u5bbd\u5e26\u9699\u534a\u5bfc\u4f53\u6765\u5b9e\u73b0\u65e0\u504f\u7684\u6574\u4f53\u6c34\u5206\u89e3\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u65b0\u578bPEC\u7535\u6c60\u914d\u7f6e\u7684\u8bbe\u8ba1\u548c\u6784\u9020\u53ef\u4ee5\u63d0\u4f9b\u53e6\u4e00\u79cd\u65b9\u6cd5\u6765\u63d0\u9ad8\u6574\u4f53\u6c34\u5206\u89e3\u7684\u6548\u7387\u3002\u968f\u7740\u5355\u6676\u7845\u57fa\u5149\u7535\u6781\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0c\u7528\u4e8e\u6c34\u5206\u89e3\u7684\u5355\u6676\u7845\u57fa\u4e32\u8054\u7535\u6c60\u5c06\u5b9e\u73b0\u5feb\u901f\u5730\u53d1\u5c55\u548c\u5e94\u7528\u3002<\/p>\n

Single-crystal silicon-based electrodes for unbiased solar water splitting: current status and prospects<\/a><\/p>\n

(Chem. Soc. Rev., 2018, DOI: 10.1039\/c8cs00638e)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002\u00a0<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead\u3002\u00a0<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u592a\u9633\u80fd\u662f\u4e00\u79cd\u4e30\u5bcc\u4e14\u53d6\u4e4b\u4e0d\u5c3d\u7684\u81ea\u7136\u8d44\u6e90\uff0c\u662f\u4f20\u7edf\u5316\u77f3\u71c3\u6599\u7684\u7406\u60f3\u66ff\u4ee3\u54c1\uff0c\u53ef\u4ee5\u7f13\u89e3\u5168\u7403\u6240\u9762\u4e34\u7684\u80fd\u6e90\u5371\u673a\u3002\u81ea\u4ece1972\u5e74Honda\u548cFujishima\u5229\u7528TiO…<\/p>\n","protected":false},"author":7336,"featured_media":165146,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[18],"class_list":["post-165142","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu","tag-xinnengyuan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/165142"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7336"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=165142"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/165142\/revisions"}],"predecessor-version":[{"id":165689,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/165142\/revisions\/165689"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/165146"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=165142"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=165142"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=165142"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}