{"id":168600,"date":"2019-03-03T06:38:36","date_gmt":"2019-03-02T22:38:36","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=168600"},"modified":"2019-03-03T18:16:56","modified_gmt":"2019-03-03T10:16:56","slug":"%e6%9c%aa%e5%9b%9e%e5%a4%8d-%e5%8d%97%e5%bc%80%e9%99%88%e6%b0%b8%e8%83%9cadv-energy-mater-%e4%be%9b-%e5%8f%97%e4%bd%93%e8%83%bd%e7%ba%a7%e5%8c%b9%e9%85%8d%e7%9a%84%e6%96%b0%e5%9e%8b%e8%92%bd","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=168600","title":{"rendered":"\u5357\u5f00\u9648\u6c38\u80dcAdv. Energy Mater. : \u4f9b\/\u53d7\u4f53\u80fd\u7ea7\u5339\u914d\u7684\u65b0\u578b\u84bd\u57fa\u975e\u5bcc\u52d2\u70ef\u53d7\u4f53\u52a9\u529b\u9ad8\u6548\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5927\u90e8\u5206\u5c0f\u5206\u5b50\u4f9b\u4f53\u548c\u53d7\u4f53\u6750\u6599\u5177\u6709\u53d7\u4f53-\u4f9b\u4f53-\u53d7\u4f53(A-D-A)\u7ed3\u6784\u3002\u5bf9\u4e8eADA\u7ed3\u6784\u5206\u5b50\uff0c\u4e2d\u5fc3\u201cD\u201d\u5355\u5143\u4e0d\u4ec5\u4f5c\u4e3a\u5bcc\u7535\u5b50\u57fa\u56e2\u8bf1\u5bfc\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\uff0c\u800c\u4e14\u5728\u4e3a\u7535\u8377\u5206\u79bb\u548c\u8f93\u9001\u5b9e\u73b0\u5408\u9002\u7684\u80fd\u7ea7\u548c\u5206\u5b50\u5806\u79ef\u4ee5\u53ca\u4e3a\u6eb6\u6db2\u52a0\u5de5\u6027\u63d0\u4f9b\u8db3\u591f\u7684\u6eb6\u89e3\u5ea6\u65b9\u9762\u4e5f\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u901a\u5e38\uff0c\u6269\u5c55\u878d\u5408\u73af\u4f9b\u4f53\u6838\u5fc3\u5728\u975e\u5bcc\u52d2\u70ef\u5c0f\u5206\u5b50\u53d7\u4f53(NF-SMA)\u4e2d\u7684\u03c0\u5171\u8f6d\u5c06\u6539\u5584\u5176\u7ed9\u7535\u5b50\u80fd\u529b\u548c\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\u6548\u5e94\u4ee5\u83b7\u5f97\u66f4\u7a84\u7684\u5e26\u9699\uff0c\u5e76\u589e\u5f3a\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u4ee5\u589e\u5f3a\u5206\u5b50\u5806\u79ef\uff0c\u83b7\u5f97\u66f4\u9ad8\u7684\u7535\u8377\u8fc1\u79fb\u7387\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u7cbe\u786e\u8c03\u8282\u672b\u7aef\u53d7\u4f53\u201cA\u201d\u5355\u5143\u662f\u8c03\u8282\u5206\u5b50\u80fd\u7ea7\uff0c\u589e\u52a0\u5206\u5b50\u95f4\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\u548c\u6539\u5584\u7535\u5b50\u8fc1\u79fb\u7387\u7684\u53e6\u4e00\u79cd\u6709\u6548\u65b9\u5f0f\u3002 \u6b64\u5916\uff0c\u5728NF-SMA\u4e0a\u5177\u6709\u4e0d\u540c\u5438\u7535\u5b50\u80fd\u529b\u7684\u7aef\u57fa\u4ea4\u66ff\u53ef\u5bfc\u81f4\u4e0d\u540c\u7684\u80fd\u7ea7\uff0c\u56e0\u6b64\u53ef\u7528\u4e8e\u4e0e\u4e0d\u540c\u7684\u4f9b\u4f53\u6750\u6599\u66f4\u597d\u5730\u5339\u914d\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u7cbe\u7ec6\u7684\u5206\u5b50\u8bbe\u8ba1\u8fdb\u884c\u7cbe\u7ec6\u4fee\u9970\u548c\u4f9b\u4f53\u6838\u5fc3\u548c\u7aef\u57fa\u7684\u9002\u5f53\u7ec4\u5408\u975e\u5e38\u91cd\u8981\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u9648\u6c38\u80dc\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e24\u79cd\u57fa\u4e8e\u4e03\u73af\u84bd(\u73af\u620a\u4e8c\u567b\u5429)(AT)\u6838\u548c\u4e0d\u540c\u5438\u7535\u5b50\u7aef\u57fa\u7684\u65b0\u578bNF-SMAs\u2014\u2014AT-NC\u548cAT-4Cl\uff0c\u5e76\u5728Adv. Energy Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cNew Anthracene-Fused Nonfullerene Acceptors for High-Efficiency Organic Solar Cells: Energy Level Modulations Enabling Match of Donor and Acceptor<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u867d\u7136\u4e24\u79cd\u65b0\u7684\u53d7\u4f53\u5206\u5b50\u5177\u6709\u4e0d\u540c\u7aef\u57fa\uff0c\u4f46\u8418\u57fa\u7a20\u5408\u7684\u831a\u916e(NINCN)\u548c\u6c2f\u5316\u7684INCN(INCN-2Cl)\u5177\u6709\u7c7b\u4f3c\u7684\u5149\u5438\u6536\u3002\u7531\u4e8e\u6c2f\u539f\u5b50\u7684\u5f3a\u5438\u7535\u5b50\u80fd\u529b\uff0c\u4ee5\u6c2f\u5316INCN\u4f5c\u4e3a\u7aef\u57fa\u7684AT-4Cl\u663e\u8457\u79fb\u52a8\u3002\u56e0\u6b64\uff0c\u5f53\u4ee5\u805a\u5408\u7269PBDB-T\u4f5c\u4e3aAT-NC\u53d7\u4f53\u7684\u7535\u5b50\u4f9b\u4f53\u65f6\uff0c\u53ef\u5b9e\u73b0\u9884\u671f\u7684Voc\u548c\u5149\u4f0f\u6027\u80fd\uff0c\u5e76\u9009\u62e9\u5177\u6709\u964d\u4f4e\u80fd\u7ea7\u7684\u6c1f\u5316\u7c7b\u4f3c\u7269PBDB-TF\u4e0eAT-4Cl\u5171\u6df7\u3002\u56e0\u6b64\uff0cPBDBTF:AT-4Cl\u57fa\u5668\u4ef6\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\u4e3a13.27%\uff0cVoc<\/sub>\u7565\u4f4e\u4e8e0.901 V\uff0c19.52 mA\u00b7cm-2<\/sup>\u7684Jsc<\/sub>\u548c75.5 %\u7684\u586b\u5145\u56e0\u5b50\u76f8\u5bf9\u4e8ePBDB-T:AT-NC\u7684\u503c\u663e\u8457\u589e\u5f3a\u3002\u4e0a\u8ff0\u7ed3\u679c\u8868\u660e\uff0c\u4f7f\u7528\u65b0\u578b\u5bcc\u7535\u5b50AT\u6838\u5fc3\u4ee5\u53ca\u7aef\u57fa\u4f18\u5316\u5b9e\u73b0\u80fd\u7ea7\u8c03\u8282\uff0c\u8fdb\u800c\u80fd\u591f\u4e0e\u805a\u5408\u7269\u4f9b\u4f53\u5339\u914d\uff0c\u662f\u6784\u5efa\u9ad8\u6027\u80fdNF-SMA\u7684\u6210\u529f\u7b56\u7565\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 AT-NC\u548cAT-4Cl\u7684\u5408\u6210\u8def\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

AT-NC\u548cAT-4Cl\u7684\u5408\u6210\u8def\u7ebf\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 \u4f9b\/\u53d7\u4f53\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

a) AT-NC\u548cAT-4Cl\u5728\u6c2f\u4eff\u6eb6\u6db2\u4e2d\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b
\n b) AT-NC\u3001AT-4C\u3001PBDB-T\u548cPBDB-TF\u8584\u819c\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\u3002<\/p>\n

\u56fe3 \u4f9b\/\u53d7\u4f53\u7684\u5316\u5b66\u7ed3\u6784\u4ee5\u53ca\u80fd\u7ea7\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

AT-NC\u3001AT-4Cl\u3001PBDB-T\u548cPBDB-TF\u7684\u5316\u5b66\u7ed3\u6784\u4ee5\u53ca\u80fd\u7ea7\u56fe\u3002<\/p>\n

\u56fe4 \u76f8\u5e94\u5668\u4ef6\u7684\u5149\u4f0f\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5728AM 1.5G(100 mW\u00b7cm-2<\/sup>)\u7167\u5c04\u4e0b\uff0c\u4f18\u5316\u6761\u4ef6\u4e0bAT-NC\u548cAT-4Cl\u57fa\u5668\u4ef6\u7684\u7535\u6d41\u5bc6\u5ea6-\u7535\u538b(J-V)\u66f2\u7ebf\uff0c\u5185\u63d2\u4e3a30\u4e2a\u5668\u4ef6\u7684PCE\u8ba1\u6570\u76f4\u65b9\u56fe\uff1b
\n b) AT-NC\u548cAT-4Cl\u57faOPV\u5668\u4ef6\u7684EQE\u66f2\u7ebf\u548cJsc<\/sub>\uff1b
\n c) Jph<\/sub>\u968fVeff<\/sub>\u7684\u53d8\u5316\uff1b
\n d) \u4f18\u5316\u5668\u4ef6\u7684Jsc<\/sub>\u968f\u5149\u5f3a\u5ea6(P)\u7684\u53d8\u5316\uff1b
\n e) PBDB-T:AT-NC\u548cPBDB-TF:AT-4Cl\u57fa\u5668\u4ef6\u7684\u77ac\u6001\u5149\u7535\u6d41\uff1b
\n f) PBDB-T:AT-NC\u548cPBDB-TF:AT-4Cl\u57fa\u5668\u4ef6\u7684\u77ac\u6001\u5149\u7535\u538b\u3002<\/p>\n

\u56fe5 GIWAXS\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

a) AT-NC\u539f\u59cb\u819c\u76842D GIWAXS\u56fe\u50cf\uff1b
\n b) PBDB-T:AT-NC\u5171\u6df7\u819c\u76842D GIWAXS\u56fe\u50cf\uff1b
\n c) PBDB-T\u539f\u59cb\u819c\u76842D GIWAXS\u56fe\u50cf\uff1b
\n d) AT-4Cl\u539f\u59cb\u819c\u76842D GIWAXS\u56fe\u50cf\uff1b
\n e) PBDB-TF:AT-4Cl\u5171\u6df7\u819c\u76842D GIWAXS\u56fe\u50cf\uff1b
\n f) PBDB-TF\u539f\u59cb\u819c\u76842D GIWAXS\u56fe\u50cf\uff1b
\n g) \u539f\u59cb\u819c\u548c\u5171\u6df7\u819c\u7684\u9762\u5916\u548c\u9762\u5185GIWAXS\u66f2\u7ebf\u3002<\/p>\n

\u56fe6 \u5171\u6df7\u819c\u7684\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

a) AT-NC\u7eaf\u819c\u7684AFM\u56fe\u50cf\uff1b
\n b,c) PBDB-T:AT-NC\u819c\u7684AFM\u548cTEM\u56fe\u50cf\uff1b
\n d) AT-4Cl\u7eaf\u819c\u7684AFM\u56fe\u50cf\uff1b
\n e,f) PBDB-TF:AT-4Cl\u819c\u7684AFM\u548cTEM\u56fe\u50cf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u5f00\u53d1\u65b0\u578bAT\u5bcc\u7535\u5b50\u6838\u5e76\u5206\u522b\u5f15\u5165\u4e24\u4e2a\u4e0d\u540c\u7684\u5438\u7535\u5b50\u7aef\u57faNINCN\u548cINCN-2Cl\uff0c\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e24\u79cd\u65b0\u7684NF-SMA\u2014\u2014AT-NC\u548cAT-4Cl\u3002\u5c3d\u7ba1\u76f8\u5bf9\u4e8eAT-NC\u5177\u6709\u76f8\u4f3c\u7684\u5438\u6536\u5149\u8c31\uff0cAT-4Cl\u8868\u73b0\u51fa\u663e\u8457\u4e0b\u79fb\u7684\u80fd\u7ea7\u3002\u56e0\u6b64\uff0c\u9009\u62e9\u4e24\u79cd\u4e0d\u540c\u7684\u4f9b\u4f53PBDB-T\u548cPBDB-TF\u4ee5\u83b7\u5f97\u66f4\u597d\u7684\u80fd\u7ea7\u5339\u914d\u548c\u66f4\u9ad8\u7684Voc<\/sub>\u3002\u4e0ePBDB-T:AT-NC\u76f8\u6bd4\uff0c\u5177\u6709\u964d\u4f4e\u7684\u5206\u5b50\u80fd\u7ea7\u7684PBDB-TF:AT-4Cl\u5171\u6df7\u819c\u663e\u793a\u51fa\u9002\u5f53\u7684\u76f8\u5206\u79bb\uff0c\u5177\u6709\u6709\u5229\u7684\u5206\u5b50\u5806\u79ef\u548c\u6df7\u6eb6\u6027\uff0c\u5e76\u4e14\u5177\u6709\u589e\u5f3a\u7684\u5438\u6536\u7cfb\u6570\u3002\u56e0\u6b64\uff0cPBDB-T:AT-NC\u57fa\u5668\u4ef6PCE\u4e3a10.91 %\uff0cVoc<\/sub>\u4e3a0.919 V\u3002PBDB-TF:AT-4Cl\u57fa\u5668\u4ef6PCE\u4e3a13.27%\uff0cVoc<\/sub>\u4e3a0.901 V\uff0cJsc\u4e3a19.52 mA\u00b7cm-2<\/sup>\uff0cFF\u4e3a75.5%\u3002\u4e0a\u8ff0\u7ed3\u679c\u8868\u660e\uff0c\u5229\u7528\u65b0\u7684\u5bcc\u7535\u5b50AT\u6838\u5fc3\u4ee5\u53ca\u7aef\u57fa\u4f18\u5316\u5b9e\u73b0\u80fd\u7ea7\u8c03\u8282\uff0c\u8fdb\u800c\u80fd\u591f\u4e0e\u805a\u5408\u7269\u4f9b\u4f53\u5339\u914d\uff0c\u662f\u6784\u5efa\u9ad8\u6027\u80fdNF-SMA\u7684\u6709\u524d\u9014\u548c\u6210\u529f\u7684\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aNew Anthracene-Fused Nonfullerene Acceptors for High-Efficiency Organic Solar Cells: Energy Level Modulations Enabling Match of Donor and Acceptor<\/a> <\/strong>(Adv. Energy Mater.<\/strong>, 2019, DOI: 10.1002\/aenm.201803541)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fc4\u4eca\u4e3a\u6b62\uff0c\u5927\u90e8\u5206\u5c0f\u5206\u5b50\u4f9b\u4f53\u548c\u53d7\u4f53\u6750\u6599\u5177\u6709\u53d7\u4f53-\u4f9b\u4f53-\u53d7\u4f53(A-D-A)\u7ed3\u6784\u3002\u5bf9\u4e8eADA\u7ed3\u6784\u5206\u5b50\uff0c\u4e2d\u5fc3\u201cD\u201d\u5355\u5143\u4e0d\u4ec5\u4f5c\u4e3a\u5bcc\u7535\u5b50\u57fa\u56e2\u8bf1\u5bfc\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\uff0c\u800c…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2678,3910],"class_list":["post-168600","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2678","tag-3910"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/168600"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=168600"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/168600\/revisions"}],"predecessor-version":[{"id":168673,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/168600\/revisions\/168673"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=168600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=168600"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=168600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}