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\u4e09\u3001\u9694\u819c<\/strong><\/p>\n

Prof. Zhenan Bao\u548cYi Cui\u5f3a\u5f3a\u8054\u5408[4]<\/sup>\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u53ef\u6709\u6548\u9632\u6b62\u9502\u7535\u6c60\u8fc7\u70ed\u8d77\u706b\u7684\u65b0\u6280\u672f\uff0c\u4ed6\u4eec\u60f3\u5728\u60c5\u51b5\u4e0d\u53ef\u6536\u62fe\u4e4b\u524d\u5173\u95ed\u7535\u6c60\uff0c\u901a\u8fc7\u5728\u9502\u7535\u6c60\u4e2d\u589e\u52a0\u4e00\u4e2a\u70ed\u654f\u9ad8\u5206\u5b50\u805a\u5408\u7269\u8584\u819c\u201c\u5f00\u5173\u201d\u6750\u6599\uff0c\u5f53\u7535\u6c60\u6e29\u5ea6\u8fc7\u9ad8\u5c31\u4f1a\u8fc5\u901f\u5207\u65ad\u7535\u6c60\u5185\u7535\u8def\uff0c\u4f7f\u4e4b\u964d\u6e29\uff1b\u5f53\u6e29\u5ea6\u964d\u81f3\u6b63\u5e38\uff0c\u8be5\u805a\u5408\u7269\u8584\u819c\u53c8\u80fd\u6062\u590d\u6b63\u5e38\u72b6\u6001\uff0c\u8ba9\u7535\u6c60\u91cd\u65b0\u5de5\u4f5c\uff08\u56fe2\uff09\u3002\u4ed6\u4eec\u5c06\u5177\u6709\u77f3\u58a8\u70ef\u6d82\u5c42\u7684\u954d\u94a0\u7c73\u7c92\u5b50\u5d4c\u5165\u805a\u4e59\u70ef\u6750\u6599\u4e2d\uff0c\u5236\u5907\u51fa\u4e00\u79cd\u8f7b\u8584\u53c8\u5177\u6709\u67d4\u6027\u7684\u5bfc\u7535\u5851\u6599\u8584\uff0c\u7528\u8fd9\u79cd\u805a\u5408\u7269\u819c\u7ec4\u88c5\u6210\u7684\u9502\u7535\u6c60\uff0c\u5728\u6b63\u5e38\u7684\u5de5\u4f5c\u6e29\u5ea6\u4e0b\uff0c\u7535\u6d41\u5f88\u5bb9\u6613\u901a\u8fc7\u8584\u819c\uff0c\u7535\u6c60\u53ef\u4ee5\u6b63\u5e38\u5145\u7535\u548c\u653e\u7535\uff0c\u4f46\u662f\u5f53\u7535\u6c60\u7684\u6e29\u5ea6\u5347\u9ad8\u523070\u2103\u65f6\uff0c\u805a\u4e59\u70ef\u5f00\u59cb\u81a8\u80c0\uff0c\u63a8\u52a8\u954d\u7eb3\u7c73\u7c92\u5b50\u5f7c\u6b64\u5206\u5f00\uff0c\u8fd9\u6837\u9694\u819c\u7684\u5bfc\u7535\u6027\u5728\u77ed\u77ed\u76841s\u4e4b\u5185\u5c31\u4f1a\u964d\u4f4e1000\u4ebf\u500d\uff0c\u7535\u6c60\u4e2d\u7684\u7535\u8377\u79fb\u52a8\u505c\u6b62\uff0c\u4ece\u800c\u4f7f\u7535\u6c60\u7684\u6e29\u5ea6\u4e0b\u964d\u3002\u800c\u4e14\uff0c\u5f53\u6e29\u5ea6\u4f4e\u4e8e\u8fd9\u79cd\u805a\u5408\u726970\u2103\u65f6\uff0c\u8be5\u805a\u5408\u7269\u53ef\u4ee5\u5f88\u5bb9\u6613\u7684\u6062\u590d\u5230\u539f\u6765\u7684\u6784\u578b\uff0c\u5bfc\u7535\u6027\u4e5f\u6062\u590d\u6b63\u5e38\uff0c\u6062\u590d\u7535\u6c60\u529f\u80fd\u3002<\/p>\n

\u56fe2. \u805a\u5408\u7269\u819c\u5728\u9ad8\u6e29\u4e0b\u7684\u5de5\u4f5c\u673a\u7406\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

Prof. Xianluo Hu\u548cYingjie Zhu\u7b49\u4eba[5]<\/sup>\u6210\u529f\u7684\u7814\u53d1\u51fa\u4e00\u79cd\u65b0\u578b\u7f9f\u57fa\u78f7\u7070\u77f3\u8d85\u957f\u7eb3\u7c73\u7ebf\u57fa\u8010\u9ad8\u6e29\u9502\u7535\u6c60\u9694\u819c\uff0c\u8be5\u7535\u6c60\u9694\u819c\u9664\u4e86\u5177\u6709\u67d4\u97e7\u6027\u9ad8\u3001\u529b\u5b66\u5f3a\u5ea6\u597d\u3001\u5b54\u9699\u7387\u9ad8\u3001\u7535\u89e3\u6db2\u6da6\u6e7f\u548c\u5438\u9644\u6027\u80fd\u4f18\u826f\u7684\u7279\u70b9\u5916\uff0c\u66f4\u91cd\u8981\u7684\u662f\u70ed\u7a33\u5b9a\u6027\u9ad8\u3001\u8010\u9ad8\u6e29\u3001\u963b\u71c3\u8010\u706b\uff0c\u5728700\u2103\u7684\u9ad8\u6e29\u4e0b\u4ecd\u53ef\u4fdd\u6301\u5176\u7ed3\u6784\u5b8c\u6574\u6027\u3002\u91c7\u7528\u7f9f\u57fa\u78f7\u7070\u77f3\u8d85\u957f\u7eb3\u7c73\u7ebf\u57fa\u8010\u9ad8\u6e29\u7535\u6c60\u9694\u819c\u7ec4\u88c5\u7684\u7535\u6c60\u5728150\u2103\u9ad8\u6e29\u73af\u5883\u4e2d\u80fd\u591f\u4fdd\u6301\u6b63\u5e38\u5de5\u4f5c\u72b6\u6001\uff0c\u5e76\u70b9\u4eae\u5c0f\u706f\u6ce1\uff0c\u800c\u91c7\u7528PP\u9694\u819c\u7ec4\u88c5\u6210\u7684\u7535\u6c60\u5728150\u2103\u9ad8\u6e29\u4e0b\u5f88\u5feb\u53d1\u751f\u77ed\u8def\uff0c\u53ef\u4ee5\u6709\u6548\u63d0\u9ad8\u9502\u7535\u6c60\u7684\u5de5\u4f5c\u6e29\u5ea6\u548c\u5b89\u5168\u6027\u3002<\/p>\n

\u56db\u3001\u7535\u89e3\u6db2<\/strong><\/p>\n

\u9502\u7535\u6c60\u7535\u89e3\u6db2\u57fa\u672c\u4e0a\u662f\u6709\u673a\u78b3\u9178\u916f\u7c7b\u7269\u8d28\uff0c\u662f\u4e00\u7c7b\u6613\u71c3\u7269\u3002\u5e38\u7528\u7535\u89e3\u8d28\u76d0\u516d\u6c1f\u78f7\u9178\u9502\uff08LiPF6\uff09\u5b58\u5728\u70ed\u5206\u89e3\u653e\u70ed\u53cd\u5e94\u3002\u56e0\u6b64\u63d0\u9ad8\u7535\u89e3\u6db2\u7684\u5b89\u5168\u6027\u5bf9\u52a8\u529b\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5b89\u5168\u6027\u63a7\u5236\u81f3\u5173\u91cd\u8981\u3002LiPF6\u7684\u70ed\u7a33\u5b9a\u6027\u662f\u5f71\u54cd\u7535\u89e3\u6db2\u70ed\u7a33\u5b9a\u7684\u4e3b\u8981\u56e0\u7d20\uff0c\u56e0\u6b64\u76ee\u524d\u4e3b\u8981\u6539\u5584\u65b9\u6cd5\u662f\u91c7\u7528\u70ed\u7a33\u5b9a\u6027\u66f4\u597d\u7684\u9502\u76d0\u3002\u4f46\u7531\u4e8e\u7535\u89e3\u6db2\u672c\u8eab\u5206\u89e3\u7684\u53cd\u5e94\u70ed\u5341\u5206\u5c0f\uff0c\u5bf9\u7535\u6c60\u5b89\u5168\u6027\u80fd\u5f71\u54cd\u5341\u5206\u6709\u9650\u3002\u5bf9\u7535\u6c60\u5b89\u5168\u6027\u5f71\u54cd\u66f4\u5927\u7684\u662f\u5176\u6613\u71c3\u6027\u3002\u964d\u4f4e\u7535\u89e3\u6db2\u53ef\u71c3\u6027\u7684\u9014\u5f84\u4e3b\u8981\u662f\u91c7\u7528\u963b\u71c3\u6dfb\u52a0\u5242\uff0c\u4f46\u662f\u8fd9\u4e9b\u963b\u71c3\u5242\u5f80\u5f80\u4f1a\u5bf9\u9502\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u4ea7\u751f\u4e25\u91cd\u7684\u5f71\u54cd\uff0c\u56e0\u6b64\u96be\u4ee5\u5728\u5b9e\u9645\u4e2d\u5e94\u7528\u3002Hongfa Xiang\u7b49\u4eba[6]<\/sup>\u91c7\u7528\u78f7\u9178\u4e09\u7532\u916f\uff08TMP\uff09\u4e3a\u6eb6\u5242\uff0c\u53cc\u6c1f\u78fa\u9170\u4e9a\u80fa\u9502\u4e3a\u6eb6\u8d28\uff0c\u7814\u53d1\u51fa\u4e00\u79cd\u65b0\u578b\u9ad8\u6d53\u5ea6\u4e0d\u71c3\u7535\u89e3\u6db2\u3002\u5728\u9ad8\u6d53\u5ea6\uff085mol\/L\uff09\u4e0b\uff0c\u7535\u89e3\u6db2\u4e2d\u5927\u90e8\u5206TMP\u6eb6\u5242\u5206\u5b50\u548cLi+\u914d\u4f4d\uff0c\u5f62\u6210\u7279\u6b8a\u7684\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u8fd9\u4f7f\u5f97\u6eb6\u5242\u5206\u5b50\u4e0e\u8d1f\u6781\u4e4b\u95f4\u7684\u526f\u53cd\u5e94\u51cf\u5c11\uff0c\u5927\u5927\u63d0\u9ad8\u4e86\u7535\u6c60\u7684\u5b89\u5168\u6027\u3002\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u5723\u8fed\u6208\u5206\u6821\u7684Yu Qiao\u56e2\u961f[7]<\/sup>\u91c7\u7528\u80f6\u56ca\u5c01\u88c5\u7684\u65b9\u5f0f\u5c06\u963b\u71c3\u5242\u4e8c\u82c4\u80fa\uff08DBA\uff09\u50a8\u5b58\u5728\u5fae\u578b\u80f6\u56ca\u91cc\uff0c\u5206\u6563\u5728\u7535\u89e3\u6db2\u4e2d\uff0c\u6b63\u5e38\u72b6\u6001\u4e0b\u4e0d\u4f1a\u5bf9\u9502\u7535\u6c60\u7684\u6027\u80fd\u4ea7\u751f\u5f71\u54cd\uff0c\u5f53\u7535\u6c60\u53d7\u5230\u6324\u538b\u7b49\u5916\u529b\u7834\u574f\u65f6\uff0c\u80f6\u56ca\u4e2d\u7684\u963b\u71c3\u5242\u5c31\u4f1a\u88ab\u91ca\u653e\u51fa\u6765\uff0c\u201c\u6bd2\u5316\u201d\u7535\u6c60\u4f7f\u7535\u6c60\u5931\u6548\uff0c\u4ece\u800c\u907f\u514d\u70ed\u5931\u63a7\u7684\u53d1\u751f\u3002\u4e4b\u540e\uff0c\u4ed6\u4eec\u56e2\u961f\u53c8\u91c7\u7528\u540c\u6837\u7684\u6280\u672f\uff0c\u5c06\u4e59\u4e8c\u9187\u548c\u4e59\u4e8c\u80fa\u4f5c\u4e3a\u963b\u71c3\u5242\uff0c\u5c01\u88c5\u540e\u88c5\u5165\u9502\u7535\u6c60\uff0c\u80fd\u591f\u663e\u8457\u964d\u4f4e\u9502\u7535\u6c60\u70ed\u5931\u63a7\u7684\u98ce\u9669[8]<\/sup>\u3002Prof. Atsuo Yamada\u7b49\u4eba[9]<\/sup>\u91c7\u7528\u9ad8\u6d53\u5ea6NaN(SO2<\/sub>F)2<\/sub>\u6216\u8005LiN(SO2<\/sub>F)2<\/sub>\u4f5c\u4e3a\u9502\u76d0\uff0c\u6dfb\u52a0\u5e38\u89c1\u7684\u963b\u71c3\u5242\u78f7\u9178\u4e09\u7532\u916fTMP\uff0c\u5236\u5907\u7684\u7535\u89e3\u6db2\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u9502\u7535\u6c60\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u800c\u4e14\u963b\u71c3\u5242\u7684\u6dfb\u52a0\u5e76\u6ca1\u6709\u5bf9\u9502\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u4ea7\u751f\u5f71\u54cd\u3002\u9488\u5bf9\u52a8\u529b\u7535\u6c60\u5728\u4f7f\u7528\u4e2d\u53ef\u80fd\u9762\u4e34\u51b2\u51fb\u7684\u60c5\u51b5\uff0cGabriel M. Veith\u7b49\u4eba[10]<\/sup>\u8bd5\u56fe\u5728\u6839\u6e90\u4e0a\u907f\u514d\u5916\u529b\u5bfc\u81f4\u7684\u9502\u7535\u6c60\u5185\u77ed\u8def\u53d1\u751f\uff0c\u8bbe\u8ba1\u4e86\u4e00\u79cd\u5177\u6709\u526a\u5207\u589e\u7a20\u7279\u6027\u7684\u7535\u89e3\u6db2\uff08\u56fe3\uff09\uff0c\u8be5\u7535\u89e3\u6db2\u5229\u7528\u975e\u725b\u987f\u6d41\u4f53\u7684\u7279\u6027\uff0c\u5728\u6b63\u5e38\u72b6\u6001\u4e0b\uff0c\u7535\u89e3\u6db2\u5448\u73b0\u6db2\u4f53\u72b6\u6001\uff0c\u5728\u906d\u9047\u7a81\u7136\u7684\u51b2\u51fb\u540e\u5219\u4f1a\u5448\u73b0\u56fa\u4f53\u72b6\u6001\uff0c\u53d8\u5f97\u5f02\u5e38\u575a\u56fa\uff0c\u751a\u81f3\u80fd\u591f\u8fbe\u5230\u9632\u5f39\u7684\u6548\u679c\uff0c\u4ece\u800c\u4ece\u6839\u6e90\u4e0a\u907f\u514d\u4e86\u5728\u52a8\u529b\u7535\u6c60\u53d1\u751f\u78b0\u649e\u65f6\u7535\u6c60\u5185\u77ed\u8def\u5bfc\u81f4\u70ed\u5931\u63a7\u7684\u98ce\u9669\u3002<\/p>\n

\u56fe3. \u526a\u5207\u589e\u7a20\u7535\u89e3\u6db2\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u4e94\u3001\u5bfc\u7535\u5242\u4e0e\u7c98\u7ed3\u5242<\/strong><\/p>\n

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\u53c2\u8003\u6587\u732e:<\/strong><\/p>\n

1.Hyejung Kim, Min Gyu Kim, Hu Young Jeong et al.\u00a0A new coating method for alleviating surface degradation of LiNi0.6<\/sub>Co0.2<\/sub>Mn0.2<\/sub>O2<\/sub>\u00a0cathode material: nanoscale surface treatment of primary particles. Nano Letters, 2015, 15:2111-2119.<\/p>\n

2. Hyejung Kim, Sanghan Lee, Hyeon Cho et al. Enhancing Interfacial Bonding between Anisotropically Oriented Grains Using a Glue-Nanofiller for Advanced Li-Ion Battery Cathode.Adv. Mater.<\/i><\/em>,2016,\u00a028:4705-4712.<\/p>\n

3.Heng Li, Long Peng, Dabei Wu et al. Ultrahigh-capacity and fire-resistant LiFePO4-based composite cathodes for advanced lithium-ion batteries. Advanced Energy Materials. 2019, 9:1802930.<\/p>\n

4.Zheng Chen, Po-Chun Hsu, Jeffrey Lopez et al. Fast and reversible thermoresponsive polymer switching materials for safer batteries.\u00a0Nature Energy, 2016,1:15009.<\/p>\n

5.Heng Li, Dabei Wu, Jin Wuet al. Flexible, High-Wettability and Fire-Resistant Separators Based on Hydroxyapatite Nanowires for Advanced Lithium-Ion Batteries. Adv. Mater.<\/i><\/em>,2017,\u00a029:170354.<\/p>\n

6.Pengcheng Shi, Hao Zheng, Xin Liang et al. A highly concentrated phosphate-based electrolyte for high-safety rechargeable lithium batteries. Chem. Commun.<\/i><\/em>,\u00a02018,\u00a054:4453-4456.<\/p>\n

7.Yang Shi, Daniel J. Noelle, Meng Wang et al. Exothermic behaviors of mechanically abused lithium-ion batteries with dibenzylamine, Journal of Power Sources, 2016, 326:514-521.<\/p>\n

8.Daniel J. Noelle, Yang Shi, Meng Wang et al. Aggressive electrolyte poisons and multifunctional fluids comprised of diols and diamines for emergency shutdown of lithium-ion batteries. Journal of Power Sources, 2018, 384:93-97.<\/p>\n

9.Jianhui Wang, Yuki Yamada, Keitaro Sodeyama et al. Fire-extinguishing organic electrolytes for safe batteries. Nature Energy, 2018, 3:22-29.<\/p>\n

10.Gabriel M. Veith, Beth L. Armstrong, Hsin Wang et al. Shear thickening electrolytes for high impact resistant batteries. ACS Energy Lett. <\/i><\/em>2017, 2:2084-2088.<\/p>\n

11.Mi Lu, Yongzhi Mao, Jian Wang et al. Surface heterogeneity in Li0.5<\/sub>CoO2<\/sub>within a porous composite electrode. Chem. Commun.<\/i><\/em>, 2018, 10:1039.<\/p>\n

\u5f80\u671f\u56de\u987e\uff1a<\/strong><\/p>\n

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\u672c\u6587\u7531\u6750\u6599\u4eba\u79d1\u6280\u987e\u95ee\u00a0April\u00a0<\/b>\u4f9b\u7a3f\uff0c<\/b><\/strong>\u6750\u6599\u4eba\u7f16\u8f91\u90e8Alisa\u7f16\u8f91\u3002<\/p>\n

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