{"id":173058,"date":"2019-04-21T06:30:35","date_gmt":"2019-04-20T22:30:35","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=173058"},"modified":"2019-04-26T14:19:40","modified_gmt":"2019-04-26T06:19:40","slug":"cof%e5%8f%91%e5%b1%95%e7%9a%84%e9%87%8c%e7%a8%8b%e7%a2%91%e3%80%81%e5%91%bd%e5%90%8d%e8%a7%84%e5%88%99%e4%bb%a5%e5%8f%8a%e4%bb%a3%e8%a1%a8%e6%80%a7cof%e6%80%bb%e7%bb%93","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=173058","title":{"rendered":"\u76d8\u70b9\uff1aCOF\u53d1\u5c55\u7684\u91cc\u7a0b\u7891\u3001\u547d\u540d\u89c4\u5219\u4ee5\u53ca\u4ee3\u8868\u6027COF\u603b\u7ed3"},"content":{"rendered":"

\u5f15\u8a00<\/b><\/strong><\/p>\n

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\u5185\u5bb9\u6982\u8981<\/b><\/strong><\/p>\n

1\uff1a\u00a0COFs\u4ecb\u7ecd\uff1a\u4ec0\u4e48\u662f\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff1f<\/strong><\/p>\n

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COFs\u6750\u6599\u6309\u7167\u62d3\u6251\u7ed3\u6784\u53ef\u4ee5\u5206\u6210\u4e8c\u7ef4\u548c\u4e09\u7ef4COFs\uff0c\u5728\u4e8c\u7ef4COFs\u4e2d\uff0c\u5355\u4f53\u901a\u8fc7\u5171\u4ef7\u952e\u8fde\u63a5\u5728\u5e73\u9762\u5185\u5f62\u6210\u5c42\u72b6\u7ed3\u6784\uff0c\u5c42\u4e0e\u5c42\u4e4b\u95f4\u901a\u8fc7\u03c0-\u03c0\u4f5c\u7528\u5f62\u6210\u5171\u8f6d\u4f53\u7cfb\uff0c\u540c\u65f6\u4e5f\u5f62\u6210\u4e00\u7ef4\u7684\u5b54\u9053\uff0c\u5176\u5b54\u9053\u5927\u5c0f\u4e0e\u5f62\u72b6\u4e0e\u5c42\u95f4\u7684\u5806\u79ef\u65b9\u5f0f\u5bc6\u5207\u76f8\u5173\uff1b\u5bf9\u4e8e\u4e09\u7ef4COFs\uff0c\u5355\u4f53\u901a\u8fc7\u5171\u4ef7\u952e\u65e0\u9650\u5ef6\u5c55\uff0c\u5f62\u6210\u5177\u6709\u89c4\u6574\u3001\u5468\u671f\u6027\u7ed3\u6784\u7684\u6846\u67b6\u3002\u4e0e\u4e8c\u7ef4COFs\u4e0d\u540c\u7684\u662f\uff0c\u4e09\u7ef4COFs\u5728\u4e09\u7ef4\u7a7a\u95f4\u5ef6\u5c55\u7684\u65f6\u5019\uff0c\u5bb9\u6613\u5f62\u6210\u8f83\u5927\u7684\u7b3c\u72b6\u7a7a\u8154\uff0c\u800c\u5355\u4f53\u53ef\u4ee5\u5728\u7a7a\u8154\u91cc\u7ee7\u7eed\u53cd\u5e94\uff0c\u5411\u5916\u751f\u957f\uff0c\u4ece\u800c\u4f7f\u5f97\u4e09\u7ef4COF\u5f80\u5f80\u5f97\u5230\u7684\u662f\u591a\u91cd\u7a7f\u63d2\u7684\u7ed3\u6784\u3002<\/p>\n

2\uff1aCOF \u53d1\u5c55\u7684\u91cc\u7a0b\u7891\uff1a\u91cd\u8981COF\u7b80\u4ecb\u3002<\/strong><\/p>\n

2005\u5e74Yaghi\u8bfe\u9898\u7ec41<\/b><\/sup><\/strong><\/a>\u9996\u6b21\u62a5\u9053\u4e86\u7531\u787c\u9178\u81ea\u805a\u548c\u787c\u9178\u548c\u591a\u915a\u5316\u5408\u7269\u7f29\u805a\u5f97\u5230\u7684\u4e24\u4e2aCOFs, COF-1\u548cCOF-5\u3002\u5982\u540cMOF\u7cfb\u5217\u547d\u540d\u4e00\u6837\uff0cYaghi\u8bfe\u9898\u7ec4\u5bf9COF\u7684\u547d\u540d\u4e5f\u662fCOF-x\u7cfb\u5217\u3002COF-1\u662f\u4e8c\u7ef4\u516d\u65b9\u7684\u5e73\u9762\u62d3\u6251\uff0c\u5c42\u4e4b\u95f4\u91c7\u53d6AB\u5806\u79ef\u65b9\u5f0f\uff0cCOF-5\u4e5f\u662f\u4e8c\u7ef4\u516d\u65b9\u7684\u5e73\u9762\u62d3\u6251\uff0c\u5c42\u95f4\u91c7\u53d6\u5b8c\u5168\u91cd\u53e0\u7684AA\u5806\u79ef\u6a21\u5f0f\u3002<\/p>\n

\u56fe1. COF-1\u548cCOF-5\u7684\u5408\u6210\u4e0e\u7ed3\u6784\u5f0f<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2007\u5e74Yaghi\u8bfe\u9898\u7ec42<\/b><\/sup><\/strong><\/a>\u9996\u6b21\u62a5\u9053\u4e86\u56db\u4f8b\u4e09\u7ef4COFs, \u5176\u8bbe\u8ba1\u7684\u5173\u952e\u5728\u4e8e\u9009\u62e9\u4e86\u5177\u6709Td<\/sub>\u5bf9\u79f0\u6027\u7684\u6b63\u56db\u9762\u4f53\u6784\u578b\u5355\u4f53\uff1a\u56db\u82ef\u57fa\u7532\u70f7\u787c\u9178\uff08TBPM\u548cTBPS\uff09\uff0c\u8ddfC3<\/sub>\u5bf9\u79f0\u6027\u7684\u4e09\u89d2\u5f62\u6784\u578b\u7684\u591a\u915a\u5316\u5408\u7269HHTP\u7ec4\u5408\uff0c TBPM\u548cTBPS\u81ea\u7f29\u805a\u5f62\u6210COF-102\u548cCOF-103, TBPM\u548cTBPS\u5206\u522b\u4e0eHHTP\u7f29\u805a\u5f97\u5230COF-105\u548cCOF-108\uff0c\u5176\u4e2dCOF-102\u3001 COF-103\u548cCOF-108\u4e3actn<\/b><\/strong>\u4e09\u7ef4\u62d3\u6251\u6784\u578b\uff0cCOF-105\u4e3abor<\/b><\/strong>\u4e09\u7ef4\u62d3\u6251\u6784\u578b\u3002<\/p>\n

\u56fe2.\u4e09\u7ef4COF-102, COF-103, COF-105\u548c COF-108\u7684\u62d3\u6251\u548c\u7ed3\u6784\u5f0f<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2008\u5e74\uff0cArne Thomas\u7b493<\/b><\/sup><\/strong><\/a>\u901a\u8fc7\u6c30\u57fa\u7684\u4e09\u805a\u7f29\u5408\u5f97\u5230\u4e09\u55ea\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff0cCTF-1.\u8be5\u7c7b\u578bCOF\u5927\u591a\u6570\u662f\u5728ZnCl2<\/sub>\u50ac\u5316\uff0c400\u2103\u6761\u4ef6\u4e0b\u53cd\u5e94\u5f97\u5230\uff0c\u867d\u7136\u5176\u7a33\u5b9a\u6027\u5f88\u597d\uff0c\u4f46\u5927\u90e8\u5206\u6c30\u57fa\u7684\u7f29\u805a\u5f97\u5230\u7684\u7ed3\u6676\u6027\u5e76\u4e0d\u597d\uff0c\u8fd9\u4e5f\u9650\u5236\u4e86CTF\u7684\u53d1\u5c55\u3002<\/p>\n

\u56fe3. CTF-1\u7684\u7ed3\u6784\u5f0f<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2011\u5e74\u738b\u4e3a\u8bfe\u9898\u7ec44<\/b><\/sup><\/strong><\/a>\u62a5\u9053\u4e86\u7531\u5747\u4e09\u82ef\u7532\u919b\u548c\u5bf9\u82ef\u4e8c\u80fa\u5408\u6210\u7684\u919b\u80fa\u8fde\u63a5\u7684COF-LZU-1\uff0c\u540c\u65f6\u4e5f\u5c06\u5176\u901a\u8fc7\u5c06\u918b\u9178\u94af\u8d1f\u8f7d\u5230COF-LZU1\u7684\u5c42\u95f4\u8ddd\u4e2d\uff0c\u5c06\u5176\u5e94\u7528\u5728Suzuki-Miyaura\u5076\u8054\u53cd\u5e94\u7684\u50ac\u5316\u4e0a\uff0c\u8fd9\u4e5f\u662f\u9996\u6b21\u5c06\u591a\u5b54\u7684COF\u6750\u6599\u505a\u4e3a\u50ac\u5316\u5242\u8f7d\u4f53\uff0c\u5e94\u7528\u4e8e\u5f02\u76f8\u50ac\u5316\u9886\u57df\uff0c\u50ac\u5316\u4e5f\u662f\u76ee\u524dCOF\u5e94\u7528\u6700\u4e3a\u5e7f\u6cdb\u7684\u9886\u57df\u4e4b\u4e00\u3002<\/p>\n

\u56fe4. COF-LZU-1\u7684\u5408\u6210\u53ca\u8d1f\u8f7dPd\u50ac\u5316<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2015\u5e74\uff0c\u6c5f\u4e1c\u6797\u8bfe\u9898\u7ec45<\/b><\/sup><\/strong><\/a>\u901a\u8fc7\u5728\u6784\u5efa\u5355\u5143\u7684\u4e8c\u919b\u5355\u4f53\u4e0a\u5f15\u5165\u4e24\u4e2a\u7532\u6c27\u57fa\uff0c\u6210\u529f\u5408\u6210\u4e86\u9996\u4f8b\u5728\u5f3a\u9178\u5f3a\u78b1\u548c\u6cb8\u6c34\u4e2d\u90fd\u80fd\u7a33\u5b9a\u5b58\u5728\u7684COFs\u3002\u901a\u8fc7\u540e\u4fee\u9970\u7684\u65b9\u6cd5\uff0c\u6210\u529f\u5730\u5c06\u624b\u6027\u5421\u54af\u70f7\u50ac\u5316\u5242\u5f15\u5165\u5230COFs\u5b54\u9053\u4e2d\uff0c\u5f97\u5230\u7684\u529f\u80fd\u5316\u50ac\u5316\u5242\u53ef\u4ee5\u5728\u6c34\u4e2d\u9ad8\u6548\u50ac\u5316\u4e0d\u5bf9\u79f0Michael\u52a0\u6210\u53cd\u5e94\u3002<\/p>\n

\u56fe5. TPB-DMTP-COF\u7684\u7ed3\u6784\u5f0f\u53ca\u540e\u4fee\u9970\u624b\u6027\u50ac\u5316\u5242<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2016\u5e74\uff0c\u5f20\u5e06\u8bfe\u9898\u7ec46<\/b><\/sup><\/strong><\/a>\u9996\u6b21\u62a5\u9053\u4e86\u78b3\u78b3\u53cc\u952e\u8fde\u63a5\u7684\u7a33\u5b9aCOF, 2DPPV\uff0c\u7531\u4e8e\u78b3\u78b3\u53cc\u952e\u4e0e\u7ec4\u6210COF\u9aa8\u67b6\u7684\u82ef\u73af\u03c0-\u03c0\u5171\u8f6d\u7a0b\u5ea6\u9ad8\u5ea6\u4e00\u81f4\uff0c\u4f7f\u5f97\u8be5\u7c7b\u6750\u6599\u5728\u5149\u7535\u9886\u57df\u5177\u6709\u8bf1\u4eba\u7684\u5e94\u7528\u524d\u666f\uff0c\u800c\u78b3\u78b3\u53cc\u952e\u6bd4\u76ee\u524d\u4e3b\u6d41\u7684\u4e9a\u80fa\u952eCOF\u66f4\u52a0\u7a33\u5b9a\uff0c\u5176\u8fb9\u7f18\u6b8b\u7559\u7684\u6c30\u57fa\u5219\u4e3a\u5c06\u6765\u7684\u540e\u4fee\u9970\u7559\u4e0b\u66f4\u591a\u7684\u60f3\u8c61\u7a7a\u95f4\uff0c\u8be5\u5de5\u4f5c\u53d1\u8868\u5728\u9ad8\u5206\u5b50\u9886\u57df\u7684\u4e13\u4e1a\u671f\u520aPolymer Chemistry\u4e0a\uff0c\u4f46\u65e0\u7591\u8fd9\u662fCOF\u8fde\u63a5\u7c7b\u578b\u4e43\u81f3COF\u53d1\u5c55\u53f2\u4e0a\u7684\u7684\u5de8\u5927\u7a81\u7834\u3002\u800c\u57282018\u5e74\uff0c\u6c5f\u4e1c\u6797\u8bfe\u9898\u7ec47<\/b><\/sup><\/strong><\/a>\u4e5f\u62a5\u9053\u4e86\u7c7b\u4f3c\u7684\u78b3\u78b3\u53cc\u952e\u8fde\u63a5\u7684COF: sp2<\/sup>c-COF\uff0c\u5e76\u8be6\u7ec6\u8868\u5f81\u4e86\u8fd9\u79cd\u5168sp2<\/sup>c\u5171\u8f6d\u8986\u76d6\u7684COF\u5728\u78c1\u6027\uff0c\u81ea\u7531\u57fa\u7b49\u65b9\u9762\u7684\u57fa\u672c\u6027\u80fd\u3002<\/p>\n

\u56fe6. (\u5de6)<\/b><\/strong>\u00a02DPPV <\/b><\/strong>\u2013<\/b><\/strong>COF\u548c(\u53f3) sp<\/b><\/strong>2<\/b><\/sup><\/strong>c-COF<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

2018\u5e74\uff0c\u738b\u4e3a\u8bfe\u9898\u7ec4\u4e0e\u5b59\u4fca\u826f\uff0cYaghi\u7b498<\/b><\/sup><\/strong>\u5408\u4f5c\uff0c\u9996\u6b21\u5b9e\u73b0\u4e86\u57fa\u4e8e\u4e9a\u80fa\u952e\u7684\u4e09\u7ef4COF\u5927\u5c3a\u5bf8\u3001\u5355\u6676\u7684\u751f\u957f\u548cX-\u5c04\u7ebf\u884d\u5c04\uff08SXRD\uff09\u7ed3\u6784\u89e3\u6790\u3002\u867d\u7136\u6b64\u524d\u4e5f\u6709\u4e9a\u785d\u57fa\u952e\u5408\u7684\u5355\u66769<\/b><\/sup><\/strong>\uff0c\u4ee5\u53ca\u901a\u8fc7\u7535\u5b50\u884d\u5c04\u786e\u5b9a\u7ed3\u6784\u7684\u62a5\u905310<\/b><\/sup><\/strong>\uff0c\u8be5\u5de5\u4f5c\u63d0\u51fa\u4e86\u901a\u8fc7\u6dfb\u52a0\u7ade\u4e89\u6027\u8c03\u8282\u5242\u548c\u6210\u6838\u6291\u5236\u5242\u7684\u7b56\u7565\uff0c\u65e0\u7591\u66f4\u5177\u6709\u666e\u9002\u6027\u548c\u53ef\u64cd\u4f5c\u6027\uff0c\u800c\u4e14\u4e9a\u80fa\u952eCOF\u662f\u76ee\u524d\u5e94\u7528\u6700\u4e3a\u5e7f\u6cdb\u7684COF\uff0c\u4e9a\u80fa\u952eCOF\u5355\u6676\u7684\u6210\u529f\u6784\u5efa\uff0c\u4e3a\u9ad8\u8d28\u91cf\u7ed3\u6676\u6027COF\u7684\u5b9e\u9645\u5e94\u7528\u5960\u5b9a\u4e86\u575a\u5b9e\u57fa\u7840\u3002<\/p>\n

\u56fe7. \u4e09\u7ef4\u5355\u6676COF<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe7. JUC-505\/506\u7684\u5408\u6210<\/b><\/strong><\/p>\n

\"\"<\/p>\n

3\uff1aCOF \u547d\u540d\u89c4\u5219\u3002<\/strong><\/p>\n

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COF- LZU-x\u7cfb\u5217\uff1a\u5170\u5dde\u5927\u5b66\u738b\u4e3a\u8bfe\u9898\u7ec4\u4f7f\u7528\u3002<\/p>\n

SIOC-COF-x\u7cfb\u5217\uff1a\u6709\u673a\u6240\u8d75\u65b0\u8bfe\u9898\u7ec4\u4f7f\u7528\uff0c\u4e0d\u8fc7\u8d75\u8001\u5e08\u5e76\u4e0d\u662f\u6240\u6709COF\u90fd\u6309\u8fd9\u4e2a\u89c4\u5219\u547d\u540d\uff0c\u4ed6\u4eec\u8bfe\u9898\u7ec4\u4e5f\u6709\u5927\u91cf\u7684COF\u547d\u540d\u91c7\u7528\u5355\u4f53\u9996\u5b57\u6bcd\u7ec4\u5408\uff0c\u5982COF-TTTA-TPTA\u7b49\u3002<\/p>\n

CCOF-x\u7cfb\u5217\uff1a\u624b\u6027COF\u4ee3\u53f7\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u5d14\u52c7\u8bfe\u9898\u7ec4\u4f7f\u7528\uff0c\u76ee\u524d\u7684CCOF-1\u5230CCOF-8\u5747\u53d1\u8868\u5728JACS\u4e0a\uff0c CCOF\u7cfb\u5217\u547d\u540d\u7279\u6307\u6784\u7b51\u5355\u4f53\u672c\u5f81\u5177\u6709\u624b\u6027\u7684COF\uff0c\u8be5\u8bfe\u9898\u4e5f\u62a5\u9053\u4e00\u4e9b\u4fee\u9970\u6216\u8005\u8bf1\u5bfc\u65b9\u5f0f\u5f97\u5230\u7684\u624b\u6027COF\uff0c\u7136\u800c\u5e76\u6ca1\u6709\u4f7f\u7528CCOF-x\u7684\u4ee3\u53f7\u3002<\/p>\n

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4\uff1a\u5c55\u671b<\/strong><\/p>\n

\u901a\u8fc7COF\u6750\u6599\u7684\u53d1\u5c55\u53f2\u6211\u4eec\u53ef\u4ee5\u770b\u51fa\uff0c\u8fd1\u5341\u5e74\u6765\uff0c\u4e00\u4e2a\u53c8\u4e00\u4e2a\u65b0COF\u88ab\u5408\u6210\u3001\u8868\u5f81\u3001\u53d1\u8868\uff0c\u6570\u636e\u5e93\u9010\u6e10\u4e30\u5bcc\u3002\u968f\u7740COF\u6750\u6599\u79cd\u7c7b\u7684\u65e5\u76ca\u589e\u591a\u4ee5\u53ca\u590d\u5408COF\u6750\u6599\u7684\u9010\u6e10\u5174\u8d77\uff0cCOF\u6750\u6599\u5c06\u6709\u4e0d\u53ef\u4f30\u91cf\u7684\u5e94\u7528\u524d\u666f\u3002\u7136\u800c\uff0cCOF\u7684\u5408\u6210\u76ee\u524d\u4ecd\u7136\u662f\u4e2a\u96be\u9898\uff0c\u4ece\u952e\u5408\u65b9\u5f0f\u7684\u4e0d\u65ad\u53d1\u5c55\uff0c\u5230\u5408\u6210\u6761\u4ef6\uff0c\u5de5\u827a\u7684\u521b\u65b0\u3002\u4ee5\u53ca\u5404\u79cd\u6027\u80fd\u7684\u5f00\u62d3\uff0c\u90fd\u9700\u8981\u4f17\u591a\u79d1\u7814\u4eba\u5458\u4e0d\u61c8\u52aa\u529b\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

(1) C\u00f4t\u00e9, A. P.; Benin, A. I.; Ockwig, N. W.; O’Keeffe, M.; Matzger, A. J.; Yaghi, O. M. Porous, Crystalline, Covalent Organic Frameworks. Science<\/strong>.<\/i><\/em>\u00a02005<\/b><\/strong>, 310<\/i><\/em>, 1166.<\/p>\n

(2) El-Kaderi, H. M.; Hunt, J. R.; Mendoza-Cort\u00e9s, J. L.; C\u00f4t\u00e9, A. P.; Taylor, R. E.; O’Keeffe, M.; Yaghi, O. M. Designed Synthesis of 3D Covalent Organic Frameworks. Science.<\/i><\/em><\/strong>\u00a02007<\/b><\/strong>, 316<\/i><\/em>, 268.<\/p>\n

(3) Kuhn, P.; Antonietti, M.; Thomas, A. Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis. Angew. Chem., Int. Ed.<\/i><\/em><\/strong>\u00a02008<\/b><\/strong>, 47<\/i><\/em>, 3450.<\/p>\n

(4) Ding, S.-Y.; Gao, J.; Wang, Q.; Zhang, Y.; Song, W.-G.; Su, C.-Y.; Wang, W. Construction of Covalent Organic Framework for Catalysis: Pd\/COF-LZU1 in Suzuki\u2013Miyaura Coupling Reaction. J. Am. Chem. Soc.<\/strong><\/i><\/em>\u00a02011<\/b><\/strong>, 133<\/i><\/em>, 19816.<\/p>\n

(5) Xu, H.; Gao, J.; Jiang, D. Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts. Nat. Chem.<\/i><\/em>\u00a02015<\/b><\/strong>, 7<\/i><\/em>, 905.<\/p>\n

(6) Zhuang, X.; Zhao, W.; Zhang, F.; Cao, Y.; Liu, F.; Bi, S.; Feng, X. A two-dimensional conjugated polymer framework with fully sp2-bonded carbon skeleton. Polymer Chemistry.<\/i><\/em>\u00a02016<\/b><\/strong>, 7<\/i><\/em>, 4176.<\/p>\n

(7) Jin, E.; Asada, M.; Xu, Q.; Dalapati, S.; Addicoat, M. A.; Brady, M. A.; Xu, H.; Nakamura, T.; Heine, T.; Chen, Q.; Jiang, D. Two-dimensional sp2<\/sup>\u00a0carbon\u2013conjugated covalent organic frameworks. Science<\/strong>.<\/i><\/em>\u00a02017<\/b><\/strong>, 357<\/i><\/em>, 673.<\/p>\n

(8) Ma, T.; Kapustin, E. A.; Yin, S. X.; Liang, L.; Zhou, Z.; Niu, J.; Li, L.-H.; Wang, Y.; Su, J.; Li, J.; Wang, X.; Wang, W. D.; Wang, W.; Sun, J.; Yaghi, O. M. Single-crystal x-ray diffraction structures of covalent organic frameworks. Science.<\/i><\/em>\u00a02018<\/b><\/strong>, 361<\/i><\/em>, 48.<\/p>\n

(9) Beaudoin, D.; Maris, T.; Wuest, J. D. Constructing monocrystalline covalent organic networks by polymerization. Nat. Chem<\/strong>.<\/i><\/em>\u00a02013<\/b><\/strong>, 5<\/i><\/em>, 830.<\/p>\n

(10) Zhang, Y.-B.; Su, J.; Furukawa, H.; Yun, Y.; Ga\u0301ndara, F.; Duong, A.; Zou, X.; Yaghi, O. M. Single-crystal structure of a covalent organic framework. J. Am. Chem. Soc<\/strong>.<\/i><\/em>\u00a02013<\/b><\/strong>, 135<\/i><\/em>, 16336.<\/p>\n

(11) Zhang, B.; Wei, M.; Mao, H.; Pei, X.; Alshmimri, S. A.; Reimer, J. A.; Yaghi, O. M. Crystalline Dioxin-Linked Covalent Organic Frameworks from Irreversible Reactions. J. Am. Chem.<\/strong> Soc.<\/i><\/em>\u00a02018<\/b><\/strong>, 140<\/i><\/em>, 12715.<\/p>\n

(12) Guan, X.; Li, H.; Ma, Y.; Xue, M.; Fang, Q.; Yan, Y.; Valtchev, V.; Qiu, S. Chemically stable polyarylether-based covalent organic frameworks. Nat. Chem.<\/i><\/em><\/strong>\u00a02019<\/b><\/strong>.\u00a0DOI:10.1038\/s41557-019-0238-5<\/p>\n

\u5f80\u671f\u56de\u987e\uff1a<\/strong><\/p>\n

\u6253\u901aMOFs\u4efb\u7763\u4e8c\u8109 \u2014\u2014 \u77e5\u540d\u671f\u520a\u8fd1\u671f\u901f\u89c8<\/a><\/p>\n

\u53d8\u5f62\u8bb0\uff1a\u5982\u4f55\u6784\u5efaMOF\u7684\u516b\u9762\u73b2\u73d1\u5fc3<\/a><\/p>\n

MOF\u4e13\u680f & PPT \u2014\u2014 \u56fd\u9645\u77e5\u540dMOF\u5927\u725b\u96c6\u9526<\/a><\/div>\n
\u00a0<\/div>\n
MOF\u4e13\u680f & PPT\u2014\u2014\u56fd\u5185MOF\u5927\u725b\u96c6\u9526<\/a><\/div>\n
\u00a0<\/div>\n
\u88abNature\u3001Science\u6367\u7ea2\u7684\u660e\u661f: MOF\u53d1\u5c55\u7684\u91cc\u7a0b\u7891\u3001\u547d\u540d\u89c4\u5219\u4ee5\u53ca\u4ee3\u8868\u6027MOF\u603b\u7ed3<\/a><\/div>\n
\u00a0<\/div>\n

\u672c\u6587\u7531\u77f3\u6960\u82b1\u5f00Say-goodbye\u00a0<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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\u5f15\u8a00 \u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u00a0\u662f\u8fd1\u5e74\u6765\u53d1\u5c55\u7684\u4e00\u7c7b\u901a\u8fc7\u5171\u4ef7\u952e\u8fde\u63a5\u7684\u591a\u5b54\u6709\u673a\u6676\u4f53\u6750\u6599\u3002COFs\u6750\u6599\u7684\u591a\u5b54\u6027\u3001 \u7ed3\u6676\u6027\u53ca\u4e8c\u7ef4\u65b9\u5411\u7684\u03c0\u7535\u5b50\u5171\u8f6d\u4f53\u7cfb\u3001\u5c42\u95f4\u6709\u5e8f\u7684\u03c0-\u03c0\u67f1…<\/p>\n","protected":false},"author":10213,"featured_media":174193,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-173058","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/173058"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=173058"}],"version-history":[{"count":11,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/173058\/revisions"}],"predecessor-version":[{"id":173240,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/173058\/revisions\/173240"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/174193"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=173058"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=173058"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=173058"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}