{"id":166101,"date":"2019-01-28T06:30:50","date_gmt":"2019-01-27T22:30:50","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=166101"},"modified":"2019-01-27T22:51:19","modified_gmt":"2019-01-27T14:51:19","slug":"%e5%b7%b2%e6%a0%a1-%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6adv-funct-mater-%e6%97%a0%e9%93%85%e5%8d%a4%e5%8c%96%e7%89%a9%e5%8f%8c%e9%92%99%e9%92%9b%e7%9f%bf%e6%99%b6%e7%95%8c%e7%bc%ba%e9%99%b7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=166101","title":{"rendered":"\u6e05\u534e\u5927\u5b66Adv. Funct. Mater. : \u65e0\u94c5\u5364\u5316\u7269\u53cc\u9499\u949b\u77ff\u6676\u754c\u7f3a\u9677\u5de5\u7a0b\u6539\u5584\u5149\u7535\u6027\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\n \u7531\u4e8eCH3<\/sub>NH3<\/sub>PbI3<\/sub>\u5177\u6709\u94c5\u6bd2\u6027\u548c\u4e0d\u7a33\u5b9a\u6027\uff0c\u56e0\u6b64\u63a2\u7d22\u65e0\u6bd2\u3001\u7a33\u5b9a\u7684\u5364\u5316\u7269\u9499\u949b\u77ff\u975e\u5e38\u6709\u610f\u4e49\u3002\u6700\u8fd1\uff0c\u65b0\u4e00\u4ee3\u65e0\u94c5\u5364\u5316\u7269\u53cc\u9499\u949b\u77ff(HDPs)(A2<\/sub>B1+<\/sup>B’3+<\/sup>X6<\/sub>)\u662f\u4e00\u79cd\u6709\u671b\u514b\u670d\u6709\u673a\u65e0\u673a\u5364\u5316\u7269\u9499\u949b\u77ff\u6750\u6599\u56fa\u6709\u7f3a\u70b9\u7684\u7a33\u5b9a\u73af\u4fdd\u7684\u5149\u7535\u6750\u6599\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u7814\u7a76\u4eba\u5458\u5df2\u6210\u529f\u5408\u6210\u4e86\u51e0\u79cdHDP\uff0c\u5982Cs2<\/sub>AgInCl6<\/sub>\u3001Cs2<\/sub>AgBiX6<\/sub>(X = Cl, Br)\u7b49\u3002\u7136\u800c\uff0c\u5b9e\u9a8c\u4e2d\u6240\u89c2\u6d4b\u5230\u7684HDP\u7684\u5668\u4ef6\u6027\u80fd\u4f4e\u4e8e\u5176\u7406\u60f3\u503c\uff0c\u56e0\u6b64\u63a2\u7d22\u5176\u6027\u80fd\u5dee\u8ddd\u7684\u7269\u7406\u8d77\u6e90\u4ee5\u53ca\u5982\u4f55\u63d0\u9ad8\u5176\u6548\u7387\u6210\u4e3a\u4e00\u4e2a\u91cd\u8981\u7684\u79d1\u5b66\u95ee\u9898\u3002\u4e0e\u5176\u4ed6\u4f20\u7edf\u534a\u5bfc\u4f53\u7c7b\u4f3c\uff0cHDP\u7684\u5668\u4ef6\u6027\u80fd\u53ef\u80fd\u53d7\u5176\u6709\u5bb3\u7f3a\u9677\u7684\u9650\u5236\uff0c\u5305\u62ec\u6676\u4f53\u5185\u90e8(GI)\u548c\u6676\u754c(GB)\u7f3a\u9677\u3002\u56e0\u6b64\uff0c\u4e9f\u5f85\u4e86\u89e3HDP\u4e2d\u4f4e\u80fd\u6676\u754c\u7684\u7535\u5b50\u7279\u6027\u4ee5\u53ca\u5176\u5982\u4f55\u5f71\u54cdHDP\u7684\u5149\u7535\u548c\u5668\u4ef6\u6027\u80fd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\n \u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662\u67f3\u767e\u65b0\u9662\u58eb\u8bfe\u9898\u7ec4(\u7b2c\u4e00\u5355\u4f4d)\u7b49<\/strong>\u5229\u7528\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\uff0c\u53d1\u73b0\u4e00\u4e9b\u7279\u5b9a\u79cd\u7c7b\u7684\u6676\u754c\u7531\u4e8e\u5176\u8f83\u4f4e\u7684\u5f62\u6210\u80fd\u800c\u5f88\u5bb9\u6613\u5728\u591a\u6676HDP\u4e2d\u51fa\u73b0\uff0c\u800c\u5728\u5176\u4ed6\u4f20\u7edf\u9499\u949b\u77ff\u6750\u6599\u4e2d\u6676\u754c\u7684\u5f62\u6210\u80fd\u5f80\u5f80\u8f83\u9ad8\u3002\u66f4\u4e3a\u91cd\u8981\u7684\u662f\uff0c\u4f4e\u80fd\u91cf\u7684\u03a35(310) \u6676\u754c\u4f1a\u5728\u7b2cI\u7c7b\u548c\u7b2cII\u7c7bHDP\u7684\u5e26\u9699\u4e2d\u95f4\u4ea7\u751f\u6df1\u80fd\u7ea7\u7f3a\u9677\u6001\uff0c\u8fd9\u4e9b\u6df1\u80fd\u7ea7\u7f3a\u9677\u6001\u6709\u53ef\u80fd\u4f1a\u6210\u4e3a\u7535\u5b50-\u7a7a\u7a74\u590d\u5408\u4e2d\u5fc3\u800c\u6781\u5927\u5730\u635f\u5bb3HDP\u7684\u670d\u5f79\u6027\u80fd\u3002\u672c\u5de5\u4f5c\u7814\u7a76\u8005\u901a\u8fc7\u5bf9\u6676\u754c\u4e2d\u7684\u7f3a\u9677\u8fdb\u884c\u8c03\u63a7\u8bbe\u8ba1\u6765\u5b9e\u73b0\u65e0\u94c5HDP\u6750\u6599\u66f4\u4f18\u8d8a\u7684\u5149\u7535\u6027\u80fd\u3002\u53d1\u73b0\u901a\u8fc7\u7279\u5b9a\u7684\u672c\u5f81\u7f3a\u9677\u6216\u8005\u7f3a\u9677\u590d\u5408\u7269\u7684\u5f15\u5165\u53ef\u4ee5\u5206\u522b\u6709\u6548\u6d88\u9664\u7b2cII\u7c7b\u548c\u7b2cI\u7c7bHDP\u6676\u754c\u4e2d\u7684\u6df1\u80fd\u7ea7\u7f3a\u9677\u3002\u540c\u65f6\uff0c\u901a\u8fc7\u7ec6\u81f4\u7684\u5316\u5b66\u52bf\u70b9\u7b5b\u9009\uff0c\u53d1\u73b0\u5728\u4e00\u4e9b\u9884\u5148\u8bbe\u8ba1\u7684\u7279\u5b9a\u7cbe\u786e\u7684\u751f\u957f\u6761\u4ef6\u4e0b\uff0c\u8fd9\u4e9b\u7f3a\u9677\u6216\u7f3a\u9677\u590d\u5408\u7269\u4f1a\u81ea\u53d1\u5730\u504f\u805a\u5230HDP\u7684\u6676\u754c\u4e2d\u5fc3\uff0c\u800c\u4e14\u53ef\u4ee5\u6709\u6548\u5730\u6291\u5236\u4f53\u76f8\u4e2d\u7684\u6709\u5bb3\u6df1\u80fd\u7ea7\u7f3a\u9677\u3002\u6b64\u5916\uff0c\u548c\u5f88\u591a\u5176\u4ed6\u534a\u5bfc\u4f53\u7c7b\u4f3c\uff0c\u672c\u5de5\u4f5c\u7814\u7a76\u8005\u53d1\u73b0\u5728\u88ab\u7f3a\u9677\u6216\u7f3a\u9677\u590d\u5408\u7269\u949d\u5316\u540e\u7684\u6676\u754c\u4e2d\u4f1a\u51fa\u73b0\u80fd\u5e26\u5f2f\u66f2\u7684\u73b0\u8c61\uff0c\u8fd9\u6709\u5229\u4e8eHDP\u8584\u819c\u4e2d\u8f7d\u6d41\u5b50\u7684\u5206\u79bb\u3002\u901a\u8fc7\u72ec\u7279\u7684\u5316\u5b66\u65b9\u6cd5\u5bf9\u6676\u754c\u8fdb\u884c\u8c03\u63a7\u662f\u4e00\u79cd\u666e\u4e16\u7684\u65b9\u6cd5\uff0c\u53ef\u4ee5\u5e94\u7528\u5230\u5176\u4ed6\u591a\u6676\u6750\u6599\u4e2d\uff0c\u8fd9\u4e3a\u8bbe\u8ba1\u5177\u6709\u66f4\u4f18\u8d8a\u5149\u7535\u6027\u80fd\u7684\u591a\u6676\u9499\u949b\u77ff\u63d0\u4f9b\u4e86\u65b0\u7684\u89c2\u70b9\u548c\u6307\u5bfc\u3002<\/p>\n

\u7814\u7a76\u6210\u679c\u4ee5\u201cDefect Engineering of Grain Boundaries in Lead-Free Halide Double Perovskites for Better Optoelectronic Performance<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u300aAdvanced Functional Materials<\/strong>\u300b\u4e0a[Adv. Funct. Mater. 2019, 1805870]\u3002\u6e05\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662\u535a\u58eb\u751f\u5f90\u5065\u4e3a\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\uff0c\u5408\u4f5c\u8005\u5305\u62ec\u5317\u4eac\u8ba1\u7b97\u79d1\u5b66\u7814\u7a76\u4e2d\u5fc3\u7684\u9ec4\u5175\u7814\u7a76\u5458\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u4e24\u7c7bHDP\u7684\u7535\u5b50\u7ed3\u6784\u4ee5\u53ca\u4e24\u79cd\u5178\u578b\u6676\u754c\u7684\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

a) ABO3<\/sub>\u548cA2<\/sub>B1+<\/sup>B’3+<\/sup>XVII<\/sup>6<\/sub>\u9499\u949b\u77ff\u7684\u6676\u4f53\u7ed3\u6784\uff1b
\n b) HSE + SOC\u8ba1\u7b97\u7684\u7b2cI\u7c7bHDP(\u4ee5Cs2<\/sub>AgInCl6<\/sub>\u4e3a\u4f8b)\u548c\u7b2cII\u7c7bHDP(\u4ee5Cs2<\/sub>AgBiCl6<\/sub>\u4e3a\u4f8b)\u7684\u7535\u5b50\u80fd\u5e26\u7ed3\u6784\uff1b
\n c) SrTiO3<\/sub>\u548cCs2<\/sub>AgInCl6<\/sub>\u4e2d\u539f\u03a35(310)GB\u7684\u5c40\u90e8\u539f\u5b50\u7ed3\u6784\u6bd4\u8f83\uff1b
\n d) SrTiO3<\/sub>\u548cCs2<\/sub>AgInCl6<\/sub>\u4e2d\u539f\u03a33 \"\"GB\u7684\u5c40\u90e8\u539f\u5b50\u7ed3\u6784\u6bd4\u8f83\u3002<\/p>\n

\u56fe2 \u542b\u6676\u754c\u7684\u4e24\u7c7bHDP\u7684\u80fd\u5e26\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5177\u6709\u539f\u03a35(310)GB\u7684Cs2<\/sub>AgInCl6<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\uff0c\u5176\u4e2d\u5e26\u9699\u5185\u7684\u6df1\u80fd\u7ea7\u7f3a\u9677\u6001[a\u56fe\u4e2d\u7684S1,S2\u548cS3\u6001\u4ee5\u53cac\u56fe\u4e2d\u7684T1\u548cT2\u6001]\u4ee5\u7c97\u7ebf\u7a81\u51fa\u663e\u793a\uff0c\u800c\u4f53\u76f8\u6001\u7531\u9634\u5f71\u533a\u57df\u7a81\u51fa\u663e\u793a(\u4e0b\u540c)\uff1b
\n b) \u5177\u6709\u539f\u03a33 \"\"GB\u7684Cs2<\/sub>AgInCl6<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\uff1b
\n c) \u5177\u6709\u539f\u03a35(310)GB\u7684Cs2<\/sub>AgBiCl6<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\uff1b
\n d) \u5177\u6709\u539f\u03a33\"\" GB\u7684Cs2<\/sub>AgBiCl6<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\u3002<\/p>\n

\u56fe3 \u7b2cI\u7c7bHDP\u4e2d\u4e0d\u5229\u6676\u754c\u5904\u7f3a\u9677(\u53ca\u590d\u5408\u7269)\u7684\u5f62\u6210<\/strong><\/p>\n

\"\"<\/p>\n

a) Cli<\/sub>\u63ba\u5165\u540e\uff0c\u5177\u6709\u03a35(310)GB\u7684Cs2<\/sub>AgInCl6<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\uff0c\u800c\u4f53\u76f8\u6001\u7531\u9634\u5f71\u533a\u57df\u7a81\u51fa\u663e\u793a(\u4e0b\u540c)\uff1b
\n b) InAg + Cli<\/sub>\u63ba\u5165\u540e\uff0c\u5177\u6709\u03a35(310)GB\u7684Cs2<\/sub>AgInCl6<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\uff1b
\n c) Cs2<\/sub>AgInCl6<\/sub>\u4e2d\u03a35(310)GB\u5904Cli<\/sub>\u548cInAg + Cli<\/sub>\u63ba\u5165\u5bf9\u80fd\u5e26\u7ed3\u6784\u8c03\u63a7\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe4 \u751f\u957f\u4f53\u76f8Cs2<\/sub>AgInCl6<\/sub>\u7684\u7a33\u5b9a\u5316\u5b66\u52bf\u533a\u57df<\/strong><\/p>\n

\"\"<\/p>\n

a-d) \u5728\u0394\u03bcAg<\/sub>= 0\u3001-0.1\u3001-0.2\u548c-0.3eV\u7a33\u5b9a\u7684\u5316\u5b66\u52bf\u533a\u57df\u4e2d\uff0cInAg + Cli<\/sub>\u63ba\u5165Cs2<\/sub>AgInCl6<\/sub> \u03a35(310)GB\u7684\u7f3a\u9677\u5f62\u6210\u80fd\u968f\u0394\u03bcCs<\/sub>\u548c\u0394\u03bcIn<\/sub>\u7684\u53d8\u5316\uff0c\u5176\u4e2d\u767d\u8272\u865a\u7ebf\u8868\u793a\u0394Hf<\/sub>[InAg + Cli<\/sub>]> 0\u7684\u533a\u57df(\u4e0b\u65b9)\u548c\u0394Hf<\/sub>[InAg + Cli<\/sub>] <0\u7684\u533a\u57df(\u4e0a\u65b9)\u7684\u8fb9\u754c\u3002<\/p>\n

\u56fe5 Cs2<\/sub>AgInCl6<\/sub>\u4f53\u76f8\u4e2d\u672c\u5f81\u7f3a\u9677\u7269\u7406\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

\u5728\u0394\u03bcAg<\/sub>= 0 eV\u70b9A(\u56fea)\u3001\u0394\u03bcAg<\/sub>= -0.1 eV\u70b9B(\u56feb)\u548c\u0394\u03bcAg<\/sub>= -0.2 eV\u70b9C(\u56fec)\u751f\u957f\u6761\u4ef6\u4e0b\uff0cCs2<\/sub>AgInCl6<\/sub>\u4e2d20\u79cd\u672c\u5f81\u70b9\u7f3a\u9677\u7684\u5f62\u6210\u80fd\u3002\u7528\u4e8e\u7f3a\u9677\u8ba1\u7b97\u7684\u4e09\u4e2a\u4ee3\u8868\u6027\u5316\u5b66\u52bf\u70b9A-C\u5728\u56fe4\u4e2d\u7528\u9ec4\u8272\u5706\u5708\u8868\u793a\u3002<\/p>\n

\u56fe6 \u7b2cII\u7c7bHDP\u4e2d\u4e0d\u5229\u6676\u754c\u5904\u7f3a\u9677(\u53ca\u590d\u5408\u7269)\u7684\u5f62\u6210<\/strong><\/p>\n

\"\"<\/p>\n

a) Cli<\/sub>\u63ba\u5165\u540e\uff0c\u5177\u6709\u03a35(310)GB\u7684Cs2<\/sub>AgBiCl6<\/sub>\u7684\u80fd\u5e26\u7ed3\u6784\uff0c\u800c\u4f53\u76f8\u6001\u7531\u9634\u5f71\u533a\u57df\u7a81\u51fa\u663e\u793a\uff1b<\/p>\n

b) Cs2<\/sub>AgBiCl6<\/sub>\u4e2d\u03a35(310)GB\u5904Cli\u63ba\u5165\u5bf9\u80fd\u5e26\u7ed3\u6784\u8c03\u63a7\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe7 \u751f\u957f\u4f53\u76f8Cs2<\/sub>AgBiCl6<\/sub>\u7684\u7a33\u5b9a\u5316\u5b66\u52bf\u533a\u57df<\/strong><\/p>\n

\"\"<\/p>\n

a-c) \u5728\u0394\u03bcAg<\/sub>= 0\u3001-0.4\u548c-0.8 eV\u7a33\u5b9a\u7684\u5316\u5b66\u52bf\u533a\u57df\u4e2d\uff0cCli<\/sub>\u63ba\u5165Cs2<\/sub>AgBiCl6<\/sub> \u03a35(310)GB\u7684\u7f3a\u9677\u5f62\u6210\u80fd\u968f\u0394\u03bcCs<\/sub>\u548c\u0394\u03bcBi<\/sub>\u7684\u53d8\u5316\uff0c\u5176\u4e2d\u9ed1\u8272\u865a\u7ebf\u8868\u793a\u0394Hf<\/sub>[Cli<\/sub>] > 0\u7684\u533a\u57df(\u53f3)\u548c\u0394Hf[Cli<\/sub>] < 0\u7684\u533a\u57df(\u5de6)\u7684\u8fb9\u754c\u3002<\/p>\n

\u56fe8 Cs2<\/sub>AgBiCl6<\/sub>\u4f53\u76f8\u4e2d\u672c\u5f81\u7f3a\u9677\u7269\u7406\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

a-c) \u5728\u0394\u03bcAg<\/sub>= 0 eV\u3001-0.4 eV\u548c-0.8 eV\u7684\u6761\u4ef6\u4e0b\uff0c\u5728\u4f18\u9009\u5316\u5b66\u52bf\u533a\u57df(\u56fe7\u4e2d\u6807\u6ce8)\u4e2dCs2<\/sub>AgBiCl6<\/sub>\u4f53\u76f8\u4e2d\u7684\u7f3a\u9677\u7269\u7406\u5206\u4e3a\u4e09\u79cd\u60c5\u51b5\uff0c\u8868\u793a\u4e3acase1\u3001case2\u548ccase3\uff0c\u76f8\u5e94\u7684\u5316\u5b66\u52bf\u70b9\u5206\u522b\u7528\u7ea2\u8272\u3001\u7eff\u8272\u548c\u84dd\u8272\u4ee3\u8868\uff1b
\n \u5728\u0394\u03bcAg<\/sub>= 0 eV\u70b9D(\u56fed)\uff0c\u0394\u03bcAg<\/sub>= -0.4 eV\u70b9E(\u56fee)\u548c\u0394\u03bcAg<\/sub>= -0.8 eV\u70b9F(\u56fef)\u751f\u957f\u6761\u4ef6\u4e0bCs2<\/sub>AgBiCl6<\/sub>\u4e2d20\u79cd\u672c\u5f81\u70b9\u7f3a\u9677\u7684\u5f62\u6210\u80fd\u3002\u7528\u4e8e\u7f3a\u9677\u8ba1\u7b97\u7684\u4e09\u4e2a\u4ee3\u8868\u6027\u5316\u5b66\u52bf\u70b9D-F\u5728\u56fe7\u4e2d\u7528\u767d\u8272\u5706\u5708\u8868\u793a\u3002<\/p>\n

\u56fe9 HDP\u4e2d\u6676\u754c\u8bf1\u5bfc\u80fd\u5e26\u5f2f\u66f2\u6548\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5177\u6709\u539f\u03a33 GB\"\"\u7684Cs2<\/sub>AgBiCl6<\/sub>\u6001\u5bc6\u5ea6\uff1b
\n b) \u5177\u6709\u539f\u03a35(310)GB\u7684Cs2<\/sub>AgBiCl6<\/sub>\u6001\u5bc6\u5ea6\uff1b
\n c) Cli<\/sub>\u63ba\u6742\u03a35(310)GB\u7684Cs2<\/sub>AgBiCl6<\/sub>\u6001\u5bc6\u5ea6\uff1b
\n d) \u5177\u6709\u539f\u03a33 \"\"GB\u7684Cs2<\/sub>AgBiCl6<\/sub>\u80fd\u5e26\u793a\u610f\u56fe\uff1b
\n e) \u5177\u6709\u539f\u03a35(310)GB\u7684Cs2<\/sub>AgBiCl6<\/sub>\u80fd\u5e26\u793a\u610f\u56fe\uff1b
\n f) Cli<\/sub>\u63ba\u6742\u03a35(310)GB\u7684Cs2<\/sub>AgBiCl6<\/sub>\u80fd\u5e26\u793a\u610f\u56fe\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDefect Engineering of Grain Boundaries in Lead-Free Halide Double Perovskites for Better Optoelectronic Performance<\/a> <\/strong>(Adv. Funct. Mater.,<\/strong> 2019, DOI: 10.1002\/adfm.201805870)<\/p>\n

\u672c\u6587\u7531\u6e05\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662\u67f3\u767e\u65b0\u9662\u58eb\u8bfe\u9898\u7ec4\u6821\u5bf9\uff0c\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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