{"id":173120,"date":"2019-04-21T06:30:35","date_gmt":"2019-04-20T22:30:35","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=173120"},"modified":"2019-04-20T17:43:58","modified_gmt":"2019-04-20T09:43:58","slug":"%e3%80%90%e6%a0%a1%e7%a8%bf%e6%9c%aa%e5%9b%9e%e5%a4%8d%e3%80%91%e5%8d%97%e6%96%b9%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6nat-chem-%e5%9f%ba%e4%ba%8e%e5%87%86%e8%81%9a%e8%bd%ae%e7%83%b7%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=173120","title":{"rendered":"\u5357\u65b9\u79d1\u6280\u5927\u5b66Nat. Chem.: \u57fa\u4e8e\u51c6\u805a\u8f6e\u70f7\u7684\u77ac\u6001\u9ad8\u5ea6\u53ef\u62c9\u4f38\u6c34\u51dd\u80f6\u7684\u526a\u5207\u8bf1\u5bfc\u7ec4\u88c5"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5206\u5b50\u81ea\u7ec4\u88c5\u662f\u751f\u7269\u7cfb\u7edf\u4e2d\u7684\u4e00\u79cd\u5e38\u89c1\u73b0\u8c61\uff0c\u4e5f\u662f\u6784\u7b51\u5177\u6709\u9ad8\u7ea7\u529f\u80fd\u7ed3\u6784\u7684\u6709\u6548\u624b\u6bb5\u3002\u901a\u8fc7\u5411\u81ea\u7136\u5b66\u4e60\uff0c\u5316\u5b66\u5bb6\u4eec\u5df2\u7ecf\u5229\u7528\u81ea\u7ec4\u88c5\u65b9\u6cd5\u6784\u5efa\u4e86\u5404\u79cd\u8d85\u5206\u5b50\u7ed3\u6784\uff0c\u800c\u4e14\u8fd9\u4e9b\u5206\u5b50\u81ea\u7ec4\u88c5\u7ed3\u6784\u901a\u5e38\u662f\u70ed\u529b\u5b66\u7a33\u5b9a\u7684\u3002\u7136\u800c\u5b9e\u9645\u751f\u547d\u4f53\u4e2d\u7684\u5206\u5b50\u81ea\u7ec4\u88c5\u591a\u662f\u9700\u8981\u8bf8\u5982\u5149\u3001\u7535\u3001\u78c1\u7b49\u7684\u9a71\u52a8\u4e0b\u5b8c\u6210\u7684\uff0c\u8fd9\u79cd\u7ec4\u88c5\u673a\u5236\u88ab\u79f0\u4e3a\u8017\u6563\u81ea\u7ec4\u88c5\u3002\u8017\u6563\u81ea\u7ec4\u88c5\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u975e\u5e38\u6709\u5438\u5f15\u529b\uff0c\u56e0\u4e3a\u5b83\u53ef\u4ee5\u4ea7\u751f\u6a21\u4eff\u751f\u7269\u4f53\u7cfb\u7684\u7279\u6027\u5982\u81ea\u6211\u4fee\u590d\u548c\u9002\u5e94\u6027\u7b49\uff0c\u4f46\u662f\u5927\u591a\u6570\u5df2\u77e5\u7684\u8017\u6563\u81ea\u7ec4\u88c5\u7cfb\u7edf\u663e\u793a\u51fa\u8f83\u5dee\u7684\u673a\u68b0\u6027\u80fd\u3002\u867d\u7136\u526a\u5207\u529b\u4f1a\u7834\u574f\u81ea\u7ec4\u88c5\u4f53\u7cfb\uff0c\u5728\u7279\u5b9a\u60c5\u51b5\u4e0b\u526a\u5207\u4e5f\u4f1a\u5f15\u53d1\u67d0\u4e9b\u77ac\u6001\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u5982\u526a\u5207\u589e\u7a20\u6d41\u4f53\u7b49\u3002\u76ee\u524d\u4e5f\u6709\u5728\u526a\u5207\u6761\u4ef6\u4e0b\u5f62\u6210\u51dd\u80f6\u7684\u62a5\u9053\uff0c\u53ea\u662f\u8fd9\u4e9b\u77ac\u6001\u51dd\u80f6\u975e\u5e38\u67d4\u8f6f\u5e76\u6ca1\u6709\u5b9e\u9645\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u65b9\u79d1\u6280\u5927\u5b66\u848b\u4f1f\u6559\u6388<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u8d85\u5206\u5b50\u6c34\u51dd\u80f6\u5728\u526a\u5207\u529b\u6761\u4ef6\u4e0b\u7684\u81ea\u7ec4\u88c5\uff0c\u8be5\u81ea\u7ec4\u88c5\u4f53\u7cfb\u5305\u62ec\u805a\u4e59\u4e8c\u9187\u3001\u5206\u5b50\u7ba1\u3001Cu(NO3<\/sub>)2<\/sub>\u548c\u53bb\u79bb\u5b50\u6c34\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u5f53\u901a\u8fc7\u6da1\u65cb\u632f\u8361\u5668\u65bd\u52a0\u526a\u5207\u529b\u65f6\uff0c\u6240\u5f97\u6df7\u5408\u7269\u4ece\u6eb6\u80f6\u8f6c\u53d8\u4e3a\u51dd\u80f6\u3002\u77ac\u6001\u6c34\u51dd\u80f6\u53ef\u5728\u5ba4\u6e29\u4e0b\u6301\u7eed\u6570\u5c0f\u65f6\u6216\u6570\u5929\uff0c\u5177\u6709\u4f18\u5f02\u7684\u62c9\u4f38\u6027\u548c\u5feb\u901f\u81ea\u6108\u6027\u3002\u6c34\u51dd\u80f6\u80fd\u591f\u9010\u6e10\u677e\u5f1b\u53d8\u4e3a\u6eb6\u80f6\u72b6\u6001\uff0c\u6eb6\u80f6\u53c8\u53ef\u4ee5\u5728\u526a\u5207\u529b\u4e0b\u8f6c\u53d8\u56de\u51dd\u80f6\uff0c\u800c\u4e14\u8be5\u8fc7\u7a0b\u53ef\u4ee5\u91cd\u590d\u591a\u6b21\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a” Shear-induced assembly of a transient yet highly stretchable hydrogel based on pseudopolyrotaxanes <\/strong>“\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNature Chemistry<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u5316\u5b66\u7ed3\u6784\u548c\u51dd\u80f6\u5316\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5206\u5b50\u7ba11\u548c2\u7684\u5316\u5b66\u7ed3\u6784\uff1b<\/p>\n

(b) \u5206\u5b50\u7ba1\u548cPEG\u94fe\u7684\u793a\u610f\u56fe\u4ee5\u53ca\u5b83\u4eec\u4e4b\u95f4\u53ef\u80fd\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff1b<\/p>\n

(c) \u901a\u8fc7\u91d1\u5c5e\u914d\u4f4d\u5230\u51c6\u805a\u8f6e\u70f7\u7684\u51dd\u80f6\u673a\u5236\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(d) OEGs\u7684\u5316\u5b66\u7ed3\u6784\u548c\u5b83\u4eec\u7684\u7532\u919a\u5bf9\u5e94\u7269\u4f5c\u4e3a\u5bf9\u7167\u5316\u5408\u7269\u3002<\/p>\n

\u56fe2 \u526a\u5207\u5f15\u8d77\u7684\u51dd\u80f6\u5316<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u7528\u4e0d\u540c\u91d1\u5c5e\u79bb\u5b50\u51dd\u80f6\u5316\u7684\u5012\u7f6e\u7ba1\u8bd5\u9a8c\uff1b<\/p>\n

(b) \u57fa\u4e8eCu\u6c34\u51dd\u80f6\u7684\u523a\u6fc0\u54cd\u5e94\u7279\u6027\uff1b<\/p>\n

(c) \u51dd\u80f6\u548c\u6eb6\u80f6\u72b6\u6001\u4e0bCu\u57fa\u6c34\u51dd\u80f6\u7684\u6d41\u53d8\u6027\u8d28\uff1b<\/p>\n

(d) \u968f\u7740\u65f6\u95f4\u63a8\u79fb\u51dd\u80f6\u50a8\u80fd\u6a21\u91cf\u7684\u6f14\u53d8\uff1b<\/p>\n

(e) \u901a\u8fc7\u6447\u52a830\u79d2\u5e76\u7b49\u5f8512\u5c0f\u65f6\u91cd\u590d\u51dd\u80f6-\u6eb6\u80f6\u5faa\u73af\u3002<\/p>\n

\u56fe3 OEG\u548c1a\u4e4b\u95f4\u7684\u7ed3\u5408\u4eb2\u548c\u529b\u548c\u9a71\u52a8\u529b<\/strong><\/p>\n

\"\"<\/p>\n

(a) 7@2b\u7684X\u5c04\u7ebf\u5355\u6676\u7ed3\u6784\uff1b<\/p>\n

(b) \u5728\u7528D2<\/sub>O : H2<\/sub>O (1 : 9)\u4e2d\u76847\u6ef4\u5b9a1a\u7684\u90e8\u52061<\/sup>H NMR\u8c31\u56fe\uff1b<\/p>\n

(c) \u7f14\u5408\u5e38\u6570\u4e0eOEGs\u4e2d\u4e59\u4e8c\u9187\u5355\u5143\u6570\u4e4b\u95f4\u7684\u7ebf\u6027\u5173\u7cfb\u3002<\/p>\n

\u56fe4 \u526a\u5207\u8bf1\u5bfc\u51dd\u80f6\u5316\u548c\u70ed\u677e\u5f1b\u7684\u673a\u7406\u548c\u8bc1\u636e<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u63d0\u51fa\u7684\u526a\u5207\u8bf1\u5bfc\u51dd\u80f6\u5316\u548c\u70ed\u677e\u5f1b\u673a\u5236\uff1b<\/p>\n

(b) DFT\u4f18\u5316\u7684\u94fe\u5185\u914d\u4f4d\u7edc\u5408\u7269\u4e0eCu\u79bb\u5b50\u30011a\u548c\u4e03\u805a\u4e59\u4e8c\u9187\u7684\u7ed3\u6784\uff1b<\/p>\n

(c) \u5728\u6da1\u65cb\u632f\u8361\u5668\u4e0a\u632f\u8361\u6eb6\u6db230\u79d2\u5e76\u7b49\u5f8512\u5c0f\u65f6\u540e\uff0cCu\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

(d) \u6447\u52a8\u548c\u8001\u5316\u4e4b\u95f4\u7684\u4e94\u4e2a\u5faa\u73af\u3002<\/p>\n

\u56fe5 \u77ac\u6001\u6c34\u51dd\u80f6\u7684\u6027\u8d28\u548c\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u6c34\u51dd\u80f6\u53ef\u62c9\u4f38\u6027\u7684\u8bc1\u660e\uff1b<\/p>\n

(b) \u6c34\u51dd\u80f6\u9ad8\u62c9\u4f38\u6027\u673a\u5236\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(c) \u526a\u5207\u8f85\u52a9\u6c34\u51dd\u80f6\u7684\u5feb\u901f\u81ea\u6211\u4fee\u590d\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u4e00\u79cd\u526a\u5207\u8bf1\u5bfc\u7684\u77ac\u6001\u6c34\u51dd\u80f6\uff0c\u5267\u70c8\u6447\u52a8\u53ef\u4ee5\u5c06\u6eb6\u80f6\u8f6c\u53d8\u6210\u6c34\u51dd\u80f6\uff0c\u800c\u968f\u7740\u65f6\u95f4\u7684\u63a8\u79fb\u5176\u53c8\u80fd\u591f\u677e\u5f1b\u56de\u6eb6\u80f6\u72b6\u6001\uff0c\u8be5\u5faa\u73af\u53ef\u4ee5\u91cd\u590d\u81f3\u5c11\u4e94\u6b21\u3002\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u673a\u5236\uff0c\u5176\u4f9d\u8d56\u4e8e\u526a\u5207\u8bf1\u5bfc\u7684\u4ece\u94fe\u5185\u5230\u94fe\u95f4\u7684\u914d\u4f4d\u8f6c\u53d8\u4ee5\u53ca\u968f\u540e\u7684\u70ed\u5f1b\u8c6b\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u5904\u4e8e\u975e\u5e73\u8861\u6001\u7684\u77ac\u6001\u6c34\u51dd\u80f6\u662f\u9ad8\u5ea6\u53ef\u62c9\u4f38\u7684\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u5206\u5b50\u7ba1\u5728\u805a\u4e59\u4e8c\u9187\u94fe\u4e0a\u7684\u201c\u6469\u64e6\u201d\u6ed1\u52a8\u3002\u8be5\u7814\u7a76\u8868\u660e\u4e86\u8017\u6563\u81ea\u7ec4\u88c5\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u5de8\u5927\u6f5c\u529b\uff0c\u5c24\u5176\u662f\u5728\u673a\u68b0\u54cd\u5e94\u6027\u6750\u6599\u7684\u8bbe\u8ba1\u548c\u5236\u5907\u4e2d\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aShear-induced assembly of a transient yet highly stretchable hydrogel based on pseudopolyrotaxanes<\/a>\u00a0(Nat. Chem. 2019, DOI: 10.1038\/s41557-019-0235-8)<\/strong><\/p>\n

\u672c\u6587\u7531biotech\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u5ba1\u6838\u6574\u7406\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002<\/strong>\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5206\u5b50\u81ea\u7ec4\u88c5\u662f\u751f\u7269\u7cfb\u7edf\u4e2d\u7684\u4e00\u79cd\u5e38\u89c1\u73b0\u8c61\uff0c\u4e5f\u662f\u6784\u7b51\u5177\u6709\u9ad8\u7ea7\u529f\u80fd\u7ed3\u6784\u7684\u6709\u6548\u624b\u6bb5\u3002\u901a\u8fc7\u5411\u81ea\u7136\u5b66\u4e60\uff0c\u5316\u5b66\u5bb6\u4eec\u5df2\u7ecf\u5229\u7528\u81ea\u7ec4\u88c5\u65b9\u6cd5\u6784\u5efa\u4e86\u5404\u79cd\u8d85\u5206\u5b50\u7ed3\u6784\uff0c\u800c\u4e14\u8fd9\u4e9b\u5206\u5b50…<\/p>\n","protected":false},"author":7746,"featured_media":173121,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3336,2600],"class_list":["post-173120","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-3336","tag-2600"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/173120"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7746"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=173120"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/173120\/revisions"}],"predecessor-version":[{"id":173401,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/173120\/revisions\/173401"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/173121"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=173120"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=173120"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=173120"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}