{"id":173904,"date":"2019-04-25T08:11:24","date_gmt":"2019-04-25T00:11:24","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=173904"},"modified":"2019-04-25T10:00:16","modified_gmt":"2019-04-25T02:00:16","slug":"%e4%bb%8a%e6%97%a5nature%e6%9b%b4%e5%8a%a0%e9%ab%98%e6%95%88%e7%9a%84%e6%96%b0%e5%9e%8b%e5%90%88%e6%88%90%e6%b0%a8%e6%96%b9%e6%b3%95","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=173904","title":{"rendered":"\u4eca\u65e5Nature:\u66f4\u52a0\u9ad8\u6548\u7684\u65b0\u578b\u5408\u6210\u6c28\u65b9\u6cd5"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u7531\u4e8e\u6c2e\u80a5\u7684\u666e\u904d\u4f7f\u7528\uff0c\u5229\u7528\u6c2e\u6c14\u5236\u5907\u6c28\u957f\u671f\u4ee5\u6765\u90fd\u662f\u6700\u91cd\u8981\u7684\u5de5\u4e1a\u751f\u4ea7\u8fc7\u7a0b\u4e4b\u4e00\u3002\u76ee\u524d\uff0cHaber-Bosch\u6cd5\u662f\u5de5\u4e1a\u5408\u6210\u6c28\u7684\u4e3b\u8981\u65b9\u5f0f\uff0c\u5176\u751f\u4ea7\u6761\u4ef6\u9700\u8981\u9ad8\u6e29\u9ad8\u538b\uff0c\u56e0\u6b64\u5408\u6210\u6c28\u5de5\u4e1a\u662f\u5178\u578b\u7684\u80fd\u6e90\u5bc6\u96c6\u578b\u5de5\u4e1a\u3002\u4e3a\u4e86\u6709\u6548\u964d\u4f4e\u80fd\u8017\uff0c\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u8fd8\u539f\u6c2e\u6c14\u5408\u6210\u6c28\u88ab\u8ba4\u4e3a\u662f\u5177\u6709\u5de8\u5927\u524d\u666f\u7684\u66ff\u4ee3\u65b9\u6cd5\u3002\u5728\u8fd9\u7c7b\u53cd\u5e94\u7cfb\u7edf\u4e2d\uff0c\u901a\u5e38\u5229\u7528\u8302\u91d1\u5c5e\u6216\u8005\u94be\u77f3\u58a8\u4f5c\u4e3a\u8fd8\u539f\u5242\uff0c\u5421\u5576\u7684\u5171\u8f6d\u9178\u6216\u8005\u76f8\u5173\u5316\u5408\u7269\u4f5c\u4e3a\u8d28\u5b50\u6765\u6e90\u3002\u7136\u800c\uff0c\u4e3a\u4e86\u53d1\u5c55\u4e0b\u4e00\u4ee3\u56fa\u6c2e\u7cfb\u7edf\uff0c\u5bfb\u627e\u66f4\u52a0\u4f4e\u5ec9\u3001\u6613\u83b7\u5f97\u4ee5\u53ca\u73af\u5883\u53cb\u597d\u7684\u8bd5\u5242\u6765\u66ff\u4ee3\u73b0\u6709\u8fd8\u539f\u5242\u548c\u8d28\u5b50\u6765\u6e90\u5c31\u6210\u4e86\u4e9f\u5f85\u89e3\u51b3\u7684\u96be\u9898\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p>\u8fd1\u671f\uff0c<strong>\u4e1c\u4eac\u5927\u5b66\u7684<\/strong><strong>Y. Nishibayashi<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5c55\u793a\u4e86\u5c06\u9187\u7c7b\u6216\u8005\u6c34\u4e0e\u4e8c\u7898\u5316\u9490\uff08SmI<sub>2<\/sub>\uff09\u8054\u5408\u4f7f\u7528\u53ef\u4ee5\u56fa\u5b9a\u6c2e\u5143\u7d20\uff0c\u5e76\u4f7f\u5176\u53ef\u5728\u6b63\u5e38\u73af\u5883\u6761\u4ef6\u4e0b\u88ab\u50ac\u5316\u8fd8\u539f\u3002\u4e8c\u7898\u5316\u9490\u662f\u4e00\u79cd\u6210\u719f\u7684\u8fd8\u539f\u5242\uff0c\u5728\u6709\u673a\u53cd\u5e94\u4e2d\u53ef\u4ee5\u9ad8\u6548\u8fd8\u539f\u591a\u79cd\u529f\u80fd\u5316\u57fa\u56e2\u3002\u56e0\u6b64\uff0c\u7814\u7a76\u4eba\u5458\u5229\u7528\u4e8c\u7898\u5316\u9490\u4f5c\u4e3a\u5408\u6210\u6c28\u7684\u8fd8\u539f\u5242\uff0c\u5e76\u4ee5\u4e59\u4e8c\u9187\u6216\u8005\u6c34\u4f5c\u4e3a\u8d28\u5b50\u6765\u6e90\uff0c\u5728\u94bc\u590d\u5408\u7269\u50ac\u5316\u5242\u7684\u4f5c\u7528\u4e0b\uff0c\u53ef\u6709\u6548\u5229\u7528\u6c28\u6c14\u50ac\u5316\u5408\u6210\u6c28\u3002\u5f53\u8f6c\u6362\u9891\u7387\uff08TOF\uff09\u8fbe\u5230117\u6bcf\u5206\u949f\u5de6\u53f3\u65f6\uff0c\u8be5\u53cd\u5e94\u4f53\u7cfb\u53ef\u4ee5\u751f\u4ea7\u9ad8\u8fbe4350\u5f53\u91cf\u7684\u6c28\uff0c\u6bd4\u5df2\u62a5\u9053\u7684\u4ea7\u91cf\u9ad8\u4e86\u4e00\u5230\u4e24\u4e2a\u6570\u91cf\u7ea7\uff0c\u5e76\u4e14\u751f\u6210\u901f\u7387\u63a5\u8fd1\u56fa\u6c2e\u9176\u4f53\u7cfb\u3002\u8be5\u7814\u7a76\u8ba4\u4e3a\uff0c\u8fd9\u4e00\u9ad8\u6548\u50ac\u5316\u53cd\u5e94\u4f53\u7cfb\u7684\u5b9e\u73b0\u5f97\u76ca\u4e8e\u9187\u6216\u8005\u6c34\u4e0e\u4e8c\u7898\u5316\u9490\u914d\u4f4d\u8fc7\u7a0b\u4e2d\u5b58\u5728\u8f83\u5f31\u7684O-H\u952e\uff0c\u4f7f\u5f97\u8d28\u5b50\u8026\u5408\u7684\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u5f97\u4ee5\u5b9e\u73b0\u4ece\u800c\u63d0\u9ad8\u56fa\u6c2e\u4f53\u7cfb\u7684\u53cd\u5e94\u6548\u7387\u3002\u5c3d\u7ba1\u8fdc\u672a\u8fbe\u5230\u5de5\u4e1a\u6c34\u5e73\uff0c\u4f46\u8fd9\u4e00\u5de5\u4f5c\u4e3a\u6df1\u5165\u7814\u7a76\u50ac\u5316\u56fa\u6c2e\u4f53\u7cfb\u5960\u5b9a\u4e86\u57fa\u7840\u30022019\u5e7404\u670824\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water<\/strong>\u201d\u7684\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728<strong>Nature<\/strong>\u4e0a\u3002<\/p>\n<p>\u3010<strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><strong>\u56fe1 <\/strong><strong>\u6c2e\u6c14\u50ac\u5316\u8fd8\u539f\u4ea7\u751f\u6c28\u7684\u8fc7\u7a0b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-173905\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/1-29.jpg\" alt=\"\" width=\"600\" height=\"263\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/1-29.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/1-29-300x132.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe2<\/strong><strong> \u4e8c\u7898\u5316\u9490-\u9187\/\u6c34\u53cd\u5e94\u4f53\u7cfb\u4e2d\u7684\u6c28\u5408\u6210\u53cd\u5e94<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-173906\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/2-29.jpg\" alt=\"\" width=\"592\" height=\"473\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/2-29.jpg 592w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/2-29-300x240.jpg 300w\" sizes=\"(max-width: 592px) 100vw, 592px\" \/><\/p>\n<p><strong>\u56fe3 \u50ac\u5316\u8fd8\u539f\u53cd\u5e94\u4e2d\u7684\u9490<\/strong> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-173907\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/3-27.jpg\" alt=\"\" width=\"600\" height=\"519\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/3-27.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/3-27-300x260.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe4 \u5178\u578b\u7684\u8f6c\u6362\u9891\u7387\u4e0e\u5316\u5b66\u8fc7\u7535\u52bf<\/strong> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-173908\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/4-26.jpg\" alt=\"\" width=\"600\" height=\"405\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/4-26.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/4-26-300x203.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41586-019-1134-2\" target=\"_blank\" rel=\"noopener\">Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water<\/a>\uff08Nature, 2019, DOI: 10.1038\/s41586-019-1134-2\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4NanoCJ\u4f9b\u7a3f\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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