{"id":170674,"date":"2019-03-26T11:20:33","date_gmt":"2019-03-26T03:20:33","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=170674"},"modified":"2019-03-27T12:32:43","modified_gmt":"2019-03-27T04:32:43","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e7%89%a9%e7%90%86%e6%89%80energy-storage-materials%e6%9c%89%e5%88%a9%e4%ba%8e%e9%ab%98%e6%b8%a9%e4%b8%8b%e7%a8%b3%e5%ae%9a%e8%bf%90%e8%a1%8c%e7%9a%84%e9%94%82%e9%87%91","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=170674","title":{"rendered":"\u4e2d\u79d1\u9662\u7269\u7406\u6240Energy Storage Materials:\u6709\u5229\u4e8e\u9ad8\u6e29\u4e0b\u7a33\u5b9a\u8fd0\u884c\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u6db2\u6001\u7535\u89e3\u8d28"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u53ef\u5145\u7535\u9502\u91d1\u5c5e\u7535\u6c60\u7531\u4e8e\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u800c\u5f15\u8d77\u5e7f\u6cdb\u5173\u6ce8\u3002\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\uff0c\u7531\u4e8e\u590d\u6742\u7684\u5e94\u7528\u73af\u5883\uff0c\u5728\u5b89\u5168\u6027\u548c\u5faa\u73af\u5bff\u547d\u65b9\u9762\uff0c\u9502\u7535\u6c60\u80fd\u5728\u9ad8\u6e29\u4e0b\u7a33\u5b9a\u8fd0\u884c\u662f\u8d1f\u6781\u4e3a\u91d1\u5c5e\u9502\u6216\u5305\u542b\u91d1\u5c5e\u9502\u7684\u7535\u6c60\u5fc5\u987b\u8981\u89e3\u51b3\u7684\u95ee\u9898\u3002\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0cLIB\u7684\u70ed\u5931\u63a7\u5f80\u5f80\u662f\u7531\u7535\u6c60\u7684\u9ad8\u6e29\u8fd0\u884c\u5f15\u8d77\u3002\u901a\u5e38\uff0c\u5546\u7528LIB\u7684\u8fd0\u884c\u6e29\u5ea6\u5728-20~55\u2103\u7684\u8303\u56f4\u5185\u3002\u9ad8\u4e8e55o<\/sup>C\uff0c\u4e00\u4e9b\u526f\u53cd\u5e94\u7684\u53d1\u751f\u4f7f\u5f97LIB\u7684\u70ed\u5931\u63a7\u98ce\u9669\u589e\u52a0\u3002\u4f8b\u5982\uff0cLiPF6<\/sub>\u572855\u2103\u4ee5\u4e0a\u5f00\u59cb\u5206\u89e3\u4ea7\u6210HF\uff0c\u4e0e\u6b63\u8d1f\u6781\u8868\u9762\u53cd\u5e94\uff0c\u9010\u6e10\u5f15\u8d77\u70ed\u5931\u63a7\u3002\u4e00\u822c\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u7684\u90e8\u5206\u6210\u5206\u572865\u2103\u4ee5\u4e0a\u9010\u6e10\u5f00\u59cb\u5206\u89e3\u3002\u6b64\u5916\uff0c\u78b3\u9178\u4e8c\u7532\u916f\uff08DMC\uff09\uff0c\u78b3\u9178\u4e8c\u4e59\u916f\uff08DEC\uff09\u6216\u78b3\u9178\u7532\u4e59\u916f\uff08EMC\uff09\u7b49\u78b3\u9178\u916f\u6eb6\u5242\u7684\u4f7f\u7528\u4e5f\u4f1a\u7531\u4e8e\u5176\u6325\u53d1\u6027\u548c\u9ad8\u5ea6\u6613\u71c3\u6027\u800c\u5c06\u7535\u6c60\u7684\u8fd0\u884c\u6e29\u5ea6\u9650\u5236\u5728\u4f4e\u4e8e60\u2103\u4e4b\u5185\u3002\u5982\u679cLi\u91d1\u5c5e\u7535\u6c60\u80fd\u591f\u572855\u2103\u4ee5\u4e0a\u7a33\u5b9a\u8fd0\u884c\uff0c\u5b83\u5c06\u6709\u6548\u5730\u964d\u4f4e\u70ed\u5931\u63a7\u98ce\u9669\u5e76\u7b80\u5316\u7535\u6c60\u7684\u70ed\u7ba1\u7406\u3002<\/p>\n

\u3010\u7814\u7a76\u8fdb\u5c55\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u7269\u7406\u6240\u803f\u632f\u535a\u58eb\uff08\u7b2c\u4e00\u4f5c\u8005\uff09\u3001\u674e\u6cd3\u7814\u7a76\u5458\u7b49<\/strong>\uff08\u901a\u8baf\u4f5c\u8005<\/strong>\uff09\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u5c06\u4e24\u79cd\u70ed\u7a33\u5b9a\u6027\u597d\u7684Li\u76d0\uff08\u5373LiTFSI \u548cLiDFOB\uff09\u4e00\u8d77\u52a0\u5165\u5230\u5177\u6709\u9ad8\u6cb8\u70b9\/\u95ea\u70b9EC\u548cPC\u7684\u78b3\u9178\u76d0\u6eb6\u5242\u7684\u65b0\u7535\u89e3\u6db2\u4f53\u7cfb\uff0c\u8fd8\u8fdb\u4e00\u6b65\u6dfb\u52a0\u5c11\u91cfLiPF6<\/sub>\u4ee5\u9632\u6b62\u94dd(Al)\u96c6\u6d41\u4f53\u7684\u8150\u8680\u3002\u7ed3\u679c\u8868\u660e\uff0c\u65b0\u578b\u7535\u89e3\u6db2\u5c55\u793a\u4e86\u8f83\u4e3a\u7a33\u5b9a\u7684\u9ad8\u6e29\u5faa\u73af\u6027\u80fd\uff0c\u8fd9\u79cd\u7535\u89e3\u6db2\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4e5f\u6709\u6548\u6291\u5236\u4e86\u9502\u679d\u6676\u7684\u5f62\u6210\u3002\u57fa\u4e8e\u8fd9\u79cd\u7535\u89e3\u8d28\u7684Li\u91d1\u5c5e\u7535\u6c60\uff08Li\/LiCoO2<\/sub>\uff09\u572880\u2103\u7684\u9ad8\u6e29\u4e0b\u6d4b\u8bd5 \u5faa\u73af100\u6b21\u5bb9\u91cf\u4fdd\u6301\u7387\u8fbe\u523090%\u3002\u6b64\u65b9\u6cd5\u4e3a\u53d1\u5c55\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u6df7\u5408\u56fa\u6db2\u7535\u89e3\u8d28\u6216\u57fa\u4e8e\u539f\u4f4d\u56fa\u6001\u5316\u7684\u5168\u56fa\u6001\u91d1\u5c5e\u9502\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u79cd\u7535\u89e3\u8d28\u7684\u8bbe\u8ba1\u601d\u8def\u3002\u5982\u679c\u672a\u6765\u7684\u7535\u6c60\u80fd\u540c\u65f6\u5728\u4f4e\u6e29\u548c\u9ad8\u6e29\u6b63\u5e38\u5de5\u4f5c\uff0c\u53ef\u4ee5\u6709\u6548\u964d\u4f4e\u7535\u6c60\u70ed\u5931\u63a7\u98ce\u9669\uff0c\u6709\u5229\u4e8e\u53bb\u6389\u76ee\u524d\u5728\u52a8\u529b\u7535\u6c60\u4e2d\u5360\u6709\u8f83\u9ad8\u8d28\u91cf\u548c\u4f53\u79ef\u7684\u6db2\u6001\u51b7\u5374\u7cfb\u7edf\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u201cLithium Metal Batteries Capable of Stable Operation at Elevated Temperature<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Energy Storage Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u7535\u89e3\u6db2\u7684\u7a33\u5b9a\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4f7f\u7528\u4e0d\u540c\u7535\u89e3\u8d28\u7684\u626b\u63cf\u901f\u7387\u4e3a0.1mV\/s\u7684Li\/Al\u7535\u6c60\u7684LSV\u66f2\u7ebf<\/p>\n

\uff08b\uff09\u5177\u67092 Ah\u5bb9\u91cf\uff08\u5145\u7535-\u653e\u7535\u8fc7\u7a0b\u524d\uff09\u7684Li\/LiCoO2<\/sub>\u8f6f\u5305\u7535\u6c60\u7684ARC\u6d4b\u8bd5\u7684\u6e29\u5ea6-\u65f6\u95f4\u66f2\u7ebf\uff0c\u52a0\u70ed\u6e29\u5ea6\u6b65\u957f\u4e3a10\u2103\uff0c\u7136\u540e\u7b49\u5f8530\u5206\u949f\u3002<\/p>\n

\u56fe\u4e8c\u7535\u5316\u5b66\u6027\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09\u5728\uff08a\uff0925\u2103\u548c\uff08b\uff0980\u2103\u4e0b\u4f7f\u75281M LiPF6<\/sub>\u7535\u89e3\u6db2\u7684Li\/LiCoO2<\/sub>\u7535\u6c60\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

\uff08c\uff0cd\uff09\u5728\uff08c\uff0925\u2103\u548c\uff08d\uff0980\u2103\u4e0b\u4f7f\u75280.8M LiTFSI-0.2M LiDFOB-0.01M LiPF6<\/sub>\u7535\u89e3\u6db2\u7684Li\/LiCoO2<\/sub>\u7535\u6c60\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

\uff08e\uff09\u4f7f\u7528\u4e0d\u540c\u7535\u89e3\u6db2\u572880\u2103\u4e0b\u5faa\u73afLi\/LiCoO2<\/sub>\u7535\u6c60\u7684\u6027\u80fd<\/p>\n

\uff08f\uff09\u5177\u67092 Ah\u5bb9\u91cf\uff0870\uff05\u5145\u7535\u72b6\u6001\uff09\u7684Li\/LiCoO2<\/sub>\u8f6f\u5305\u7535\u6c60\u7684ARC\u6d4b\u8bd5\u7684\u6e29\u5ea6 -\u65f6\u95f4\u66f2\u7ebf\uff0c\u52a0\u70ed\u6e29\u5ea6\u6b65\u957f\u4e3a10\u2103\uff0c\u7136\u540e\u7b49\u5f8530\u5206\u949f\u3002<\/p>\n

\u56fe\u4e09\u9502\u91d1\u5c5e\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u5faa\u73af\u540e\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-d\uff09\u9502\u91d1\u5c5e\u5728\u4f7f\u75281M LiPF6<\/sub>\u7535\u89e3\u6db2\u7684Li\u9633\u6781\u7684\u8868\u9762SEM\u56fe\u50cf\u548c\u622a\u9762\u56fe<\/p>\n

\uff08e-h\uff09\u9502\u91d1\u5c5e\u5728\u4f7f\u75280.8M LiTFSI-0.2M LiDFOB-0.01M LiPF6<\/sub>\u7535\u89e3\u6db2\u7684Li\u9633\u6781\u7684\u8868\u9762SEM\u56fe\u50cf\u548c\u622a\u9762\u56fe<\/p>\n

\u56fe\u56db\u534a\u7535\u6c60\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-b\uff09\u9502\u5bf9\u79f0\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

\uff08c-e\uff09\u9502\u8d1f\u6781\u76843DAFM\u56fe\u50cf<\/p>\n

\u56fe\u4e94\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u9502\u91d1\u5c5e\u8868\u9762\u7684<\/strong>SEI<\/strong>\u7684\u6210\u5206\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09\u4f7f\u75281M LiPF6<\/sub>\u7535\u89e3\u6db2\uff0c\u572825\u2103\u4e0b100\u6b21\u5faa\u73af\u540e\u7684Li\u9633\u6781\u7684C 1s\u548c\uff08b\uff09O 1s XPS\u56fe\u50cf<\/p>\n

\uff08c\uff0cd\uff09\u4f7f\u75280.8M LiTFSI-0.2M LiDFOB-0.01M LiPF6<\/sub>\u7535\u89e3\u8d28\uff0c\u572825\u2103\u4e0b100\u6b21\u5faa\u73af\u540e\uff0cLi\u9633\u6781\u7684C 1s\u548c\uff08d\uff09O 1s XPS\u56fe\u50cf<\/p>\n

\uff08c\uff0cd\uff09\u5728Li\u8d1f\u6781\u4e0a\u7684SEI\u7684\u6210\u5206\u53d8\u5316<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u603b\u4e4b\uff0c\u901a\u8fc7\u5229\u7528\u70ed\u7a33\u5b9a\u7684Li\u76d0\uff08\u5373LiTFSI\uff0cLiDFOB\uff09\u548c\u5177\u6709\u9ad8\u6cb8\u70b9\/\u95ea\u70b9\u7684\u6709\u673a\u78b3\u9178\u916f\u6eb6\u5242\uff08\u5373EC\uff0cPC\uff09\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u8010\u9ad8\u6e29\u7535\u89e3\u6db2\u3002\u8fd8\u6dfb\u52a0\u5c11\u91cfLiPF6<\/sub>\u7528\u6765\u9632\u6b62Al\u96c6\u6d41\u4f53\u7684\u8150\u8680\u3002\u7ed3\u679c\u8868\u660e\uff0c\u8fd9\u79cd\u7535\u89e3\u6db2\u5177\u6709\u826f\u597d\u7684\u9ad8\u6e29\u6027\u80fd\uff0c\u540c\u65f6\u8fd8\u80fd\u6709\u6548\u6291\u5236Li\u679d\u6676\u7684\u5f62\u6210\u3002\u57fa\u4e8e0.8M LiTFSI-0.2M LiDFOB-0.01M LiPF6<\/sub>\u7535\u89e3\u6db2\u7684Li\/LiCoO2<\/sub>\u7535\u6c60\u5728\u9ad8\u8fbe80\u2103\u7684\u9ad8\u6e29\u4e0b\u663e\u793a\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\u3002\u57281.2 mA\/cm2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u548c100\u6b21\u5faa\u73af\u540e\uff0c\u5b83\u5177\u670990\uff05\u7684\u9ad8\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u5176\u514b\u670d\u4e86\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5de5\u4f5c\u6e29\u5ea6\u4e0a\u9650\uff08\u537355-60\u2103\uff09\uff0c\u8fd9\u6709\u53ef\u80fd\u964d\u4f4e\u70ed\u5931\u63a7\u98ce\u9669\u5e76\u7b80\u5316Li\u91d1\u5c5e\u7535\u6c60\u7684\u70ed\u7ba1\u7406\u3002\u4e3a\u53ef\u5145\u7535\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u6df7\u5408\u56fa\u6db2\u7535\u89e3\u8d28\u4f53\u7cfb\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u79cd\u6280\u672f\u9009\u62e9\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>\u201cLithium metal batteries capable of stable operation at elevated temperature<\/a>\u201d<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\u4f9b\uff0c\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u674e\u5f18\u7814\u7a76\u5458\u4fee\u6b63\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip \u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u53ef\u5145\u7535\u9502\u91d1\u5c5e\u7535\u6c60\u7531\u4e8e\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u800c\u5f15\u8d77\u5e7f\u6cdb\u5173\u6ce8\u3002\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\uff0c\u7531\u4e8e\u590d\u6742\u7684\u5e94\u7528\u73af\u5883\uff0c\u5728\u5b89\u5168\u6027\u548c\u5faa\u73af\u5bff\u547d\u65b9\u9762\uff0c\u9502\u7535\u6c60\u80fd\u5728\u9ad8\u6e29\u4e0b\u7a33\u5b9a\u8fd0\u884c\u662f\u8d1f\u6781\u4e3a\u91d1\u5c5e\u9502\u6216\u5305…<\/p>\n","protected":false},"author":7084,"featured_media":170680,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[129],"class_list":["post-170674","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-battery"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/170674"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7084"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=170674"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/170674\/revisions"}],"predecessor-version":[{"id":171118,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/170674\/revisions\/171118"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/170680"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=170674"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=170674"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=170674"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}