{"id":172938,"date":"2019-05-07T06:30:10","date_gmt":"2019-05-06T22:30:10","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=172938"},"modified":"2019-05-07T21:20:48","modified_gmt":"2019-05-07T13:20:48","slug":"%e7%94%b5%e5%82%ac%e5%8c%96%e6%96%b0%e5%ae%a0%e4%b9%8b%e5%b8%b8%e6%b8%a9%e5%b8%b8%e5%8e%8b%e6%b0%ae%e8%bf%98%e5%8e%9f%ef%bc%88nrr%ef%bc%89%ef%bc%8c%e6%9c%80%e5%85%a8nrr%e4%bb%8b%e7%bb%8d%ef%bc%8c","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=172938","title":{"rendered":"\u7535\u50ac\u5316\u65b0\u5ba0\u4e4b\u5e38\u6e29\u5e38\u538b\u6c2e\u8fd8\u539f\uff08NRR\uff09\uff0c\u6700\u5168NRR\u4ecb\u7ecd\uff0c\u4f60\u60f3\u8981\u7684\u90fd\u5728\u8fd9\uff01"},"content":{"rendered":"

\u4e00\u3001\u80cc\u666f\u4ecb\u7ecd<\/strong><\/p>\n

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2017\u5e74\u521a\u63a5\u89e6\u7535\u5316\u5b66\u5408\u6210\u6c28\u65f6\u80fd\u591f\u68c0\u7d22\u5230\u7684\u76f8\u5173\u6587\u732e\u5be5\u5be5\u65e0\u51e0\uff0c\u4f46\u662f\u4ece17\u5e74\u5e74\u5e95\u4ee5nitrogen reduction reaction\uff08NRR\uff09\u6216\u8005electrochemical\u00a0synthesis of ammonia\uff08ESA\uff09\u4e3a\u5173\u952e\u8bcd\u641c\u7d22\u7684\u65f6\u5019\uff0c\u660e\u663e\u611f\u89c9\u5230\u6587\u732e\u6570\u91cf\u5feb\u901f\u589e\u957f\u3002\u4ee5\u4e0b\u662f\u7535\u5316\u5b66\u5408\u6210\u6c28\u51e0\u7bc7\u7ecf\u5178\u6587\u732e17\u5e74\u524d\u540e\u5728web of science\u7684\u5f15\u7528\u91cf\uff0c\u5f15\u7528\u91cf\u5747\u4ece17\u5e74\u5f00\u59cb\u6fc0\u589e\uff0c\u7d27\u8ddfORR, OER, HER\u7684\u6b65\u4f10\uff0cNRR\u4f5c\u4e3a\u7535\u50ac\u5316\u9886\u57df\u4e2d\u4e00\u9897\u5189\u5189\u65b0\u661f\u6b63\u5f0f\u51fa\u9053\u4e86\u3002<\/p>\n

[1] G.K.a.C.L. V. Kordali, Electrochemical synthesis of ammonia at atmospheric pressure and low temperature in a solid polymer electrolyte cell, Chem. Commun 17 (2000) 1673.<\/p>\n

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[2] B.C. Stuart Licht, Baohui Wang, Fang-Fang Li, Jason Lau, Shuzhi Liu, Ammonia synthesis by N2<\/sub>\u00a0and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2<\/sub>O3<\/sub>, Science, 345 (2014) 640.<\/p>\n

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[3] R. Lan, J.T. Irvine, S. Tao, Synthesis of ammonia directly from air and water at ambient temperature and pressure, Sci Rep, 3 (2013) 1145.<\/p>\n

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[4] S. Chen, S. Perathoner, C. Ampelli, C. Mebrahtu, D. Su, G. Centi, Electrocatalytic Synthesis of Ammonia at Room Temperature and Atmospheric Pressure from Water and Nitrogen on a Carbon-Nanotube-Based Electrocatalyst, Angew Chem Int Ed Engl, 56 (2017) 2699-2703.<\/p>\n

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2. \u7535\u6781\u6d4b\u8bd5\u7cfb\u7edf<\/strong><\/p>\n

\u4e09\u7535\u6781\u4f53\u7cfb\u6d4b\u8bd5\u7cfb\u7edf\uff1a\u5236\u5907\u597d\u7684\u7535\u6781\u7528\u4f5c\u5de5\u4f5c\u7535\u6781\uff0c\u78b3\u68d2\u6216\u94c2\u7247\u7528\u4f5c\u5bf9\u7535\u6781\uff0c\u53c2\u6bd4\u7535\u6781\u5373\u4e3a\u5e38\u89c4\u7684Ag\/Ag\/Cl\u3001Hg\/HgO\u6216\u9971\u548c\u7518\u6c5e\u7535\u6781\u3002\u7535\u89e3\u6db2\u53ef\u4ee5\u7528\u9178\u6027\u7684H2<\/sub>SO4<\/sub>\u6eb6\u6db2[6]<\/sup>\uff0c\u78b1\u6027\u76841\u00a0M\/0.1\u00a0M\u00a0KOH\u6eb6\u6db2[7]<\/sup>\uff0c\u6216\u8005LiClO4<\/sub>\u00a0\u6eb6\u6db2[8]<\/sup>\uff0cKHCO3<\/sub>\u7a00\u6eb6\u6db2[4]<\/sup>\u7b49\u3002\u73bb\u78b3\u7535\u6781\u53ef\u7528ORR\u4e94\u53e3\u7535\u89e3\u6c60\uff0c\u78b3\u7eb8\u8d1f\u8f7d\u50ac\u5316\u5242\u591a\u7528H\u578b\u5bc6\u5c01\u7535\u89e3\u69fd\uff0c\u793a\u610f\u56fe\u5982\u4e0b\u56fe\u3002<\/p>\n

\"\"<\/p>\n

\u800c\u819c\u7535\u6781\u6240\u7528\u7535\u89e3\u6c60\u79cd\u7c7b\u8f83\u591a\uff0c\u591a\u6570\u9700\u6839\u636e\u6d4b\u8bd5\u6761\u4ef6\u5b9a\u5236\uff0c\u4e0b\u56fe\u5206\u522b\u662f\u819c\u7535\u6781\u53ef\u7528\u7684H\u578b\u7535\u89e3\u6c60\u548c\u5355\u7535\u6c60\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

 <\/p>\n

3. N2<\/sub>, Ar\u6c14\u6c1b\u4e0bLSV\u66f2\u7ebf\u5bf9\u6bd4<\/strong><\/p>\n

\u4e0e\u7535\u50ac\u5316\u4e2dOER, ORR, HER\u76f8\u540c\uff0c\u6781\u5316\u66f2\u7ebfLSV\u662f\u7531\u7ebf\u6027\u4f0f\u5b89\u6cd5\u6d4b\u5f97\uff0c\u626b\u901f\u6162\u81f31-5mV\/s\uff0c\u8fbe\u5230\u7a33\u6001\u6d4b\u8bd5\u7684\u6761\u4ef6\uff0c\u7535\u6d41\u968f\u7535\u538b\u7684\u5f71\u54cd\u5373\u4e3a\u6781\u5316\u66f2\u7ebf\u3002\u7a33\u6001\u7535\u6d41\u5168\u90e8\u7528\u4e8e\u7535\u5316\u5b66\u53cd\u5e94\uff0c\u6781\u5316\u7535\u6d41\u5bc6\u5ea6\u5c31\u5bf9\u5e94\u4e8e\u7535\u5316\u5b66\u53cd\u5e94\u7684\u901f\u7387\u3002\u6d4b\u8bd5\u524d\u8fdb\u884c\u51e0\u5341\u5708CV\uff0c\u4fdd\u8bc1LSV\u66f2\u7ebf\u7684\u51c6\u786e\u4e0e\u7a33\u5b9a\u6027\u3002\u4e0eOER, ORR, HER\u4e0d\u540c\u7684\u662f\uff0cLSV\u6781\u5316\u66f2\u7ebf\u7684\u610f\u4e49\u5e76\u4e0d\u4ec5\u4ec5\u662f\u8ba1\u7b97\u8fc7\u7535\u52bf\uff0c\u8fd8\u5305\u62ecN2<\/sub>, Ar\u6c14\u6c1b\u4e0b\u7684LSV\u66f2\u7ebf\u5bf9\u6bd4\uff0c\u901a\u8fc7\u4e24\u79cd\u6c14\u6c1b\u4e0bLSV\u66f2\u7ebf\u7684\u5dee\u522b\u6765\u5224\u65ad\u6c2e\u8fd8\u539f\u53cd\u5e94\u53ef\u80fd\u53d1\u751f\u7684\u7535\u4f4d\u533a\u95f4\u548cNRR\u6d3b\u6027\u5927\u5c0f\u3002\u539f\u7406\u5982\u4e0b\uff1a\u7535\u50ac\u5316\u5408\u6210\u6c28\u53cd\u5e94\u4e2d\u9633\u6781\u53cd\u5e94\u662fOER\uff0c\u6211\u4eec\u6240\u9700\u8981\u7684\u662f\u9634\u6781\u53d1\u751fNRR\uff0c\u800c\u73b0\u5b9e\u60c5\u51b5\u662f\u5373\u4f7f\u662f\u6709\u9ad8\u6c2e\u8fd8\u539f\u50ac\u5316\u6d3b\u6027\u7684\u50ac\u5316\u5242\u505a\u5de5\u4f5c\u7535\u6781\u65f6\uff0c\u9634\u6781\u53cd\u5e94\u4e5f\u662f\u4ee5HER\u4e3a\u4e3b\uff0cNRR\u4e3a\u8f85\uff0c\u5373\u8d85\u8fc790%\u7684\u7535\u80fd\u7528\u4e8e\u50ac\u5316HER\u800c\u4e0d\u662fNRR\u3002Ar\u6c14\u6c1b\u4e0b\u7684LSV\u66f2\u7ebf\u5c31\u4ee3\u8868\u4ec5\u53d1\u751fHER\u65f6\u7684\u6781\u5316\u66f2\u7ebf\uff0cN2<\/sub>\u6c14\u6c1b\u4e0b\u7684LSV\u66f2\u7ebf\u5219\u4ee3\u8868HER\u548cNRR\u540c\u65f6\u53d1\u751f\u7684\u6781\u5316\u66f2\u7ebf\uff0c\u4e24\u66f2\u7ebf\u7684\u7535\u6d41\u5dee\u503c\u53ef\u4ee5\u770b\u505a\u662f\u7531NRR\u53cd\u5e94\u6240\u8d21\u732e\u7684\uff0c\u56e0\u6b64\u67d0\u79cd\u7a0b\u5ea6\u4e0a\u4e24\u6781\u5316\u66f2\u7ebf\u7535\u6d41\u5dee\u503c\u53ef\u4ee5\u4ee3\u8868\u50ac\u5316\u5242\u5bf9\u6c2e\u8fd8\u539f\u53cd\u5e94\u7684\u50ac\u5316\u6d3b\u6027\u5927\u5c0f\uff0c\u4e24\u66f2\u7ebf\u7531\u91cd\u5408\u9010\u6e10\u5206\u5f00\u5230\u518d\u6b21\u91cd\u5408\u7684\u7535\u538b\u533a\u95f4\u4e5f\u5927\u6982\u7387\u662f\u6c2e\u8fd8\u539f\u53cd\u5e94\u53d1\u751f\u7684\u7535\u538b\u533a\u95f4\u3002\u6700\u8fd1\u4e24\u5e74\u53d1\u8868\u7684\u6587\u732e\u591a\u6570\u90fd\u4f1a\u7ed9\u51fa\u8fd9\u79cdLSV\u66f2\u7ebf\u5bf9\u6bd4\u56fe\uff0c\u7ed3\u5408\u5b9e\u9645\u6d4b\u5f97\u7684\u4e0d\u540c\u7535\u538b\u4e0b\u7684\u6c28\u6c14\u4ea7\u7387\u89e3\u91ca\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe\u7247\u6765\u81ea\u53c2\u8003\u6587\u732e[9]<\/sup><\/p>\n

4 .\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf<\/strong><\/p>\n

\u8ba1\u65f6\u7535\u6d41\u6cd5\u7684\u5de5\u4f5c\u539f\u7406\u662f\u5728\u5de5\u4f5c\u7535\u6781\u4e0e\u53c2\u6bd4\u7535\u6781\u4e4b\u95f4\u65bd\u52a0\u4e00\u4e2a\u9636\u8dc3\u7535\u52bf\u4f5c\u4e3a\u6fc0\u52b1\uff0c\u7531\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4ea7\u751f\u7684\u968f\u65f6\u95f4\u53d8\u5316\u7684\u54cd\u5e94\u7535\u6d41\u6d41\u8fc7\u5de5\u4f5c\u7535\u6781\u548c\u5bf9\u7535\u6781\uff0c\u8bb0\u5f55\u8be5\u7535\u6d41\u968f\u65f6\u95f4\u7684\u53d8\u5316\u3002\u8be5\u66f2\u7ebf\u7684\u4f5c\u7528\u4e0eOER, ORR, HER\u4e2d\u76f8\u4f3c\uff0c\u53ef\u4ee5\u53cd\u6620\u50ac\u5316\u5242\u5728\u67d0\u4e00\u7535\u4f4d\u4e0b\u50ac\u5316\u53cd\u5e94\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe\u7247\u6765\u81ea\u53c2\u8003\u6587\u732e[10]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe\u7247\u6765\u81ea\u53c2\u8003\u6587\u732e[9]<\/sup><\/p>\n

5 .\u6c28\u6c14\u4ea7\u91cf\u53ca\u6cd5\u62c9\u7b2c\u6548\u7387\u66f2\u7ebf<\/strong><\/p>\n

\uff081\uff09\u6c28\u6c14\u4ea7\u91cf\u68c0\u6d4b\u65b9\u6cd5\uff08\u6b65\u6b65\u7cbe\u51c6–\u624d\u80fd\u5f97\u5230\u4e00\u4e2a\u4ee4\u4eba\u4fe1\u670d\u7684\u6570\u636e\uff09<\/p>\n

\u5e38\u7528\u7684\u6c28\u6c14\u4ea7\u91cf\u68c0\u6d4b\u65b9\u6cd5\u6709\u79bb\u5b50\u8272\u8c31\u6cd5\u548c\u5206\u5149\u5149\u5ea6\u6cd5\uff0c\u79bb\u5b50\u8272\u8c31\u6cd5\u5177\u6709\u8bb8\u591a\u4f18\u70b9\uff08\u4f8b\u5982\u9ad8\u7075\u654f\u5ea6\u548c\u826f\u597d\u7684\u91cd\u73b0\u6027\uff09\uff0c\u4f46\u4ef7\u683c\u6602\u8d35\u4e14\u9700\u8981\u590d\u6742\u7684\u4eea\u5668\uff0c\u5206\u5149\u5149\u5ea6\u6cd5\u56e0\u6210\u672c\u8f83\u4f4e\u800c\u88ab\u66f4\u5e7f\u6cdb\u5730\u4f7f\u7528\uff0c\u5176\u4e2d\u7eb3\u6c0f\u8bd5\u5242\u6cd5\u548c\u975b\u915a\u84dd\u65b9\u6cd5\u662f\u6700\u5e38\u89c1\u7684[11]<\/sup>\u3002<\/p>\n

\u7eb3\u6c0f\u8bd5\u5242\u662f\u542b\u6709K2<\/sub>HgI4<\/sub>\u548cKOH\u7684\u6eb6\u6db2\uff0c\u7898\u5316\u7269\u548c\u6c5e\u79bb\u5b50\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u4e0e\u6c28\u53cd\u5e94\u4ea7\u751f\u7ea2\u68d5\u8272\u914d\u5408\u7269\uff0c\u5728420nm\u6ce2\u957f\u5904\u6709\u5f3a\u70c8\u5438\u6536\u3002\u53cd\u5e94\u5982\u4e0b\u5f0f\uff1a<\/p>\n

\"\"<\/p>\n

\u5728\u6ca1\u6709\u5e72\u6270\u7269\u7684\u60c5\u51b5\u4e0b\uff0c\u5438\u5149\u5ea6\u4e0e\u6c28\u6d53\u5ea6\u6210\u6b63\u6bd4\u3002\u4e3a\u4e86\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u6765\u81ea\u5176\u4ed6\u79bb\u5b50\uff08Fe3+<\/sup>\uff0cCo2+<\/sup>\uff0cNi2+<\/sup>\uff0cCr3+<\/sup>\uff0cAg+<\/sup>\uff0cS2+<\/sup>\u7b49\uff09\u7684\u5e72\u6270\uff0c\u68c0\u6d4b\u8fc7\u7a0b\u4e2d\u8fd8\u9700\u52a0\u5165\u9152\u77f3\u9178\u94be\u94a0\u6eb6\u6db2\u3002\u9700\u8981\u6ce8\u610f\u7684\u662fi\uff09Nesslers\u8bd5\u5242\u4e2d\u7684\u6c5e\u79bb\u5b50\u6709\u6bd2\uff0c\u5e94\u5c0f\u5fc3\u4f7f\u7528\u8bd5\u5242; ii\uff09Nesslers\u8bd5\u5242\u7684\u5bff\u547d\u76f8\u5bf9\u8f83\u77ed\uff08\u7ea6\u4e09\u5468\uff09; iii\uff09\u7528\u4e8e\u5236\u5907Nesslers\u8bd5\u5242\u6eb6\u6db2\u7684\u6c34\u5fc5\u987b\u4e0d\u542b\u6c28\uff08\u8d85\u7eaf\u6c34\uff09;iv\uff09\u6c28\u4e0eNesslers\u8bd5\u5242\u7684\u53cd\u5e94\u65f6\u95f4\u4e5f\u5f71\u54cdNH3<\/sub>\u7684\u51c6\u786e\u5b9a\u91cf\uff0c\u5efa\u8bae\u53cd\u5e94\u65f6\u95f4\u4e3a10-30\u5206\u949f\u3002<\/p>\n

\u975b\u915a\u84dd\u65b9\u6cd5\u6d89\u53ca\u6c28\u4e0e\u82ef\u915a\u548c\u6b21\u6c2f\u9178\u76d0\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\u7684\u53cd\u5e94\uff0c\u4ee5\u4ea7\u751f\u84dd\u8272\u975b\u915a\u4ea7\u7269\u3002\u4f7f\u7528\u785d\u666e\u94a0\u4f5c\u4e3a\u50ac\u5316\u5242\u6765\u5f3a\u5316\u975b\u915a\u53cd\u5e94\u4e2d\u7684\u989c\u8272\u53d8\u5316\uff0c\u67e0\u6aac\u9178\u76d0\u7f13\u51b2\u6db2\u7528\u4e8e\u7a33\u5b9a\u53cd\u5e94\u6eb6\u6db2\u7684pH\u3002<\/p>\n

\"\"<\/p>\n

\u4e3a\u4e86\u5b9e\u9a8c\u7684\u51c6\u786e\u6027\uff0c\u5efa\u8bae\u81f3\u5c11\u4f7f\u7528\u4e24\u79cd\u68c0\u6d4b\u624b\u6bb5\uff0c\u5e76\u53d6\u5176\u5e73\u5747\u503c\uff0c\u4e3b\u8981\u5b9e\u9a8c\u7ed3\u679c\u5e94\u5177\u5907\u4e09\u6b21\u4ee5\u4e0a\u91cd\u590d\u6027[12]<\/sup>\u3002<\/p>\n

\u4f17\u6240\u5468\u77e5\uff0c\u5e38\u6e29\u5e38\u538b\u7535\u5316\u5b66\u5408\u6210\u6c28\u8fc7\u7a0b\u4e2d\u6c28\u6c14\u7684\u4ea7\u91cf\u975e\u5e38\u5c0f\uff0c\u4e00\u822c\u60c5\u51b5\u4e0b\u5b9e\u9a8c\u4ea7\u7387\u572810~1000\u00a0nmol\u3002\u800c\u4e14\u6c28\u5728\u5b9e\u9a8c\u5ba4\u73af\u5883\u4e2d\u65e0\u5904\u4e0d\u5728\uff0c\u662f\u5316\u5b66\u54c1\u7279\u522b\u662f\u6c14\u4f53\u4e2d\u7684\u5e38\u89c1\u6c61\u67d3\u7269\u3002\u4f5c\u4e3a\u6325\u53d1\u6027\u6c14\u4f53\uff0c\u5b83\u8fd8\u503e\u5411\u4e8e\u968f\u7740\u65f6\u95f4\u79ef\u805a\u5728\u666e\u901a\u73bb\u7483\u5668\u76bf\u8868\u9762\u6216\u6c34\u6eb6\u6db2\u4e2d\uff0c\u5728\u7a7a\u6c14\u8d28\u91cf\u53d7\u635f\u7684\u5730\u533a\uff0c\u5927\u6c14\u4e2d\u7684\u6c28\u542b\u91cf\u53ef\u4ee5\u8fbe\u5230\u66f4\u9ad8\u7684\u6c34\u5e73\uff0c\u7a7a\u6c14\u4e2d\u7684\u6c28\u6e90\u4e5f\u662f\u5f71\u54cd\u5b9e\u9a8c\u51c6\u786e\u5ea6\u7684\u4e00\u4e2a\u91cd\u8981\u5f71\u54cd\u56e0\u7d20\u3002\u5728NRR\u4e2d\uff0c\u4f7f\u7528\u542b\u6c2e\u7684\u6750\u6599\u3001\u50ac\u5316\u5242\u3001\u7535\u89e3\u8d28\u6eb6\u5242\u548c\u6c14\u4f53\u90fd\u53ef\u80fd\u5f71\u54cd\u6c28\u7684\u6d4b\u91cf\u3002\u6c27\u5316\u5f62\u5f0f\u7684\u6c2e\uff08NOx\uff09\u5305\u62ec\u5316\u5b66\u54c1\u548c\u6eb6\u5242\u4e2d\u7684\u9634\u79bb\u5b50\uff0c\u4ee5\u53ca\u4f9b\u5e94\u6c14\u4f53\u4e2d\u7684\u6c2e\u6c27\u5316\u7269\u4e5f\u662f\u5f88\u96be\u6392\u9664\u7684\u5f71\u54cd\u56e0\u7d20\uff0c\u56e0\u4e3a\u5b83\u4eec\u5f88\u5bb9\u6613\u88ab\u8fd8\u539f\u6210\u6c28\u3002\u4f9b\u5e94\u6c14\u4f53\u4e2d\u7684NOx\u5c24\u5176\u503c\u5f97\u5173\u6ce8\uff0c\u56e0\u4e3a\u8fd9\u79cd\u5916\u6e90\u901a\u5e38\u5728\u5b9e\u9a8c\u4e2d\u957f\u671f\u8fde\u7eed\u4f9b\u5e94\uff0c\u56e0\u6b64\u5373\u4f7f\u89c2\u5bdf\u5230\u957f\u65f6\u95f4\u5185\u7a33\u5b9a\u4ea7\u751fNH3<\/sub>\u4e5f\u4e0d\u80fd\u591f\u4f5c\u4e3aNRR\u53d1\u751f\u7684\u660e\u786e\u8bc1\u636e\u3002\u6b64\u5916\uff0cNOx\u4e5f\u662f\u5e38\u89c1\u7684\u5b9e\u9a8c\u5ba4\u5668\u5177\u6c61\u67d3\u7269\u3002\u5373\u4f7f\u7ecf\u8fc7\u591a\u6b21\u51b2\u6d17\uff0c\u53ea\u8981\u7535\u6781\u6216\u7535\u89e3\u8d28\u6750\u6599\u4e2d\u5b58\u5728\u53ef\u8fd8\u539f\u7684\u542b\u6c2e\u7269\u8d28\uff0c\u6c2e\u5316\u7269\u6216\u5176\u4ed6\u8fd8\u539f\u5242\uff0c\u5c31\u4f1a\u51fa\u73b0\u76f8\u5173\u95ee\u9898\u3002\u968f\u7740\u8fd1\u4e24\u5e74\u6709\u5173\u7535\u50ac\u5316\u5408\u6210\u6c28\u6587\u7ae0\u6570\u91cf\u7684\u6fc0\u589e\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u8005\u4e5f\u5f00\u59cb\u8d28\u7591\u4e00\u4e9b\u5df2\u53d1\u8868\u6210\u679c\u7684\u51c6\u786e\u6027[13]<\/sup>\u3002\u56e0\u6b64\uff0c\u660e\u786e\u5730\u8bc1\u660e\u5728NRR\u5b9e\u9a8c\u4e2d\u6d4b\u5b9a\u7684\u6c28\u662f\u901a\u8fc7\u7535\u5316\u5b66\u8fd8\u539fN2<\/sub>\u800c\u4e0d\u662f\u4ece\u5176\u4ed6\u4e00\u4e9b\u5916\u6e90\u6765\u6e90\u4ea7\u751f\u7684\u5728\u7535\u50ac\u5316\u5408\u6210\u6c28\u5b9e\u9a8c\u4e2d\u5c24\u4e3a\u91cd\u8981\u3002\u4e0b\u6587\u5c06\u4f1a\u4ecb\u7ecd\u7ecf\u8fc7\u4e25\u8c28\u8bbe\u8ba1\u7684\u5177\u4f53\u7684\u63a7\u5236\u5b9e\u9a8c\u6b65\u9aa4\uff0c\u5e2e\u52a9\u5f97\u5230\u4e00\u4e2a\u4ee4\u4eba\u4fe1\u670d\u7684\u6c28\u4ea7\u91cf\u5b9e\u9a8c\u6570\u636e\u3002<\/p>\n

\u51c0\u5316\u6c14\u4f53\uff1a\u5b9e\u9a8c\u8fc7\u7a0b\u6240\u9700\u6c14\u4f53\uff08Ar\uff0c14<\/sup>N2<\/sub>\u548c15<\/sup>N2<\/sub>\uff09\u9700\u8981\u6e05\u6d17\uff0c\u7528\u79bb\u5b50\u8272\u8c31\u6216\u5206\u5149\u5149\u5ea6\u6cd5\u68c0\u6d4b\u51fa\u51c0\u5316\u540e\u6c14\u4f53\u4e2d\u7684\u6c28\u542b\u91cf\uff0c\u4ee5\u53bb\u9664\u5916\u6e90\u6c2e\u7269\u79cd\uff08x-NH3<\/sub>\uff09\u4ee5\u53caNOx\u6c61\u67d3\u7269\u4e2d\u7684\u80cc\u666f\u6c28\u542b\u91cf\u3002<\/p>\n

\u5f00\u8def\u6d4b\u8bd5\uff1a\u5728\u5f00\u8def\u7535\u538b\u4e0b\u8fdb\u884c\u6d4b\u8bd5\uff0c\u6355\u96c6\u6eb6\u6db2\u4e2d\u7684x-NH3<\/sub>\u3002\u6c2e\u6c14\u6761\u4ef6\u4e0b\u7684\u5f00\u8def\u6d4b\u8bd5\u6d4b\u5f97\u7684x-NH3<\/sub>\u6d53\u5ea6\u5e94\u8be5\u7b49\u4e8e\u6216\u4f4e\u4e8e\u6c29\u6c14\u6761\u4ef6\u4e0b\u7684\u6d4b\u5f97\u503c\u3002\u5982\u679c\u4e0d\u4f4e\u4e8e\u8be5\u503c\uff0c\u5219\u9700\u8981\u518d\u6b21\u51c0\u5316\u6c14\u4f53\u3002<\/p>\n

\u6c29\u6c14\u6761\u4ef6\u4e0b\u7535\u5316\u5b66\u6d4b\u8bd5\uff1a\u5728\u6bcf\u4e2a\u6d4b\u91cf\u7535\u4f4d\u4e0b\uff0c\u5e94\u4ee5\u6c2e\u6c14\u3001\u6c29\u6c14\u4e3a\u63a7\u5236\u53d8\u91cf\u8fdb\u884c\u6d4b\u8bd5\u3002\u56e0\u4e3a\u6c28\u4f1a\u968f\u7740\u65f6\u95f4\u7684\u63a8\u79fb\u79ef\u805a\u5728\u5668\u76bf\u8868\u9762\u548c\u6eb6\u6db2\u4e0a\uff0c\u6240\u4ee5\u6bcf\u6b21NRR\u5b9e\u9a8c\u4e4b\u524d\u90fd\u5e94\u8fdb\u884c\u6c29\u6c14\u6761\u4ef6\u4e0b\u7684\u7535\u5316\u5b66\u6d4b\u8bd5\uff0c\u5e76\u4fdd\u8bc1\u6d4b\u8bd5\u65f6\u95f4\u4e0e\u6c2e\u6c14\u6761\u4ef6\u4e0b\u6d4b\u8bd5\u65f6\u95f4\u76f8\u540c\u3002\u5bf9\u4e8e\u6d89\u53ca\u542b\u6c2e\u6d3b\u6027\u4f4d\u70b9\u7684\u7535\u50ac\u5316\u5242\uff0c\u6216\u5728\u4efb\u4f55\u9636\u6bb5\u4f7f\u7528\u542b\u6c2e\u6eb6\u5242\u6216\u5316\u5408\u7269\uff08\u5982\u785d\u9178\u76d0\uff09\u5236\u5907\u7684\u7535\u50ac\u5316\u5242\uff0c\u5728\u5404\u6d4b\u91cf\u7535\u4f4d\u4e0b\u7684\u6c29\u6c14\u63a7\u5236\u5b9e\u9a8c\u4e2d\u53ef\u80fd\u4ea7\u751f\u80cc\u666f\u6c28\u542b\u91cfx-NH3<\/sub>\uff0c\u5efa\u8bae\u5728\u9759\u6b62\u548c\u7535\u89e3\u9636\u6bb5\u91cd\u590d\u8fdb\u884c\u6c29\u6c14\u5bf9\u7167\u5b9e\u9a8c\u3002<\/p>\n

\u603b\u7ed3\u4e00\u4e0b\u5c31\u662f\u5728\u6700\u540e\u4e00\u6b65\u752815<\/sup>N2<\/sub>\u8fdb\u4e00\u6b65\u786e\u8ba4\u6c2e\u6e90\u4e4b\u524d\uff0c\u7535\u5316\u5b66\u6d4b\u8bd5\u5305\u62ec\u4e86\u65e0\u5de5\u4f5c\u7535\u6781\u5f00\u8def\u6d4b\u6c28\u542b\u91cf\u68c0\u6d4b\u6c14\u4f53\u7eaf\u5ea6\uff0c\u6709\u5de5\u4f5c\u7535\u6781\u65f6Ar\u3001N2<\/sub>\u5f00\u8def\u6d4b\u8bd5[x-NH3<\/sub>]Ar <\/sub>OC<\/sup>(t)\u00a0[x-NH3<\/sub>]N2<\/sub>OC<\/sup>(t)\uff0c\u5bf9\u6bd4\u6c28\u542b\u91cf\u8fdb\u4e00\u6b65\u786e\u5b9a\u6c14\u4f53\u7eaf\u5ea6\uff0c\u786e\u5b9a\u5de5\u4f5c\u7535\u6781\u5728\u4e24\u79cd\u6c14\u4f53\u6761\u4ef6\u4e0b\u5728\u7535\u89e3\u8fc7\u7a0b\u4e2d\u7684\u7a33\u5b9a\u6027\uff0c\u53ef\u7528\u4e8e\u6392\u9664\u50ac\u5316\u5242\u672c\u8eab\u6240\u542b\u6c2e\u7684\u5f71\u54cd\u3002\u6709\u5de5\u4f5c\u7535\u6781\u65f6Ar\u3001N2<\/sub>\u6d4b\u91cf\u7535\u4f4d\u4e0b\u6d4b\u8bd5\u6c28\u4ea7\u91cf[x-NH3<\/sub>]Ar <\/sub>(t, E)\u00a0[x-NH3<\/sub>]N2 <\/sub>(t, E)\u3002\u6700\u7ec8\u50ac\u5316\u53cd\u5e94\u7684\u6c28\u4ea7\u91cf[NH3<\/sub>]cat <\/sub>(t, E) = [x-NH3<\/sub>]N2 <\/sub>(t, E) – [x-NH3<\/sub>]Ar <\/sub>(t, E) – [x-NH3<\/sub>]N2<\/sub>OC<\/sup>(t) – [x-NH3<\/sub>]Ar <\/sub>OC<\/sup>(t)\uff0c\u6b64\u4ea7\u91cf\u5e94\u8fdc\u5927\u4e8eN2<\/sub>\u5f00\u8def\u6d4b\u8bd5\u6240\u5f97\u6c28\u542b\u91cf\uff0c\u5e76\u968f\u65f6\u95f4\u589e\u52a0\u800c\u589e\u52a0\uff0c\u8bf4\u660e\u6c28\u4ea7\u81ea\u7535\u89e3\u8fc7\u7a0b\uff0c\u800c\u4e0d\u662f\u542b\u6c2e\u7269\u79cd\u7684\u50ac\u5316\u5242\u4e0d\u7a33\u5b9a\u6240\u81f4\u3002<\/p>\n

\u6700\u540e\u4e00\u6b65\u662f\u5229\u752815<\/sup>N2<\/sub>\u7ed3\u5408\u6838\u78c1\u6d4b\u8bd5\u6392\u9664\u542b\u6c2e\u6750\u6599\u7684\u5f71\u54cd\uff0c\u4ee5\u8bc1\u660e\u4ea7\u751f\u7684\u6c28\u4ec5\u6e90\u81eaN2<\/sub>\u3002<\/p>\n

\u8be6\u7ec6\u7684\u6b65\u9aa4\u8bf7\u53c2\u8003\u4e0b\u56fe\uff0c\u53c2\u8003\u6587\u732e[14]<\/sup><\/p>\n

\"\"<\/p>\n

\uff082\uff09\u6c28\u6c14\u4ea7\u91cf\u53ca\u6cd5\u62c9\u7b2c\u6548\u7387\u8ba1\u7b97\u65b9\u6cd5<\/p>\n

\"\"<\/p>\n

\u5176\u4e2dR\uff08mol cm-2<\/sup>\u00a0s-1<\/sup>\uff09\u662f\u6c28\u751f\u6210\u901f\u7387\uff0c[NH4<\/sub>+<\/sup>]\uff08mol L-1<\/sup>\uff09\u662f\u7535\u89e3\u6db2\u4e2d\u7684\u6c28\u6d53\u5ea6\uff0cV\uff08L\uff09\u662f\u7535\u89e3\u6db2\u7684\u4f53\u79ef\uff0ct\uff08s\uff09\u662f\u53cd\u5e94\u65f6\u95f4 S\uff08cm-2<\/sup>\uff09\u662f\u7535\u6781\u7684\u6709\u6548\u9762\u79ef\u3002\u4e5f\u6709\u5f88\u591a\u6587\u732e\u6c28\u7684\u751f\u6210\u901f\u7387\u5355\u4f4d\u7528\u4e86\u03bcg h-1<\/sup>\u00a0mgcat<\/sub>-1<\/sup>\uff0c\u4e24\u4e2a\u5355\u4f4d\u53ef\u4ee5\u6362\u7b97\uff0c\u73bb\u78b3\u7535\u6781\u6d4b\u8bd5\u4e00\u822c\u4f1a\u9009\u62e9\u8d28\u91cf\u6d3b\u6027\u5373\u03bcg h-1<\/sup>\u00a0mgcat<\/sub>-1<\/sup>\uff0c\u78b3\u5e03\/\u7eb8\u66f4\u591a\u9009\u62e9\u9762\u79ef\u6d3b\u6027\uff08mol cm-2<\/sup>\u00a0s-1<\/sup>\uff09\u3002<\/p>\n

\u5047\u8bbe\u6bcf\u6d88\u8017\u4e09\u4e2a\u7535\u5b50\u4ea7\u751f\u4e00\u4e2aNH3<\/sub>\u5206\u5b50\uff0c\u5219\u6cd5\u62c9\u7b2c\u6548\u7387\uff1a
\n <\/i><\/em><\/p>\n

\"\"<\/p>\n

\u5176\u4e2dF\uff08C mol-1<\/sup>\uff09\u662f\u6cd5\u62c9\u7b2c\u5e38\u6570\uff0cnNH4+<\/sub>\uff08mol\uff09\u662f\u7535\u89e3\u6db2\u4e2d\u6c28\u7684\u91cf\uff0cQ\uff08C\uff09\u662f\u65bd\u52a0\u7684\u7535\u91cf\u3002<\/p>\n

\u56db\u3001\u7535\u50ac\u5316NRR\u5927\u725b<\/strong><\/p>\n

1\u3001Stuart Licht\uff08\u7f8e\u56fd\u4e54\u6cbb\u00b7\u534e\u76db\u987f\u5927\u5b66\uff09<\/strong><\/p>\n

\u5c0f\u7f16\u5f00\u542f\u7535\u50ac\u5316\u5408\u6210\u6c28\u7814\u7a76\u62dc\u8bfb\u7684\u7b2c\u4e00\u7bc7\u6587\u732e\u5c31\u662fStuart Licht 2014\u5e74\u53d1\u8868\u5728Science\u4e0a\u7684\u7535\u5316\u5b66\u5408\u6210\u6c28\uff0c\u4ee5\u592a\u9633\u80fd\u4e3a\u80fd\u6e90\uff0c\u6c34\u548c\u6c2e\u6c14\u5728\u7194\u878d\u7684\u6c22\u6c27\u5316\u7269\u5185\u76f4\u63a5\u76f8\u4e92\u4f5c\u7528\u6765\u5408\u6210\u6c28\uff0c\u8be5\u53cd\u5e94\u662f\u5229\u7528\u592a\u9633\u80fd\u7684\u9ad8\u6e29\u548c\u4ea7\u751f\u7684\u7535\u80fd\uff0c\u5728\u5206\u6563\u4e8e\u6574\u4e2a\u7194\u878d\u6c22\u6c27\u5316\u7269\u7684\u7eb3\u7c73\u6c27\u5316\u94c1\u7684\u50ac\u5316\u4e0b\u5b8c\u6210\u7684[2]<\/sup>\u3002\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u540c\u5e74\u53c8\u53d1\u8868\u5728Inorganic Chemistry\u4e0a[15]<\/sup>\u3002Stuart Licht\u548c\u4e1c\u5317\u77f3\u6cb9\u5927\u5b66\u7684\u5d14\u5b9d\u81e3\u3001\u738b\u5b9d\u8f89\u3001\u5218\u6dd1\u829d\u4e09\u4f4d\u6559\u6388\u6709\u8f83\u591a\u5408\u4f5c\uff0c\u6df1\u5165\u7814\u7a76\u4e86\u94c1\u57fa\u7535\u50ac\u5316\u5408\u6210\u6c28\u50ac\u5316\u5242[16]<\/sup>\u3002<\/p>\n

2\u3001Douglas R. MacFarlane\uff08\u6fb3\u5927\u5229\u4e9a\u83ab\u7eb3\u4ec0\u5927\u5b66\uff09<\/strong><\/p>\n

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3\u3001Holger Braunschweig\uff08\u5fb7\u56fd\u7ef4\u5c14\u8328\u5821\u5927\u5b66\uff09<\/strong><\/p>\n

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5\u3001\u5b59\u65ed\u5e73\u8bfe\u9898\u7ec4\uff08\u7535\u5b50\u79d1\u6280\u5927\u5b66\uff09<\/strong><\/p>\n

\u5b59\u65ed\u5e73\u8bfe\u9898\u7ec4\u9996\u6b21\u53d1\u73b0\u975e\u91d1\u5c5e\u7535\u50ac\u5316\u5242\u78b3\u5316\u787c\u7eb3\u7c73\u7247\u53ef\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u5b9e\u73b0\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027\uff08\u65e0\u526f\u4ea7\u7269\u6c34\u5408\u80bc\u4ea7\u751f\uff09\u7684\u4eba\u5de5\u56fa\u6c2e\u5408\u6210\u6c28\u3002\u4e14\u7ecf\u7406\u8bba\u7814\u7a76\u8868\u660e\uff0c\u787c\u662f\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u3002\u8be5\u6210\u679c\u53d1\u8868\u5728Nature Communications\u4e0a[15]<\/sup>\u3002\u8be5\u8bfe\u9898\u7ec4\u8fd8\u62a5\u9053\u4e86\u786b\u63ba\u6742\u78b3\u7eb3\u7c73\u7403\u4f5c\u4e3a\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5408\u6210\u6c28\u50ac\u5316\u5242\uff0c\u53d1\u73b0\u786b\u7684\u5f15\u5165\u5927\u5927\u63d0\u9ad8\u4e86\u6750\u6599\u7684\u6c2e\u8fd8\u539f\u6027\u80fd[16]<\/sup>\u3002<\/p>\n

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Ps\uff1a\u4f5c\u4e3a\u5b64\u519b\u594b\u6218\u5728\u7535\u50ac\u5316\u5408\u6210\u6c28\u9886\u57df\u7684\u5b64\u519b\u672c\u519b\uff0c\u771f\u662f\u7fa1\u6155\u8fd9\u6837\u7684\u519b\u56e2\u3002\u7531\u4e8e\u6587\u7ae0\u7bc7\u5e45\u6709\u9650\uff0c\u8fd8\u6709\u5f88\u591a\u5728\u7535\u5316\u5b66\u5408\u6210\u6c28\u9886\u57df\u505a\u4e86\u91cd\u8981\u53d1\u73b0\u7684\u79d1\u5b66\u5bb6\u4eec\u4e0d\u80fd\u4e00\u4e00\u5217\u51fa\uff0c\u6b22\u8fce\u5927\u5bb6\u63a8\u8350\u8865\u5145\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n

[1] G.K.a.C.L. V. Kordali, Electrochemical synthesis of ammonia at atmospheric pressure and low temperature in a solid polymer electrolyte cell, Chem. Commun 17 (2000) 1673.<\/p>\n

[2] B.C. Stuart Licht, Baohui Wang, Fang-Fang Li, Jason Lau, Shuzhi Liu, Ammonia synthesis by N2<\/sub>\u00a0and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2<\/sub>O3<\/sub>, Science, 345 (2014) 640.<\/p>\n

[3] R. Lan, J.T. Irvine, S. Tao, Synthesis of ammonia directly from air and water at ambient temperature and pressure, Sci Rep, 3 (2013) 1145.<\/p>\n

[4] S. Chen, S. Perathoner, C. Ampelli, C. Mebrahtu, D. Su, G. Centi, Electrocatalytic Synthesis of Ammonia at Room Temperature and Atmospheric Pressure from Water and Nitrogen on a Carbon-Nanotube-Based Electrocatalyst, Angew Chem Int Ed Engl, 56 (2017) 2699-2703.<\/p>\n

[5] S. Mukherjee, D.A. Cullen, S. Karakalos, K. Liu, H. Zhang, S. Zhao, H. Xu, K.L. More, G. Wang, G. Wu, Metal-organic framework-derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N2<\/sub>\u00a0and H2<\/sub>O in alkaline electrolytes, Nano Energy, 48 (2018) 217-226.<\/p>\n

[6] X. Yu, P. Han, Z. Wei, L. Huang, Z. Gu, S. Peng, J. Ma, G. Zheng, Boron-Doped Graphene for Electrocatalytic N 2 Reduction, Joule, (2018).<\/p>\n

[7] D. Bao, Q. Zhang, F.L. Meng, H.X. Zhong, M.M. Shi, Y. Zhang, J.M. Yan, Q. Jiang, X.B. Zhang, Electrochemical Reduction of N2<\/sub>\u00a0under Ambient Conditions for Artificial N2<\/sub>\u00a0Fixation and Renewable Energy Storage Using N2<\/sub>\u00a0\/NH3<\/sub>\u00a0Cycle, Adv Mater, 29 (2017) 1604799.<\/p>\n

[8] M. Nazemi, S.R. Panikkanvalappil, M.A. El-Sayed, Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages, Nano Energy, 49 (2018) 316-323.<\/p>\n

[9] F. Pang, Z. Wang, K. Zhang, J. He, W. Zhang, C. Guo, Y. Ding, Bimodal nanoporous Pd3<\/sub>Cu1<\/sub>\u00a0alloy with restrained hydrogen evolution for stable and high yield electrochemical nitrogen reduction, Nano Energy, 58 (2019) 834-841.<\/p>\n

[10] S.J. Li, D. Bao, M.M. Shi, B.R. Wulan, J.M. Yan, Q. Jiang, Amorphizing of Au Nanoparticles by CeOx -RGO Hybrid Support towards Highly Efficient Electrocatalyst for N2<\/sub>\u00a0Reduction under Ambient Conditions, Adv Mater, 29 (2017) 1700001.<\/p>\n

[11] Y. Zhao, R. Shi, X. Bian, C. Zhou, Y. Zhao, S. Zhang, F. Wu, G.I.N. Waterhouse, L.-Z. Wu, C.-H. Tung, T. Zhang, Ammonia Detection Methods in Photocatalytic and Electrocatalytic Experiments: How to Improve the Reliability of NH3<\/sub>\u00a0Production Rates?, Advanced Science, (2019) 1802109.<\/p>\n

[12] C. Guo, J. Ran, A. Vasileff, S.-Z. Qiao, Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH3<\/sub>) under ambient conditions, Energy & Environmental Science, 11 (2018) 45-56.<\/p>\n

[13] H.-L. Du, T.R. Gengenbach, R. Hodgetts, D.R. MacFarlane, A.N. Simonov, Critical Assessment of the Electrocatalytic Activity of Vanadium and Niobium Nitrides toward Dinitrogen Reduction to Ammonia, ACS Sustainable Chemistry & Engineering, 7 (2019) 6839-6850.<\/p>\n

[14] B.H.R. Suryanto, H.-L. Du, D. Wang, J. Chen, A.N. Simonov, D.R. MacFarlane, Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia, Nature Catalysis, (2019).<\/p>\n

[15] F.F. Li, S. Licht, Advances in understanding the mechanism and improved stability of the synthesis of ammonia from air and water in hydroxide suspensions of nanoscale Fe2<\/sub>O3<\/sub>, Inorg Chem, 53 (2014) 10042-10044.<\/p>\n

[16] B. Cui, J. Zhang, S. Liu, X. Liu, W. Xiang, L. Liu, H. Xin, M.J. Lefler, S. Licht, Electrochemical synthesis of ammonia directly from N2 <\/sub>and water over iron-based catalysts supported on activated carbon, Green Chem., 19 (2017) 298-304.<\/p>\n

[17] F. Zhou, L.M. Azofra, M. Ali, M. Kar, A.N. Simonov, C. McDonnell-Worth, C. Sun, X. Zhang, D.R. MacFarlane, Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids, Energy & Environmental Science, 10 (2017) 2516-2520.<\/p>\n

[18] Marc-Andr\u00e9 L\u00e9gar\u00e9, 2 Guillaume B\u00e9langer-Chabot,1,2 Rian D. Dewhurst,1,2Eileen Welz,3 Ivo Krummenacher,1,2 Bernd Engels,3 Holger Braunschweig1,, Nitrogen fixation and reduction at boron, Science, 359 (2018) 869-900.<\/p>\n

\u5f80\u671f\u56de\u987e\uff1a<\/strong><\/p>\n

\u8ba4\u8bc6\u8fd9\u4e9b\u5e26\u4f60\u8f7b\u677e\u4e0a\u738b\u8005\u2014\u2014\u7535\u50ac\u5316\u4ea7\u6c27\uff08OER\uff09\u6d4b\u8bd5\u624b\u6bb5\u89e3\u6790<\/a><\/p>\n

\u4f60\u771f\u7684\u4e86\u89e3\u7535\u50ac\u5316\u4ea7\u6c22\u8fd9\u4e9b\u77e5\u8bc6\u5417\uff1f\u5df2\u4e3a\u4f60\u603b\u7ed3\u597d\uff0c\u5feb\u6233\uff01<\/a><\/p>\n

\u7ecf\u5178\u7efc\u8ff0\u96c6\u9526\uff1a\u8fc8\u8fdb\u5149\u7535\u50ac\u5316\u5927\u95e8\uff0c\u8bf7\u4ece\u8fd9\u5341\u7bc7\u7efc\u8ff0\u5f00\u59cb\uff01<\/a><\/p>\n

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\u672c\u6587\u7531\u6625\u6625<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

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