{"id":165318,"date":"2019-01-18T12:00:44","date_gmt":"2019-01-18T04:00:44","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=165318"},"modified":"2019-01-17T21:13:04","modified_gmt":"2019-01-17T13:13:04","slug":"%e6%a5%bc%e9%9b%84%e6%96%87%e9%ab%98%e4%b9%a6%e7%87%95angew-chem-int-ed-%e5%a4%9a%e5%b1%82%e7%a1%ab%e5%8c%96%e9%92%b4%e7%ba%b3%e7%b1%b3%e7%9b%92%e7%9a%84%e6%9e%84%e7%ad%91%e5%8f%8a%e5%85%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=165318","title":{"rendered":"\u697c\u96c4\u6587&\u9ad8\u4e66\u71d5Angew. Chem. Int. Ed. :\u591a\u5c42\u786b\u5316\u94b4\u7eb3\u7c73\u76d2\u7684\u6784\u7b51\u53ca\u5176\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\n \u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269(TMS)\u4e0e\u76f8\u5e94\u6c27\u5316\u7269\u76f8\u6bd4\u5177\u6709\u4e30\u5bcc\u7684\u6c27\u5316\u8fd8\u539f\u4f4d\u70b9\u3001\u9ad8\u5bb9\u91cf\u548c\u589e\u5f3a\u7684\u5bfc\u7535\u6027\uff0c\u56e0\u6b64\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60(SIB)\u7684\u8d1f\u6781\u6750\u6599\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u7531\u4e8e\u957f\u671f\u5faa\u73af\u671f\u95f4\u4e0d\u53ef\u907f\u514d\u7684\u4f53\u79ef\u53d8\u5316\uff0cTMS\u7684\u5b9e\u9645\u5e94\u7528\u4ecd\u7136\u53d7\u9650\u4e8e\u500d\u7387\u6027\u80fd\u5dee\u4ee5\u53ca\u53ef\u9006\u5bb9\u91cf\u7684\u5feb\u901f\u8870\u51cf\u3002\u4e3a\u514b\u670d\u4e0a\u8ff0\u95ee\u9898\uff0c\u5408\u7406\u8bbe\u8ba1\u4e2d\u7a7a\u6750\u6599\uff0c\u5e76\u4f7f\u5176\u5185\u90e8\u7ed3\u6784\u590d\u6742\u5316\u662f\u4e00\u79cd\u884c\u4e4b\u6709\u6548\u7684\u65b9\u6cd5\u3002\u76f8\u6bd4\u7b80\u5355\u4e2d\u7a7a\u7ed3\u6784\uff0c\u590d\u6742\u4e2d\u7a7a\u7ed3\u6784\u80fd\u591f\u63d0\u4f9b\u66f4\u591a\u7684\u7535\u5316\u5b66\u6d3b\u6027\u4f4d\u70b9\uff0c\u5e76\u63d0\u9ad8\u5185\u90e8\u7a7a\u95f4\u5229\u7528\u6548\u7387\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u7535\u6781\u6750\u6599\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u7531\u4e8e\u7f3a\u4e4f\u9002\u5408\u7684\u5408\u6210\u7b56\u7565\uff0c\u6784\u7b51\u591a\u5c42TMS\u7528\u4e8eSIB\u7684\u7814\u7a76\u4ecd\u7136\u5f88\u5c11\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\n \u8fd1\u65e5\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u697c\u96c4\u6587\u6559\u6388\u3001\u6cb3\u5357\u5e08\u8303\u5927\u5b66\u9ad8\u4e66\u71d5\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u4ee5\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOF)\u4e3a\u81ea\u727a\u7272\u6a21\u677f\uff0c\u5229\u7528\u9634\u79bb\u5b50\u8f6c\u5316\u548c\u4ea4\u6362\u7b56\u7565\u6784\u7b51\u4e86\u786b\u5316\u94b4\u591a\u5c42\u7eb3\u7c73\u76d2(MSNBs)\uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cSynthesis of Cobalt Sulfide Multi-shelled Nanoboxes with Precisely Controlled Two to Five Shells for Sodium-Ion Batteries<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u901a\u8fc7\u6539\u53d8\u6e29\u5ea6\u53ef\u4ee5\u5bb9\u6613\u5730\u63a7\u5236\u7eb3\u7c73\u76d2\u7684\u5c42\u6570(2-5\u5c42)\u3002\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u65f6\uff0c\u6240\u5f97\u786b\u5316\u94b4\u591a\u5c42\u7eb3\u7c73\u76d2\u7684\u50a8\u94a0\u6027\u80fd\u663e\u8457\u589e\u5f3a\uff0c\u4f8b\u5982\uff0c\u5bf9\u4e8e\u4e09\u5c42\u7eb3\u7c73\u76d2\uff0c\u5728500 mA\u00b7g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b100\u6b21\u5faa\u73af\u540e\u4ecd\u4fdd\u7559438 mAh\u00b7g-1<\/sup>\u7684\u9ad8\u6bd4\u5bb9\u91cf\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u786b\u5316\u94b4MSNBs\u7684\u5f62\u6210\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

I) \u901a\u8fc7\u591a\u9492\u9178\u76d0\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u8fdb\u884c\u79bb\u5b50\u4ea4\u6362\u53cd\u5e94\u5c06ZIF-67 NC\u8f6c\u5316\u4e3aZIF-67\/\u591a\u9492\u9178\u94b4YSNC\uff1b
\n II) \u901a\u8fc7\u591a\u9492\u9178\u76d0\u5206\u89e3\u4ee5\u53ca\u91ca\u653e\u7684\u4e8c\u9492\u9178\u6839\u79bb\u5b50\u4e0eZIF-67\u6838\u5fc3\u4e4b\u95f4\u7684\u539f\u4f4d\u79bb\u5b50\u4ea4\u6362\u53cd\u5e94\u5f62\u6210\u94b4\u4e8c\u9492\u9178\u76d0MSNB\uff1b
\n III) \u901a\u8fc7\u786b\u5316\u53cd\u5e94\u5f62\u6210\u786b\u5316\u94b4MSNB\u3002<\/p>\n

\u56fe2 ZIF-67 NCs\u548cZIF-67\/\u591a\u9492\u9178\u94b4 YSNCs\u7684\u5f62\u8c8c\u548c\u7ec4\u6210\u5143\u7d20<\/strong><\/p>\n

\"\"<\/p>\n

a) ZIF-67 NCs\u7684FESEM\u56fe\u50cf\uff1b
\n b) ZIF-67\/\u591a\u9492\u9178\u94b4 YSNCs\u7684FESEM\u56fe\u50cf\uff1b
\n c) ZIF-67\/\u591a\u9492\u9178\u94b4 YSNCs\u7684TEM\u56fe\u50cf\uff1b
\n d) ZIF-67\/\u591a\u9492\u9178\u94b4 YSNCs\u7684\u5143\u7d20\u5206\u5e03\u56fe\u50cf\u3002<\/p>\n

\u56fe3 \u4e8c\u9492\u9178\u94b4MSNBs\u7684\u5f62\u8c8c\u548c\u7ec4\u6210\u5143\u7d20<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u4e8c\u9492\u9178\u94b4TSNBs\u7684TEM\u56fe\u50cf\uff1b
\n c) \u4e8c\u9492\u9178\u94b4TSNBs\u7684\u5143\u7d20\u5206\u5e03\u56fe\u50cf\uff1b
\n d,e) \u4e8c\u9492\u9178\u94b4QuiSNBs\u7684TEM\u56fe\u50cf\uff1b
\n f,g) \u4e8c\u9492\u9178\u94b4QuaSNBs\u7684TEM\u56fe\u50cf\uff1b
\n h,i) \u4e8c\u9492\u9178\u94b4DSNBs\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe4 \u786b\u5316\u94b4MSNBs\u7684\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

a,e,i) \u786b\u5316\u94b4TSNBs\u7684TEM\u56fe\u50cf\uff1b
\n b,f,j) \u786b\u5316\u94b4QuiSNBs\u7684TEM\u56fe\u50cf\uff1b
\n c,g,k) \u786b\u5316\u94b4QuaSNBs\u7684TEM\u56fe\u50cf\uff1b
\n d,h,l) \u786b\u5316\u94b4DSNBs\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe5 \u786b\u5316\u94b4MSNBs\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5728500 mA\u00b7g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7b2c\u4e8c\u6b21\u5faa\u73af\u7684\u4e0d\u540c\u5c42\u6570\u786b\u5316\u94b4MSNB\u7684\u5145-\u653e\u7535\u7535\u538b\u66f2\u7ebf\uff1b
\n b) \u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u786b\u5316\u94b4TSNB\u7684\u500d\u7387\u6027\u80fd\uff1b
\n c) \u5728200 mA\u00b7g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b100\u4e2a\u5faa\u73af\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5229\u7528\u79bb\u5b50\u8f6c\u6362\u4ea4\u6362\u7b56\u7565\uff0c\u4ece\u94b4\u57faMOF\u524d\u9a71\u4f53\u5f00\u59cb\uff0c\u901a\u8fc7\u7cbe\u786e\u64cd\u7eb5\u8bbe\u8ba1\u7684\u79bb\u5b50\u8f6c\u5316\u548c\u4ea4\u6362\u8fc7\u7a0b\uff0c\u83b7\u5f97\u5177\u6709\u53ef\u63a7\u5c42\u6570\u7684\u786b\u5316\u94b4\u591a\u5c42\u7eb3\u7c73\u76d2\u3002\u5f97\u76ca\u4e8e\u72ec\u7279\u7684\u7ed3\u6784\u548c\u7ec4\u6210\uff0c\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u65f6\uff0c\u4e0a\u8ff0\u786b\u5316\u94b4\u591a\u5c42\u7eb3\u7c73\u76d2\u5177\u6709\u589e\u5f3a\u7684\u7535\u5316\u5b66\u6027\u8d28\u3002\u7279\u522b\u5730\uff0c\u4e09\u5c42\u7eb3\u7c73\u76d2\u5728500 mA\u00b7g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b100\u6b21\u5faa\u73af\u540e\u4ecd\u6709438 mAh\u00b7g-1<\/sup>\u7684\u9ad8\u6bd4\u5bb9\u91cf\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSynthesis of Cobalt Sulfide Multi-shelled Nanoboxes with Precisely Controlled Two to Five Shells for Sodium-Ion Batteries<\/a> <\/strong>(Angew. Chem. Int. Ed.<\/strong>, 2019, DOI: 10.1002\/anie.201812387)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269(TMS)\u4e0e\u76f8\u5e94\u6c27\u5316\u7269\u76f8\u6bd4\u5177\u6709\u4e30\u5bcc\u7684\u6c27\u5316\u8fd8\u539f\u4f4d\u70b9\u3001\u9ad8\u5bb9\u91cf\u548c\u589e\u5f3a\u7684\u5bfc\u7535\u6027\uff0c\u56e0\u6b64\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60(SIB)\u7684\u8d1f\u6781\u6750\u6599\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u7531\u4e8e\u957f…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3446,1316,1884,3834],"class_list":["post-165318","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-mof","tag-louxiongwen","tag-1884","tag-3834"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/165318"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=165318"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/165318\/revisions"}],"predecessor-version":[{"id":166309,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/165318\/revisions\/166309"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=165318"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=165318"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=165318"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}