{"id":175730,"date":"2019-05-26T06:29:10","date_gmt":"2019-05-25T22:29:10","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=175730"},"modified":"2019-05-25T21:29:25","modified_gmt":"2019-05-25T13:29:25","slug":"%e4%b8%ad%e5%9b%bd%e7%a7%91%e5%ad%a6%e9%99%a2%e7%89%a9%e7%90%86%e7%a0%94%e7%a9%b6%e6%89%80%e8%83%a1%e5%8b%87%e8%83%9c%e9%99%86%e9%9b%85%e7%bf%94nature-energy%ef%bc%9a%e9%ab%98%e6%af%94%e8%83%bd","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=175730","title":{"rendered":"\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u80e1\u52c7\u80dc&\u9646\u96c5\u7fd4Nature Energy\uff1a\u9ad8\u6bd4\u80fd\u957f\u5bff\u547d\u6c34\u7cfb\u94be\u79bb\u5b50\u5168\u7535\u6c60"},"content":{"rendered":"

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n

\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u7684\u848b\u793c\u5a01\uff08\u7b2c\u4e00\u4f5c\u8005\uff09\u5728\u80e1\u52c7\u80dc\u7814\u7a76\u5458\u548c\u9646\u96c5\u7fd4\u526f\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7684\u6307\u5bfc\u4e0b\uff0c<\/strong>\u91c7\u7528Fe\u90e8\u5206\u53d6\u4ee3Mn\u7684\u5bcc\u9530\u94be\u57fa\u666e\u9c81\u58eb\u84ddKx<\/sub>Fey<\/sub>Mn1-y<\/sub>[Fe(CN)6<\/sub>]w<\/sub>\u00b7zH2<\/sub>O\u4e3a\u6b63\u6781\u3001\u6709\u673a\u67d3\u6599\u82dd\u8273\u7d2b\u7ea229 \uff08PTCDI\uff09\uff08CAS\uff1a81-33-4\uff09\u4e3a\u8d1f\u6781\u300122 mol\/L\u7684\u4e09\u6c1f\u7532\u57fa\u78fa\u9178\u94be\u6c34\u6eb6\u6db2\u4e3a\u7535\u89e3\u6db2\uff0c\u6210\u529f\u6784\u5efa\u4e86\u4e00\u6b3e\u6c34\u7cfb\u94be\u79bb\u5b50\u5168\u7535\u6c60\u3002\u7814\u7a76\u8868\u660e\uff0c\u8be5\u6c34\u7cfb\u94be\u79bb\u5b50\u5168\u7535\u6c60\u53ef\u4ee5\u57280\u52302.6 V\u7535\u538b\u533a\u95f4\u5185\u8fd0\u884c\uff0c\u5176\u80fd\u91cf\u5bc6\u5ea6\u53ef\u8fbe80 Wh\/kg\uff0c\u529f\u7387\u5bc6\u5ea6\u53ef\u8fbe1612 W\/kg\uff0c\u5bff\u547d\u53ef\u8fbe2000\u6b21\u4ee5\u4e0a\uff08\u4fdd\u6301\u738773%\uff09\u3002\u4f5c\u8005\u8fd8\u7ec4\u88c5\u4e8611 mAh\u7684\u6c34\u7cfb\u94be\u79bb\u5b50\u8f6f\u5305\u7535\u6c60\uff0c\u5e76\u6f14\u793a\u4e86\u8f6f\u5305\u7535\u6c60\u826f\u597d\u7684\u4f4e\u500d\u7387\uff080.1C\u548c0.5C\uff09\u548c\u9ad8\u4f4e\u6e29(-20-60 o<\/sup>C\uff09\u6027\u80fd\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cBuilding aqueous K-ion batteries for energy storage<\/strong>\u201d\u4e3a\u9898\uff0c\u8fd1\u65e5\u53d1\u8868\u5728Nature Energy<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

\u56fe1. K1.85<\/sub>Fe0.33<\/sub>Mn0.67<\/sub>[Fe(CN)6<\/sub>]0.98<\/sub>\u00b70.77H2<\/sub>O (KFeMnHCF-3565) \u6b63\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

\"\"<\/p>\n

(a) <\/strong>KFeMnHCF-3565\u7535\u6781\u57280.5C\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

(b) <\/strong>KFeMnHCF-3565\u7535\u6781\u57280.5-10C\u7684\u6bd4\u5bb9\u91cf\/\u6548\u7387-\u5faa\u73af\u5468\u6570\u56fe\u3002<\/p>\n

(c)<\/strong> KFeMnHCF-3565\u7535\u6781\u572810-120C\u7684\u5178\u578b\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

(d) <\/strong>KFeMnHCF-3565\u7535\u6781\u4e0e\u5176\u4ed6\u5728\u62a5\u9053\u7684\u6c34\u7cfb\u94be\/\u94a0\/\u6c22\u79bb\u5b50\u7535\u6c60\u7684\u6bd4\u5bb9\u91cf-\u500d\u7387\u5bf9\u6bd4\u56fe\u3002<\/p>\n

(e) <\/strong>KFeMnHCF-3565\u7535\u6781\u5148\u7ecf\u8fc710C-120C\u7684\u500d\u7387\u6d4b\u8bd5\u540e\u518d\u7ecf\u8fc7100C\u7684\u957f\u5faa\u73af\u56fe\u3002<\/p>\n

\u56fe2.KFeMnHCF-3565\u6b63\u6781\u7684\u7ed3\u6784\u53d8\u5316\u548c\u7535\u8377\u8865\u507f\u7684\u673a\u7406<\/p>\n

\"\"<\/p>\n

\u00a0(a) <\/strong>KFeMnHCF-3565\u6b63\u6781\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u975e\u539f\u4f4dXRD<\/p>\n

\uff08b-c\uff09<\/strong>KFeMnHCF-3565\u6b63\u6781\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2dFe\u7684X\u5c04\u7ebf\u5438\u6536\u8c31<\/p>\n

\uff08d-e\uff09<\/strong>KFeMnHCF-3565\u6b63\u6781\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2dMn\u7684X\u5c04\u7ebf\u5438\u6536\u8c31<\/p>\n

\u56fe3.22M KCF3<\/sub>SO3<\/sub>\u7535\u89e3\u6db2\u548cPTCDI\u8d1f\u6781\u7684\u6027\u80fd<\/p>\n

\"\"<\/p>\n

(a)<\/strong>\u3001(b)<\/strong>\u548c(e)<\/strong>\u5206\u522b\u4e3a22mol\/L\u4e09\u6c1f\u7532\u78fa\u9178\u94be\u7535\u89e3\u6db2\u7684\u7a97\u53e3\u3001\u62c9\u66fc\u548c\u7535\u5bfc\u7387\u3002<\/p>\n

(c)<\/strong>\u548c(d)<\/strong>\u5206\u522b\u4e3aPTCDI\u7535\u6781\u57280.5C\/4C\/10C\/20C\u7684\u5178\u578b\u5145\u653e\u7535\u66f2\u7ebf\u548c\u572820C\u4e0b\u7684\u957f\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

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\"\"<\/p>\n

(a)<\/strong>\u6263\u5f0f<\/strong>\u5168\u7535\u6c60\u57280-2.6V\u4e4b\u95f4\u4ee54C\u8fd0\u884c\u7684\u7535\u5316\u5b66\u66f2\u7ebf\u3002<\/p>\n

(b)<\/strong>\u5168\u7535\u6c60\u4e0e\u5df2\u62a5\u9053\u7684\u6c34\u7cfb\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u5e73\u5747\u7535\u538b\u3001\u6bd4\u5bb9\u91cf\u4ee5\u53ca\u80fd\u91cf\u5bc6\u5ea6\u5bf9\u6bd4\u56fe\u3002<\/p>\n

(c)<\/strong>\u6263\u5f0f<\/strong>\u5168\u7535\u6c60\u5728\u5168\u7535\u6c60\u57280-2.6V\u4e4b\u95f4\u4ee54C\u8fd0\u884c\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

(d)<\/strong>\u548c<\/strong>(e)<\/strong>\u5206\u522b\u4e3a\u8f6f\u5305\u5168\u7535\u6c60\u5728\u4e0d\u540c\u6e29\u5ea6\uff08-20\u2103\/-10\u2103\/25\u2103\/60\u2103\/\uff09\u4e0b\u4ee5\u4f4e\u500d\uff080.1C\/0.5C\uff09\u8fd0\u884c\u7684\u5145\u653e\u7535\u66f2\u7ebf\u548c\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

\u4f5c\u8005\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u6b3e\u5177\u5907\u9ad8\u6bd4\u80fd\u3001\u9ad8\u529f\u7387\u3001\u5bbd\u6e29\u533a\u3001\u957f\u5bff\u547d\u7b49\u7279\u6027\u6c34\u7cfb\u94be\u79bb\u5b50\u5168\u7535\u6c60\u3002\u5176\u4e2dFe\u53d6\u4ee3\u7684\u5bccMn\u666e\u9c81\u58eb\u84dd\u6b63\u6781\u540c\u65f6\u5b9e\u73b0\u4e86\u9ad8\u5bb9\u91cf\u9ad8\u500d\u7387\u957f\u5bff\u547d\u7b49\u7279\u6027\uff0c\u6709\u673a\u6750\u6599PTCDI\u8d1f\u6781\u4e5f\u5177\u6709\u8f83\u9ad8\u5bb9\u91cf\u548c\u500d\u7387\u6027\u80fd\uff0c\u4e09\u6c1f\u7532\u57fa\u78fa\u9178\u94be\u7684\u9ad8\u76d0\u6d53\u5ea6\u6c34\u6eb6\u6db2\u5177\u6709\u5bbd\u7535\u538b\u7a97\u53e3\u3001\u9ad8\u7535\u5bfc\u7387\u548c\u6291\u5236\u7535\u6781\u6eb6\u89e3\u7279\u6027\u3002\u4ed6\u4eec\u6700\u540e\u5bf9\u6c34\u7cfb\u94be\u79bb\u5b50\u7535\u6c60\u7684\u673a\u9047\u548c\u6311\u6218\u8fdb\u884c\u4e86\u5c55\u671b\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u53d1\u5c55\u9ad8\u6027\u80fd\u7684\u6c34\u7cfb\u94be\u79bb\u5b50\u7535\u6c60\u63d0\u4f9b\u4e86\u91cd\u8981\u6307\u5bfc\u610f\u4e49\uff0c\u662f\u6c34\u7cfb\u94be\u79bb\u5b50\u7535\u6c60\u9886\u57df\u7684\u4e00\u9879\u91cd\u8981\u8fdb\u5c55\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aBuilding aqueous K-ion batteries for energy storage<\/a>\u00a0\uff08Nat. Energy\uff0c2019\uff0cDOI:\u00a010.1038\/s41560-019-0388-0\uff09<\/strong><\/p>\n

\u672c\u6587\u7531kv1004\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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