{"id":174326,"date":"2019-04-30T06:30:25","date_gmt":"2019-04-29T22:30:25","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=174326"},"modified":"2019-04-29T17:22:00","modified_gmt":"2019-04-29T09:22:00","slug":"%e5%8c%97%e5%8c%96%e5%b0%b9%e6%a2%85%e8%b4%9e%e6%95%99%e6%8e%88jacs-%e7%bb%bf%e5%85%89%e8%af%b1%e5%af%bc%e5%81%b6%e6%b0%ae%e8%8b%af%e8%a1%8d%e7%94%9f%e7%89%a9%e5%9b%ba%e6%b6%b2%e6%80%81%e8%bd%ac","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=174326","title":{"rendered":"\u5317\u5316\u5c39\u6885\u8d1e\u6559\u6388JACS: \u7eff\u5149\u8bf1\u5bfc\u5076\u6c2e\u82ef\u884d\u751f\u7269\u56fa\u6db2\u6001\u8f6c\u53d8\u7528\u4f5c\u7c98\u5408\u5242"},"content":{"rendered":"

\u3010\u524d\u8a00<\/strong>\u3011<\/b><\/p>\n

\u7c98\u5408\u5242\u4f5c\u4e3a\u8fde\u63a5\u4e24\u79cd\u6750\u6599\u7684\u6865\u6881\uff0c\u5728\u751f\u4ea7\u751f\u6d3b\u4e2d\u90fd\u626e\u6f14\u7740\u975e\u5e38\u91cd\u8981\u7684\u89d2\u8272\u3002\u7c98\u5408\u5242\u6750\u6599\u7528\u9014\u5e7f\uff0c\u54c1\u79cd\u591a\uff0c\u56e0\u6b64\u4e5f\u79f0\u4e3a\u5de5\u4e1a\u5473\u7d20\uff0c\u5728\u8bb8\u591a\u73b0\u4ee3\u4ea7\u4e1a\u4e2d\u6210\u4e3a\u4e0d\u53ef\u6216\u7f3a\u7684\u6750\u6599\u3002\u5728\u751f\u6d3b\u4e2d\uff0c\u7c98\u5408\u5242\u66f4\u662f\u65e0\u5904\u4e0d\u5728\u3002\u4f8b\u5982\u5e38\u89c1\u7684\u80f6\u6c34\u4f7f\u7528\u8d77\u6765\u5341\u5206\u65b9\u4fbf\u3001\u7b80\u5355\uff0c\u53ef\u662f\u5982\u679c\u6ef4\u5230\u624b\u4e0a\u5374\u5f88\u96be\u6d17\u6389\uff0c\u5e76\u4e14\u4e0d\u80fd\u91cd\u590d\u5229\u7528\u3002\u7c98\u5408\u5242\u6750\u6599\u9762\u4e34\u7740\u6e05\u6d17\u56f0\u96be\u3001\u4e0d\u53ef\u91cd\u590d\u4f7f\u7528\u7684\u96be\u9898\uff0c\u8fd9\u4e5f\u7ed9\u73af\u5883\u548c\u8d44\u6e90\u5e26\u6765\u5de8\u5927\u7684\u6311\u6218\u3002\u56e0\u6b64\uff0c\u53d1\u5c55\u7eff\u8272\u53ef\u5faa\u73af\u4f7f\u7528\u7684\u7c98\u5408\u5242\u5bf9\u4e8e\u5316\u5b66\u79d1\u5b66\u3001\u6750\u6599\u79d1\u5b66\u3001\u73af\u5883\u4fdd\u62a4\u548c\u8d44\u6e90\u8282\u7ea6\u7684\u53d1\u5c55\u90fd\u5177\u6709\u91cd\u8981\u7684\u5b66\u672f\u4ef7\u503c\u548c\u5b9e\u9645\u5e94\u7528\u610f\u4e49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/b><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u5c39\u6885\u8d1e\u8bfe\u9898\u7ec4<\/b><\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u7eff\u5149\u8bf1\u5bfc\u5076\u6c2e\u82ef\u884d\u751f\u7269\u56fa\u6db2\u6001\u8f6c\u53d8\u7684<\/b><\/strong>\u65b0\u578b<\/b><\/strong>\u6750\u6599\uff0c\u5f00\u53d1\u51fa<\/b><\/strong>\u4e00\u79cd<\/b><\/strong>\u9ad8\u5ea6\u53ef\u9006<\/b><\/strong>\u7684\u5149\u63a7<\/b><\/strong>\u7c98\u5408\u5242<\/b><\/strong>\u3002\u8be5\u7c98\u5408\u5242\u6781\u6613\u6eb6\u4e8e\u4e8c\u6c2f\u7532\u70f7\u7b49\u5e38\u89c1\u6709\u673a\u6eb6\u5242\uff0c\u5bb9\u6613\u6e05\u6d17\u56de\u6536\uff0c\u53ef\u91cd\u590d\u4f7f\u7528<\/b><\/strong>\uff0c\u4e3a\u5236\u5907\u7eff\u8272\u73af\u4fdd\u578b\u7c98\u5408\u5242\u63d0\u4f9b\u4e00\u79cd\u65b0<\/b><\/strong>\u65b9\u6cd5<\/b><\/strong>\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cGreen-Light-Triggered Phase Transition of Azobenzene Derivatives toward Reversible Adhesives\u201d\u4e3a\u9898\u53d1\u8868\u5728Journal of the American Chemical Society\u4e0a\uff0cDOI: 10.1021\/jacs.9b01056\u3002\u5317\u4eac\u5316\u5de5\u5927\u5b66\u535a\u58eb\u751f\u5434\u632f<\/b><\/strong>\u4e3a\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u5c39\u6885\u8d1e\u6559\u6388<\/b><\/strong>\u4e3a\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb<\/strong>\u3011<\/b><\/p>\n

\u56fe1 \u00a0P1\u5728\u7eff\u5149\u4f5c\u7528\u4e0b\u7684\u56fa\u6db2\u6001\u8f6c\u53d8<\/b><\/strong>\u3002<\/b><\/strong><\/p>\n

\"\" \u00a0\u00a0\u00a0<\/p>\n

\uff08a\uff09\u5076\u6c2e\u82ef\u884d\u751f\u7269P1<\/b><\/strong>\u548cP2<\/b><\/strong>\u7684\u7ed3\u6784\u5f0f;\uff08b\uff09P1<\/b><\/strong>\u968f\u7740\u7eff\u5149\u7167\u5c04\u65f6\u95f4\u7684\u5347\u6e29\u53ca\u56fa\u6db2\u6001\u8f6c\u53d8\u56fe\u7247\u3002<\/p>\n

\u56fe2 <\/b><\/strong>\u7d2b\u5916\u5149\u3001\u7eff<\/b><\/strong>\u5149\u4f5c\u7528\u524d\u540e\u6838\u78c1\u8868\u5f81<\/b><\/strong>\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u539f\u59cb\u6837\u54c1;\uff08b\uff09\u7eff\u5149\u7167\u5c04\u540e;\uff08c\uff09\u7d2b\u5916\u5149\u7167\u5c04\u540e\u3002<\/p>\n

\u56fe3 <\/b><\/strong>\u6fc0\u53d1\u6001\u548c\u57fa\u6001<\/b><\/strong>\u80fd\u91cf<\/b><\/strong>\u5dee<\/b><\/strong>\u4e0e\u7eff\u5149\u6ce2\u957f\u5339\u914d<\/b><\/strong>\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5076\u6c2e\u82ef\u884d\u751f\u7269P1<\/b><\/strong>\u548cP2<\/b><\/strong>\u56fa\u4f53\u5438\u6536\u5149\u8c31;\uff08b\uff09P1<\/b><\/strong>\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u3002<\/p>\n

\u56fe4 \u00a0P1\u7c98\u5408\u5242\u6027\u80fd<\/b><\/strong>\u8868\u5f81\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09P1<\/b><\/strong>\u7c98\u5408\u5242\u7684\u5236\u5907\u8fc7\u7a0b\u548c\u5149\u8bf1\u5bfc\u8131\u80f6\u793a\u610f\u56fe;\uff08b\uff09P1<\/b><\/strong>\u548cAPAO\u7c98\u5408\u5242\u7684\u5e94\u529b\u5e94\u53d8\u66f2\u7ebf\u3002<\/p>\n

\u56fe5 <\/b><\/strong>\u53ef\u9006\u7684\u5149\u63a7<\/b><\/strong>\u7c98\u5408\u5242<\/b><\/strong>\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u7eff\u5149\u5f00\u5173\u7684\u7c98\u5408\u5242\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u603b\u7ed3<\/strong>\u3011<\/b><\/p>\n

\u7efc\u4e0a\u4f5c\u8005\u901a\u8fc7\u8bbe\u8ba1\u4e00\u5b9a\u957f\u5ea6\u7684\u70f7\u57fa\u94fe\u548c\u53cc\u8418\u915a\uff0c\u4f7f\u4e4b\u534f\u540c\u8c03\u8282P1<\/b><\/strong>\u5230\u4e00\u4e2a\u7a0d\u9ad8\u4e8e\u5ba4\u6e29\u7684\u7194\u70b9\u3002\u7eff\u5149\u7167\u5c04\u4e0b\uff0cP1<\/b><\/strong>\u7684\u5149\u70ed\u6548\u5e94\u5bfc\u81f4\u4e86\u56fa\u4f53\u5230\u6db2\u4f53\u7684\u8f6c\u53d8\u3002\u505c\u6b62\u5149\u7167\uff0c\u968f\u7740\u70ed\u91cf\u7684\u91ca\u653e\uff0c\u6e29\u5ea6\u964d\u5230\u7194\u70b9\u4e4b\u4e0b\uff0c\u6db2\u6001P1<\/b><\/strong>\u91cd\u65b0\u53d8\u6210\u56fa\u6001\u3002\u6db2\u6001P1\u81ea\u53d1\u4e14\u5feb\u901f\u7684\u56fa\u5316\u8fc7\u7a0b<\/b><\/strong>\u4e0d\u662f\u57fa\u4e8ecis<\/i><\/em>\u5230trans<\/i><\/em>\u7684\u5316\u5b66\u8f6c\u53d8\uff0c\u800c\u662f\u4e00\u4e2a\u653e\u70ed\u7684\u7269\u7406\u53d8\u5316\u3002\u76f8\u540c\u529f\u7387\u548c\u5149\u7167\u65f6\u95f4\u7684\u6761\u4ef6\u4e0b\uff0c\u53ea\u6709\u7eff\u5149<\/b><\/strong>\u80fd\u591f\u5b9e\u73b0P1<\/b><\/strong>\u4ece\u56fa\u6001\u5230\u6db2\u6001\u7684\u8f6c\u53d8\uff0c\u7d2b\u5916\u5149\u3001\u84dd\u5149\u3001\u7ea2\u5149\u5219\u4e0d\u80fd\u5b9e\u73b0\u3002\u901a\u8fc7\u5faa\u73af\u4f0f\u5b89\u5faa\u73af\u66f2\u7ebf\u6cd5\uff0c\u6d4b\u5f97P1<\/b><\/strong>\u7684\u57fa\u6001\u548c\u6fc0\u53d1\u6001\u4e4b\u95f4\u7684\u80fd\u91cf\u5dee\u521a\u597d\u5339\u914d\u7eff\u5149\u7684\u80fd\u91cf\u8303\u56f4\uff0c\u56e0\u6b64P1<\/b><\/strong>\u66f4\u5bb9\u6613\u5438\u6536\u7eff\u5149\u7684\u80fd\u91cf\u3002\u6db2\u6001P1<\/b><\/strong>\u56fa\u5316\u540e\u5c55\u73b0\u51fa\u975e\u5e38\u597d\u7684\u7c98\u5408\u6027\u80fd\uff0c\u7eff\u5149\u8f90\u5c04\u540e\uff0cP1<\/b><\/strong>\u5347\u6e29\u7194\u5316\uff0c\u5931\u53bb\u7c98\u5408\u6027\u80fd\uff1b\u51b7\u5374\u5230\u5ba4\u6e29\u540e\u91cd\u65b0\u53d8\u6210\u56fa\u6001\uff0c\u53c8\u5c55\u73b0\u51fa\u5f88\u5f3a\u7684\u7c98\u5408\u529b\uff0c\u6b64\u8fc7\u7a0b\u9ad8\u5ea6\u53ef\u9006<\/b><\/strong>\u3002\u8fd9\u79cd\u5149\u63a7\u7c98\u5408\u5242\u6613\u6eb6\u4e8e\u5e38\u89c1\u6709\u673a\u6eb6\u5242\uff0c\u5bb9\u6613\u6e05\u6d17\u56de\u6536\uff0c\u53ef\u591a\u6b21\u5faa\u73af\u4f7f\u7528\uff0c\u5728\u7eff\u8272\u73af\u4fdd\u3001\u8d44\u6e90\u8282\u7ea6\u7684\u7c98\u5408\u5242\u9886\u57df\u5c55\u73b0\u51fa\u5de8\u5927\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u8be5\u7814\u7a76\u7684\u610f\u4e49<\/b><\/strong>\uff1a\u901a\u8fc7\u7eff\u5149\u5149\u70ed\u6548\u5e94\u8bf1\u5bfc\u6750\u6599\u5b9e\u73b0\u5feb\u901f\u7684\u56fa\u6db2\u6001\u8f6c\u53d8\uff0c\u5e76\u5e94\u7528\u4e8e\u9ad8\u5ea6\u53ef\u9006\u7684\u5149\u63a7\u7c98\u5408\u5242\uff0c\u4e3a\u5236\u5907\u7eff\u8272\u73af\u4fdd\u578b\u7c98\u5408\u5242\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u65b9\u6cd5\u3002<\/p>\n

\u6587\u7ae0\u4fe1\u606f\uff1a<\/b><\/strong><\/p>\n

Zhen Wu, Chendong Ji, Xujie Zhao, Yilong Han, Klaus M\u00fcllen, Kai Pan, and Meizhen Yin*<\/b><\/strong>, Green-Light-Triggered Phase Transition of Azobenzene Derivatives toward Reversible Adhesives, J. Am. Chem. Soc.<\/i><\/em>\u00a02019<\/b><\/strong>, DOI: 10.1021\/jacs.9b01056.<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

https:\/\/pubs.acs.org.ccindex.cn\/doi\/10.1021\/jacs.9b01056<\/u><\/a><\/p>\n

\u5c39\u6885\u8d1e\u6559\u6388\u7b80\u4ecb\uff1a<\/b><\/strong><\/p>\n

\u5c39\u6885\u8d1e\uff0c\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u5fb7\u56fd\u5fb7\u7d2f\u65af\u987f\u7406\u5de5\u5927\u5b66\u535a\u58eb\uff082001-2004\uff09\uff0c\u5fb7\u56fd\u9ad8\u5206\u5b50\u9a6c\u666e\u6240\u535a\u58eb\u540e\uff082005-2008\uff09\uff0c\u73b0\u4e3a\u5317\u4eac\u5316\u5de5\u5927\u5b66\u6559\u6388\u3002\u4e3b\u8981\u4ece\u4e8b\u8367\u5149\u7eb3\u7c73\u6750\u6599\u7684\u7cbe\u51c6\u6784\u5efa\u4e0e\u5e94\u7528\u7814\u7a76\uff0c\u5305\u62ec\u7279\u5f02\u6027\u8367\u5149\u5206\u5b50\u6807\u8bb0\u3001\u751f\u7269\u5206\u5b50\u9ad8\u6548\u8fd0\u8f7d\u3001\u6709\u5bb3\u6c14\u4f53\u4ee5\u53ca\u91d1\u5c5e\u7684\u7279\u5f02\u6027\u68c0\u6d4b\u3001\u8d85\u654f\u611f\u523a\u6fc0\u54cd\u5e94\u6027\u7b49\u5e94\u7528\u7814\u7a76\u3002\u5728Nat. Commun., J. Am. Chem. Soc., Angew. Chem. Int. Ed., Adv. Mater., Chem. Soc. Rev, Prog. Polym. Sci., ACS Nano, Small, Chem. Commun. \u7b49\u56fd\u9645\u6742\u5fd7\u4e0a\u53d1\u8868\u8bba\u658790 \u4f59\u7bc7\uff0c\u6388\u6743\u4e13\u522921\u9879\u3002\u8363\u83b7\u7b2c\u5341\u4e09\u5c4a\u201c\u4e2d\u56fd\u9752\u5e74\u5973\u79d1\u5b66\u5bb6\u5956\u201d\u3001\u5165\u9009\u7b2c\u4e09\u6279\u56fd\u5bb6\u4e07\u4eba\u8ba1\u5212\uff08\u9886\u519b\u4eba\u624d\uff09\u3001\u6559\u80b2\u90e8\u65b0\u4e16\u7eaa\u4eba\u624d\u652f\u6301\u8ba1\u5212\u3001\u79d1\u6280\u90e8\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\u3001\u7b2c\u4e5d\u5c4a\u4faf\u5fb7\u699c\u5316\u5de5\u79d1\u6280\u521b\u65b0\u5956\u3001\u5317\u4eac\u5e02\u4e09\u516b\u7ea2\u65d7\u5956\u7ae0\u3002<\/p>\n

\u672c\u6587\u7531\u5317\u4eac\u5316\u5de5\u5927\u5b66\u5c39\u6885\u8d1e\u8bfe\u9898\u7ec4<\/b><\/strong>\u4f9b\u7a3f<\/b><\/strong>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u524d\u8a00\u3011 \u7c98\u5408\u5242\u4f5c\u4e3a\u8fde\u63a5\u4e24\u79cd\u6750\u6599\u7684\u6865\u6881\uff0c\u5728\u751f\u4ea7\u751f\u6d3b\u4e2d\u90fd\u626e\u6f14\u7740\u975e\u5e38\u91cd\u8981\u7684\u89d2\u8272\u3002\u7c98\u5408\u5242\u6750\u6599\u7528\u9014\u5e7f\uff0c\u54c1\u79cd\u591a\uff0c\u56e0\u6b64\u4e5f\u79f0\u4e3a\u5de5\u4e1a\u5473\u7d20\uff0c\u5728\u8bb8\u591a\u73b0\u4ee3\u4ea7\u4e1a\u4e2d\u6210\u4e3a\u4e0d\u53ef\u6216\u7f3a\u7684\u6750\u6599\u3002\u5728…<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-174326","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/174326"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=174326"}],"version-history":[{"count":7,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/174326\/revisions"}],"predecessor-version":[{"id":174444,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/174326\/revisions\/174444"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=174326"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=174326"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=174326"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}