{"id":169555,"date":"2019-03-14T06:21:32","date_gmt":"2019-03-13T22:21:32","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=169555"},"modified":"2019-03-13T15:22:15","modified_gmt":"2019-03-13T07:22:15","slug":"%e9%83%91%e5%b7%9e%e5%a4%a7%e5%ad%a6%e9%82%b5%e5%9b%bd%e8%83%9cj-mater-chem-a-%e4%b8%80%e4%bd%93%e5%8c%96%e5%85%a8%e5%9b%ba%e6%80%81%e7%94%b5%e6%b1%a0%e5%88%9d%e6%8e%a2%ef%bc%8c%e8%88%b9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=169555","title":{"rendered":"\u90d1\u5dde\u5927\u5b66\u90b5\u56fd\u80dcJ. Mater. Chem. A:\u00a0\u4e00\u4f53\u5316\u5168\u56fa\u6001\u7535\u6c60\u521d\u63a2\uff0c\u8239\u95f8\u6a21\u578b\uff08\u5229\u7528\u7279\u6b8a\u7f13\u51b2\u5c42\u50cf\u8c03\u63a7\u6c34\u4f4d\u4e00\u6837\u8c03\u63a7\u5168\u56fa\u6001\u7535\u6c60\u4e2d\u7684\u7535\u4f4d\uff09"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u5b89\u5168\u6027\u80fd\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u6291\u5236\u9502\u679d\u6676\u7b49\u7279\u6027\u5f15\u8d77\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u4ee5\u65e0\u673a\u78f7\u786b\u5316\u5408\u7269\u4e3a\u4ee3\u8868\u7684\u56fa\u6001\u7535\u89e3\u8d28(SSE)\u4f53\u7cfb\uff0c\u5982Li10<\/sub>GeP2<\/sub>S12<\/sub>(LGPS)\u548cLi6<\/sub>PS5<\/sub>Cl (\u786b\u94f6\u9517\u77ff\u578b)\u7b49\u5747\u80fd\u5b9e\u73b0Li\u79bb\u5b50\u7684\u5feb\u901f\u4f20\u8f93\uff0c\u8fbe\u5230\u751a\u81f3\u8fdc\u8d851mS\u00a0cm–<\/sup>1<\/sup>\u7684\u884c\u4e1a\u6807\u51c6\uff0c\u8868\u73b0\u51fa\u4e0e\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u76f8\u5ab2\u7f8e\u7684Li\u79bb\u5b50\u8f93\u8fd0\u80fd\u529b\u3002<\/p>\n

\u7136\u800c\uff0c\u5168\u56fa\u6001\u7535\u6c60\u4e2d\u7684\u56fa-\u56fa\u754c\u9762\u7684\u7a33\u5b9a\u6027\u3001\u517c\u5bb9\u6027\u3001\u5339\u914d\u5ea6\u7b49\u8bf8\u591a\u95ee\u9898\u76f4\u63a5\u5f71\u54cd\u7740\u5168\u56fa\u6001\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4f7f\u5f97\u5168\u56fa\u6001\u7535\u6c60\u7684\u5b9e\u7528\u5316\u4e4b\u8def\u5145\u6ee1\u8bf8\u591a\u6311\u6218\u3002\u5177\u4f53\u4e3a\uff1a\uff08a\uff09L<\/b><\/strong>i|SSE<\/b><\/strong>\u95f4\u7684\u56fa\u76f8\u754c\u9762\u95ee\u9898<\/b><\/strong>\u3002\u4f8b\u5982:\u901a\u8fc7\u672c\u6587\u8ba1\u7b97\u4f5c\u8005\u53d1\u73b0Li10<\/sub>GeP2<\/sub>S12<\/sub>\u548cLi6<\/sub>PS5<\/sub>Cl\u4e0eLi\u4e0d\u7a33\u5b9a\uff0c\u5176\u4e2dP<\/b><\/strong>S<\/b><\/strong>4<\/b><\/sub><\/strong>\u56db\u9762\u4f53\u5fae\u7ed3\u6784\u5355\u5143\u4f1a\u88ab\u5206\u89e3\u6210<\/b><\/strong>Li<\/b><\/strong>x<\/b><\/sub><\/strong>P<\/b><\/strong>\u548c<\/b><\/strong>Li<\/b><\/strong>2<\/b><\/sub><\/strong>S<\/b><\/strong>\u3002\u540c\u65f6\uff0c\u5927\u91cf\u539f\u4f4d\u5b9e\u9a8c\u5de5\u4f5c\u4e5f\u8bc1\u660e\u4e86\u8be5\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff1b\uff08b\uff09S<\/b><\/strong>SE|SSE<\/b><\/strong>\u95f4\u7684\u56fa\u76f8\u754c\u9762\u95ee\u9898<\/b><\/strong>\u3002\u4f8b\u5982\uff1a\u901a\u8fc7\u4f18\u5316\u70e7\u7ed3\u6d41\u7a0b\u3001\u73bb\u7483\u5316\u3001\u63ba\u6742\u3001\u590d\u5408\u7b49\u5b9e\u9a8c\u624b\u6bb5\u80fd\u6709\u6548\u5730\u51cf\u5c0f\u56fa\u6001\u7535\u89e3\u8d28\u7684\u754c\u9762\u963b\u6297<\/b><\/strong>\uff1b\uff08<\/b><\/strong>c<\/b><\/strong>\uff09S<\/b><\/strong>SE|<\/b><\/strong>\u6b63\u6781\u95f4\u7684\u56fa\u76f8\u754c\u9762\u95ee\u9898\u3002\u4f8b\u5982\uff1a<\/b><\/strong>\u901a\u8fc7\u8ba1\u7b97\u4f5c\u8005\u53d1\u73b0\u78f7\u786b\u5316\u5408\u7269Li10<\/sub>GeP2<\/sub>S12<\/sub>\u548cLi6<\/sub>PS5<\/sub>Cl\u7a33\u5b9a\u7535\u5316\u5b66\u7a97\u53e3\u5f88\u7a84<\/b><\/strong>\uff0c\u5176\u4e2dLi6<\/sub>PS5<\/sub>Cl\u6700\u5927\u6c27\u5316\u7535\u4f4d<\/b><\/strong>\u4ec5\u4e3a2<\/b><\/strong>.19 V<\/b><\/strong>\u3002\u56e0\u6b64\uff0c\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u5f53\u7535\u538b\u5e73\u53f0\u8fbe\u52303V\u65f6\uff0cLi6<\/sub>PS5<\/sub>Cl\u5728\u4e0e\u6b63\u6781\u6d3b\u6027\u6750\u6599\u63a5\u89e6\u754c\u9762\u5904<\/b><\/strong>\uff0c\u4f1a\u4ea7\u751fS + LiCl + P2<\/sub>Sx<\/sub>\u00a0\u7684L<\/b><\/strong>i<\/b><\/strong>\u8017\u5c3d\u5c42<\/b><\/strong>\u3002\u5927\u91cf\u539f\u4f4d\u5b9e\u9a8c\u5de5\u4f5c\u540c\u6837\u4f50\u8bc1\u4e86\u8be5\u8017\u5c3d\u5c42\u7684\u5b58\u5728\u3002\u6545\uff0c\u56fa\u76f8\u754c\u9762\u95ee\u9898\u5bf9\u5168\u56fa\u6001\u7535\u6c60\u7684\u5faa\u73af\u3001\u5927\u529f\u7387\u5145\u653e\u7b49\u7684\u7a33\u5b9a\u6027\u4f1a\u5e26\u6765\u8bf8\u591a\u4e0d\u5229\u56e0\u7d20\u3002<\/p>\n

\u56e0\u6b64\uff0c\u8bbe\u8ba1\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\u76f8\u5339\u914d<\/b><\/strong>\u7684\u65b0\u578b\u7f13\u51b2\u529f\u80fd\u5c42<\/b><\/strong>\u6750\u6599\uff0c\u514b\u670d\u56fa\u76f8\u754c\u9762\u5b58\u5728\u7684\u8bf8\u591a\u95ee\u9898\uff0c\u63a2\u5bfb\u6784\u9020\u4e00\u4f53\u5316\u5168\u56fa\u6001\u7535\u6c60\u7684\u53ef\u884c\u6027\u65b9\u6848\uff0c\u5bf9\u76f8\u5173\u5b9e\u9a8c\u7684\u5f00\u5c55\u5177\u6709\u524d\u77bb\u6027\u548c\u6307\u5bfc\u4f5c\u7528\u3002<\/b><\/strong>\u6b64\u5916\uff0c\u4f18\u5f02\u7684\u7f13\u51b2\u5c42\u6750\u6599\u5fc5\u987b\u5177\u5907\u5982\u4e0b\u7279\u5f81\uff1a\uff08a\uff09\u4f18\u79c0\u7684L<\/b><\/strong>i<\/b><\/strong>\u79bb\u5b50\u5bfc\u4f53<\/b><\/strong>\u2014\u4e0d\u5f71\u54cdLi\u7684\u8f93\u8fd0\uff1b\uff08b\uff09\u5177\u5907\u5bbd\u7684\u7535\u5316\u5b66\u7a97\u53e3<\/b><\/strong>\u2014\u4e0e\u9ad8\u7535\u538b\u6b63\u6781\u6d3b\u6027\u6750\u6599\u517c\u5bb9\uff0c\u6d88\u9664L<\/b><\/strong>i<\/b><\/strong>\u7684\u8017\u5c3d\u5c42\uff1b\uff08<\/b><\/strong>c<\/b><\/strong>\uff09\u4e0e\u6b63\u6781\u6d3b\u6027\u7269\u8d28\u5316\u5b66\u6027\u8d28\u7a33\u5b9a<\/b><\/strong>\u2014\u907f\u514d\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff1b\uff08d\uff09\u5c0f\u7684\u6676\u683c\u9002\u914d\u5ea6<\/b><\/strong>\u2014\u51cf\u5c0f\u5c42\u4e0e\u5c42\u95f4\u7684\u5e94\u529b\u3002\u7531\u6b64\uff0c\u4f5c\u8005\u5f15\u5165\u8239\u95f8\u6a21\u578b\u5982\u56fe\u4e00\u6240\u793a\uff0c\u5229\u7528\u7279\u6b8a\u7f13\u51b2\u5c42\u50cf\u8c03\u63a7\u6c34\u4f4d\u4e00\u6837\u8c03\u63a7\u5168\u56fa\u6001\u7535\u6c60\u4e2d\u7684\u7535\u4f4d\uff0c\u5bf9\u6784\u9020\u4e00\u4f53\u5316\u5168\u56fa\u6001\u7535\u6c60\u8fdb\u884c\u521d\u6b65\u7406\u8bba\u63a2\u7d22\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1\uff1a\u8be5\u5de5\u4f5c\u88ab\u8bc4\u4e3a\u70ed\u70b9\u6587\u7ae0\uff0c\u5e76\u88ab\u9009\u4e3a\u5f53\u6708\u671f\u520a\u5916\u5c01\u9762<\/strong><\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u00a0\u00a0\u90d1\u5dde\u5927\u5b66\u90b5\u56fd\u80dc\u7814\u7a76\u56e2\u961f<\/strong>\u5728Journal of Materials Chemistry A\u53d1\u8868\u9898\u4e3a\u201cA theoretical approach to address interfacial\u00a0problems in all-solid-state lithium ion batteries:\u00a0tuning materials chemistry for electrolyte and\u00a0buffer coatings based on Li6<\/sub>PA5<\/sub>Cl hali-chalcogenides\u201d\u7684\u6587\u7ae0\uff0cDOI: 10.1039\/c8ta11151k<\/u>\uff0cJ. Mater. Chem. A, 2019, 7,5239\u3002\u88ab\u8bc4\u4e3a2<\/b><\/strong>019 JMCA<\/b><\/strong>\u70ed\u70b9\u6587\u7ae0\uff0c<\/b><\/strong>2019<\/b><\/strong>\u5e74J<\/b><\/strong>MCA<\/b><\/strong>\u7b2c\u4e03\u671f\u5916\u5c01\u9762\u6587\u7ae0)<\/b><\/strong>\u3002\u5982\u56fe\u4e00\u6240\u793a\uff1a<\/p>\n

\uff08https:\/\/pubs.rsc.org\/en\/content\/articlehtml\/2019\/ta\/c8ta11151k<\/u><\/a>\uff09<\/p>\n

\u672c\u5de5\u4f5c\u57fa\u4e8e\u6750\u6599\u57fa\u56e0\u7ec4\u65b9\u6cd5\uff0c\u901a\u8fc7\u9ad8\u901a\u91cf\u7684\u8ba1\u7b97\u8bbe\u8ba1\uff0c\u9488\u5bf9Li6<\/sub>PS5<\/sub>Cl\u5168\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u6784\u9020\u4e00\u4f53\u5316\u5168\u56fa\u6001\u7535\u6c60\u3002 \u672c\u6587\u91c7\u7528\u7684\u6750\u6599\u57fa\u56e0\u7ec4\u65b9\u6cd5\u5305\u62ec\uff1a\uff081\uff09\u5e73\u8861\u76f8\u56fe\u8ba1\u7b97\uff1b\uff082\uff09USPEX\u9057\u4f20\u7b97\u6cd5\uff1b\uff083\uff09\u57fa\u4e8e\u56e2\u7c07\u5c55\u5f00\u7b97\u6cd5\u4f7f\u7528ATAT\u5bf9\u7535\u538b\u5e73\u53f0\u505a\u51fa\u9884\u4f30\uff1b\uff084\uff09\u5f62\u6210\u80fd\u8ba1\u7b97\uff1b\uff085\uff09\u5409\u5e03\u65af\u81ea\u7531\u80fd\u8ba1\u7b97\uff1a\u9488\u5bf9\u76f8\u5173\u5316\u5408\u7269\uff0c\u505a\u51fa\u80fd\u91cf\u7a33\u5b9a\u6027\u4e0a\u7684\u8bc4\u4f30\uff1b\uff086\uff09\u58f0\u5b50\u8ba1\u7b97\uff1a\u9488\u5bf9\u76f8\u5173\u5316\u5408\u7269\uff0c\u505a\u51fa\u7ed3\u6784\u7a33\u5b9a\u6027\u4e0a\u7684\u8bc4\u4f30\uff1b\uff087\uff09\u540c\u8d28\u8282\u7684\u6784\u9020\uff1b\uff088\uff09\u5206\u5b50\u52a8\u529b\u5b66AIMD\u8ba1\u7b97\uff1a\u5bf9\u4e8e\u76f8\u5173\u5316\u5408\u7269\uff0c\u505a\u51fa\u4f20\u8d28\u80fd\u529b\u7684\u8bc4\u4f30,\u5e76\u5224\u65ad\u5206\u6790\u5316\u5408\u7269\u4e0e\u9502\u7684\u517c\u5bb9\u6027\uff1b<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe2\uff1a\u91c7\u7528AIMD\u5206\u6790Li6<\/sub>PS5<\/sub>Cl\u4e0e\u91d1\u5c5e\u9502\u754c\u9762\u95f4\u7684\u76f8\u5bf9\u7a33\u5b9a\u6027\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u901a\u8fc7AIMD\u8ba1\u7b97\uff0c\u5982\u56fe2\u6240\u793a\uff0c\u4f5c\u8005\u5206\u6790Li6<\/sub>PS5<\/sub>Cl\u4e0e\u91d1\u5c5e\u9502\u754c\u9762\u95f4\u7684\u76f8\u5bf9\u7a33\u5b9a\u6027\u6781\u5dee\uff0c\u5176\u4e2dPS4<\/sub>\u56db\u9762\u4f53\u5fae\u7ed3\u6784\u4e0eLi\u4e0d\u7a33\u5b9a\uff0c\u4f1a\u88ab\u5206\u89e3\u6210Lix<\/sub>P\u548cLi2<\/sub>S\u7b49\u4ea7\u7269\uff0c\u56e0\u6b64Li6<\/sub>PS5<\/sub>Cl\u4e0e\u91d1\u5c5eLi\u4e0d\u7a33\u5b9a\u3002<\/p>\n

\u56fe3\uff1a\u57fa\u4e8e\u56e2\u7c07\u5c55\u5f00\u65b9\u6cd5\uff0c\u91c7\u7528ATAT\uff0c\u8ba1\u7b97Li6<\/sub>PS5<\/sub>Cl\u7684\u7535\u5316\u5b66\u7a97\u53e3\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u5982\u56fe3\u6240\u793a\uff0cLi6<\/sub>PS5<\/sub>Cl\u7684\u7535\u5316\u5b66\u7a97\u53e3\u4e3a1.7~2.19 V\uff0c\u7a97\u53e3\u5bbd\u5ea6\u4ec5\u4e3a0.49 V\u3002\u5f53\u653e\u7535\u5e73\u53f0\u8fbe\u52302.93V\u65f6\uff0c\u5bf9\u5e94\u4e8eS + LiCl + P2<\/sub>Sx<\/sub>\u00a0\u7ed3\u6784\u5982\u56fe3\uff08f\uff09\u6240\u793a\uff0c\u5feb\u79bb\u5b50\u5bfc\u4f53\u7ed3\u6784\u5b8c\u5168\u574d\u584c\u3002\u8be5Li\u8017\u5c3d\u5c42\u7684\u5b58\u5728\u4f1a\u6781\u5927\u7684\u5f71\u54cd\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56e0\u6b64\uff0c\u9488\u5bf9Li6<\/sub>PS5<\/sub>Cl\u7684\u7535\u5316\u5b66\u7a97\u53e3\u7a84\uff0c\u4e0eLi\u548c\u9ad8\u7535\u538b\u6d3b\u6027\u6750\u6599\u4e0d\u517c\u5bb9\u7684\u95ee\u9898\uff0c\u8bbe\u8ba1\u540c\u65cf\u7684\u65b0\u578b\u7f13\u51b2\u5c42\u6750\u6599Li6<\/sub>PO5<\/sub>Cl\u548cLi6<\/sub>PO4<\/sub>SCl\uff0c\u7c7b\u4f3c\u7684\u6210\u5206\u6709\u52a9\u4e8e\u907f\u514d\u5176\u95f4\u526f\u53cd\u5e94\u7684\u53d1\u751f\u3002\u6587\u4e2d\u8be6\u7ec6\u7684\u8bba\u8bc1\u4e86Li6<\/sub>PO5<\/sub>Cl\u548cLi6<\/sub>PO4<\/sub>SCl\u7684\u80fd\u91cf\u7a33\u5b9a\u6027\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\uff0c\u4fdd\u8bc1\u5b9e\u9a8c\u4e0a\u7684\u53ef\u5408\u6210\u6027\u3002\u5982\u56fe4\u30015\u30016\u6240\u793a\u3002\u5176\u4e2dLi6<\/sub>PO5<\/sub>Cl\uff0cLi6<\/sub>PO4<\/sub>SCl\u4e0eLi6<\/sub>PS5<\/sub>Cl\u5177\u6709\u76f8\u540c\u7684\u6676\u4f53\u5bf9\u79f0\u6027\uff0c\u6b64\u5916\uff0cLi6<\/sub>PS5<\/sub>Cl\u4e2d\u4e0d\u7a33\u5b9a\u7684PS4<\/sub>\u5fae\u7ed3\u6784\u88abPO4<\/sub>\u4ee3\u66ff\u3002<\/p>\n

\u56fe4\uff1a<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Li6<\/sub>PO5<\/sub>Cl\u57280K\u4e0b\u7684\u5e73\u8861\u76f8\u56fe\u3002\uff08b\uff09Li6<\/sub>PO5<\/sub>Cl\u00a0\u7684\u7ed3\u6784\u56fe\u3002\uff08c\uff09Li6<\/sub>PO5<\/sub>Cl\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u3002<\/p>\n

\u56fe5\uff1a<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u57fa\u4e8eATAT\u56e2\u7c07\u5c55\u5f00\uff0c\u641c\u7d22\u5728O\/S\u6df7\u5408\u5360\u4f4dLi6<\/sub>PO5<\/sub>(1-x)S5<\/sub>x Cl (0\u2264x\u22641)\u7684\u60c5\u51b5\uff0c\u00a0convex hull \u8fb9\u754c\u4e0a\u7684\u5373\u4e3a\u7a33\u5b9a\u6210\u5206\uff0c \u5982\uff08b\uff09 Li6<\/sub>PO5<\/sub>Cl\uff0c\uff08c\uff09 Li6<\/sub>PO4.335<\/sub>S0.665<\/sub>Cl\uff0c\uff08d\uff09 Li6<\/sub>PO4<\/sub>SCl\uff0c\uff08e\uff09Li6<\/sub>PS5<\/sub>Cl\u3002<\/p>\n

\u56fe6\uff1a\u58f0\u5b50\u5e26\u8ba1\u7b97\uff1a<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Li3<\/sub>PO4<\/sub>\uff1b\uff08b\uff09Li6<\/sub>PO5<\/sub>Cl\uff1b\uff08c\uff09Li6<\/sub>PO4<\/sub>SCl\uff0c\u5176\u4e2d\u9ed1\u8272\u865a\u7ebf\u4ee3\u88680\u00a0THz\u3002<\/strong><\/p>\n

\u6b64\u5916\uff0c\u4ee5Li3<\/sub>PO4<\/sub>\u4f5c\u4e3a\u53c2\u7167\u5bf9\u8c61\uff0c\u5982\u56fe6\u9ed1\u8272\u7bad\u5934\u6240\u793a\uff0c\u53d1\u73b0Li6<\/sub>PO5<\/sub>Cl\u548cLi6<\/sub>PO4<\/sub>SCl\u8f83Li3<\/sub>PO4<\/sub>\u58f0\u5b50\u5e26\u4e0b\u79fb\uff0c\u8868\u660eLi6<\/sub>PO5<\/sub>Cl\u548cLi6<\/sub>PO4<\/sub>SCl\u8f83Li3<\/sub>PO4<\/sub>\u6676\u683c\u66f4\u52a0\u201c\u8f6f\u5316\u201d\uff0cLi\u53d7\u5230\u7684\u675f\u7f1a\u66f4\u5f31\uff0c\u6709\u52a9\u4e8eLi\u7684\u6269\u6563\u3002\u901a\u8fc7AIMD\u8ba1\u7b97\uff0c<\/b><\/strong>\u5982\u56fe7\u6240\u793a\uff0c\u53d1\u73b0\u504f\u5316\u5b66\u8ba1\u91cf\u6bd4Li6.25<\/sub>PO5.25<\/sub>Cl0.75<\/sub>\u7684\u79bb\u5b50\u8f93\u8fd0\u80fd\u529b\u660e\u663e\u4f18\u4e8eLi3<\/sub>PO4<\/sub>\uff1b\u504f\u5316\u5b66\u8ba1\u91cf\u6bd4Li6.25<\/sub>PO4<\/sub>S1.25<\/sub>Cl0.75<\/sub>,\u8868\u73b0\u51fa\u5feb\u79bb\u5b50\u5bfc\u4f53\u7279\u5f81\u3002<\/p>\n

\u56fe7\uff1a AIMD\u5206\u5b50\u52a8\u529b\u5b66\u8ba1\u7b97\uff0c\u9502\u79bb\u5b50\u5728\u4e0d\u540c\u6750\u6599\u4e2d\u7684\u6269\u6563\u7cfb\u6570\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe8: \u91c7\u7528ATAT\uff0c\u5206\u522b\u8ba1\u7b97(a,b) Li6<\/sub>PO4<\/sub>SCl\u548c(c,d)\u00a0Li6<\/sub>PO5<\/sub>Cl\u7684\u7535\u5316\u5b66\u7a97\u53e3\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u65b0\u578b\u79bb\u5b50\u5bfc\u4f53Li6<\/sub>PO4<\/sub>SCl\u4e2dPO4<\/sub>\u57fa\u56e2\u5bf9Li\u7a33\u5b9a\uff0c\u89e3\u51b3\u4e86\u4e0eLi\u7a33\u5b9a\u6027\u7684\u95ee\u9898\u3002\u6b64\u5916\uff0c\u5982\u56fe8\u6240\u793a\uff1a(a,b) Li6<\/sub>PO4<\/sub>SCl\u7684\u7a33\u5b9a\u7535\u5316\u5b66\u7a97\u53e3\u4e3a0\u20142.62 V\u3002(c,d)\u00a0Li6<\/sub>PO5<\/sub>Cl\u7684\u7535\u538b\u5e73\u53f0\uff0c\u5176\u7a33\u5b9a\u7684\u7535\u5316\u5b66\u7a97\u53e3\u5206\u522b\u4e3a0\u20143.49 V\u3002\u53ef\u89c1\uff0c\u65b0\u578b\u7f13\u51b2\u6750\u6599Li6<\/sub>PO4<\/sub>SCl\u548cLi6<\/sub>PO5<\/sub>Cl\u8f83Li6<\/sub>PS5<\/sub>Cl\uff081.7~2.19 V\uff09\u7684\u7535\u5316\u5b66\u7a97\u53e3\u5927\u5927\u63d0\u9ad8\u3002\u5176\u4e2d\u7531\u4e8eLi6<\/sub>PO4<\/sub>SCl\u4f18\u4f18\u5f02\u7684Li\u79bb\u5b50\u8f93\u8fd0\u80fd\u529b\uff0c\u4e0eLi\u7684\u517c\u5bb9\u6027\uff0c\u66f4\u52a0\u6709\u5229\u4e8e\u505a\u4e3a\u91d1\u5c5eLi\u7684\u8868\u9762\u4fee\u9970\u5c42\uff1b\u800cLi6<\/sub>PO5<\/sub>Cl\u5177\u6709\u66f4\u9ad8\u6c27\u5316\u7535\u4f4d\u7279\u5f81\uff0c\u66f4\u52a0\u6709\u5229\u4e8e\u4ee5\u8584\u5c42\u5305\u8986\u5728\u6b63\u6781\u6d3b\u6027\u6750\u6599\u8868\u9762\uff0c\u4f5c\u4e3a\u51cf\u538b\u6750\u6599\u3002<\/p>\n

\u56fe9<\/b><\/u><\/strong><\/u>:<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5168\u56fa\u6001\u4e00\u4f53\u5316\u9502\u79bb\u5b50\u7535\u6c60\u8bbe\u8ba1\u56feLi0.25<\/sub>MnO2<\/sub>|Li6<\/sub>PO5<\/sub>Cl|Li6<\/sub>PO4<\/sub>SCl|Li\u3002\uff08b\uff09\u5168\u56fa\u6001\u7535\u6c60\u4e2d\u5404\u4e2a\u90e8\u5206\u76f8\u5bf9\u5e94\u7684\u7535\u538b\u5e73\u53f0\u53ca\u53ef\u9006\u5bb9\u91cf\u3002\u9634\u5f71\u90e8\u5206\u4ee3\u8868\u7406\u8bba\u8ba1\u7b97\u5f97\u51fa\u7684LMO\u6b63\u6781\u7684\u80fd\u91cf\u5bc6\u5ea6\uff08436.054 mW h g-1<\/sup>\uff09\u3002<\/p>\n

\u00a0\u6b64\u5916\uff0c\u5982\u56fe9\u6240\u793a\uff0c\u9009\u53d6\u5c16\u6676\u77f3\u578bLi0.25<\/sub>MnO2<\/sub>\u00a0\u4e3a\u6b63\u6781\u6750\u6599\uff08\u7535\u538b\u5e73\u53f0\u8303\u56f42.47\u20133.65 V\uff09\uff0cLi6<\/sub>PO5<\/sub>Cl\u4e3a\u6b63\u6781\u6750\u6599\u5305\u8986\u51cf\u538b\u5c420\u20133.49 V\uff0cLi\u79bb\u5b50\u8f93\u8fd0\u5c42 Li6<\/sub>PS5<\/sub>Cl\uff0cLi\u91d1\u5c5e\u8868\u9762\u4fee\u9970\u5c42Li6<\/sub>PO4<\/sub>SCl\uff080\u20132.62 V\uff09\uff0c\u8c03\u63a7\u5168\u56fa\u6001\u7535\u6c60\u4e2d\u7535\u538b\u7535\u4f4d\u8fde\u7eed\u53d8\u5316\uff0c\u6d88\u9664\u76f8\u5e94\u529f\u80fd\u6750\u6599\u7535\u5316\u5b66\u4e0d\u7a33\u5b9a\u7684\u533a\u57df\u3002\u6709\u671b\u7684\u5927\u5e45\u5ea6\u63d0\u5347\u5168\u56fa\u6001\u7684\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5168\u7535\u6c60\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe436.054 mW h g-1<\/sup>\u3002\u6b64\u5916\uff0c\u6240\u9009\u62e9\u6750\u6599\u95f4\u7684\u6676\u683c\u5931\u914d\u5ea6\u6781\u5c0f\uff0c\u6700\u5927\u4ec5\u4ec54.6%\u22646%\uff0c\u6709\u52a9\u4e8e\u6d88\u9664\u5168\u56fa\u6001\u7535\u6c60\u7684\u5185\u90e8\u5e94\u529b\uff0c\u6709\u52a9\u4e8e\u5b9e\u73b0\u5927\u500d\u7387\u5145\u653e\u7535\u3002<\/p>\n

\u56fe10: TOC\uff0c\u4e00\u4f53\u5316\u5168\u56fa\u6001\u7535\u6c60\u521d\u63a2\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u603b\u7ed3\u53ca\u5c55\u671b\u3011<\/b><\/strong><\/p>\n

\u5982\u4e0a\u6240\u8ff0\uff0c\u901a\u8fc7\u6750\u6599\u57fa\u56e0\u7ec4\u65b9\u6cd5\uff0c\u901a\u8fc7\u7cfb\u7edf\u5730\u7406\u8bba\u7814\u7a76\uff0c\u5bf9\u786b\u94f6\u9517\u77ffLi6<\/sub>PS5<\/sub>Cl\u4f53\u7cfb\u4e0e\u91d1\u5c5e\u9502\u7684\u4e0d\u76f8\u5bb9\u6027\u53ca\u5176\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u505a\u4e86\u8be6\u7ec6\u5206\u6790\uff0c\u540c\u65f6\uff0c\u901a\u8fc7\u5bf9Li6<\/sub>PS5<\/sub>Cl\u8fdb\u884c\u6539\u6027\uff0c\u7528O\u6765\u66ff\u4ee3\u5176\u4e2d\u7684\u5168\u90e8\u6216\u90e8\u5206S\u5143\u7d20\uff0c\u8bbe\u8ba1\u51fa\u65b0\u578bLi6<\/sub>PO5<\/sub>Cl\u7f13\u51b2\u5c42\u548c\u7535\u89e3\u8d28\u6750\u6599Li6<\/sub>PO4<\/sub>SCl\u3002\u540c\u65f6\uff0c\u901a\u8fc7\u7406\u8bba\u8bbe\u8ba1\uff0c\u53d1\u73b0Li6<\/sub>PO5<\/sub>Cl\u8fc7\u6e21\u5c42\u7684\u7535\u5316\u5b66\u7a97\u53e3\u80fd\u591f\u4e0e\u6c27\u5316\u7269\u6b63\u6781LMO\u7684\u9ad8\u7535\u538b\u7535\u538b\u5e73\u53f0\u76f8\u5339\u914d\u3002\u9488\u5bf9\u4e0d\u540c\u7684\u7535\u89e3\u8d28\u6750\u6599\u4f53\u7cfb\uff0c\u901a\u8fc7\u6709\u9488\u5bf9\u6027\u5730\u7406\u8bba\u8bbe\u8ba1\u5de5\u4f5c\u80fd\u4e3a\u540e\u7eed\u5b9e\u9a8c\u63d0\u4f9b\u4e86\u5d2d\u65b0\u7684\u7814\u7a76\u601d\u8def\uff0c\u6709\u52a9\u4e8e\u6211\u4eec\u5728\u5b9e\u9a8c\u4e2d\u89e3\u51b3\u8be5\u7c7b\u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u5b58\u5728\u7684\u56fa-\u56fa\u754c\u9762\u95ee\u9898\u3002\u671f\u671b\u80fd\u901a\u8fc7\u5408\u9002\u7684\u529f\u80fd\u6750\u6599\u4f53\u7cfb\uff0c\u80fd\u50cf\u8c03\u63a7\u6c34\u4f4d\u4e00\u6837\uff0c\u8fbe\u5230\u8c03\u63a7\u7535\u4f4d\u7684\u76ee\u7684\uff0c\u540c\u65f6\u6d88\u9664\u7535\u6c60\u4e2d\u5185\u90e8\u5e94\u529b\uff0c\u771f\u6b63\u5b9e\u73b0\u4e00\u4f53\u5316\u7684\u5168\u56fa\u6001\u7535\u6c60\u4f53\u7cfb\u3002<\/p>\n

\u8be5\u8bba\u6587\u7684\u5728\u90d1\u5dde\u5927\u5b66\u5343\u4eba\u6559\u6388\u90b5\u56fd\u80dc\u6307\u5bfc\u4e0b\u5b8c\u6210\uff08\u901a\u8baf\u4f5c\u8005\uff09\uff1b\u90d1\u5dde\u5927\u5b66\uff0c\u5f90\u7ea2\u6770\uff08\u535a\u58eb\u7814\u7a76\u751f\uff09\uff0c\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff1b\u90d1\u5dde\u5927\u5b66\uff0c\u4e8e\u7389\u7136\uff08\u7855\u58eb\u7814\u7a76\u751f\uff09\uff0c\u4e3a\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff1b\u90d1\u5dde\u5927\u5b66\uff0c\u738b\u5353\uff08\u526f\u6559\u6388\uff09\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002\u8be5\u5de5\u4f5c\u5728\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u3001\u90d1\u5dde\u5927\u5b66\u6750\u6599\u5b66\u9662\u3001\u90d1\u5dde\u65b0\u4e16\u7eaa\u6750\u6599\u57fa\u56e0\u7ec4\u5de5\u7a0b\u7814\u7a76\u9662\uff08http:\/\/www.zmgi.net\/\uff09\u8d44\u52a9\u4e0b\u5b8c\u6210\u3002\u611f\u8c22JMCA\u5bf9\u7406\u8bba\u63a2\u7d22\u5de5\u4f5c\u7684\u91cd\u89c6\u3002\u540c\u65f6\uff0c\u8981\u611f\u8c22\u90d1\u5dde\u3001\u8365\u9633\u653f\u5e9c\u5bf9\u6750\u6599\u57fa\u56e0\u9662\u7684\u5927\u529b\u652f\u6301\uff0c\u4f7f\u6211\u4eec\u80fd\u591f\u901a\u8fc7\u6e90\u5934\u521b\u65b0\u3002\u611f\u8c22\u4e94\u821f\u9ad8\u6027\u80fd\u8ba1\u7b97\uff0c\u5bf9\u672c\u8bfe\u9898\u63d0\u4f9b\u7684\u670d\u52a1\u5668\u6280\u672f\u65b9\u9762\u7684\u652f\u6301\u3002<\/p>\n

\u90b5\u56fd\u80dc<\/b><\/strong>\uff0c\u5343\u4eba\u8ba1\u5212\u521b\u65b0A\u7c7b\u6750\u6599\u5b66\u4e13\u5bb6\u3002\u66fe\u4efb\u804c\u82f1\u56fd\u8428\u5229\u5927\u5b66\u8d44\u6df1\u7814\u7a76\u5b98\uff1b\u5e03\u9c81\u5948\u5c14\u5927\u5b66\u6750\u6599\u5b66\u526f\u6559\u6388\uff1b\u82f1\u56fd\u535a\u5c14\u987f\u5927\u5b66\u8ba1\u7b97\u6750\u6599\u5b66\u6559\u6388\u3001\u65b0\u80fd\u6e90\u7814\u7a76\u6240\u6240\u957f\u3001\u5de5\u7a0b\u9662\u9662\u957f\u3001\u7406\u5de5\u53ca\u4f53\u80b2\u5b66\u90e8\u4e3b\u4efb\u7b49\uff1b\u82f1\u56fd\u6750\u6599\u5316\u5b66\u59d4\u5458\u4f1a\u59d4\u5458\u3001\u53ef\u6301\u7eed\u80fd\u6e90\u6750\u6599\u5de5\u4f5c\u7ec4\u6210\u5458\u30022010\u5e74\u5165\u9009\u56fd\u5bb6\u201c\u5343\u4eba\u8ba1\u5212\u201d\uff0c\u670d\u52a1\u4e8e\u90d1\u5dde\u5927\u5b66\uff0c\u521b\u5efa\u4e86\u4e2d\u82f1\u7eb3\u7c73\u591a\u529f\u80fd\u6750\u6599\u7814\u7a76\u4e2d\u5fc3\uff082012\uff09\uff0c\u5e76\u88ab\u8ba4\u5b9a\u4e3a\u6cb3\u5357\u7701\u4f4e\u78b3\u53ca\u73af\u5883\u6750\u6599\u56fd\u9645\u8054\u5408\u5b9e\u9a8c\u5ba4\uff082014\uff0c \u79d1\u6280\u5385\uff09\u3001 \u56fd\u5bb6\u7ea7\u4f4e\u78b3\u53ca\u73af\u4fdd\u6750\u6599\u667a\u80fd\u8bbe\u8ba1\u56fd\u9645\u8054\u5408\u5b9e\u9a8c\u5ba4\uff082015\uff0c \u79d1\u6280\u90e8\uff09\u30022016\u5e74\u4e8e\u201c\u4e2d\u539f\u667a\u8c37\u201d\u521b\u5efa\u90d1\u5dde\u65b0\u4e16\u7eaa\u6750\u6599\u57fa\u56e0\u7ec4\u5de5\u7a0b\u7814\u7a76\u9662\u3002\u521b\u529e\u4e86\u56fd\u9645\u671f\u520a\u300aEnergy & Environmental Materials (EEM)\u300b\uff0c\u7531John Wiley & Sons, Inc\u51fa\u7248\u3002\u7814\u7a76\u96c6\u4e2d\u4e8e\u591a\u5c3a\u5ea6\u6750\u6599\u6a21\u62df\u53ca\u667a\u80fd\u6750\u6599\u8bbe\u8ba1\u3001\u7eb3\u7c73\u53ca\u8584\u819c\u6750\u6599\u5236\u5907\u6280\u672f\u3001\u5148\u8fdb\u6750\u6599\u8868\u5f81\u3001\u65b0\u80fd\u6e90\u53ca\u73af\u5883\u6e05\u6d01\u6750\u6599\u6280\u672f\u7b49\u3002\u53d1\u8868\u5305\u62ec\u300aNature\u300b\u5728\u5185\u7684\u56fd\u9645\u8457\u540d\u671f\u520a\u8bba\u6587200\u4f59\u7bc7\uff0c\u7533\u8bf7\u5e76\u83b7\u5f97\u56fd\u5185\u5916\u4e13\u5229\u591a\u9879\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n

A theoretical approach to address interfacial\u00a0problems in all-solid-state lithium ion batteries:\u00a0tuning materials chemistry for electrolyte and\u00a0buffer coatings based on Li6<\/sub>PA5<\/sub>Cl hali-chalcogenides, Hongjie Xu, Yuran Yu, and Zhuo Wang*<\/sup>, Guosheng Shao*<\/sup>, \u00a0J. Mater. Chem. A, 2019, 7,5239.\u00a0DOI: 10.1039\/c8ta11151k<\/p>\n

https:\/\/pubs.rsc.org\/en\/Content\/ArticleLanding\/2019\/TA\/C8TA11151K#!divAbstract<\/p>\n

\u672c\u6587\u7531\u90d1\u5dde\u5927\u5b66\u90b5\u56fd\u80dc\u7814\u7a76\u56e2\u961f<\/strong>\u4f9b\u7a3f\uff0c<\/b><\/strong>\u6750\u6599\u4eba\u7f16\u8f91\u90e8Alisa\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5168\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u5b89\u5168\u6027\u80fd\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u6291\u5236\u9502\u679d\u6676\u7b49\u7279\u6027\u5f15\u8d77\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u4ee5\u65e0\u673a\u78f7\u786b\u5316\u5408\u7269\u4e3a\u4ee3\u8868\u7684\u56fa\u6001\u7535\u89e3\u8d28(SSE)\u4f53\u7cfb\uff0c\u5982Li10G…<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-169555","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/169555"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=169555"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/169555\/revisions"}],"predecessor-version":[{"id":169624,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/169555\/revisions\/169624"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=169555"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=169555"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=169555"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}