{"id":174086,"date":"2019-05-04T06:43:52","date_gmt":"2019-05-03T22:43:52","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=174086"},"modified":"2019-05-03T20:44:21","modified_gmt":"2019-05-03T12:44:21","slug":"afm%e4%ba%8c%e7%bb%b4%e9%93%81%e7%a3%81%e4%bd%93%e7%9a%84%e9%9d%9e%e6%98%93%e5%a4%b1%e6%80%a7%e7%94%b5%e6%8e%a7%e5%88%b6%e5%92%8c%e5%bc%82%e8%b4%a8%e7%95%8c%e9%9d%a2%e8%af%b1%e5%af%bc%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=174086","title":{"rendered":"AFM:\u4e8c\u7ef4\u94c1\u78c1\u4f53\u7684\u975e\u6613\u5931\u6027\u7535\u63a7\u5236\u548c\u5f02\u8d28\u754c\u9762\u8bf1\u5bfc\u7684\u534a\u91d1\u5c5e\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u94c1\u78c1\u4f5c\u4e3a\u7269\u7406\u5b66\u7684\u57fa\u672c\u6982\u5ff5\uff0c\u662f\u78c1\u5b58\u50a8\u548c\u8bb8\u591a\u7535\u5b50\u8bbe\u5907\u7684\u57fa\u7840\u3002\u81ea\u77f3\u58a8\u70ef\u53d1\u73b0\u4ee5\u6765\uff0c \u539f\u5b50\u539a\u5ea6\u7684\u8303\u5fb7\u534e\uff08vdW\uff09\u6750\u6599\u4e00\u76f4\u5904\u4e8e\u6750\u6599\u7814\u7a76\u7684\u524d\u6cbf\u3002\u51e0\u4e4e\u6240\u6709\u4f53\u6750\u6599\u7684\u51dd\u805a\u6001\u884c\u4e3a\uff0c\u5982\u8d85\u5bfc\u3001\u534a\u5bfc\u4f53\u3001\u534a\u91d1\u5c5e\u548c\u94c1\u7535\u7b49\uff0c\u90fd\u5df2\u7ecf\u5728\u4e8c\u7ef4vdW\u6750\u6599\u4e2d\u88ab\u89c2\u6d4b\u5230\u3002\u7136\u800c\uff0c\u4e00\u76f4\u52302017\u5e74\uff0c\u4e8c\u7ef4\u94c1\u78c1\u6027\u624d\u5728\u53cc\u5c42Cr2<\/sub>Ge2<\/sub>Te6<\/sub>\u548c\u5355\u5c42\u7684CrI3<\/sub>\u4e2d\u88ab\u89c2\u6d4b\u5230\u3002<\/p>\n

\u4e8c\u7ef4\u94c1\u78c1\u6750\u6599\u7684\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728\u4e24\u4e2a\u65b9\u5411\uff1a\uff08\u2170\uff09\u63a2\u7d22\u65b0\u7684\u9ad8\u6027\u80fdvdW\u94c1\u78c1\u4f53\uff0c\u5982\u9ad8\u8fc1\u79fb\u7387\u7684\u94c1\u78c1\u534a\u5bfc\u4f53\uff0c\u5bbd\u81ea\u65cb\u95f4\u9699\u7684\u534a\u91d1\u5c5e\uff0c\u548c\u9ad8\u5c45\u91cc\u6e29\u5ea6\u7684\u94c1\u78c1\u4f53\u7b49\uff1b\uff08ii\uff09\u5bf9\u4e8e\u5b9e\u9a8c\u4e0a\u5df2\u77e5\u7684vdW\u94c1\u78c1\u4f53\uff0c\u5f00\u53d1\u65b0\u7684\u5e94\u7528\uff0c \u5982\u5b9e\u73b0\u539f\u5b50\u539avdW\u94c1\u78c1\u4f53\u7684\u5408\u7406\u63a7\u5236\u3002<\/p>\n

\u7535\u63a7\u5236\u662f\u8c03\u5236\u539f\u5b50\u539avdW\u94c1\u78c1\u4f53\u7684\u6709\u6548\u7b56\u7565\u3002\u7136\u800c\uff0c\u73b0\u884c\u65b9\u6cd5\u5177\u6709\u6613\u5931\u6027\uff0c\u5373\u9700\u8981\u6301\u4e45\u7684\u65bd\u52a0\u7535\u63a7\u5236\uff0c\u5426\u5219\u7531\u7535\u63a7\u5236\u8bf1\u5bfc\u7684\u72b6\u6001\u5f88\u96be\u7ef4\u7cfb\u3002\u8fd9\u4e0d\u4ec5\u5bfc\u81f4\u80fd\u91cf\u7684\u8fc7\u5ea6\u6d88\u8017\uff0c\u800c\u4e14\u8fd8\u963b\u788d\u4e86vdW\u94c1\u78c1\u4f53\u5728\u975e\u6613\u5931\u6027\u78c1\u7535\u7eb3\u7c73\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n

\u5728\u4e09\u7ef4\u5757\u4f53\u6750\u6599\u4e2d\uff0c\u591a\u94c1\u6027\u5f02\u8d28\u7ed3\u6784\u662f\u5b9e\u73b0\u78c1\u6027\u548c\u7535\u6027\u7684\u975e\u6613\u5931\u6027\u8026\u5408\u7684\u6700\u6709\u6548\u7b56\u7565\u4e4b\u4e00\u3002\u8fd9\u79cd\u7b56\u7565\u5bf9\u539f\u5b50\u539a\u5ea6\u7684\u4e8c\u7ef4\u94c1\u78c1\u4f53\u662f\u5426\u4e5f\u6709\u6548\u5462\uff1f\u94c1\u7535\u6750\u6599\u5177\u6709\u53cc\u7a33\u5b9a\u6781\u5316\u72b6\u6001P\u2191\u548cP\u2193\uff0c\u94c1\u7535\u6750\u6599\u5728\u8fd9\u4e24\u79cd\u6781\u5316\u72b6\u6001\u4e4b\u95f4\u7684\u7535\u8f6c\u6362\u662f\u975e\u6613\u5931\u6027\u7684\uff0c\u4e5f\u5c31\u662f\u8bf4\uff0c\u5373\u4f7f\u79fb\u9664\u5916\u90e8\u7535\u573a\uff0c\u76f8\u5e94\u7684\u6781\u5316\u72b6\u6001\u4e5f\u4f1a\u5f97\u4ee5\u4fdd\u7559\u3002\u539f\u5219\u4e0a\uff0c\u5982\u679c\u591a\u94c1\u6027\u5f02\u8d28\u7ed3\u6784\u4e2d\u7684\u4e8c\u7ef4\u94c1\u78c1\u4f53\u4e0e\u94c1\u7535\u7684P\u2191\u548cP\u2193\u72b6\u6001\u6709\u8026\u5408\uff0c\u90a3\u4e48\uff0c\u4e8c\u7ef4\u94c1\u78c1\u4f53\u7684\u7535\u63a7\u5236\u4e5f\u5c06\u662f\u975e\u6613\u5931\u6027\u7684\u3002<\/p>\n

\u5728\u4e0a\u9762\u601d\u8def\u6307\u5f15\u4e0b\uff0c\u7f8e\u56fd\u6ce2\u591a\u9ece\u5404\u5927\u5b66\u9648\u4e2d\u65b9\u6559\u6388<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4<\/b><\/strong>\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\uff0c\u8bc1\u5b9e\u5229\u7528\u94c1\u7535\u6750\u6599\u4f5c\u4e3a\u8f85\u52a9\u5c42\u53ef\u4ee5\u6709\u6548\u5b9e\u73b0\u4e8c\u7ef4\u94c1\u78c1\u4f53\u7684\u975e\u6613\u5931\u6027\u7535\u63a7\u5236\u3002\u5177\u4f53\u6765\u8bb2\uff0c \u5f53\u94c1\u78c1\u5355\u5c42CrI3<\/sub>\u548c\u94c1\u7535MXene Sc2<\/sub>CO2<\/sub>\u4e00\u8d77\u5f62\u6210\u591a\u94c1\u6027\u5f02\u8d28\u7ed3\u6784\u65f6\uff0cP\u2191\u00a0Sc2<\/sub>CO2<\/sub>\u4e0d\u4f1a\u6539\u53d8CrI3<\/sub>\u7684\u534a\u5bfc\u4f53\u6027\u8d28\uff0c\u4f46P\u2193\u00a0Sc2<\/sub>CO2<\/sub>\u4f1a\u4f7fCrI3<\/sub>\u6210\u4e3a\u534a\u91d1\u5c5e\u3002\u56e0\u6b64\uff0c\u5229\u7528\u4e24\u4e2a\u76f8\u53cd\u7684\u94c1\u7535\u6781\u5316\u72b6\u6001\u4e4b\u95f4\u975e\u6613\u5931\u6027\u7684\u8f6c\u53d8\uff0c\u53ef\u4ee5\u95f4\u63a5\u5730\u5b9e\u73b0CrI3<\/sub>\u94c1\u78c1\u534a\u5bfc\u4f53\u548c\u534a\u91d1\u5c5e\u4e4b\u95f4\u7684\u975e\u6613\u5931\u6027\u7535\u63a7\u5236\u3002\u503c\u5f97\u5f3a\u8c03\u7684\u662f\uff0cCrI3<\/sub>\u4e2d\u7531\u5f02\u8d28\u754c\u9762\u8bf1\u5bfc\u7684\u534a\u91d1\u5c5e\u6027\u5177\u6709\u672c\u5f81\u6027\uff0c\u4e0d\u9700\u8981\u4efb\u4f55\u5316\u5b66\u4fee\u9970\u6216\u7269\u7406\u6539\u6027\uff0c\u8fd9\u5bf9\u5b9e\u9645\u5e94\u7528\u662f\u76f8\u5f53\u6709\u5229\u7684\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u4e8c\u7ef4vdW\u94c1\u78c1\u4f53\u7684\u975e\u6613\u5931\u6027\u7535\u63a7\u5236\u548cCrI3<\/sub>\u5728\u534a\u91d1\u5c5e\u57fa\u7eb3\u7c73\u7535\u5b50\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u94fa\u5e73\u4e86\u9053\u8def\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cNonvolatile Electrical Control and Heterointerface-Induced Half-Metallicity of 2D Ferromagnets<\/b><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Adv. Funct. Mater.<\/b><\/strong><\/b>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe\u4e00\u3001<\/b><\/strong>\u4e8c\u7ef4<\/b><\/strong>\u94c1\u78c1\u4f53\u7535\u63a7\u5236\u793a\u610f\u56fe<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff0cb\uff09\u539f\u5b50\u539avdW\u94c1\u78c1\u4f53\u6613\u5931\u6027\uff08a\uff09\u548c\u975e\u6613\u5931\u6027\uff08b\uff09\u7684\u7535\u63a7\u5236\u7684\u793a\u610f\u56fe;<\/p>\n

\uff08c\uff0cd\uff09\u5355\u5c42CrI3<\/sub>\uff08c\uff09\u548cMXene Sc2<\/sub>CO2<\/sub>\uff08d\uff09\u7684\u9876\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\uff0c\u5176\u4e2dI\uff0cCr\uff0cSc\uff0cC\u548cO\u539f\u5b50\u5206\u522b\u7528\u6df1\u7ea2\u8272\uff0c\u84dd\u8272\uff0c\u767d\u8272\uff0c\u7070\u8272\u548c\u7ea2\u8272\u8868\u793a;\u00a0<\/p>\n

\uff08e\uff0cf\uff09CrI3<\/sub>\u548cP\u2191\uff08e\uff09\u4e0eP\u2193\uff08f\uff09Sc2<\/sub>CO2<\/sub>\u7ec4\u6210\u7684\u5f02\u8d28\u7ed3\u6784\u3002<\/p>\n

\u56fe\u4e8c\u3001\u80fd\u5e26\u7ed3\u6784<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\uff08a-f\uff09CrI3<\/sub>\uff08a\uff09\u548cMXene Sc2<\/sub>CO2<\/sub>\uff08b\uff09\u7535\u5b50\u80fd\u5e26\u7ed3\u6784\u4ee5\u53caCrI3<\/sub>\/P\u2191 Sc2<\/sub>CO2<\/sub>\uff08c\uff0cd\uff09\u548cCrI3<\/sub>\/P\u2193 Sc2<\/sub>CO2<\/sub>\uff08e\uff0cf\uff09\u5f02\u8d28\u7ed3\u6784\u5bf9\u5e94\u7684\u7535\u5b50\u80fd\u5e26\u7ed3\u6784\u3002\u7ea2\u7ebf\u548c\u7eff\u7ebf\u5206\u522b\u8868\u793aCrI3<\/sub>\u7684\u81ea\u65cb\u5411\u4e0a\uff08S\u2191\uff09\u548c\u5411\u4e0b\uff08S\u2193\uff09\u7684\u8d21\u732e\uff0c\u800c\u84dd\u7ebf\u8868\u793aMXene Sc2<\/sub>CO2<\/sub>\u7684\u8d21\u732e\u3002EF<\/sub>\u4ee3\u8868\u8d39\u7c73\u80fd\u7ea7\u3002<\/p>\n

\u56fe\u4e09\u3001<\/b><\/strong>\u94c1\u78c1<\/b><\/strong>\u534a\u5bfc\u4f53\u5230\u534a\u91d1\u5c5e<\/b><\/strong>\u8f6c\u53d8<\/b><\/strong><\/b>\u7684\u5185\u5728\u673a\u5236<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\uff08a\uff09S\u2191\u00a0CrI3<\/sub>\uff0cS\u2193\u00a0CrI3<\/sub>\uff0cP\u2191\u00a0Sc2<\/sub>CO2<\/sub>\u548cP\u2193\u00a0Sc2<\/sub>CO2<\/sub>\u76f8\u5bf9\u4e8e\u771f\u7a7a\u80fd\u7ea7Evac<\/sub>\u7684\u5e26\u8fb9\u4ee5\u53ca\u534a\u5bfc\u4f53\u5230\u534a\u91d1\u5c5e\u8f6c\u53d8\u7684\u5185\u5728\u673a\u5236\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5355\u4e2aCrI3<\/sub>\u548cMXene Sc2<\/sub>CO2<\/sub>\u7684xy\u5e73\u9762\u5e73\u5747\u9759\u7535\u52bf\uff1b<\/p>\n

\uff08c\uff0cd\uff09CrI3<\/sub>\/Sc2<\/sub>CO2<\/sub>\u5f02\u8d28\u7ed3\u6784\u7684\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u548c\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u7684\u79ef\u5206\uff0c\u5176\u4e2d\u7ea2\u7ebf\u4ee3\u8868\u5728xy\u5e73\u9762\u5bc6\u5ea6\u7684\u79ef\u5206\uff0c\u800c\u9ed1\u7ebf\u662f\u6cbfz\u65b9\u5411\u7684\u7ea2\u7ebf\u7684\u79ef\u5206\uff1b<\/p>\n

\uff08e\uff0cf\uff09CrI3<\/sub>\/P\u2191 Sc2<\/sub>CO2<\/sub>\uff08e\uff09\u548cCrI3<\/sub>\/P\u2193 Sc2<\/sub>CO2<\/sub>\uff08f\uff09\u5f02\u8d28\u7ed3\u6784\u7684\u7535\u8377\u8f6c\u79fb\uff08\u9ed1\u7ebf\uff09\uff0c\u5176\u4e2d\u7ea2\u7ebf\u548c\u84dd\u7ebf\u5206\u522b\u4e3a\u81ea\u65cb\u5411\u4e0a\u548c\u81ea\u65cb\u5411\u4e0b\u7684\u8d21\u732e\u3002<\/p>\n

\u56fe\u56db\u3001<\/b><\/strong>\u53ef\u80fd\u7684\u5e94\u7528\uff1a<\/b><\/strong>CrI<\/b><\/strong>3<\/b><\/sub><\/strong>\u63a5\u89e6\u7684Sc<\/b><\/strong>2<\/b><\/sub><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u573a\u6548\u5e94\u6676\u4f53\u7ba1\uff08FET\uff09<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\uff08a\uff09CrI3<\/sub>\u63a5\u89e6\u7684Sc2<\/sub>CO2<\/sub>\u00a0<\/sub>FET\u6a21\u578b\uff1b<\/p>\n

\uff08b\uff09\u91d1\u5c5e\u7535\u6781\uff08CrI3<\/sub>\/P\u2193 Sc2<\/sub>CO2<\/sub>\u5f02\u8d28\u7ed3\u6784\uff09\u7684\u8d39\u7c73\u80fd\u7ea7\u548c\u534a\u5bfc\u4f53Sc2<\/sub>CO2<\/sub>\u7684\u4ef7\u5e26\u9876\u00a0\uff08VBM\uff09\uff1b<\/p>\n

\uff08c\uff0cd\uff09\u534a\u5bfc\u4f53Sc2<\/sub>CO2<\/sub>\u7684\u4ef7\u5e26\uff08VB\uff09\uff08c\uff09\u548c\u00a0\u5bfc\u5e26\uff08CB\u00a0\uff09\uff1b<\/p>\n

\uff08e\uff09\u534a\u5bfc\u4f53Sc2<\/sub>CO2<\/sub>\u7684\u7a7a\u7a74\uff08\u84dd\u8272\uff09\u548c\u7535\u5b50\uff08\u7ea2\u8272\uff09\u8fc1\u79fb\u7387\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\u3002<\/p>\n

\u56fe\u4e94\u3001<\/b><\/strong>\u53ef\u80fd\u7684\u5e94\u7528\uff1a<\/b><\/strong>\u539f\u5b50\u539a<\/b><\/strong>CrI<\/b><\/strong>3<\/b><\/sub><\/strong>\/Sc<\/b><\/strong>2<\/b><\/sub><\/strong>CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u591a\u94c1\u5b58\u50a8\u5668<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\uff08a\uff0cb\uff09\u539f\u5b50\u539aCrI3<\/sub>\/Sc2<\/sub>CO2<\/sub>\u591a\u94c1\u5b58\u50a8\u5668\u6a21\u578b\u3002\u6570\u636e\u5199\u5165\u53d6\u51b3\u4e8e\u94c1\u7535Sc2<\/sub>CO2<\/sub>\uff0c\u6570\u636e\u8bfb\u53d6\u662f\u57fa\u4e8e\u94c1\u78c1CrI3<\/sub>\u4e0e\u94c1\u7535Sc2<\/sub>CO2<\/sub>\u7684\u6781\u5316\u6001P\u2193\uff08a\uff09\u548cP\u2191\uff08b\uff09\u4e4b\u95f4\u7684\u8026\u5408\u6240\u5f15\u8d77\u7684\u4e0d\u540c\u7535\u4fe1\u53f7\u6216\u5149\u4fe1\u53f7\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u5728\u672c\u6587\u4e2d\uff0c\u901a\u8fc7DFT\u8ba1\u7b97\uff0c\u8868\u660e\u5728CrI3<\/sub>\/Sc2<\/sub>CO2<\/sub>\u591a\u94c1\u6027\u5f02\u8d28\u7ed3\u6784\u4e2d\uff0c\u94c1\u78c1CrI3<\/sub>\u5355\u5c42\u4e0e\u94c1\u7535Sc2<\/sub>CO2<\/sub>\u7684P\u2191\u548cP\u2193\u6001\u5b58\u5728\u8026\u5408\u3002\u5f53\u4e0eP\u2191 Sc2<\/sub>CO2<\/sub>\u63a5\u89e6\u65f6\uff0cCrI3<\/sub>\u4fdd\u6301\u534a\u5bfc\u4f53\u6027\uff0c\u4f46\u5f53P\u2191\u7535\u8f6c\u6362\u4e3aP\u2193\u00a0\u65f6\uff0cCrI3<\/sub>\u53d8\u4e3a\u534a\u91d1\u5c5e\u3002\u8fdb\u4e00\u6b65\u7684\u5206\u6790\u8868\u660e\uff0cCrI3<\/sub>\u4e0e\u94c1\u7535Sc2<\/sub>CO2<\/sub>\u7684\u6781\u5316\u72b6\u6001\u7684\u8026\u5408\u6e90\u81ea\u4e8e\u94c1\u7535\u4f53\u4e2d\u88ab\u6253\u7834\u7684\u7a7a\u95f4\u53cd\u6f14\u5bf9\u79f0\u6027\uff1b\u4e0eP\u2193 Sc2<\/sub>CO2<\/sub>\u63a5\u89e6\u65f6\uff0c\u94c1\u78c1CrI3<\/sub>\u7684\u534a\u91d1\u5c5e\u884c\u4e3a\u5f52\u56e0\u4e8e\u5f02\u8d28\u754c\u9762\u7684\u7535\u8377\u8f6c\u79fb\u548c\u94c1\u78c1\u4f53\u4e2d\u88ab\u6253\u7834\u7684\u65f6\u95f4\u53cd\u6f14\u5bf9\u79f0\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u63d0\u4f9b\u4e86\u5c06\u4e8c\u7ef4\u94c1\u78c1\u4f53\u8c03\u5236\u6210\u534a\u91d1\u5c5e\u7684\u6709\u6548\u65b9\u6cd5\uff08\u5f02\u8d28\u754c\u9762\u5de5\u7a0b\uff09\uff0c\u800c\u4e14\u63d0\u51fa\u4e86\u4e00\u79cd\u53ef\u884c\u7684\u9014\u5f84\uff08\u5f15\u5165\u94c1\u7535\u6750\u6599\u4f5c\u4e3a\u8f85\u52a9\u5c42\uff09\uff0c\u6765\u5b9e\u73b0\u4e8c\u7ef4\u94c1\u78c1\u4f53\u7684\u975e\u6613\u5931\u6027\u7535\u63a7\u5236\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/b><\/strong>Nonvolatile Electrical Control and Heterointerface-Induced<\/b><\/u><\/strong>
\n <\/b><\/u><\/strong>Half-Metallicity of 2D Ferromagnets<\/b><\/u><\/strong><\/a><\/b>\u201d(Adv. Funct. Mater<\/b><\/strong>\uff0c<\/b><\/strong>2019\uff0cDOI:10.1002\/adfm.201901420 \u00a0)<\/b><\/strong><\/p>\n

\u672c\u6587\u7531CYM\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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