{"id":171240,"date":"2019-04-03T06:30:27","date_gmt":"2019-04-02T22:30:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=171240"},"modified":"2019-04-26T14:24:05","modified_gmt":"2019-04-26T06:24:05","slug":"%e5%8f%98%e5%bd%a2%e8%ae%b0%ef%bc%9a%e5%a6%82%e4%bd%95%e6%9e%84%e5%bb%bamof%e7%9a%84%e5%85%ab%e9%9d%a2%e7%8e%b2%e7%8f%91%e5%bf%83","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=171240","title":{"rendered":"\u53d8\u5f62\u8bb0\uff1a\u5982\u4f55\u6784\u5efaMOF\u7684\u516b\u9762\u73b2\u73d1\u5fc3"},"content":{"rendered":"

\u3010\u5f15\u8bed\u3011<\/strong><\/p>\n

MOF\u4e13\u680f\uff1a\u4e0d\u5b9a\u671f\u68b3\u7406\u603b\u7ed3MOF\u76f8\u5173\u77e5\u8bc6\u5185\u5bb9<\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u8bde\u751f\u4e8e\u4e0a\u4e16\u7eaa 90 \u5e74\u4ee3 \uff0c\u8fd9\u79cd\u5177\u6709\u5468\u671f\u6027\u7f51\u7edc\u7ed3\u6784\u7684\u6676\u4f53\u6750\u6599\u3002\u5728\u5438\u9644\u3001\u5206\u79bb\u3001\u50ac\u5316\u3001\u836f\u7269\u4f20\u8f93\u53ca\u542b\u80fd\u6750\u6599\u7b49\u65b9\u9762\u5747\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u5df2\u6210\u4e3a\u65b0\u6750\u6599\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u4e0e\u524d\u6cbf\u3002\u7136\u800c\u4eba\u5de5\u5408\u6210\u7684\u6750\u6599\u901a\u5e38\u7531\u79cd\u7c7b\u8f83\u5c11\u7684\u7ed3\u6784\u57fa\u5143\u6784\u5efa\u800c\u6210\uff0c\u56e0\u6b64\u5176\u7ec4\u6210\u548c\u7ed3\u6784\u8f83\u4e3a\u7b80\u5355\u3002\u4e3a\u4e86\u83b7\u53d6\u7c7b\u4f3c\u4e8e\u751f\u7269\u6750\u6599\u7684\u529f\u80fd\u6027\uff0c\u7814\u7a76\u4eba\u5458\u8bd5\u56fe\u63d0\u5347MOF\u7684\u7ed3\u6784\u57fa\u5143\u6570\u76ee\u3002\u8fd1\u671f\uff0c\u590d\u65e6\u5927\u5b66\u674e\u5de7\u4f1f\u6559\u6388\u548c\u6885\u897f\u5927\u5b66\u7684Shane Telfer\u6559\u6388\u63d0\u51fa\u4e86\u5168\u65b0\u7684\u8282\u70b9\u7ed3\u6784\u7b56\u7565\u62a5\u9053\u4e86\u542b\u4e94\u79cd\u57fa\u5143\u7684MOF\u6750\u6599\u3002<\/p>\n

\u968f\u7740\u57fa\u5143\u6570\u76ee\u7684\u589e\u52a0\uff0c\u5f97\u5230\u542b\u591a\u7ec4\u5206\u7684\u5355\u6676\u6750\u6599\u7684\u96be\u5ea6\u5448\u6307\u6570\u7ea7\u589e\u957f\uff0c\u8fd9\u9700\u8981\u901a\u8fc7\u591a\u79cd\u914d\u4f4d\u4f5c\u7528\u7684\u534f\u540c\uff0c\u7cbe\u51c6\u8bbe\u8ba1\u591a\u79cd\u7ed3\u6784\u57fa\u5143\u7b49\u7b49\u5f97\u5230\u591a\u7ec4\u5206\u7f51\u7edc\u7ed3\u6784\uff0c\u8fd9\u663e\u7136\u5177\u6709\u6311\u6218\u6027\u3002<\/p>\n

\u4e0b\u9762\u5c0f\u7f16\u7ed9\u5927\u5bb6\u68b3\u7406\u4e00\u4e0bMOFs\u4ece\u4e8c\u57fa\u5143\u5230\u4e94\u57fa\u5143\u6784\u5efa\u7684\u6f14\u53d8\u8fc7\u7a0b\uff0c\u4e00\u8d77\u6765\u5b66\u4e60\u4e00\u4e0b\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u5947\u601d\u5999\u60f3\u3002<\/p>\n

\u4e00\u3001\u6784\u5efa\u4e8c\u57fa\u5143MOF\u7ed3\u6784<\/strong><\/p>\n

\u4e8c\u57fa\u5143\u6784\u9020\u7684MOF\u7ed3\u6784\u662f\u6700\u4e3a\u5e38\u89c1\u7684\u57fa\u672c\u6784\u578b\uff0cYaghi\u6559\u6388\u8bfe\u9898\u7ec4\u65e9\u57281995\u5e74\u62a5\u9053\u4e86\u76f8\u5173\u5de5\u4f5c\u3002\u4ece\u4f7f\u7528\u4e8c\u4ef7\u94dc\u79bb\u5b50\u548c4,4′-\u8054\u5421\u5576\u5408\u6210\u4e86\u91d1\u521a\u70f7\u578b\u7684\u7f51\u72b6\u7ed3\u6784MOF-11<\/sup>\uff0c\u62d3\u6251\u5448ths\u578b\uff0c\u63d0\u51fa\u5229\u7528\u5206\u5b50\u57fa\u672c\u7ec4\u4ef6\u6216\u6b21\u7ea7\u57fa\u672c\u7ec4\u4ef6\uff08Secondary Building Block\uff0cSBU\uff09\u6765\u6784\u7b51MOF\u7ed3\u6784\u3002\u5230\u5176\u4e2d\u6700\u51fa\u540d\u7684MOF-52<\/sup>\uff0c\u6765\u81ea\u4ed6\u4eec1999\u5e74\u53d1\u8868\u5728Nature \u4e0a\u7684\u6587\u7ae0\u3002\u8fd9\u4e2a\u7ed3\u6784\u4f7f\u7528\u4e86\u950c\u79bb\u5b50\u548c1,4-\u5bf9\u82ef\u4e8c\u7532\u9178\uff0cSBU\u53d8\u6210\u4e86\u56db\u6838\u950c\u6b63\u7acb\u65b9\u4f53\u578b\u914d\u4f4d\uff0c\u62d3\u6251\u5448pcu\u578b\u3002\u8be5\u7ed3\u6784\u5bf9\u6c14\u4f53\u548c\u6709\u673a\u5206\u5b50\u8868\u73b0\u51fa\u5f88\u597d\u7684\u5438\u9644\u80fd\u529b\uff0c\u6bd4\u8868\u9762\u79ef\u8fbe2,900 m2<\/sup>\u00a0g-1<\/sup>\u3002\u5728\u6b64\u540e\u7684\u7814\u7a76\u4e2d\uff0cYaghi\u6559\u6388\u62a5\u5bfc\u4e86MOF-1773<\/sup>\uff0c\u8fd9\u4e2a\u7ed3\u6784\u540c\u6837\u4f7f\u7528\u4e86\u56db\u6838\u950c\u6b63\u56db\u9762\u4f53\u578b\uff0c\u4f46\u6709\u673a\u914d\u4f53\u6539\u6210\u4e861,3,5-\u4e09(4-\u7fa7\u57fa\u82ef\u57fa)\u82ef\uff08BTB\uff09\uff0c\u6784\u6210\u4e86\u4e00\u4e2a\u4e09\u7ef4\u6846\u67b6\u7ed3\u6784\uff0c\u62d3\u6251\u5448pyr\u578b\u3002\u6bd4\u8868\u9762\u79ef\u8fbe\u52304,500 m2<\/sup>\u00a0g-1<\/sup>\u3002\u5e76\u4e14\u901a\u8fc7\u5728BTB\u4e0a\u4fee\u9970\u4e0d\u540c\u57fa\u56e2\uff0c\u5c06\u4e2a\u6027\u5316\u529f\u80fd\u5408\u5e76\u5728MOF-177\u4e0a\uff0c\u6784\u5efa\u4e86MTV-MOFs(\u591a\u53d8\u91cfMOF)\u3002\u53e6\u5916\uff0cZIF-84<\/sup>\u4f5c\u4e3aZIFs\u6709\u4ee3\u8868\u6027\u7684\u4e00\u79cd\u9aa8\u67b6\u7ed3\u6784\u662f\u7531\u91d1\u5c5e\u950c\u79bb\u5b50\u4e0e\u7532\u57fa\u54aa\u5511\u4e2d\u7684N\u539f\u5b50\u76f8\u8fde\u5f62\u6210\u7684ZnN4<\/sub>\u56db\u9762\u4f53\u7ed3\u6784\u5355\u5143\u6784\u6210\u3002\u5177\u6709\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u5178\u578b\u7684\u5c0f\u5b54\u5f84\u5927\u5b54\u7b3c\u7279\u5f81\u3002\u7531\u4e8e\u4e8c\u57fa\u5143\u6784\u5efa\u7684MOFs\u6bd4\u8f83\u5e38\u89c1\uff0c\u4e0d\u518d\u8be6\u7ec6\u4ecb\u7ecd\u3002<\/p>\n

\u4e8c\u3001\u6784\u5efa\u4e09\u57fa\u5143MOF\u7ed3\u6784<\/strong><\/p>\n

\u4e09\u57fa\u5143\u6784\u9020\u7684MOFs\u4e0e\u4e8c\u57fa\u5143MOFs\u6bd4\u8f83\u6765\u8bf4\u7a0d\u5fae\u590d\u6742\u4e00\u70b9\uff0c\u8981\u8003\u8651\u5230\u914d\u4f53\u95f4\u7684\u534f\u8c03\u53ca\u4e0e\u4e2d\u5fc3\u539f\u5b50\u7684\u6784\u5efa\u95ee\u9898\uff0c\u901a\u5e38\u53ef\u4ee5\u662f\u540c\u91d1\u5c5e\u914d\u4e24\u4e2a\u6709\u673a\u5355\u5143\uff0c\u5f02\u91d1\u5c5e\u914d\u4e00\u4e2a\u6709\u673a\u5355\u5143\u3002<\/p>\n

\u7f8e\u56fd\u5bc6\u897f\u6839\u5927\u5b66Matzger \u6559\u6388\uff0c\u5229\u7528thieno[3,2-b]thiophene-2,5-dicarboxylate (T2DC) \u548cBTB\u4e0e\u950c\u7684\u914d\u4f4d\u4f5c\u7528\u4ea7\u751f\u4e86\u4e00\u79cd\u5177\u6709\u5fae\u5b54\u548c\u4e2d\u5b54\u7b3c\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599UMCM-25<\/sup>(\u5982\u56fe1)\u3002UMCM-2\u7684N2<\/sub>\u5438\u6536\u7387\u548c\u6bd4\u8868\u9762\u79ef\u5747\u8d85\u8fc7\u4e86\u7eaf\u8fde\u63a5\u5242\u7684\u5438\u6536\u7387\u548c\u6bd4\u8868\u9762\u79ef\uff0c\u8868\u660e\u5176\u914d\u4f4d\u5171\u805a\u5177\u6709\u975e\u5e38\u5149\u660e\u7684\u524d\u666f\u3002<\/p>\n

\u56fe1<\/p>\n

\"\" \u00a0\u00a0\u00a0<\/p>\n

\u00a0(a) 2\u4e2aZn4<\/sub>O\u7c07\u4e0e3\u4e2aT2DC\u548c8\u4e2aBTB\u534f\u8c03\u94fe\u63a5\u3002(b)\u6cbfc\u8f74\u89c2\u5bdfUMCM-2\u7684\u7ed3\u6784\u3002<\/p>\n

Yaghi\u6559\u63882010\u5e74\u62a5\u9053\u4e86\u4e00\u7cfb\u5217MOFs\u7684\u6210\u5458\u663e\u793a\u51fa\u5f02\u5e38\u7684\u5b54\u9699\u5ea6\u548c\u6c14\u4f53(\u6c22\u3001\u7532\u70f7\u548c\u4e8c\u6c27\u5316\u78b3)\u7684\u5438\u6536\u80fd\u529b\uff0c\u5176\u4e2dMOF-205 \u548cMOF-210\u4e3aZn4<\/sub>O(CO2<\/sub>)6<\/sub>\u5355\u5143\u4e0e\u4e24\u79cd\u6709\u673a\u5355\u5143\u8fde\u63a5\uff08\u5982\u56fe2\uff09\u30026<\/sup><\/p>\n

\u56fe2\u00a0MOF-205 \u548cMOF-210\u7a7a\u95f4\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

2014\u5e74\u5fb7\u56fd\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66stefan.kaskel\u6559\u6388\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u4ecb\u5b54MOF (DUT-32)7<\/sup>\uff0c\u542b\u7ebf\u6027\u53cc\u5149\u5b50\u914d\u4f53bpdc2-<\/sup>(4,4′-biphenylenedicarboxylic acid)\u548cbtctb3-<\/sup>(4,4′,4”-[benzene-1,3,5-triyltris(carbonylimino)]tris-benzoate)\uff08\u5982\u56fe3\uff09\u3002\u9ad8\u5b54\u9699\u5ea6\u56fa\u4f53\u7684\u603b\u5b54\u9699\u4f53\u79ef\u4e3a3.16 cm3<\/sup>\u00a0g-1<\/sup>\uff0c\u6bd4\u8868\u9762\u79ef\u4e3a6411 m2<\/sup>\u00a0g-1<\/sup>\uff0c\u5c06\u8be5\u5316\u5408\u7269\u6dfb\u52a0\u5230BET\u8868\u9762\u79ef\u6700\u9ad8\u7684\u5341\u5927\u591a\u5b54\u6750\u6599\u4e2d\u3002\u4ee5\u4e0a\u4f8b\u5b50\u4e3a\u540c\u91d1\u5c5e\u578b\u4e09\u57fa\u5143MOFs\uff0c\u53ef\u4ee5\u53d1\u73b0\u6676\u4f53\u7ed3\u6784\u4e2d\u591a\u5b58\u5728\u950c\u7684\u56db\u9762\u4f53\u56e2\u7c07[ Zn40(C02)6]\u3002\u53ef\u4ee5\u770b\u51fa\u6709\u673a\u914d\u4f53\u4ece\u5421\u5576\u8f6c\u4e3a\u7fa7\u9178\u66f4\u5177\u6709\u5f3a\u7684\u914d\u4f4d\u80fd\u529b\u548c\u7a7a\u95f4\u6548\u5e94\u3002<\/p>\n

\u56fe3\u00a0DUT-32\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

\u6742\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5177\u6709\u66f4\u5927\u7684\u6210\u5206\u548c\u7ed3\u6784\u591a\u6837\u6027\u6f5c\u529b\uff0c2016\u5e74\u52a0\u5dde\u5927\u5b66\u6cb3\u6ee8\u5206\u6821\u51af\u5e73\u4e91\u6559\u6388\u901a\u8fc7\u5c06\u4e09\u4ef7\u548c\u4e8c\u4ef7\u91d1\u5c5e\u79bb\u5b50\u4e0e3,3\u2032,5,5\u2032-azobenzenetetracarboxylic acid (H4ABTC)\u7ec4\u5408\u5f97\u5230\u4e00\u7cfb\u5217\u5177\u6709\u8f83\u5f3aCO2<\/sub>\u5438\u6536\u80fd\u529b\u7684\u65b0MOFs(CPM-200s)8<\/sup>\uff08\u5982\u56fe4\uff09\uff0c\u5728273k\u548c1bar\u65f6\u5438\u6536\u80fd\u529b\u53ef\u8fbe207.6 cm3<\/sup>\/g\u3002CPM200s\u5bb6\u65cf\u7684\u4e00\u4e9b\u6210\u5458\u7531\u91d1\u5c5e\u79bb\u5b50(\u5982Mg\/Ga\u3001Mg\/Fe\u3001Mg\/V\u3001Mg\/Sc)\u7ec4\u5408\u800c\u6210\uff0c\u8fd9\u4e9b\u91d1\u5c5e\u79bb\u5b50\u4ece\u672a\u5728\u4efb\u4f55\u5df2\u77e5\u7684\u6676\u4f53\u591a\u5b54\u6750\u6599\u4e2d\u5171\u5b58\u8fc7\u3002<\/p>\n

\u56fe4\u00a0M2+<\/sup>\u548cM3+<\/sup>\u7ec4\u5408\u7528\u4e8eCPM-200s<\/p>\n

\"\"<\/p>\n

\u8fd1\u671f\uff0c\u5357\u5f00\u5927\u5b66\u8d75\u658c\u6559\u6388\u3001\u6e05\u534e\u5927\u5b66\u80e1\u61be\u77f3\u526f\u6559\u6388\u548c\u82f1\u56fd\u66fc\u5f7b\u65af\u7279\u5927\u5b66Kaltsoyannis\u6559\u6388\u5408\u4f5c\u5f97\u5230\u9996\u4f8b\u57fa\u4e8e\u8fc7\u6e21\u91d1\u5c5e\/\u948d\u7684\u5f02\u91d1\u5c5eMOF\uff0c\u53ef\u7528\u4e8e\u653e\u5c04\u6027\u7269\u8d28\u7684\u5bcc\u96c69<\/sup>\u3002\u8fc7\u6e21\u91d1\u5c5e\u954d\u548c\u4f4e\u653e\u5c04\u6027\u5143\u7d20\u948d\u5728\u5c0f\u5206\u5b50\u5f02\u70df\u9178\u914d\u4f53\u7684\u6865\u8fde\u4f5c\u7528\u4e0b\uff0c\u901a\u8fc7\u6eb6\u5242\u70ed\u81ea\u7ec4\u88c5\u83b7\u5f97\u4e86\u5177\u6709\u7eb3\u7c73\u7b3c\u72b6\u7ed3\u6784\u7684\u4e09\u57fa\u5143MOFs\uff08\u5982\u56fe5\uff09\u3002\u5bf9\u653e\u5c04\u6027\u9ad8\u951d\u9178\u6839\u6a21\u62df\u7269\u9ad8\u94fc\u9178\u6839\u5438\u9644\u7814\u7a76\u8868\u660e\uff0c1g\u8be5\u6750\u6599\u53ef\u5438\u9644807 mg\u9ad8\u94fc\u9178\u6839\uff0c\u8868\u660e\u8be5MOF\u5bf9\u653e\u5c04\u6027\u7269\u8d28\u5177\u6709\u51fa\u8272\u7684\u5bcc\u96c6\u4f5c\u7528\u3002<\/p>\n

\u56fe5\u00a0[Th48Ni6<\/sub>]\u7eb3\u7c73\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u6784\u5efa\u56db\u57fa\u5143MOF\u7ed3\u6784<\/strong><\/p>\n

\u4ece\u56db\u57fa\u5143MOF\u7684\u6784\u5efa\u5f00\u59cb\uff0c\u6676\u4f53\u5206\u5b50\u7ed3\u6784\u7684\u8bbe\u8ba1\u624d\u663e\u5f97\u66f4\u5177\u6709\u6311\u6218\u6027\u3002\u4e00\u79cd\u7efc\u5408\u7b56\u7565\u662f\u5f15\u5165\u201c\u987a\u5e8f\u5185\u7684\u5f02\u6784\u4f53\u201d\uff0c\u00a0\u901a\u8fc7\u5bf9\u4e0d\u540c\u914d\u4f53\u7684\u9ad8\u4fdd\u771f\u5206\u7c7b\u548c\u6392\u5217\uff0c\u5e76\u5c06\u5b83\u4eec\u7684\u53d6\u4ee3\u6a21\u5f0f\u4e0e\u7a7a\u95f4\u7fa4\u5bf9\u79f0\u6027\u4ed4\u7ec6\u5339\u914d\uff0c\u4ece\u800c\u8fbe\u5230\u89c4\u5f8b\u6027\u548c\u5468\u671f\u6027\uff0c\u4ee5\u51cf\u8f7b\u6676\u4f53\u5b66\u548c\u4f4d\u7f6e\u65e0\u5e8f\u3002\u914d\u4f53\u88ab\u9ad8\u5ea6\u8bbe\u8ba1\u5c06\u4e0d\u540c\u62d3\u6251\u6784\u578b\u548c\u4e0d\u540c\u94fe\u63a5\u5408\u5e76\u5230\u4e00\u4e2a\u6846\u67b6\u4e2d\u3002\u53e6\u4e00\u79cd\u5b9e\u73b0\u66f4\u9ad8\u7a0b\u5ea6MOFs\u529f\u80fd\u7684\u7b56\u7565\u662f\u5728\u6676\u683c\u7684\u7cbe\u786e\u4f4d\u7f6e\u653e\u7f6e\u591a\u4e2a\u62d3\u6251\u4e0d\u540c\u7684\u94fe\u63a5\u6784\u5efaMTV-MOFs\u3002<\/p>\n

2013\u5e74\u6885\u897f\u5927\u5b66Telfer\u6559\u6388\u63d0\u51fa\u4e86\u4e00\u79cd\u7b56\u7565\uff0c\u4f7f\u7528\u4e86\u4e00\u4e2a\u7531\u4e09\u4e2a\u4e0d\u540c\u62d3\u6251\u7ed3\u6784\u7684\u914d\u4f53\u7ec4\u6210\u7684\u56e2\u7c07\u6765\u7f16\u7801\u4e00\u4e2a\u9ad8\u5ea6\u591a\u5b54\u7684\u56db\u5143MOF\u7684\uff08MUF-7\uff0910<\/sup>\uff0c\u4e3a\u4e86\u514b\u670d\u968f\u673a\u548c\u65e0\u5e8f\uff0c\u914d\u4f53\u7684\u66ff\u4ee3\u6a21\u5f0f\u88ab\u8bbe\u8ba1\u6210\u4e0e\u5176\u6676\u4f53\u5b66\u4f4d\u7f6e\u5bf9\u79f0\u6027\u76f8\u517c\u5bb9\uff08\u5982\u56fe6\u4e0a\uff09\u3002\u5728\u8fd9\u4e9b\u4f8b\u5b50\u4e2d\uff0c\u975e\u5e38\u89c4\u7684\u4e8c\u6c27\u5316\u78b3\u5438\u9644\u8d8b\u52bf\uff0c\u5305\u62ec\u63a5\u8fd1100%\u7684\u529f\u80fd\u63d0\u5347\uff0c\u90fd\u6765\u81ea\u534f\u540c\u6548\u5e94\u3002\u968f\u540eTelfer \u4f7f\u7528\u7ed3\u6784\u4e0d\u540c\u7684\u914d\u4f53\u7684\u7ec4\u5408\uff0c\u4ea7\u751f\u4e00\u4e2a\u65b0\u7cfb\u5217\u6709\u5e8f\u7684\u56db\u6838\u950c\u6b63\u7acb\u65b9\u4f53\u578b MOF\uff08MUF-77\uff0911<\/sup>\uff0c\u4ee5\u56db\u57fa\u5143MUF-77\u4e3a\u6bcd\u4f53\uff0c\u5728\u5176\u914d\u4f53\u4e0a\u6dfb\u52a0\u70f7\u57fa\u57fa\u56e2\uff0c\u7cfb\u7edf\u7684\u914d\u4f53\u8c03\u5236\u5bfc\u81f4\u4e86\u4e00\u7cfb\u5217\u5bf9\u6c34\u84b8\u6c14\u5177\u6709\u5f02\u5e38\u9ad8\u7a33\u5b9a\u6027\u7684\u6846\u67b6\u7684\u8bc6\u522b\uff08\u5982\u56fe6\u4e0b\uff09\u3002\u5b54\u9699\u4f53\u79ef\u548c\u5f62\u8c8c\u7684\u7cfb\u7edf\u53d8\u5316\u5f71\u54cdCO2<\/sub>\u548cCH4<\/sub>\u6c14\u4f53\u7684\u5438\u9644\u884c\u4e3a\u3002\u4e0e\u6bcd\u4f53\u76f8\u6bd4\uff0c\u67d0\u4e9b\u6750\u6599\u7684\u5438\u9644\u80fd\u529b\u589e\u52a0\u4e86237% (CO2<\/sub>)\u548c172% (CH4<\/sub>)\u3002<\/p>\n

\u56fe6\u00a0\u5408\u6210MUF-7a\u3001MUF-77a\u7684\u5408\u6210\u8def\u7ebf\u53ca\u4e09\u7ef4\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

2014\u5e74\u7f8e\u56fd\u5bc6\u897f\u6839\u5927\u5b66Matzger \u6559\u6388\u62a5\u9053\u4e86\u7531\u4e09\u79cd\u4e0d\u540c\u7684\u7fa7\u9178\u916f\u8fde\u63a5\u7269\u7ec4\u6210\u7684MOF\uff08UMCM-12\uff0912<\/sup>\uff08\u5982\u56fe7\uff09\u3002\u8be5\u6750\u6599\u540c\u6837\u5177\u6709\u9ad8\u7684\u8868\u9762\u79ef\u548c\u5b54\u9699\u4f53\u79ef\uff0c\u5f3a\u8c03\u4e86\u5408\u6210\u57fa\u4e8e\u6df7\u5408\u94fe\u63a5\u7b56\u7565\u7684MOFs\u7684\u6709\u7528\u6027\u3002<\/p>\n

\u56fe7\u00a0UMCM-12\u7684\u5408\u6210\u53ca\u6676\u4f53\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

2017\u5e74iChEM\u7814\u7a76\u4eba\u5458\u3001\u590d\u65e6\u5927\u5b66\u674e\u5de7\u4f1f\u6559\u6388\u8bfe\u9898\u7ec4\u91c7\u7528\u5177\u6709\u914d\u4f53\u4e24\u7aef\u4e24\u79cd\u914d\u4f4d\u4f4d\u70b9\u4e0e\u4e0d\u540c\u91d1\u5c5e\u7684\u914d\u4f4d\u9009\u62e9\u7279\u6027\uff0c\u5408\u6210\u4e86\u4e24\u79cd\u5177\u6709\u65b0\u578b\u62d3\u6251\u7684\u4ecb\u5b54\u6846\u67b6\u6750\u6599FDM-6,FDM-713<\/sup>\uff1b\u5e76\u5728\u6709\u673a\u914d\u4f53\u4e0e\u91d1\u5c5e\u5316\u914d\u4f53\u5171\u5b58\u7684\u4f53\u7cfb\u4e2d\uff0c\u5236\u5907\u5177\u6709\u56db\u79cd\u57fa\u5143\u6709\u5e8f\u5206\u5e03\u7684MOF\u6750\u6599\uff08\u5982\u56fe8\uff09\u3002\u94dc\u4f4d\u70b9\u53ef\u5b9e\u73b0\u5728Cu(I)\u548cCu(II)\u95f4\u7684\u53ef\u9006\u8f6c\u53d8\uff0c\u591a\u5b54\u6750\u6599\u5728CO\u7684\u6c27\u5316\u3001H2<\/sub>O2<\/sub>\u7684\u5206\u89e3\u4ee5\u53ca\u82b3\u9999\u9187\u7684\u6c27\u5316\u53cd\u5e94\u4e2d\u663e\u793a\u51fa\u826f\u597d\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\u56fe8\u00a0FDM-6,7\u6676\u4f53\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

\u56db\u3001\u6784\u5efa\u4e94\u57fa\u5143MOF\u7ed3\u6784<\/strong><\/p>\n

\u5728\u5408\u6210\u4e94\u57fa\u5143(\u53ca\u66f4\u9ad8\u9636)MOFs\u8fc7\u7a0b\u4e2d\u9047\u5230\u7684\u4e00\u4e2a\u96be\u9898\u662f\u5efa\u7acb\u4e00\u7ec4\u76f8\u4e92\u517c\u5bb9\u7684\u8fde\u63a5\u4f53\uff0c\u4ee5\u4fbf\u5c06\u5176\u5305\u542b\u5728\u6676\u683c\u4e2d\u3002\u867d\u7136\u8fd8\u6ca1\u6709\u51fa\u73b0\u660e\u786e\u7684\u8bbe\u8ba1\u89c4\u5219\uff0c\u4f46\u914d\u4f53\u7684\u76f8\u5bf9\u5ea6\u91cf(\u957f\u5ea6\u548c\u62d3\u6251)\u5f88\u53ef\u80fd\u662f\u4e00\u4e2a\u5173\u952e\u56e0\u7d20\u3002\u7b2c\u4e8c\u4e2a\u5173\u952e\u662f\u5206\u9636\u6bb5\u591a\u6b65\u5408\u6210\uff0c\u5728\u6bcd\u4f53MOF\u4e0a\u5f15\u5165\u591a\u4e2a\u62d3\u6251\u4e0d\u540c\u7684\u94fe\u63a5\u3002\u867d\u7136\u8fd9\u4e00\u76ee\u6807\u53ef\u4ee5\u901a\u8fc7\u4e00\u9505\u6cd5\uff0c\u6df7\u5408\u8fde\u63a5\u7b56\u7565\uff0c\u5c06\u4e0d\u540c\u8fde\u63a5\u4f53\u540c\u65f6\u7eb3\u5165\u4e00\u4e2a\u6846\u67b6\uff0c\u4f46\u5c06\u4e94\u79cd\u4e0d\u540c\u7684\u7ec4\u5206\u4ee5\u7b80\u5355\u7684\u4e00\u6b65\u8fc7\u7a0b\u6574\u5408\u5230\u6709\u5e8f\u7684MOF\u4e2d\uff0c\u4ecd\u7136\u662f\u4e00\u4e2a\u7d27\u8feb\u7684\u6311\u6218\u3002\u901a\u8fc7\u5408\u6210\u540e\u9010\u6b65\u63d2\u5165\u914d\u4f53\uff0c\u4f3c\u4e4e\u662f\u4e00\u4e2a\u66f4\u53ef\u9760\u7684\u65b9\u6cd5\u3002<\/p>\n

2018\u5e74\u5185\u5e03\u62c9\u65af\u52a0\u5927\u5b66\u6797\u80af\u5206\u6821Jian Zhang\u6559\u6388\u62a5\u544a\u4e86\u4e00\u4e2a\u62d3\u6251\u5bfc\u5411\uff0c\u7cbe\u786e\u5730\u63d2\u5165\u4e09\u4e2a\u4e0d\u540c\u7684\u6709\u673a\u57fa\u5143\u4e8c\u6b21\u8fde\u63a5\u5230\u9506\u57fa\u91d1\u5c5e\u6709\u673a\u6846\u67b6NPF-30014<\/sup>\uff08\u5982\u56fe9\u4e0a\uff09\u3002\u9aa8\u67b6\u7684\u5c3a\u5bf8\u5339\u914d\u548c\u673a\u68b0\u5e94\u53d8\u662f\u51b3\u5b9a\u63d2\u5165\u8fde\u63a5\u5242\u5316\u5b66\u7a33\u5b9a\u6027\u7684\u4e24\u4e2a\u91cd\u8981\u56e0\u7d20\u3002\u4e8c\u57fa\u5143NPF-300\u4e2d\u63d2\u5165\u7684\u4e8c\u6b21\u914d\u4f53\u4e0d\u4ec5\u4f7f\u5176\u5b54\u9699\u5ea6\u663e\u8457\u63d0\u9ad8\uff0c\u800c\u4e14\u5b89\u88c5\u591a\u8fbe\u4e09\u4e2a\u4e0d\u540c\u7684\u5b98\u80fd\u56e2\u6765\u6784\u5efa\u5177\u6709\u540c\u91d1\u5c5e\u4e2d\u5fc3\u7684\u591a\u5143MOFs\u3002\u7528\u4e8e\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u5305\u62ec\u50a8\u6c14\/\u5206\u79bb\u548c\u534f\u540c\/\u534f\u540c\u50ac\u5316\u3002\u968f\u540e\u5fb7\u5dde\u519c\u5de5\u5927\u5b66\u7684Hong-Cai Zhou\u6559\u6388\u5229\u7528\u4f4e\u5bf9\u79f0\u77e9\u9635\u6784\u9020\u4e86\u4e00\u4e2a\u591a\u53d8\u91cf\u56db\u5143\u591a\u81ea\u7531\u5ea6\u7cfb\u7edf15<\/sup>\u3002\u4e00\u4e2a\u7cbe\u5fc3\u8bbe\u8ba1\u7684\u68af\u5f62\u8fde\u63a5\u65b9\u5f0f\u964d\u4f4e\u4e86\u6846\u67b6\u7684\u6574\u4f53\u5bf9\u79f0\u6027\uff0c\u521b\u5efa\u4e86\u4e09\u4e2a\u4e0d\u540c\u957f\u5ea6\u7684\u5b54\u9699\u3002\u901a\u8fc7\u5c06\u4e09\u79cd\u957f\u5ea6\u5408\u9002\u3001\u987a\u5e8f\u5408\u9002\u7684\u8fde\u63a5\u4f53\u5408\u6210\u540e\u5b89\u88c5\u5230\u5f00\u653e\u77e9\u9635\u4e2d\uff0c\u5f97\u5230\u4e86\u5177\u6709\u591a\u5143\u5b54\u9699\u73af\u5883\u7684\u4e94\u57fa\u5143MOFs\u3002\u5355\u6676\u7ed3\u6784\u6e05\u6670\u5730\u53cd\u6620\u4e86\u914d\u4f53\u9010\u6b65\u63d2\u5165\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u8f6c\u53d8\uff08\u5982\u56fe9\u4e0b\uff09\u3002\u9664\u4e86\u63d0\u4f9b\u4e00\u4e2a\u590d\u6742\u4f46\u9ad8\u5ea6\u53ef\u63a7\u7684\u591a\u53d8\u91cfMOF\u7cfb\u7edf\uff0c\u8fd9\u9879\u5de5\u4f5c\u8fd8\u5f3a\u8c03\u4e86\u5bf9\u79f0\u7b80\u5316\u8fde\u63a5\u5728\u590d\u6742\u5b54\u9699\u73af\u5883\u5f62\u6210\u4e2d\u7684\u91cd\u8981\u6027\u3002\u5bf9\u5bf9\u79f0\u6027\u8f83\u4f4e\u7684\u914d\u4f53\u8fdb\u884c\u66f4\u6df1\u5165\u7684\u63a2\u7d22\uff0c\u65e0\u8bba\u662f\u5728\u914d\u4f53\u7684\u51e0\u4f55\u5f62\u72b6\u3001\u5b98\u80fd\u56e2\u4f4d\u7f6e\u8fd8\u662f\u914d\u4f53\u7c7b\u578b\u65b9\u9762\uff0c\u90fd\u5c06\u5bfc\u81f4\u53d1\u73b0\u66f4\u591a\u7684\u591a\u7ec4\u5206\u6846\u67b6\u4f53\u7cfb\u7ed3\u6784\u3002<\/p>\n

\u56fe9 \u57fa\u4e8eNPF-300\u53ca PCN-609\u6bcd\u4f53\u6784\u5efa\u4e94\u5143MOF<\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

\u8fd1\u671f\uff0c\u590d\u65e6\u5927\u5b66\u674e\u5de7\u4f1f\u6559\u6388\u8bfe\u9898\u7ec4\u548c\u6885\u897f\u5927\u5b66\u7684\u00a0Telfer\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u524d\u671f\u591a\u8282\u70b9\u6784\u578b\u7b56\u7565\u548c\u591a\u68f1\u8fb9\u957f\u5ea6\u7b56\u7565\u57fa\u7840\u4e0a\uff0c\u63d0\u51fa\u4e86\u5168\u65b0\u7684\u8282\u70b9\u89e3\u6784\u7b56\u7565\uff0c\u9009\u7528\u91d1\u5c5e\u950c\u548c\u94dc\u4e0e\u4e09\u79cd\u7ebf\u6027\u914d\u4f534-\u5421\u5511\u7fa7\u9178\u30011,4-\u5bf9\u82ef\u4e8c\u7532\u9178\u4ee5\u53ca2,6-\u8418\u4e8c\u7532\u9178\uff0c\u81ea\u7ec4\u88c5\u5408\u6210\u4e86\u9996\u4f8b\u4e94\u79cd\u57fa\u5143\u6709\u5e8f\u5206\u5e03\u7684\u591a\u5b54\u6676\u6001\u6750\u6599\uff08FDM-8\uff0916<\/sup>\uff08\u5982\u56fe10\uff09\u3002\u6240\u63d0\u51fa\u7684\u8282\u70b9\u89e3\u6784\u7b56\u7565\uff0c\u5229\u7528\u4e0d\u540c\u91d1\u5c5e\u5bf9\u4e0d\u540c\u914d\u4f4d\u5b98\u80fd\u56e2\u7684\u914d\u4f4d\u9009\u62e9\u6027\uff0c\u5c06\u4e09\u89d2\u5f62\u7684\u8282\u70b9\u8fdb\u4e00\u6b65\u89e3\u6784\u4e3a\u4e00\u4e2a\u4e09\u89d2\u5f62\u7684\u542b\u91d1\u5c5e\u57fa\u5143\u548c\u4e09\u6761\u6709\u673a\u914d\u4f53\u8fb9\u81c2\u3002\u4e09\u79cd\u7b56\u7565\u5e76\u7528\u662f\u5408\u6210\u8be5\u7ed3\u6784\u7684\u5173\u952e\uff0c\u4e5f\u662f\u591a\u57fa\u5143MOF\u7ed3\u6784\u590d\u6742\u5ea6\u8fdb\u5316\u8def\u7ebf\u4e2d\u7684\u91cd\u8981\u4e00\u6b65\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u5728\u8be5\u542b\u6709\u4e24\u79cd\u91d1\u5c5e\u3001\u4e09\u79cd\u914d\u4f53\u7684\u4f53\u7cfb\u4e2d\uff0c\u4f5c\u8005\u4eec\u6210\u529f\u907f\u514d\u4e86\u5df2\u62a5\u9053\u768470\u79cd\u53ef\u80fd\u7684\u6742\u76f8\u7ed3\u6784\uff0c\u4f53\u73b0\u4e86\u591a\u57fa\u5143MOF\u7684\u5408\u6210\u96be\u5ea6\u4e4b\u5927\u3002\u5728\u4e94\u79cd\u57fa\u5143\u7684\u534f\u540c\u4f5c\u7528\u4e0b\uff0c\u8be5\u6750\u6599\u5f62\u6210\u4e86\u4e00\u79cd\u4ecb\u5b54\u548c\u4e24\u79cd\u5fae\u5b54\u3002\u57fa\u4e8e\u5176\u591a\u7ea7\u5b54\u6027\u8d28\uff0c\u6750\u6599\u5448\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u7532\u70f7\u5b58\u50a8\u6027\u80fd\uff0c\u5728298 K\u300180 bar\u7684\u6761\u4ef6\u4e0b\u4f53\u79ef\u5b58\u50a8\u91cf\u9ad8\u8fbe215 cm3<\/sup>STP <\/sub>cm-3<\/sup>\uff0c\u57285\u201280 bar\u533a\u95f4\u5185\u7684\u5de5\u4f5c\u5bb9\u91cf\u9ad8\u8fbe193 cm3<\/sup>STP <\/sub>cm-3<\/sup>\u3002<\/p>\n

\u00a0<\/b><\/strong>\u56fe10<\/p>\n

\"\"<\/p>\n

\u00a0a)\u591a\u7ec4\u5206MOFs\u6f14\u5316\u8def\u5f84\u3002b) MOF-5\u3001UMCM-1\u3001MUF-7a\u3001FDM-8\u7684\u591a\u4e2a\u7ec4\u4ef6\u4e4b\u95f4\u7684\u7403\u68cd\u63d2\u56fe<\/p>\n

\u6587\u4e2d\u8bba\u8ff0\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u6279\u8bc4\u6307\u6b63\uff0c\u5c0f\u7f16\u624d\u758f\u5b66\u6d45\uff0c\u4e66\u5199\u4e2d\u53ef\u80fd\u6ca1\u6709\u987e\u53ca\u5230\u66f4\u591aMOFs\u7ed3\u6784\uff0c\u8bf7\u5927\u5bb6\u89c1\u8c05\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

1 \u00a0O. M. Yaghi, H. Li,\u00a0J. Am. Chem. Soc.<\/i><\/em>, 1995<\/b><\/strong>, 117<\/i><\/em>, 10401\u201310402.<\/p>\n

2 \u00a0H. Li, M. Eddaoudi, M. O\u2019Keeffe, O. M. Yaghi, Nature<\/i><\/em>, 1999<\/b><\/strong>, 402<\/i><\/em>, 276\u2013279.<\/p>\n

3 \u00a0H. K. Chae, D. Y. Siberio-P\u00e9rez, J. Kim, Y. Go, M. Eddaoudi, A. J. Matzger, M. O\u2019Keeffe, O. M. Yaghi, Nature<\/i><\/em>, 2004<\/b><\/strong>, 427<\/i><\/em>, 523\u2013527.<\/p>\n

4 \u00a0HUANG X C,LIN Y Y,ZHANG J P,et al.\u00a0Angew. Chem. Int. Ed., 2006,118 (10): 1587-1589.<\/p>\n

5 \u00a0Koh K , Wong-Foy A G , Matzger A J . J. Am. Chem. Soc., 2009, 131(12):4184-4185.<\/p>\n

6 \u00a0Furukawa H , Ko N , Go Y B , et al. Science, 2010, 329(5990):424-428.<\/p>\n

7 \u00a0Gr\u00fcnker, Ronny, Bon V , M\u00fcller, Philipp, et al. Chem. Comm, 2014, 50(26):3450.<\/p>\n

8 \u00a0Zhai Q G , Bu X , Mao C , et al. J. Am. Chem. Soc, 2016, 138, 2524\u22122527.<\/p>\n

9\u00a0\u00a0Angew. Chem. Int. Ed<\/i><\/em>., 2019<\/b><\/strong>, DOI: 10.1002\/anie.201901786<\/p>\n

10 \u00a0Liu L , Konstas K , Hill M R , et al. Journal of the American Chemical Society, 2013, 135(47):17731-17734.<\/p>\n

11 \u00a0Liu L , Telfer S G . J. Am. Chem. Soc., 2015, 137(11):3901-3909.<\/p>\n

12 Dutta, A. G. Wong-Foy, A. J. Matzger, Chem. Sci., 2014, 5, 3729\u20133734.<\/p>\n

13 \u00a0Tu B , Pang Q , Xu H , et al. J. Am. Chem. Soc., 2017, 139, 7998\u22128007.<\/p>\n

14 \u00a0Xin Z , Frey B L , Yu-Sheng C , et al. J. Am. Chem. Soc.,2018, 140, 7710\u22127715.<\/p>\n

15 \u00a0Pang J , Yuan S , Qin J , et al. J. Am. Chem. Soc., 2018, 140(39):12328-12332.<\/p>\n

16 \u00a0Binbin Tu, Lisa Diestel, Zhao-Lin Shi\u00a0et al. Angew. Chem. Int. Ed., 2019, 58, 1\u20137.<\/p>\n

\u5f80\u671f\u56de\u987e\uff1a<\/strong><\/p>\n

MOF\u4e13\u680f & PPT \u2014\u2014 \u56fd\u9645\u77e5\u540dMOF\u5927\u725b\u96c6\u9526<\/a><\/p>\n

MOF\u4e13\u680f & PPT\u2014\u2014\u56fd\u5185MOF\u5927\u725b\u96c6\u9526<\/a><\/p>\n

\u88abNature\u3001Science\u6367\u7ea2\u7684\u660e\u661f: MOF\u53d1\u5c55\u7684\u91cc\u7a0b\u7891\u3001\u547d\u540d\u89c4\u5219\u4ee5\u53ca\u4ee3\u8868\u6027MOF\u603b\u7ed3<\/a><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u79d1\u6280\u987e\u95ee Junas\u00a0<\/strong>\u4f9b\u7a3f\uff0c<\/b><\/strong>\u6750\u6599\u4eba\u7f16\u8f91\u90e8Alisa\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8bed\u3011 MOF\u4e13\u680f\uff1a\u4e0d\u5b9a\u671f\u68b3\u7406\u603b\u7ed3MOF\u76f8\u5173\u77e5\u8bc6\u5185\u5bb9 \u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u8bde\u751f\u4e8e\u4e0a\u4e16\u7eaa 90 \u5e74\u4ee3 \uff0c\u8fd9\u79cd\u5177\u6709\u5468\u671f\u6027\u7f51\u7edc\u7ed3\u6784\u7684\u6676\u4f53\u6750\u6599\u3002\u5728\u5438\u9644\u3001\u5206\u79bb\u3001\u50ac\u5316…<\/p>\n","protected":false},"author":10213,"featured_media":174196,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-171240","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/171240"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=171240"}],"version-history":[{"count":15,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/171240\/revisions"}],"predecessor-version":[{"id":171367,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/171240\/revisions\/171367"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/174196"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=171240"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=171240"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=171240"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}