{"id":173375,"date":"2019-04-25T06:30:26","date_gmt":"2019-04-24T22:30:26","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=173375"},"modified":"2019-04-24T19:10:50","modified_gmt":"2019-04-24T11:10:50","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e5%8c%97%e8%88%aa%e9%99%88%e7%88%b1%e5%8d%8emacromolecules%ef%bc%9a%e5%9f%ba%e4%ba%8e%e5%90%ab%e4%ba%8c%e8%8b%af%e4%b9%99%e7%83%af%e5%9f%ba%e5%b5%8c","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=173375","title":{"rendered":"\u5317\u822a\u9648\u7231\u534eMacromolecules\uff1a\u57fa\u4e8e\u542b\u4e8c\u82ef\u4e59\u70ef\u57fa\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u5177\u6709\u53ef\u8c03\u6db2\u6676\u6027\u80fd\u7684\u5355\u94feJanus\u7eb3\u7c73\u7c92\u5b50\u7684\u81ea\u7ec4\u88c5"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u7ebf\u6027\u805a\u5408\u7269\u5728\u6781\u7a00\u6eb6\u6db2\u4e2d\u901a\u8fc7\u94fe\u5185\u4ea4\u8054\u6216\u6298\u53e0\u5236\u5907\u7684\u5355\u94fe\u7eb3\u7c73\u7c92\u5b50\uff08SCNPs\uff09\u7531\u4e8e\u5176\u8d85\u5c0f\u5c3a\u5bf8\u548c\u201c\u4e8c\u6b21\u201d\u7ed3\u6784\u800c\u4ea7\u751f\u7684\u72ec\u7279\u6027\u80fd\u53ef\u6f5c\u5728\u5e94\u7528\u4e8e\u7eb3\u7c73\u50ac\u5316\u5242\u3001\u7eb3\u7c73\u53cd\u5e94\u5668\u3001\u4f20\u611f\u5668\u548c\u7eb3\u7c73\u836f\u7269\u800c\u5f15\u8d77\u4e86\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u6781\u5927\u5173\u6ce8\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u6269\u5927SCNPs\u7684\u5e94\u7528\u8303\u56f4\uff0c\u4e00\u4e9b\u529f\u80fd\u57fa\u56e2\u6216\u5355\u5143\u88ab\u5f15\u5165SCNPs\u4e2d\u3002\u6b64\u5916\uff0c\u542b\u6709\u4ea4\u8054\u7684\u201c\u5934\u201d\u548c\u4f38\u5c55\u7684\u201c\u5c3e\u201d\u94fe\u7684\u4e24\u4eb2\u6027\u874c\u86aa\u72b6\u5355\u94feJanus\u7eb3\u7c73\u7c92\uff08SCJNPs\uff09\u5728\u9009\u62e9\u6027\u6eb6\u5242\u4e2d\u53ef\u81ea\u7ec4\u88c5\u5f62\u6210\u80f6\u675f\uff0c\u5728\u754c\u9762\u5316\u5b66\u53cd\u5e94\u548c\u4eff\u751f\u77ff\u5316\u65b9\u9762\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u524d\u666f\u3002\u4e3a\u4e86\u8c03\u8282\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u805a\u5408\u7269\u7c92\u5b50\u7684\u5f62\u8c8c\uff0c\u901a\u5e38\u5728\u81ea\u7ec4\u88c5\u4f53\u7cfb\u4e2d\u5f15\u5165\u989d\u5916\u7684\u9a71\u52a8\u529b\uff0c\u5982\u6709\u5e8f\u6db2\u6676\u3001\u7ed3\u6676\u548c\u805a\u79bb\u5b50\u6db2\u4f53\u7b49\u3002\u4f46\u662f\uff0c\u76ee\u524d\u5173\u4e8e\u5177\u6709\u53ef\u8c03\u529f\u80fd\u6027SCJNP\u7684\u81ea\u7ec4\u88c5\u7684\u62a5\u9053\u4ecd\u7136\u5f88\u5c11\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u9648\u7231\u534e\u526f\u6559\u6388<\/strong>\u56e2\u961f\u901a\u8fc7\u94fe\u5185\u5149\u4ea4\u8054\u542b\u4e8c\u82ef\u4e59\u70ef\u7684\u4e24\u4eb2\u6027\u5d4c\u6bb5\u5171\u805a\u7269\uff08BCPs\uff09\uff0c\u9996\u6b21\u62a5\u9053\u4e86\u5177\u6709\u53ef\u8c03\u6db2\u6676\uff08LC\uff09\u6027\u80fd\u7684\u4e24\u4eb2\u6027\u805a\u5408\u7269\u5355\u94feJanus\u7eb3\u7c73\u7c92\u5b50\uff08SCJNPs\uff09\u7684\u5236\u5907\u53ca\u81ea\u7ec4\u88c5\u3002\u901a\u8fc7\u6539\u53d8\u7d2b\u5916\u5149\u7167\u5c04\u65f6\u95f4\u548cBCPs\u7684\u7ec4\u6210\uff0c\u89c2\u5bdf\u5230\u4e86\u7eb3\u7c73\u7c92\u5b50\u4ece\u7ba1\u72b6\u3001\u73af\u72b6\u3001\u9a6c\u978d\u72b6\u7b49\u975e\u7403\u5f62\u7ec4\u88c5\u4f53\u5230\u7403\u5f62\u7eb3\u7c73\u7c92\u5b50\u7684\u5f62\u8c8c\u8f6c\u53d8\u3002\u4f5c\u8005\u8ba4\u4e3a\u8fd9\u9879\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u79cd\u5177\u6709\u53ef\u8c03\u529f\u80fd\u6027\u7684\u805a\u5408\u7269\u7eb3\u7c73\u7c92\u5b50\u7684\u7b80\u6613\u5236\u5907\u65b9\u6cd5\uff0c\u53ef\u6f5c\u5728\u7528\u4e8e\u8fdc\u7a0b\u5149\u64cd\u4f5c\u7684\u5148\u8fdb\u6750\u6599\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cSelf-Assembly of Single Chain Janus Nanoparticles with Tunable Liquid Crystalline Properties from Stilbene-Containing Block Copolymers<\/strong>\u201d\u53d1\u8868\u4e8eMacromolecules<\/strong>\u671f\u520a\u3002<\/p>\n

\u3010\u56fe\u6587\u6458\u8981\u3011<\/strong><\/p>\n

\u5d4c\u6bb5\u5171\u805a\u7269\u524d\u9a71\u4f53\u7684\u5408\u6210\u53ca\u901a\u8fc7\u94fe\u5185\u5149\u4ea4\u8054\u5236\u5907\u6db2\u6676\u5355\u94feJanus\u7eb3\u7c73\u7c92\u5b50\u7684\u793a\u610f\u56fe
\n \"\"\"\"\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u542bLC\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u70ed\u6027\u80fd<\/strong>
\n \"\"\uff08a\uff09BCP\u524d\u9a71\u4f53PPEGMAm<\/sub>-b-PMAStbn<\/sub>\u5728\u7b2c\u4e8c\u6b21\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u7684DSC\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09PPEGMA14<\/sub>-b-PMAStb97<\/sub>\u5728\u771f\u7a7a\u4e0b\u9000\u706b\u7684SAXS\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09PPEGMA14<\/sub>-b-PMAStb97<\/sub>\u5728170\u2103\u4e0b\u89c2\u5bdf\u5230\u7684POM\u7167\u7247\u3002<\/p>\n

\u56fe\u4e8c\u3001LC-SCJNPs\u7684\u5236\u5907\u548c\u8868\u5f81<\/strong>
\n \"\"\uff08a\uff09PPEGMA14<\/sub>-b-PMAStb97<\/sub>\u5728THF\u4e2dUV\u7167\u5c04\u4e0d\u540c\u65f6\u95f4\u7684UV-vis\u5149\u8c31\uff1b<\/p>\n

\uff08b\uff09\u4e8c\u82ef\u4e59\u70ef\u57fa\u7684\u5149\u4e8c\u805a\u7a0b\u5ea6\u4e0e\u7d2b\u5916\u5149\u7167\u5c04\u65f6\u95f4\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

\uff08c\uff09\u5728\u4e0d\u540cUV\u7167\u5c04\u65f6\u95f4\u4e0b\uff0cPPEGMA14<\/sub>-b-PMAStb97<\/sub>\u76841<\/sup>H NMR\u5149\u8c31;<\/p>\n

\uff08d\uff09BCP\u524d\u9a71\u4f53PPEGMA14<\/sub>-b-PMAStb97<\/sub>\u548c\u6240\u5f97SCJNP\u7684FT-IR\u5149\u8c31\u3002<\/p>\n

\u56fe\u4e09\u3001LC-SCJNPs\u7684\u5236\u5907\u548c\u8868\u5f81<\/strong>
\n \"\"\uff08a\uff09\u57280\uff0c1\uff0c3\uff0c5\uff0c10\u548c20\u5206\u949f\u7684\u4e0d\u540c\u7167\u5c04\u65f6\u95f4\u4e0b\uff0cPPEGMA31<\/sub>-b-PMAStb98<\/sub>\u7684GPC\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09PPEGMA14<\/sub>-b-PMAStb97<\/sub>\u5728THF\u4e2d\u7167\u5c0420\u5206\u949f\u540e\uff0c\u5236\u5907\u5f97\u5230\u7684SCJNP\u7684TEM\u56fe\u50cf\u3002\uff08b\uff09\u4e2d\u7684\u63d2\u56fe\u8868\u793aSCJNP\u5728THF\u4e2d\u7684DLS\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u56db\u3001LC-SCJNPs\u7684\u5236\u5907\u548c\u8868\u5f81
\n \"\"\uff08a\uff09\u5728\u7b2c\u4e8c\u6b21\u52a0\u70ed\u8fc7\u7a0b\u4e2d\uff0c\u7531PPEGMA14<\/sub>-b-PMAStb97<\/sub> \u7167\u5c04\u4e0d\u540c\u65f6\u95f4\u5236\u5907\u7684SCJNP\u7684DSC\u66f2\u7ebf;<\/p>\n

\uff08b~e\uff09\u7531PPEGMA14<\/sub>-b-PMAStb97<\/sub>\u7167\u5c04\u4e0d\u540c\u65f6\u95f4\u5236\u5907\u7684SCJNP\u7684POM \u7167\u7247\uff1a\uff08b\uff091\uff0c\uff08c\uff093\uff0c\uff08d\uff095\u548c\uff08e\uff0910\u5206\u949f\u3002<\/p>\n

\u56fe\u4e94\u3001LC-SCJNPs\u7684\u81ea\u7ec4\u88c5\u884c\u4e3a<\/strong>
\n \"\"\u4e0d\u540c\u7ec4\u6210\u7684BCP\u524d\u9a71\u4f53\u3010\uff08a-c\uff09PPEGMA14<\/sub>-b-PMAStb97<\/sub>\uff0c\uff08d-f\uff09PPEGMA31<\/sub>-b-PMAStb98<\/sub>\uff0c\uff08g-i\uff09PPEGMA31<\/sub>-b-PMAStb68<\/sub>\u548c\uff08j-1\uff09PPEGMA31<\/sub>-b-PMAStb52<\/sub>\u3011\u5728\u4e0d\u540c\u7167\u5c04\u65f6\u95f4\u4e0b\u3010\uff08a\uff0cd\uff0cg\uff0cj\uff091\u5206\u949f\uff0c\uff08b\uff0ce\uff0ch\uff0ck\uff093\u5206\u949f\uff0c\uff08c\uff0cf\uff0cI\uff0cl\uff0910\u5206\u949f\u3011\u5f97\u5230\u7684LC-SCJNPs\u81ea\u7ec4\u88c5\u5f62\u8c8c\u7684\u4ee3\u8868\u6027TEM\u6216SEM\u56fe\u3002 (b)\uff0c(d)\u548c(g)\u7684\u63d2\u56fe\u662f\u76f8\u5e94\u6837\u54c1\u7684\u653e\u5927TEM\u56fe\u3002<\/p>\n

\u56fe\u516d\u3001LC-SCJNPs\u7684\u81ea\u7ec4\u88c5\u884c\u4e3a<\/strong>
\n \"\"\uff08a\uff09\u5177\u6709\u4e0d\u540c\u4ea4\u8054\u5ea6\u548c\u4eb2\/\u758f\u6c34\u5d4c\u6bb5\u6bd4\u7684LC-SCJNP\u5728\u9009\u62e9\u6027\u6eb6\u5242\u4e2d\u7684\u81ea\u7ec4\u88c5\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff09\u7531PPEGMA\u8d28\u91cf\u5206\u6570\u4e0d\u540c\u7684BCP\u524d\u9a71\u4f53\u5728\u4e0d\u540c\u7167\u5c04\u65f6\u95f4\u4e0b\u5f62\u6210\u7684SCNP\u6240\u5236\u5907\u7684\u7ec4\u88c5\u4f53\u7684\u76f8\u56fe\u3002<\/p>\n

\u56fe\u4e03\u3001LC-SCJNPs\u7684\u81ea\u7ec4\u88c5\u884c\u4e3a<\/strong>
\n \"\"\uff08a\uff09\u7531PPEGMA14<\/sub>-b-PMAStb97<\/sub>\u5728\u4e0d\u540c\u7167\u5c04\u65f6\u95f4\u4e0b\u5236\u5907\u7684LC-SCJNP\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u7ec4\u88c5\u4f53\u7684SAXS\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u7531PPEGMA31<\/sub>-b-PMAStb98<\/sub>\u7167\u5c043\u5206\u949f\u5236\u5907\u5f97\u5230\u7684LC-SCJNP\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u7ec4\u88c5\u4f53\u7684\u653e\u5927TEM\u56fe\uff1b<\/p>\n

\uff08c-f\uff09\u7531PPEGMA14<\/sub>-b-PMAStb97<\/sub>\u5728\u4e0d\u540c\u7167\u5c04\u65f6\u95f4\u4e0b\u5236\u5907\u7684LC-SCJNP\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u81ea\u7ec4\u88c5\u4f53\u7684POM\u7167\u7247\uff1a\uff08c\uff091\uff0c\uff08d\uff093\uff0c\uff08e\uff095\uff0c\uff08f\uff0910\u5206\u949f\u3002POM\u6837\u54c1\u662f\u6ca1\u6709\u8fdb\u884c\u4efb\u4f55\u5904\u7406\u7684\u6d53\u5ea6\u76f8\u540c\u7684\u539f\u59cb\u6c34\u6eb6\u6db2\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u94fe\u5185\u5149\u4ea4\u8054\u542b\u4e8c\u82ef\u4e59\u70ef\u7684PPEGMA-b-PMAStb\u5236\u5907\u4e86\u529f\u80fd\u6027SCJNPs\uff0c\u5e76\u7cfb\u7edf\u5730\u7814\u7a76\u4e86SCJNPs\u7684\u81ea\u7ec4\u88c5\u884c\u4e3a\u3002\u4f5c\u8005\u62a5\u9053\u4e86\u968f\u7740\u7d2b\u5916\u5149\u7167\u5c04\u65f6\u95f4\u6216\u4eb2\u6c34\u6bb5\u94fe\u957f\u7684\u589e\u52a0\uff0cLC-SCJNPs\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u80f6\u675f\u4ece\u4e00\u7ef4\u7ba1\u72b6\u7ec4\u88c5\u4f53\u5230\u7897\u72b6\u7c92\u5b50\u3001\u9a6c\u978d\u72b6\u7247\u5c42\uff0c\u6700\u7ec8\u5230\u7403\u5f62\u80f6\u675f\u7684\u4e0d\u540c\u5bfb\u5e38\u7684\u7ec4\u88c5\u5f62\u8c8c\u7684\u6f14\u5316\u8fc7\u7a0b\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u89c2\u5bdf\u5230\u7684LC-SCJNPs\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u805a\u96c6\u4f53\u5185\u90e8\u5177\u6709\u53ef\u89c1\u7684\u6709\u5e8f\u6761\u7eb9\uff0c\u8bf4\u660e\u4e86\u5176\u5185\u90e8\u662f\u8fd1\u6676 LC\u76f8\uff0c\u8fd9\u662f\u5173\u4e8eSCJNPs\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u805a\u96c6\u4f53\u4e2dLC\u6027\u8d28\u7684\u9996\u6b21\u62a5\u9053\u3002\u8be5\u5de5\u4f5c\u4e30\u5bcc\u4e86\u5177\u6709\u53ef\u63a7LC\u7279\u6027\u7684SCJNPs\u7684\u81ea\u7ec4\u88c5\u5f62\u8c8c\uff0c\u5e76\u63d0\u4f9b\u4e86\u4e00\u79cd\u5236\u5907\u5177\u6709\u53ef\u8c03\u529f\u80fd\u6027\u7684\u805a\u5408\u7269\u7c92\u5b50\u7684\u7b80\u5355\u65b9\u6cd5\uff0c\u53ef\u6f5c\u5728\u7528\u4e8e\u8fdc\u7a0b\u5149\u64cd\u4f5c\u7684\u5148\u8fdb\u6750\u6599\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSelf-Assembly of Single Chain Janus Nanoparticles with Tunable Liquid Crystalline Properties from Stilbene-Containing Block Copolymers<\/a>\uff08Macromolecules.<\/em>2019,<\/strong> DOI: 10.1021\/acs.macromol.9b00154\uff09<\/p>\n

\n \u672c\u6587\u7531\u6750\u6599\u4eba\u9ad8\u751f\u7ec4\u6211\u4ea6\u662f\u884c\u4eba\u7f16\u8bd1\uff0c\u6750\u6599\u4eba\u6574\u7406\u3002<\/p>\n

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