{"id":169459,"date":"2019-03-13T06:30:27","date_gmt":"2019-03-12T22:30:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=169459"},"modified":"2019-03-12T18:12:10","modified_gmt":"2019-03-12T10:12:10","slug":"%e8%b5%b5%e6%99%af%e7%a5%a5%e8%af%be%e9%a2%98%e7%bb%84jmca-b-n%e5%8e%9f%e5%ad%90%e6%8e%ba%e6%9d%82%e9%9d%9e%e9%87%91%e5%b1%9e%e7%9f%b3%e5%a2%a8%e7%82%94%e9%ab%98%e6%95%88%e7%94%b5%e5%82%ac","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=169459","title":{"rendered":"\u8d75\u666f\u7965\u8bfe\u9898\u7ec4JMCA:\u00a0B\/N\u539f\u5b50\u63ba\u6742\u975e\u91d1\u5c5e\u77f3\u58a8\u7094\u9ad8\u6548\u7535\u50ac\u5316\u8fd8\u539fCO2\u751f\u6210CH4\u548cC2H4"},"content":{"rendered":"<p><strong><b>\u3010\u524d\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u65e5\u524d\uff0c<strong>\u54c8\u5c14\u6ee8\u5e08\u8303\u5927\u5b66\u8d75\u666f\u7965\u8bfe\u9898\u7ec4<\/strong>Journal of Materials Chemistry A\u4e0a\u53d1\u8868\u4e86\u9898\u76ee\u4e3a<strong>[Metal-free graphdiyne doped with sp-hybridized\u00a0boron and nitrogen atoms at acetylenic sites for\u00a0high-efficiency electroreduction of CO<sub>2<\/sub>\u00a0to CH<sub>4<\/sub>\u00a0and\u00a0C<sub>2<\/sub>H<sub>4<\/sub>]<\/strong>\u7684\u6587\u7ae0\uff08DOI: 10.1039\/c8ta11825f\uff09\u3002\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u80fd\u591f\u5c06\u4e8c\u6c27\u5316\u78b3\u7a33\u5b9a\uff0c\u9ad8\u6548\u7684\u8fd8\u539f\u4e3a\u7532\u70f7\u548c\u4e59\u70ef\u7684\u7535\u50ac\u5316\u5242\u3002\u6587\u7ae0\u7b2c\u4e00\u4f5c\u8005\uff1a\u8d75\u4f73\u7855\u58eb\u7814\u7a76\u751f\uff0c\u9648\u54f2\u7855\u58eb\u7814\u7a76\u751f\uff1b\u901a\u8baf\u4f5c\u8005\uff1a\u8d75\u666f\u7965\u6559\u6388<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-169460 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724720-3.png\" alt=\"\" width=\"600\" height=\"239\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724720-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724720-3-300x120.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>DOI: 10.1039\/c8ta11825f<\/p>\n<p><strong>\u6587\u7ae0\u4eae\u70b9<\/strong><\/p>\n<p>i\u00a0\u00a0\u73af\u5883\u6761\u4ef6\u4e0b\u7535\u50ac\u5316\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3\u4e3b\u8981\u4f9d\u8d56\u4e8e\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\uff0c\u800c\u672c\u6587\u7814\u7a76\u7684B\/N\u539f\u5b50\u63ba\u6742\u77f3\u58a8\u7094\u4f5c\u4e3a\u65e0\u91d1\u5c5e\u7535\u50ac\u5316\u5242\u53ef\u4ee5\u7a33\u5b9a\uff0c\u9ad8\u6548\u5c06\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e3a\u5316\u5b66\u54c1\u3002<\/p>\n<p>ii\u00a0\u00a0\u901a\u8fc7\u4ed4\u7ec6\u7684\u7814\u7a76\u5b9a\u5236B\/N\u7684\u63ba\u6742\u4f4d\u70b9\uff0cB\/N\u63ba\u6742\u77f3\u58a8\u7094\u4e0d\u5355\u5355\u53ef\u4ee5\u4f7fCO<sub>2<\/sub>\u8f6c\u5316\u4e3a\u7532\u70f7\u7b49C1\u4ea7\u7269\uff0c\u5bf9\u4e8e\u751f\u6210C2\u4ea7\u7269-\u4e59\u70ef\u4e5f\u5177\u6709\u5f88\u9ad8\u7684\u6d3b\u6027\u3002<\/p>\n<p><strong><b>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n<p>\u76ee\u524d\uff0c\u5e94\u7528\u53ef\u518d\u751f\u7684\u7535\u529b\u5c06\u4e8c\u6c27\u5316\u78b3\u7535\u50ac\u5316\u8fd8\u539f\u4e3a\u9ad8\u4ef7\u503c\u71c3\u6599\u548c\u5316\u5b66\u54c1\uff0c\u4e0d\u4ec5\u5728\u53ef\u518d\u751f\u80fd\u6e90\u8f6c\u6362\u6280\u672f\u4e2d\u53d1\u6325\u7740\u5173\u952e\u4f5c\u7528\uff0c\u5e76\u4e14\u8fd8\u6709\u52a9\u4e8e\u51cf\u5c11\u4e8c\u6c27\u5316\u78b3\u7684\u6392\u653e\uff0c\u56e0\u6b64\u5438\u5f15\u4e86\u5f88\u591a\u7814\u7a76\u8005\u7684\u5173\u6ce8\u3002\u7136\u800c\u76ee\u524dCO<sub>2<\/sub>ER\u4e5f\u5b58\u5728\u7740\u4e00\u4e9b\u6311\u6218\uff0c\u4f8b\u5982\u6790\u6c22\uff0c\u9009\u62e9\u6027\u5dee\uff0c\u4ee5\u53ca\u9ad8\u8fc7\u7535\u4f4d\u7b49\u3002\u5f53\u524d\uff0c\u5e94\u7528\u4e8eCO<sub>2<\/sub>ER\u7684\u662f\u88ab\u5e7f\u6cdb\u4f7f\u7528\u7684\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\uff0c\u7136\u800c\u5927\u591a\u6570\u6b64\u7c7b\u50ac\u5316\u5242\u8fc7\u4e8e\u6602\u8d35\uff0c\u4f1a\u5f88\u663e\u8457\u7684\u589e\u52a0\u6210\u672c\u3002\u8fd1\u5e74\u6765\uff0c\u4e00\u4e9b\u65b0\u5174\u7684\u78b3\u7eb3\u7c73\u6750\u6599\u88ab\u5408\u6210\u4f5c\u4e3a\u975e\u91d1\u5c5e\u7535\u50ac\u5316\u5242\u5e94\u7528\u4e8e\u4e0d\u540c\u7684\u7535\u5316\u5b66\u53cd\u5e94\uff0c\u88ab\u8bc1\u5b9e\u5177\u6709\u9ad8\u5bfc\u7535\u6027\uff0c\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u548c\u4f4e\u6210\u672c\u7b49\u4f18\u70b9\uff0c\u540c\u6837\uff0c\u5f02\u8d28\u63ba\u6742\u78b3\u6750\u6599\u4e5f\u88ab\u8bc1\u5b9e\u5728\u589e\u5f3a\u4e8c\u6c27\u5316\u78b3\u50ac\u5316\u6027\u80fd\u65b9\u9762\u8d77\u7740\u91cd\u8981\u7684\u4f5c\u7528\u3002\u6700\u8fd1\uff0c\u4e00\u79cd\u5177\u6709\u4f18\u826f\u7684\u534a\u5bfc\u4f53\u7279\u6027\u7684\u65b0\u578b\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u77f3\u58a8\u7094\uff08GDY\uff09\u88ab\u6210\u529f\u5408\u6210\uff0c\u5e76\u4e14GDY\u7684\u7279\u6027\u53ef\u901a\u8fc7\u6742\u539f\u5b50\u63ba\u6742\u6765\u8fdb\u884c\u5145\u5206\u7684\u8c03\u8282\u3002\u56e0\u6b64\uff0c\u672c\u6587\u4f7f\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\uff0c\u63a2\u7a76\u4e86B\/N\u63ba\u6742GDY\u4f5c\u4e3a\u65e0\u91d1\u5c5eCO<sub>2<\/sub>ER \u00a0\u7535\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<p>\u56fe\u4e00. GDY\u548cB\/N\u63ba\u6742GDY\u7684B\u3001N\u539f\u5b50\u4f4d\u4e8e\u4e0d\u540c\u63ba\u6742\u4f4d\u70b9\u7684\u4f18\u5316\u7a33\u5b9a\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-169461 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724721-2.png\" alt=\"\" width=\"600\" height=\"518\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724721-2.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724721-2-300x259.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u3010\u56fe\u6587\u89e3\u6790\u3011<\/b><\/strong><\/p>\n<p>1.B\/N\u63ba\u6742GDY\u7684\u7ed3\u6784\u7a33\u5b9a\u6027<\/p>\n<p style=\"text-align: left;\">\u50ac\u5316\u5242\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u4e0e\u539f\u5b50\u7684\u952e\u957f\uff0c\u5f62\u6210\u80fd\u548c\u7ed3\u5408\u80fd\u6709\u7740\u5f88\u7d27\u5bc6\u7684\u8054\u7cfb\u3002\u8868\u4e00\u8868\u660e\u4e86\u7ed3\u5408\u80fd\uff0c\u5f62\u6210\u80fd\u4ee5\u53caB\/N\u539f\u5b50\u4e0e\u5176\u76f8\u8fdeC\u539f\u5b50\u7684\u6700\u77ed\u8ddd\u79bb\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\u8fd9\u4e9b\u63ba\u6742\u540eGDY\u7684\u7ed3\u5408\u80fd\uff08\u5927\u7ea6-6.97eV\uff09\u4ec5\u4ec5\u7565\u4f4e\u4e8e\u539f\u59cb\u7684\uff08-7.00eV\uff09\uff0c\u663e\u793a\u51fa\u4e86\u9ad8\u7a33\u5b9a\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cB\u63ba\u6742\u6bd4\u5728\u76f8\u540c\u4f4d\u7f6e\u7684N\u63ba\u6742\u4f1a\u66f4\u7a33\u5b9a\u4e00\u4e9b\uff0c\u540c\u65f6\uff0c\u63ba\u6742\u7684GDY\u90fd\u5177\u6709\u8f83\u5c0f\u7684\u5f62\u6210\u80fd\uff080.60~1.68eV\uff09\uff0c\u8fd9\u8868\u660eB\u548cN\u539f\u5b50\u90fd\u80fd\u5f88\u5bb9\u6613\u7684\u63ba\u6742GDY\u3002<\/p>\n<p>\u8868\u4e00. \u8ba1\u7b97\u7684\u63ba\u6742GDY\u7684\u7ed3\u5408\u80fd\uff0c\u5f62\u6210\u80fd\u4ee5\u53caB\/N\u539f\u5b50\u4e0e\u76f8\u8fdeC\u539f\u5b50\u7684\u6700\u77ed\u8ddd\u79bb<\/p>\n<p>&nbsp;<\/p>\n<table class=\" aligncenter\" style=\"height: 256px;\" width=\"612\">\n<tbody>\n<tr>\n<td style=\"text-align: center; width: 131px;\">\n<p>&nbsp;<\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>B1<\/p>\n<\/td>\n<td style=\"text-align: center; width: 65px;\">\n<p>B2<\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>B3<\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>N1<\/p>\n<\/td>\n<td style=\"text-align: center; width: 69px;\">\n<p>N2<\/p>\n<\/td>\n<td style=\"text-align: center; width: 72px;\">\n<p>N3<\/p>\n<\/td>\n<\/tr>\n<tr>\n<td style=\"text-align: center; width: 131px;\">\n<p><em><i>E<\/i><\/em><sub>coh <\/sub><\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>-6.99<\/p>\n<\/td>\n<td style=\"text-align: center; width: 65px;\">\n<p>-6.98<\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>-6.97<\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>-6.95<\/p>\n<\/td>\n<td style=\"text-align: center; width: 69px;\">\n<p>-6.97<\/p>\n<\/td>\n<td style=\"text-align: center; width: 72px;\">\n<p>-6.96<\/p>\n<\/td>\n<\/tr>\n<tr>\n<td style=\"text-align: center; width: 131px;\">\n<p><em><i>E<\/i><\/em><sub>f<\/sub><em><sub><i>\u00a0<\/i><\/sub><\/em><\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>0.62<\/p>\n<\/td>\n<td style=\"text-align: center; width: 65px;\">\n<p>1.23<\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>1.39<\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>1.68<\/p>\n<\/td>\n<td style=\"text-align: center; width: 69px;\">\n<p>0.60<\/p>\n<\/td>\n<td style=\"text-align: center; width: 72px;\">\n<p>0.92<\/p>\n<\/td>\n<\/tr>\n<tr>\n<td style=\"text-align: center; width: 131px;\">\n<p><em><i>d<\/i><\/em><sub>D-C<\/sub><\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>1.48<\/p>\n<\/td>\n<td style=\"text-align: center; width: 65px;\">\n<p>1.36<\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>1.35<\/p>\n<\/td>\n<td style=\"text-align: center; width: 76px;\">\n<p>1.34<\/p>\n<\/td>\n<td style=\"text-align: center; width: 69px;\">\n<p>1.19<\/p>\n<\/td>\n<td style=\"text-align: center; width: 72px;\">\n<p>1.19<\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>2.\u7535\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u7684\u50ac\u5316\u6027\u80fd<\/p>\n<p>\uff081\uff09\u56fe\u4e8c\u5c55\u793a\u4e86\u5728B\/N\u63ba\u6742GDY\u4e0a\u5438\u9644COOH<sup>*<\/sup>\u4e2d\u95f4\u4f53\u7684\u6784\u578b\u4ee5\u53ca\u901a\u8fc7\u8ba1\u7b97\u5bf9\u6bd4\u4e86GDY\u3001B\/N\u63ba\u6742GDY\u3001\u4ee5\u53caCu(111)\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u7684\u53d8\u5316\uff08CO<sub>2<\/sub>\u00a0\u2192\u00a0COOH<sup>*<\/sup>\uff09\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660eB\u63ba\u6742\u548cN\u63ba\u6742\u5438\u9644COOH<sup>*<\/sup>\u7684\u6d3b\u6027\u4f4d\u70b9\u4e0d\u540c\u3002\u5e76\u4e14\uff0cB1\u548cN3\u7531\u4e8e\u5f62\u6210COOH<sup>*<\/sup>\u7684\u81ea\u7531\u80fd\u5927\u4e8e1.00eV\uff0c\u8d85\u8d8a\u4e86\u5728\u6240\u6709\u91d1\u5c5e\u4e2dCO<sub>2<\/sub>ER\u6027\u80fd\u6700\u4f73\u7684Cu\uff08111\uff09\u76840.99eV, \u6240\u4ee5\u88ab\u8868\u660e\u4e0d\u80fd\u6210\u4e3a\u5408\u683c\u7684\u7535\u50ac\u5316\u5242\u3002<\/p>\n<p>\u56fe\u4e8c. B\/N\u63ba\u6742GDY\u5438\u9644COOH<sup>*<\/sup>\u7684\u7a33\u5b9a\u7ed3\u6784\u4ee5\u53ca\u751f\u6210COOH<sup>*<\/sup>\u4e2d\u95f4\u4f53\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-169462 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724722-2.png\" alt=\"\" width=\"600\" height=\"221\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724722-2.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/03\/\u56fe\u724722-2-300x111.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff082\uff09\u56fe\u4e09\u5c55\u793a\u4e86B\/N\u63ba\u6742GDY\u751f\u6210CH<sub>4<\/sub>\u548cB2\u751f\u6210C<sub>2<\/sub>H<sub>4<\/sub>\u7684\u6700\u4f18\u8def\u5f84\u53cd\u5e94\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53d8\u5316\u3002B\u63ba\u6742GDY\u548cN\u63ba\u6742GDY\u7535\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u8fd8\u662f\u5b58\u5728\u7740\u4e00\u5b9a\u7684\u5dee\u522b\u3002\u4f8b\u5982\uff0cB3\u63ba\u6742GDY\u5438\u9644CO<sup>*<\/sup>\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53d8\u5316\u5206\u522b\u4e3a-0.52eV, \u7136\u800cN2 \u63ba\u6742GDY\u5438\u9644CO<sup>*<\/sup>\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53d8\u5316\u4e3a0.51eV\u3002\u6b64\u5916\uff0cB2\u901a\u8fc7\u4e24\u4e2aCO\u5f62\u6210\u7684\u4e8c\u805a\u4f53\u6216\u8005\u662fCH<sup>*<\/sup>\u548cCO\u4e4b\u95f4\u7684CC\u8026\u5408\uff0c\u5747\u662f\u4f5c\u4e3a\u5177\u6709\u8f83\u4f4e\u9650\u5236\u7535\u4f4d\uff08-0.60eV\uff09\u7684\u51b3\u901f\u6b65\u9aa4\u50ac\u5316\u751f\u6210\u00a0C<sub>2<\/sub>H<sub>4<\/sub>\uff0c\u540c\u65f6CH<sup>*<\/sup>\u548cCO\u4e4b\u95f4\u7684\u8026\u5408\u4e5f\u53ef\u53d1\u751f\u5728B3\u4e0a\uff0c\u800cCOCO\u4e8c\u805a\u4f53\u7684\u5f62\u6210\u5219\u66f4\u5bb9\u6613\u53d1\u751f\u5728N2\u4e0a\u3002\u603b\u4f53\u800c\u8a00\uff0cB2\u3001B3\u548cN2\u4f5c\u4e3a\u7535\u50ac\u5316\u5242\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3\u751f\u6210CH<sub>4<\/sub>\u548cC<sub>2<\/sub>H<sub>4<\/sub>\u5747\u8868\u73b0\u51fa\u4e86\u8f83\u9ad8\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n<p>\u56fe\u4e09. 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