{"id":174465,"date":"2019-04-30T11:37:38","date_gmt":"2019-04-30T03:37:38","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=174465"},"modified":"2019-04-29T22:37:54","modified_gmt":"2019-04-29T14:37:54","slug":"angew-chem-int-ed-%e8%8b%9d%e4%ba%8c%e9%85%b0%e4%ba%9a%e8%83%ba-%e5%af%8c%e5%8b%92%e7%83%af%e4%bd%9c%e7%94%b5%e5%ad%90%e4%bc%a0%e8%be%93%e5%b1%82%e6%98%be%e8%91%97%e6%8f%90%e5%8d%87%e5%8f%8d","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=174465","title":{"rendered":"Angew. Chem. Int. Ed.: \u82dd\u4e8c\u9170\u4e9a\u80fa\/\u5bcc\u52d2\u70ef\u4f5c\u7535\u5b50\u4f20\u8f93\u5c42\u663e\u8457\u63d0\u5347\u53cd\u5f0f\u9499\u949b\u77ff\u7535\u6c60\u6548\u7387\u548c\u7a33\u5b9a\u6027"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u56e0\u5176\u9ad8\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u53ca\u7b80\u5355\u5ec9\u4ef7\u7684\u5236\u5907\u5de5\u827a\uff0c\u5728\u5149\u4f0f\u9886\u57df\u6380\u8d77\u4e86\u65b0\u7684\u7814\u7a76\u70ed\u6f6e\uff0c\u662f\u5f53\u524d\u53d1\u5c55\u6700\u5feb\u7684\u65b0\u4e00\u4ee3\u8584\u819c\u5149\u4f0f\u5668\u4ef6\u3002\u7ecf\u8fc7\u8fd1\u5341\u5e74\u7684\u7814\u7a76\u53d1\u5c55\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u5df2\u7ecf\u4ece3.8% \u8dc3\u5347\u81f3\u76ee\u524d\u7684\u6700\u65b0\u8ba4\u8bc1\u6548\u738724.2%\uff0c\u4e0e\u5546\u4e1a\u5316\u7684\u6676\u7845\u592a\u9633\u80fd\u7535\u6c60\u76f8\u5f53\u3002\u4ee5\u5668\u4ef6\u7ed3\u6784\u5206\u7c7b\uff0c\u9499\u949b\u77ff\u7535\u6c60\u53ef\u5206\u4e3a\u6b63\u5f0f\u7ed3\u6784 (n-i-p)\u548c\u53cd\u5f0f\u7ed3\u6784 (p-i-n)\uff0c\u4e0e\u524d\u8005\u76f8\u6bd4\uff0c\u53cd\u5f0f\u7ed3\u6784\u5668\u4ef6\u56e0\u5236\u5907\u5de5\u827a\u7b80\u5355\u3001\u53ef\u4f4e\u6e29\u6210\u819c\u3001\u65e0\u660e\u663e\u8fdf\u6ede\u6548\u5e94\u7b49\u4f18\u70b9\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002PCBM\u56e0\u5176\u4f18\u5f02\u7684\u7535\u5b50\u8fc1\u79fb\u7387\u3001\u4e0e\u9499\u949b\u77ff\u5339\u914d\u7684\u80fd\u7ea7\u7ed3\u6784\u3001\u80fd\u6709\u6548\u949d\u5316\u9499\u949b\u77ff\u7f3a\u9677\u4ee5\u53ca\u53ef\u4f4e\u6e29\u6eb6\u6db2\u5236\u5907\u7b49\u4f18\u52bf\uff0c\u5df2\u5e7f\u6cdb\u4f7f\u7528\u4f5c\u4e3a\u53cd\u5f0f\u9499\u949b\u77ff\u5668\u4ef6\u7684\u7535\u5b50\u4f20\u8f93\u5c42\uff0c\u7136\u800c\u5176\u5149\u5316\u5b66\u4e0d\u7a33\u5b9a\u6027\u9650\u5236\u4e86\u5668\u4ef6\u6548\u7387\u53ca\u7a33\u5b9a\u6027\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u5df2\u6709\u7814\u7a76\u62a5\u9053\u03c0-\u5171\u8f6d\u6709\u673a\u6750\u6599\u2212\u82dd\u4e8c\u9170\u4e9a\u80fa (PDI) \u5177\u6709\u8f83\u9ad8\u7684\u5bfc\u7535\u6027\u548c\u8fc1\u79fb\u7387\uff0c\u540c\u65f6\u53ef\u4ee5\u9694\u79bb\u9499\u949b\u77ff\u8584\u819c\u3001\u949d\u5316\u8868\u9762\u7f3a\u9677\u5e76\u9632\u6b62\u9499\u949b\u77ff\u5206\u89e3\uff0c\u7136\u800c\u57fa\u4e8ePDI\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u7535\u6c60\u6548\u7387\u5374\u4e0d\u5982\u4eba\u610f\u3002\u56e0\u6b64\u5b9e\u73b0PCBM\u548cPDI\u4f18\u52bf\u7684\u7ed3\u5408\u5c06\u6709\u671b\u5b9e\u73b0\u53cd\u5f0f\u9499\u949b\u77ff\u7535\u6c60\u6548\u7387\u548c\u7a33\u5b9a\u6027\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u6b66\u6c49\u5927\u5b66\u6768\u695a\u7f57\u6559\u6388<\/strong>\u3001<strong>\u897f\u5357\u5927\u5b66\u6731\u7433\u5a1c\u526f\u6559\u6388<\/strong>\u3001<strong>\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u6768\u4e16\u548c\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u82dd\u4e8c\u9170\u4e9a\u80fa\/\u5bcc\u52d2\u70ef\u6742\u5316\u7269PDI-C<sub>60<\/sub>\uff0c\u76f8\u6bd4\u4e8ePCBM\uff0c\u5176\u7535\u5b50\u8fc1\u79fb\u7387\u548c\u5206\u5b50\u6709\u5e8f\u6027\u5f97\u5230\u6539\u5584\u3002\u6b64\u5916\uff0c\u5728PDI\u4e2d\u7684\u4e00\u4e9b\u542b\u6709\u5b64\u5bf9\u7535\u5b50\u7684\u539f\u5b50\u6216\u57fa\u56e2\u53ef\u4e0e\u9499\u949b\u77ff\u4e2d\u672a\u914d\u4f4d\u7684Pb\u539f\u5b50\u5f62\u6210\u914d\u4f4d\u952e\uff0c\u8fdb\u800c\u6709\u6548\u6539\u5584\u5668\u4ef6\u7a33\u5b9a\u6027\u3002\u57fa\u4e8ePDI-C<sub>60<\/sub>\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u9499\u949b\u77ff\u7535\u6c60\u6700\u9ad8\u6548\u7387\u53ef\u8fbe18.6%\uff0c\u8fdc\u8fdc\u9ad8\u4e8ePCBM (16.6%) \u548cPDI (13.3%)\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u5668\u4ef6\uff0c\u540c\u65f6\u5668\u4ef6\u7a33\u5b9a\u6027\u4e5f\u5f97\u5230\u660e\u663e\u6539\u5584\u3002\u7814\u7a76\u4eba\u5458\u5229\u7528\u98de\u884c\u65f6\u95f4\u2212\u4e8c\u6b21\u79bb\u5b50\u8d28\u8c31\u4eea (TOF-SIMS)\u63ed\u793a\u5176\u7a33\u5b9a\u6027\u6539\u5584\u673a\u7406\uff0c\u8868\u660ePDI-C<sub>60<\/sub>\u5bf9\u8584\u819c\u8d77\u5230\u4e86\u5f88\u597d\u7684\u9694\u79bb\u4f5c\u7528\uff0c\u963b\u6b62\u4e86\u9499\u949b\u77ff\u7684\u5206\u89e3\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u5668\u4ef6\u7684\u7a33\u5b9a\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a<strong> \u201c Designing Perylene Diimide\/Fullerene Hybrid as Effective Electron Transporting Material in Inverted Perovskite Solar Cells with Enhanced Efficiency and Stability \u201d<\/strong>\u53d1\u8868\u5728<strong>Angew. Chem. Int. Ed.<\/strong>\u4e0a\uff0c<strong>\u6b66\u6c49\u5927\u5b66\u7684\u535a\u58eb\u751f\u7f57\u6b63\u8f89<\/strong>\u548c<strong>\u897f\u5357\u5927\u5b66\u5434\u98de\u535a\u58eb<\/strong>\u4e3a\u8bba\u6587\u7684<strong>\u5171\u540c\u7b2c\u4e00\u4f5c\u8005<\/strong>\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00 PDI-C<sub>60<\/sub>\u5408\u6210\u8def\u7ebf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-174467\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-1.jpg\" alt=\"\" width=\"600\" height=\"445\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-1.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-1-300x223.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u4e8c PDI-C<sub>60<\/sub>\u7684\u80fd\u7ea7\u7ed3\u6784\u8868\u5f81<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-174468\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-2.jpg\" alt=\"\" width=\"600\" height=\"430\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-2.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-2-300x215.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n (a) PDI-C<sub>60<\/sub>\u7684\u5faa\u73af\u4f0f\u5b89\u626b\u63cf\u66f2\u7ebf\uff0c\u4ee5\u6b64\u4f30\u8ba1LUMO\u80fd\u7ea7\uff1b<br \/>\n (b) PDI-C<sub>60<\/sub>\u7684\u6c2f\u4eff\u6eb6\u6db2\u548c\u8584\u819c\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff0c\u4ee5\u6b64\u4f30\u8ba1\u5e26\u9699\uff1b<br \/>\n (c) \u9499\u949b\u77ff\u5668\u4ef6\u4e2d\u6240\u7528\u6750\u6599\u7684\u80fd\u7ea7\u793a\u610f\u56fe\uff1b<br \/>\n (d) \u53cd\u5f0f\u9499\u949b\u77ff\u7535\u6c60\u5668\u4ef6\u7ed3\u6784\u56fe\u3002<\/p>\n<p><strong>\u56fe\u4e09 \u9499\u949b\u77ff\u7535\u6c60\u5668\u4ef6\u6027\u80fd\u8868\u5f81<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-174469\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-3.jpg\" alt=\"\" width=\"600\" height=\"446\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-3.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-3-300x223.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n (a) \u7535\u6c60J-V\u6027\u80fd\u66f2\u7ebf\uff1b <br \/>\n (b) \u7535\u6c60IPCE\u5149\u8c31\u548c\u79ef\u5206\u7535\u6d41\u66f2\u7ebf\uff1b<br \/>\n (c) \u6b63\u53cd\u626bJ-V\u6027\u80fd\u66f2\u7ebf\uff1b<br \/>\n (d) \u7a33\u6001\u5149\u7535\u6d41\u548c\u6548\u7387\u8f93\u51fa\u3002<\/p>\n<p><strong>\u56fe\u56db \u9499\u949b\u77ff\u8584\u819cPL\/TRPL\u5149\u8c31\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-174470\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-4.jpg\" alt=\"\" width=\"600\" height=\"247\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-4.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-4-300x124.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe\u4e94 \u9499\u949b\u77ff\u5668\u4ef6\u7a33\u5b9a\u6027\u6d4b\u8bd5<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-174471\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-5.jpg\" alt=\"\" width=\"600\" height=\"417\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-5.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/04\/Figure-5-300x209.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n (a) \u9499\u949b\u77ff\u7535\u6c60\u5728\u5927\u6c14\u73af\u5883\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff1b <br \/>\n (b) \u4e0d\u540c\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u63a5\u89e6\u89d2\u6d4b\u8bd5\uff1b<br \/>\n (c, d) \u9499\u949b\u77ff\u5668\u4ef6\u7684TOF-SIMS\u6df1\u5ea6\u5256\u9762\u56fe<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u5de7\u5999\u5408\u6210\u4e86PDI-C<sub>60<\/sub>\u4f5c\u4e3a\u53cd\u5f0f\u9499\u949b\u77ff\u7535\u6c60\u7684\u7535\u5b50\u4f20\u8f93\u5c42\uff0c\u76f8\u6bd4\u4e8ePCBM\uff0c\u5177\u6709\u8f83\u6d45\u7684HOMO\u548cLUMO\u503c\u3001\u66f4\u9ad8\u7684\u7535\u5b50\u8fc1\u79fb\u7387\u548c\u66f4\u5f3a\u7684\u758f\u6c34\u6027\u3002\u57fa\u4e8ePDI-C<sub>60<\/sub>\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u9499\u949b\u77ff\u7535\u6c60\u6700\u9ad8\u6548\u7387\u53ef\u8fbe18.6%\uff0c\u540c\u65f6PDI-C<sub>60<\/sub>\u5bf9\u8584\u819c\u8d77\u5230\u4e86\u5f88\u597d\u7684\u9694\u79bb\u4f5c\u7528\uff0c\u6709\u6548\u963b\u6b62\u4e86\u9499\u949b\u77ff\u7684\u5206\u89e3\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u5668\u4ef6\u7684\u7a33\u5b9a\u6027\u3002\u8be5PDI-C<sub>60<\/sub>\u6742\u5316\u7b56\u7565\u4e3a\u53cd\u5f0f\u9499\u949b\u77ff\u5668\u4ef6\u7684\u9ad8\u6548\u7535\u5b50\u4f20\u8f93\u5c42\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u7814\u7a76\u601d\u8def\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201904195\" target=\"_blank\" rel=\"noopener\">Designing Perylene Diimide\/Fullerene Hybrid as Effective Electron Transporting Material in Inverted Perovskite Solar Cells with Enhanced Efficiency and Stability<\/a><\/strong>\uff08Angew. Chem. Int. Ed. 2019, DOI: 10.1002\/anie.201904195\uff09<\/p>\n<p>\u672c\u6587\u7531\u565c\u565c\u7f16\u8bd1\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu \u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u56e0\u5176\u9ad8\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u53ca\u7b80\u5355\u5ec9\u4ef7\u7684\u5236\u5907\u5de5\u827a\uff0c\u5728\u5149\u4f0f\u9886\u57df\u6380\u8d77\u4e86\u65b0\u7684\u7814\u7a76\u70ed\u6f6e\uff0c\u662f\u5f53\u524d\u53d1\u5c55\u6700\u5feb\u7684\u65b0\u4e00\u4ee3\u8584\u819c\u5149\u4f0f\u5668\u4ef6\u3002\u7ecf\u8fc7\u8fd1\u5341\u5e74\u7684&#8230;<\/p>\n","protected":false},"author":9696,"featured_media":174471,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1029],"class_list":["post-174465","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-1029"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/174465"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/9696"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=174465"}],"version-history":[{"count":7,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/174465\/revisions"}],"predecessor-version":[{"id":174498,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/174465\/revisions\/174498"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/174471"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=174465"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=174465"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=174465"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}