{"id":176909,"date":"2019-06-07T06:33:44","date_gmt":"2019-06-06T22:33:44","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=176909"},"modified":"2019-06-11T10:20:52","modified_gmt":"2019-06-11T02:20:52","slug":"%e5%b9%b2%e8%b4%a7%ef%bc%9a%e5%b9%b6%e9%9d%9e%e8%b6%8a%e8%b4%b5%e8%b6%8a%e5%a5%bd%ef%bc%8c%e8%ae%a9%e8%ae%be%e8%ae%a1%e6%94%b9%e5%8f%98orr%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=176909","title":{"rendered":"\u5e72\u8d27\uff1a\u5e76\u975e\u8d8a\u201c\u8d35\u201d\u8d8a\u597d\uff0c\u8ba9\u8bbe\u8ba1\u6539\u53d8ORR\u50ac\u5316"},"content":{"rendered":"<p>\u6c27\u8fd8\u539f\u53cd\u5e94ORR\u662f\u76ee\u524d\u7535\u5316\u5b66\u9886\u57df\u548c\u50ac\u5316\u9886\u57df\u7814\u7a76\u6700\u5e7f\u6cdb\u7684\u8bdd\u9898\u4e4b\u4e00\uff0c\u5b83\u5728\u7535\u5316\u5b66\u80fd\u91cf\u8f6c\u5316\u548c\u80fd\u91cf\u5b58\u50a8\u4e2d\u626e\u6f14\u4e86\u91cd\u8981\u7684\u4f5c\u7528\u3002\u5c3d\u7ba1\u4eba\u4eec\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u5bf9\u5176\u7ecf\u884c\u4e86\u5927\u91cf\u7684\u7814\u7a76\uff0c\u4f46\u662f\u53cd\u5e94\u7684\u673a\u7406\u5374\u4f9d\u65e7\u4e0d\u591f\u660e\u786e\uff0c\u56e0\u4e3a\u5728\u8fd9\u4e00\u590d\u6742\u7684\u8fc7\u7a0b\u4e2d\u6d89\u53ca\u56db\u7535\u5b50\u548c\u56db\u8d28\u5b50\u5230O<sub>2<\/sub>\u7684\u8fc7\u7a0b\u4ee5\u53ca\u53cc\u952e\u6c27\u7684\u65ad\u88c2\u3002\u5728\u751f\u547d\u4f53\u957f\u671f\u7684\u8fdb\u5316\u8fc7\u7a0b\u4e2d\uff0c\u7ec6\u80de\u80fd\u591f\u901a\u8fc7\u7ec6\u80de\u8272\u7d20C\u6c27\u5316\u9176(CCO)\u548c\u6f06\u9176\u7b49\u9ad8\u6548\u7684\u9176\u5c06\u6c27\u6c14\u8fd8\u539f\u4e3a\u6c34\uff0c\u4e14\u6574\u4e2a\u8fc7\u7a0b\u4e2d\u6ca1\u6709\u8fc7\u7535\u4f4d\u4ea7\u751f\u3002ORR\u8fc7\u7a0b\u4e3a\u71c3\u6599\u7535\u6c60\u88c5\u7f6e\u4e2d\u7684\u5173\u952e\u8fc7\u7a0b\uff0c\u5206\u5b50\u6c27\u8fd8\u539f\u4e3a\u56db\u8d28\u5b50\u8026\u5408\u7684\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u751f\u6210\u6c34\u7684\u540c\u65f6\u5bf9\u5916\u8f93\u51fa\u7535\u80fd\uff0c\u4f46\u662f\u7535\u5316\u5b66\u52a8\u529b\u8fdf\u7f13\u7684\u9634\u6781\u6c27\u8fd8\u53cd\u5e94\uff0c\u6781\u5927\u7684\u964d\u4f4e\u4e86\u71c3\u6599\u7535\u6c60\u7684\u6548\u7387\u3002\u56e0\u6b64\uff0c\u501f\u9274\u751f\u7269\u4f53\u5bf9\u4e8e\u6c27\u6d3b\u5316\u7684\u57fa\u7840\u4e0a\uff0c\u5728\u5316\u5b66\u5c42\u9762\u63a2\u7a76\u6c27\u6d3b\u5316\u7684\u53cd\u5e94\u5386\u7a0b\u548c\u52a8\u529b\u5b66\u7b49\u56e0\u7d20\uff0c\u4ece\u800c\u5408\u7406\u7684\u8bbe\u8ba1\u548c\u7814\u53d1\u9ad8\u6548\u7684ORR\u50ac\u5316\u5242\u3002<\/p>\n<p><strong><b>\u4e00\u3001\u57fa\u672c\u53cd\u5e94\u539f\u7406<\/b><\/strong><\/p>\n<p>O<sub>2<\/sub>\u8fd8\u539f\u5230OH<sup>&#8211;<\/sup>\u7684\u7535\u5b50ORR\u8fc7\u7a0b\u76f8\u5bf9\u6807\u51c6\u8fd8\u539f\u7535\u52bf\u4e3aE<sup>0<\/sup>O<sub>2<\/sub>\/OH<sup>&#8211;<\/sup>=0.401V(SHE)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176912 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724753.png\" alt=\"\" width=\"687\" height=\"58\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724753.png 687w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724753-300x25.png 300w\" sizes=\"(max-width: 687px) 100vw, 687px\" \/> \u00a0\u00a0\u00a0<\/p>\n<p>\u5728\u4e24\u7535\u5b50\u53cd\u5e94\u8def\u5f84\u4e2d\uff0c\u6c27\u6c14\u88ab\u8fd8\u539f\u6210\u8fc7\u6c27\u6839\u79bb\u5b50<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176913 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724754.png\" alt=\"\" width=\"736\" height=\"47\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724754.png 736w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724754-300x19.png 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src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724758.png\" alt=\"\" width=\"650\" height=\"443\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724758.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724758-300x204.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/> \u00a0<\/p>\n<p>\u7531\u4e8e\u6c27\u6c14\u5728\u6c34\u4e2d\u7684\u6eb6\u89e3\u5ea6\u4e3a1.26*10-3 mol\/L\uff0c\u53ea\u80fd\u901a\u8fc7\u5bf9\u6d41\u6216\u8005\u5f3a\u5236\u5bf9\u6d41\u7684\u65b9\u6cd5\u8bc4\u4ef7\uff0c\u5176\u4e2d\u8fd8\u76d8\u7535\u6781(RDE)\u6280\u672f\u662f\u8bc4\u4ef7\u6c27\u8fd8\u539f\u7535\u6781\u6d3b\u6027\u7684\u6709\u6548\u65b9\u5f0f\u3002<\/p>\n<p>\u56fe2\u00a0\u5178\u578b\u7684ORR\u53cd\u5e94\u4e2d\u7684RDE\u6781\u5316\u66f2\u7ebf\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176918 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724759.png\" alt=\"\" width=\"650\" height=\"501\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724759.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724759-300x231.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p>RDE\u7535\u5316\u5b66\u4ee5\u53ca\u6d41\u4f53\u529b\u5b66\u6027\u8d28\u4e0eKoutecky-Levich(K-L)\u65b9\u7a0b\u76f8\u5173\uff0c<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176919 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724760.png\" alt=\"\" width=\"661\" height=\"129\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724760.png 661w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724760-300x59.png 300w\" sizes=\"(max-width: 661px) 100vw, 661px\" 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wen-jie\u7b49\u5229\u7528\u78b3\u7eb3\u7c73\u7ba1(CNT),\u8461\u8404\u7cd6\uff0c\u4e09\u805a\u6c30\u80fa\u4ee5\u53ca\u94c1\u76d0\u4e3a\u524d\u9a71\u4f53\uff0c\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\u968f\u7740\u94c1\u76d0\u542b\u91cf\u7684\u589e\u52a0\uff0cORR\u7684\u50ac\u5316\u6027\u80fd\u589e\u52a0\uff0c\u5f52\u56e0\u4e8e\u5177\u6709\u66f4\u591a\u7684\u7ed3\u6676\u7684\u94c1\u7269\u79cd\u3002\u800c\u8fd9\u79cd\u7ed3\u6676\u94c1\u7269\u79cd\u88ab\u63a8\u6d4b\u8bc1\u660e\u53ef\u4ee5\u589e\u5f3a\u5728\u5176\u5468\u56f4\u7684N\u4ee5\u53caFeNx\u4f4d\u70b9\u7684\u6d3b\u6027\u3002\u5176\u4ed6\u7684\u7814\u7a76\u4e5f\u8868\u660e\uff0c\u5f53\u4e0d\u540c\u7684\u8fc7\u6e21\u91d1\u5c5e\u786b\u9178\u76d0\u4f5c\u4e3a\u91d1\u5c5e\u76d0\u524d\u9a71\u4f53\uff0c\u6c28\u57fa\u5421\u5576\u4e3a\u6c2e\u6e90\uff0cBlack Pearls 2000\u00a0\u4e3a\u78b3\u6e90\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0cFe\u76d0\u548cCo\u76d0\u5f15\u5165\u4e86\u66f4\u9ad8\u7684\u5421\u5576N\u548cMeNx\u7684\u542b\u91cf\uff0c\u8fd9\u4f7f\u5f97\u76f8\u5bf9\u4e8e\u5176\u4ed6\u8fc7\u5ea6\u91d1\u5c5e\u5236\u5907\u7684\u50ac\u5316\u5242\u6216\u8005\u672a\u6dfb\u52a0\u91d1\u5c5e\u7684\u50ac\u5316\u5242\uff0c\u800c\u5177\u6709\u66f4\u4e3a\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u3002\u6b64\u5916\uff0cFe<sub>3<\/sub>C\u548cFe<sub>2<\/sub>N \u50ac\u5316\u5242\u4e2d\u63ba\u6742N\u4e0e\u672a\u63ba\u6742N\u76f8\u6bd4\u8f83\uff0c\u5728\u57fa\u5e95\u6750\u6599\u4e2d\u7684N\u53ef\u4ee5\u7a33\u5b9a\u4ea7\u751f\u7684FeNx\u6d3b\u6027\u7269\u79cd\u800c\u4f7f\u5f97ORR\u50ac\u5316\u6d3b\u6027\u63d0\u5347\u3002\u53e6\u5916\u6709\u7814\u7a76\u8868\u660e\uff0c \u5355\u4e00\u7684\u00a0Fe<sub>3<\/sub>C\u548cFe<sub>2<\/sub>N\u7684\u50ac\u5316\u6d3b\u6027\u4e0d\u9ad8\uff0c\u901a\u8fc7\u52a0\u5165W\u7684\u524d\u9a71\u4f53\u4e0eFe\uff0cCo,\u5f97\u5230WC, Fe<sub>3<\/sub>C\u548cCo<sub>3<\/sub>C\u76f8\u800c\u589e\u52a0ORR\u50ac\u5316\u6d3b\u6027\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\uff0cFe(\u2161) \u53d6\u4ee3Mo(\u2164)\u7684\u914d\u4f4d\u805a\u5408\u7269(11\u2032-bis(dipyrido[3,2-a:2\u2032,3\u2032-c]phenazine))\u53ef\u4ee5\u6709\u6548\u5730\u9632\u6b62Fe\u7684\u56e2\u805a\u4e14\u4ea7\u751fMeNx\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\uff0c\u5982\u56fe5.<\/p>\n<p><strong><b>\u5c0f\u7ed3\uff0c\u8fd9\u7c7b\u50ac\u5316\u6750\u6599\u4e2d\u5421\u5576N\u7684\u542b\u91cf\u9ad8\uff0c\u76f8\u5e94\u7684O<\/b><\/strong><strong><b>RR<\/b><\/strong><strong><b>\u50ac\u5316\u6d3b\u6027\u9ad8<\/b><\/strong><\/p>\n<p>\u56fe3 XPS\u6d4b\u5b9a\u7684N &#8211; Fe\u914d\u4f4d\u7684\u539f\u5b50\u767e\u5206\u6bd4\u4e0e\u4e0d\u540cFe\u914d\u4f4d\u73af\u5883\u50ac\u5316\u5242\u7684E1\/2\u503c\u4e4b\u95f4\u7684\u76f8\u5173\u6027\u00a0(Fe-N\u5bf9\u5e94Fe@C-FeNC-1\uff0c\u00a0\u00a0Fe-N\u548cFe-Fe\u5bf9\u5e94Fe@C-FeNC-2, and Fe-Fe for Fe@C-FeNC-3)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176920 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724761.png\" alt=\"\" width=\"487\" height=\"357\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724761.png 487w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724761-300x220.png 300w\" sizes=\"(max-width: 487px) 100vw, 487px\" \/>\u00a0\u00a0<\/p>\n<p>\u56fe4 (a)\u70ed\u89e3NPM\u50ac\u5316\u5242\u7684TEM\u56fe\u50cf\uff0c\u663e\u793a\u63ba\u6742\u77f3\u58a8\u78b3\u5305\u88f9\u7684Fe3C\u805a\u96c6\u4f53\uff0c(b)HRTEM \u4e3aFe3C\u7684\u6676\u683c\u95f4\u8ddd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176921 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724762.png\" alt=\"\" width=\"619\" height=\"296\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724762.png 619w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724762-300x143.png 300w\" sizes=\"(max-width: 619px) 100vw, 619px\" \/><\/p>\n<p>\u56fe5 Mo\u7684\u524d\u9a71\u4f53\u4e0eFe\u5f62\u6210\u914d\u4f4d\u4ee5\u53ca\u79bb\u5b50\u4ea4\u6362\u8fc7\u7a0b\uff0c\u968f\u540e\u7684\u70ed\u89e3\u4ee5\u53ca\u9178\u6d78\u5f62\u6210NMP\u50ac\u5316\u5242\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176922 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724763.png\" alt=\"\" width=\"620\" height=\"320\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724763.png 620w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724763-300x155.png 300w\" sizes=\"(max-width: 620px) 100vw, 620px\" \/><\/p>\n<p><strong><b>\uff082\uff09\u5bcc\u6c2e\u805a\u5408\u7269\u4e3a\u524d\u9a71\u4f53<\/b><\/strong><\/p>\n<p>\u6700\u521d\u5229\u7528\u5bcc\u542bN\u7684\u805a\u5408\u7269\u4e3a\u524d\u9a71\u4f53\uff0c\u4f8b\u5982\u805a\u82ef\u80fa(PANI),\u5236\u5907\u5f97\u5230\u50ac\u5316\u5242\u8868\u73b0\u51fa\u826f\u597d\u50ac\u5316\u6027\u80fd\u3002Zhu\u7b49\u7814\u7a76\u62a5\u9053\uff0c\u5229\u7528\u542bFe\u805a\u5408\u7269\u524d\u9a71\u4f53\uff0c\u5bf9\u805a\u5408\u7269\u7ed3\u6784\u4e0e\u70ed\u89e3\u50ac\u5316\u5242\u7684ORR\u50ac\u5316\u6027\u80fd\u8fdb\u884c\u6bd4\u8f83\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\u5177\u6709\u826f\u597d\u7684\u91d1\u5c5e\u5206\u6563\u6027\u4ee5\u53ca\u8f83\u9ad8\u7684\u5421\u5576N\u00a0\u542b\u91cf\u4f1a\u589e\u52a0FeNx\u6d3b\u6027\u4f4d\u70b9\u4fc3\u4f7f\u50ac\u5316\u6027\u80fd\u7684\u63d0\u5347\uff0c\u5982\u56fe6.\u540e\u7eed\u7684\u7814\u7a76\u7ed3\u679c\u4e5f\u8868\u660e\uff0c\u8f83\u597d\u7684\u50ac\u5316\u6d3b\u6027\u4e0e\u5bcc\u542bN\u7684\u805a\u5408\u7269\u6240\u4ea7\u751f\u7684FeNx\u4f4d\u70b9\u7684\u589e\u52a0\u6709\u5173\u3002Setyowati, V. A\u00a0\u7b49\u7814\u7a76\u53d1\u73b0\uff0c\u524d\u9a71\u4f53\u76d0\u7684\u5242\u91cf\u4f1a\u4f7f\u5f97\u542b\u6709\u9ad8\u542b\u91cf\u7684\u5b63N\u4ee5\u53caFe(\u2162)\u7684FeNx\u7ed3\u6784\u5bfc\u81f4\u50ac\u5316\u6027\u80fd\u7684\u63d0\u5347\u3002\u4ea6\u6709\u62a5\u9053\u79f0\uff0c\u5728\u70ed\u88c2\u89e3\u7684\u8fc7\u7a0b\u4e2d\u5229\u7528NH3\u5904\u7406\u4f7f\u5f97\u6bd4\u8868\u9762\u79ef\u589e\u52a0\uff0c\u521b\u9020\u5fae\u5b54\u9650\u4e8eFeNx\u7269\u79cd\u800c\u8fbe\u5230\u50ac\u5316\u6027\u80fd\u63d0\u5347\u7684\u76ee\u7684\u3002\u8fd1\u671f\uff0c\u76f8\u5173\u62a5\u9053\u5229\u7528\u9759\u7535\u7eba\u4e1d\u5236\u5907\u7ea4\u7ef4\u50ac\u5316\u5242\uff0c\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\u5229\u7528H2\u6216\u8005\u7a7a\u6c14\u5904\u7406\u4e5f\u80fd\u591f\u8fbe\u5230\u63d0\u5347\u50ac\u5316\u5242\u6d3b\u6027\u7684\u76ee\u7684\u3002\u521d\u6b65\u5206\u6790\u76f8\u5173\u673a\u7406\u4e3a\u521b\u9020\u4e86\u582a\u5fe7\u6d3b\u6027\u7269\u79cd\u7684\u5fae\u5b54\u3002<\/p>\n<p><strong><b>\u5c0f\u7ed3\uff1a\u5229\u7528\u70ed\u88c2\u89e3\u6280\u672f\uff0c\u9759\u7535\u7eba\u4e1d\u6280\u672f\u7b49\u5236\u5907\u624b\u6bb5\u5904\u7406\u542bN\u805a\u5408\u7269\u5f97\u5230\u7684\u50ac\u5316\u5242\uff0c\u56e0\u5177\u6709\u91d1\u5c5e-<\/b><\/strong><strong><b>Nx<\/b><\/strong><strong><b>\u6d3b\u6027\u7269\u79cd\u800c\u80fd\u591f\u6709\u6548\u63d0\u5347\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/b><\/strong><\/p>\n<p>\u56fe6\u00a0a-c\u4e3a\u4e0d\u540c\u7ed3\u6784\u7684\u82ef\u4e8c\u80fa\u5355\u4f53\u7684\u805a\u5408\u9014\u5f84\uff0c\u4f7f\u5f97\u524d\u9a71\u4f53\u6df7\u5408\u7269\u4e2d\u7684N\u5177\u6709\u4e0d\u540c\u7684\u914d\u4f4d\uff0c\u4ee5\u53ca\u4e0d\u540c\u7684\u53ef\u5229\u7528\u7684N\u7269\u79cd\u3002D \u70ad\u9ed1\u805a\u5408\u7269\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176923 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724764.png\" alt=\"\" width=\"622\" height=\"437\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724764.png 622w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724764-300x211.png 300w\" sizes=\"(max-width: 622px) 100vw, 622px\" \/> \u00a0\u00a0\u00a0<\/p>\n<p><strong><b>\uff083\uff09\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e3a\u524d\u9a71\u4f53(<\/b><\/strong><strong><b>MOFs):<\/b><\/strong><\/p>\n<p>\u6700\u8fd1\u7814\u7a76\u7684\u7b56\u7565\u662f\u4f7f\u7528\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u548c\u5176\u4ed6\u7c7b\u4f3c\u6846\u67b6\u4f5c\u4e3a\u91d1\u5c5e\uff0cN\uff0c\u78b3\u7684\u524d\u9a71\u4f53\u800c\u5f97\u5230\u591a\u5b54\u50ac\u5316\u5242\u4f7f\u5f97\u91d1\u5c5e\u5177\u6709\u826f\u597d\u7684\u5206\u6563\u6027\u3002Zitolo\u7b49\u5229\u7528\u542b\u6709\u5c11\u91cf\u83f2\u6d1b\u7433Fe\u7684ZIF (zeolitic imidazolate framework) \u901a\u8fc7\u7403\u78e8\u5206\u6563\uff0c\u5728Ar\u548cNH<sub>3<\/sub>\u4e2d\u5206\u522b\u8fdb\u884c\u70ed\u5904\u7406\uff0c\u5f97\u5230\u7684\u50ac\u5316\u5242\u5177\u6709\u591a\u7684FeNx\u6d3b\u6027\u4f4d\u70b9\u4ee5\u53ca\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u4f18\u5f02\u7684\u50ac\u5316\u8bdd\u6d3b\u6027\u3002\u6b64\u5916\uff0cYin\u7b49\u7814\u7a76\u62a5\u9053\u4e86\u5c06\u542b\u6709Co\u6e90\u7684ZIF-76\u8fdb\u884c\u70ed\u5904\u7406\u540e\u5f97\u5230\u542b\u6709\u5355\u539f\u5b50CoNx\u6d3b\u6027\u4f4d\u70b9\u7684\u50ac\u5316\u5242\uff0c\u6b64\u6d3b\u6027\u4f4d\u70b9\u53ef\u4ee5\u589e\u52a0\u5728\u70ed\u5904\u7406\u65f6Zn\u6325\u53d1\u7559\u4e0b\u7684N\u7a7a\u4f4d\uff0c\u5982\u56fe7\u3002Thomas, M\u7b49\u7814\u7a76\u4e86\u5229\u7528\u77f3\u58a8\u70ef\u5305\u8986\u7684ZIF\u7684\u50ac\u5316\u6027\u80fd\uff0c\u7ed3\u679c\u8868\u660e\u8fd9\u79cd\u7ed3\u6784\u7ecf\u8fc7\u70ed\u5904\u7406\u540e\u80fd\u591f\u4fdd\u7559\u66f4\u591a\u7684N\u3002\u8fd9\u7c7b\u6750\u6599\u4e2d\u5305\u62ec\u66f4\u591a\u7684\u5421\u5576\u7c7b\u548c\u77f3\u58a8\u7c7b\u7269\u79cd\uff0c\u4e14\u589e\u52a0\u4e862-5\u7eb3\u7c73\u7684\u5b54\u5f84\u4f7f\u5f97\u66f4\u52a0\u5bb9\u6613\u5730\u589e\u52a0N\u4f4d\u70b9\u3002<\/p>\n<p><strong><b>\u5c0f\u7ed3\uff1a\u5229\u7528M<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u5236\u5907\u7684\u50ac\u5316\u5242\uff0c\u9664\u53bb\u5177\u6709\u91d1\u5c5e-<\/b><\/strong><strong><b>N<\/b><\/strong><strong><b>\u6d3b\u6027\u4f4d\u70b9\u63d0\u5347\u50ac\u5316\u6d3b\u6027\uff0c\u76f8\u5173\u673a\u7406\u8bc1\u660e\u89e3\u91ca\u4e86\u8fd8\u4f1a\u5177\u6709\u5355\u539f\u5b50\u6d3b\u6027\u4f4d\u70b9\uff0c\u7a7a\u4f4d\u7b49\u4f4d\u70b9\u589e\u52a0<\/b><\/strong><strong><b>ORR<\/b><\/strong><strong><b>\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/b><\/strong><\/p>\n<p>\u56fe7\u00a0a ZIF-67\u70ed\u5904\u7406\u5f62\u6210Co\u7eb3\u7c73\u7c92\u5b50\uff0cb\u00a0\u5355\u539f\u5b50Co\u5728\u542b\u6709\u53cc\u91d1\u5c5eZn,Co\u7684MOF\u5f62\u6210\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176924 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724765.png\" alt=\"\" width=\"621\" height=\"641\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724765.png 621w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724765-291x300.png 291w\" sizes=\"(max-width: 621px) 100vw, 621px\" \/><\/p>\n<p>\u56fe8\u00a0\u6c27\u5316\u77f3\u58a8\u70ef\u5305\u8986\u7684ZIF-8\u7c92\u5b50\u5408\u6210\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176925 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724766.png\" alt=\"\" width=\"631\" height=\"331\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724766.png 631w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724766-300x157.png 300w\" sizes=\"(max-width: 631px) 100vw, 631px\" \/><\/p>\n<p><strong><b>\uff084\uff09\u786c\u6a21\u677f\u6cd5<\/b><\/strong><\/p>\n<p>Sebastain \u7b49\u901a\u8fc7\u5229\u7528\u785d\u9178\u94c1\u548c\u6c28\u57fa\u82ef\u4e19\u54aa\u5511\u5236\u5907\u5f97\u5230\u7684\u7845\u57fa\u6a21\u677f\uff0c\u540e\u7eed\u7ecf\u8fc7\u9178\u6d17\u4ee5\u53caNH3\u7684\u70ed\u5904\u7406\u53ef\u4ee5\u5bf9\u50ac\u5316\u6027\u6539\u5584\uff0c\u8fd9\u5f52\u56e0\u4e8e\u540e\u5904\u7406\u53ef\u4ee5\u589e\u52a0FeNx\u6d3b\u6027\u4f4d\u70b9\u7684\u66b4\u9732\u3002\u4ea6\u6709\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u6709\u4e8c\u6c27\u5316\u7845\u6a21\u677f\u751f\u6210\u7684\u5fae\u5b54\uff0c\u4f7f\u5f97\u7531\u915e\u83c1\u94c1\u70ed\u5206\u89e3\u5f97\u5230\u7684\u94c1\u5747\u5300\u7684\u5206\u5e03\u5728\u5b54\u9053\u4e2d\u800c\u4fc3\u8fdb\u50ac\u5316\u6027\u80fd\u7684\u63d0\u5347\u3002Sa\u00a0\u7b49\u5236\u5907\u4e86\u4e8c\u6c27\u5316\u7845\u5305\u8986\u7684\u542b\u6709\u94c1\u535f\u5549\u78b3\u7eb3\u7c73\u7ba1\uff0c\u5728\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u9650\u57df\u524d\u9a71\u4f53\u800c\u80fd\u6709\u6548\u9632\u6b62Fe\u7684\u56e2\u805a\uff0c\u800c\u4ea7\u751f\u66f4\u591a\u7684FeNx\u6d3b\u6027\u4f4d\u70b9\u63d0\u5347\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<p><strong><b>\u5c0f\u7ed3\uff1a\u4e00\u79cd\u6709\u6548\u7684\u5236\u5907\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5408\u6210\u7b56\u7565\uff0c\u8fd9\u662f\u56e0\u4e3a\u786c\u6a21\u677f\u6cd5\u53ef\u4ee5\u5236\u5907\u5177\u6709\u5927\u7a7a\uff0c\u4ecb\u5b54\u7ed3\u6784\u6750\u6599\u800c\u589e\u52a0\u50ac\u5316\u5242\u8868\u9762\u6d3b\u6027\u533a\u57df\uff0c\u4e14\u6613\u4e8e\u53bb\u9664\uff0c\u4f8b\u5982\u4e8c\u6c27\u5316\u7845\u53ef\u5229\u7528\u6c22\u6c27\u5316\u94be\u523b\u8680\u53bb\u9664\u3002<\/b><\/strong><\/p>\n<p>\u56fe 9 NPM\u50ac\u5316\u5242\u7684\u5408\u6210\u8def\u7ebf\u3002 \u5229\u7528\u4e8c\u6c27\u5316\u7845\u6d82\u5c42\u5c06\u524d\u9a71\u4f53\u9650\u5236\u5728\u78b3\u7eb3\u7c73\u7ba1(CNT)\u7684\u8868\u9762\u4ee5\u9632\u6b62Fe\u7684\u56e2\u805a(\u7eff\u8272\u8def\u7ebf)\u3002\u4e0d\u9002\u7528\u4e8c\u6c27\u5316\u7845\u5c42\uff0c\u751f\u6210Fe\u548cFe<sub>3<\/sub>C\u7269\u79cd(\u6a59\u8272\u8def\u7ebf)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176926 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724767.png\" alt=\"\" width=\"642\" height=\"284\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724767.png 642w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724767-300x133.png 300w\" sizes=\"(max-width: 642px) 100vw, 642px\" \/><\/p>\n<p><strong><b>\uff085\uff09N\u63ba\u6742\u78b3\u57fa\u50ac\u5316\u5242<\/b><\/strong><\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u6742\u539f\u5b50(N,B,P\u7b49)\u63ba\u6742\u7684\u78b3\u57fa\u50ac\u5316\u5242\u56e0\u5177\u6709\u7535\u5316\u5b66\u6027\u80fd\u9ad8\uff0c\u7a33\u5b9a\u6027\u9ad8\u4ee5\u53ca\u4f4e\u6210\u672c\u4e14\u6613\u5f97\u7b49\u4f18\u52bf\u5f15\u8d77\u4e86\u7814\u7a76\u8005\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u4f8b\u5982N\u63ba\u6742\u77f3\u58a8\u70ef\uff0c\u78b3\u7eb3\u7c73\u7ba1\u7b49\u88ab\u7814\u7a76\u8bc1\u660e\u5177\u6709\u78b3\u7684\u8fb9\u7f18\u6d3b\u6027\/\u7f3a\u9677\u4f4d\u70b9\u6548\u5e94\u800c\u4fc3\u8fdb\u50ac\u5316\u6027\u80fd\u7684\u63d0\u5347\u3002Stamatin\u7b49\u5236\u5907\u4e86\u77f3\u58a8\u70ef\u5305\u8986\u7684\u6c27\u5316\u94dd\u7ea4\u7ef4\uff0c\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\u77f3\u58a8\u70ef\u6d82\u5c42\u4e0a 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\u5bf9N\u63ba\u6742\u7684\u591a\u58c1\u78b3\u7eb3\u7c73\u7ba1\u7684\u521d\u59cb\u6d3b\u6027\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n<p><strong><b>\u5c0f\u7ed3:<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>N\u63ba\u6742\u7684\u78b3\u57fa\u50ac\u5316\u5242\u56e0\u5177\u6709\u7279\u5b9a\u7684\u5421\u5576N<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u6d3b\u6027\u4f4d\u70b9\uff0c\u7279\u6b8a\u7684\u8fb9\u7f18\u6d3b\u6027\/\u7f3a\u9677\u4f4d\u70b9\uff0c\u800c\u63d0\u5347\u50ac\u5316\u6d3b\u6027\u3002<\/b><\/strong><\/p>\n<p>\u56fe10\u00a0a \u77f3\u58a8\u70ef\u5305\u8986\u7684\u6c27\u5316\u94dd\u7684SEM \u56fe\uff1b b \u5229\u7528CVD \u6cd5\u5236\u5907\u7684\u4ee5\u53ca\u751f\u957f\u793a\u610f\u56fe<\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"wp-image-176927 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724768.png\" alt=\"\" width=\"640\" height=\"327\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724768.png 640w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724768-300x153.png 300w\" sizes=\"(max-width: 640px) 100vw, 640px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u7ed3\u675f\u8bed\uff1a\u7b80\u8ff0\u7684N<\/b><\/strong><strong><b>PR<\/b><\/strong><strong><b>-\u57fa\u7684O<\/b><\/strong><strong><b>RR<\/b><\/strong><strong><b>\u50ac\u5316\u5242\uff0c\u56e0\u5177\u6709\u9ad8\u6d3b\u6027\u4f4d\u70b9\u5bc6\u5ea6\u800c\u5177\u6709\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u8c03\u63a7\u5408\u6210\u5236\u5907\u5de5\u827a\u800c\u589e\u5927\u50ac\u5316\u5242\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u6784\u7b51\u5b54\u9053\uff0c\u4f8b\u5982\u5229\u7528N<\/b><\/strong><strong><b>H<\/b><\/strong><strong><b>3\u6216H<\/b><\/strong><strong><b>2<\/b><\/strong><strong><b>\u7b49\u540e\u5904\u7406\u50ac\u5316\u5242\uff0c\u9178\u6d17\u53ef\u4ee5\u4ee5\u9664\u53bb\u50ac\u5316\u5242\u8868\u9762\u7684\u975e\u6d3b\u6027\u4f4d\u70b9\uff0c\u8fd9\u4e9b\u5904\u7406\u624b\u6bb5\u53ef\u4ee5\u6709\u6548\u5730\u4f18\u5316\u50ac\u5316\u5242\u800c\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u3002\u540e\u7eed\u7684\u7814\u7a76\u4f1a\u66f4\u52a0\u8d8b\u5411\u4e8e\u5bf9<\/b><\/strong><strong><b>NPM<\/b><\/strong><strong><b>\u57fa\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u8d77\u6e90\u7684\u63a2\u7d22\u3002\u901a\u8fc7\u8bbe\u8ba1\u65b9\u6cd5\u6765\u9610\u8ff0\u6d3b\u6027\u4f4d\u70b9\u7684\u6027\u8d28\u867d\u7136\u4f9d\u65e7\u662f\u5de8\u5927\u7684\u6311\u6218\uff0c\u4f46\u662f\u901a\u8fc7\u8fd9\u4e9b\u52aa\u529b\u624d\u80fd\u591f\u4fc3\u4f7fN<\/b><\/strong><strong><b>PM<\/b><\/strong><strong><b>\u57fa\u50ac\u5316\u5242\u7684\u53d1\u5c55\u4ee5\u53ca\u5728\u71c3\u6599\u7535\u6c60O<\/b><\/strong><strong><b>RR<\/b><\/strong><strong><b>\u4e2d\u7684\u5e94\u7528\u3002<\/b><\/strong><\/p>\n<p><strong><b>\u00a0<\/b><\/strong><strong><b>\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n<p>1.Jiang, W. J.; Gu, L.; Li, L.; Zhang, Y.; Zhang, X.; Zhang, L. J.; Wang, J. Q.; Hu, J. S.; Wei, Z. D.; Wan, L. J. Understanding the High Activity of Fe-N-C Electrocatalysts in Oxygen Reduction: Fe\/Fe<sub>3<\/sub>C Nanoparticles Boost the Activity of Fe-N-X. J. Am. Chem. Soc. 2016,138, 3570-3578.<\/p>\n<p>2.Zhu, J. B.; Xiao, M. L.; Liu, C. P.; Ge, J. J.; St-Pierre, J.; Xing, W. Growth Mechanism and Active Site Probing of Fe3c@N-Doped Carbon Nanotubes\/C Catalysts: Guidance for Building Highly Efficient Oxygen Reduction Electrocatalysts. J. Mater. Chem. A 2015,3, 21451-21459.<\/p>\n<p>3.Lin, L.; Yang, Z. K.; Jiang, Y. F.; Xu, A. W. Nonprecious Bimetallic (Fe, Mo)-N\/C Catalyst for Efficient Oxygen Reduction Reaction. ACS Catal. 2016, 6, 4449-4454.<\/p>\n<p>4.Zhu, Y. S.; Zhang, B. S.; Feng, Z. B.; Su, D. S. SynthesisStructure-Performance Correlation for Poly(Phenylenediamine)S\/Iron\/Carbon Non-Precious Metal Catalysts for Oxygen Reduction Reaction. Catal. Today 2016, 260, 112-118.<\/p>\n<p>5.Yin, P. Q.; Yao, T.; Wu, Y.; Zheng, L. R.; Lin, Y.; Liu, W.; Ju, H. X.; Zhu, J. F.; Hong, X.; Deng, Z. X.; et al. Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts. Angew. Chem., Int. Ed. 2016, 55, 10800-10805.<\/p>\n<p>6.Thomas, M.; Illathvalappil, R.; Kurungot, S.; Nair, B. N.; Mohamed, A. A. P.; Anilkumar, G. M.; Yamaguchi, T.; Hareesh, U. S.Graphene Oxide Sheathed Zif-8 Microcrystals: Engineered Precursors of Nitrogen-Doped Porous Carbon for Efficient Oxygen Reduction Reaction (Orr) Electrocatalysis. ACS Appl. Mater. Interfaces 2016, 8, 29373-29382.<\/p>\n<p>7.Sa, Y. J.; Seo, D. J.; Woo, J.; Lim, J. T.; Cheon, J. Y.; Yang, S. Y.; Lee, J. M.; Kang, D.; Shin, T. J.; Shin, H. S.; et al. A General Approach to Preferential Formation of Active Fe-N-X Sites in Fe-N\/C Electrocatalysts for Efficient Oxygen Reduction Reaction. J. Am. Chem. Soc. 2016, 138, 15046-15056.<\/p>\n<p>8.Stamatin, S. N.; Hussainova, I.; Ivanov, R.; Colavita, P. E. Quantifying Graphitic Edge Exposure in Graphene-Based Materials and Its Role in Oxygen Reduction Reactions. ACS Catal. 2016, 6, 5215-5221.<\/p>\n<p><strong>\u5f80\u671f\u56de\u987e<\/strong><\/p>\n<p><a class=\"title info_flow_news_title\" href=\"http:\/\/www.cailiaoniu.com\/172938.html\" target=\"_blank\" rel=\"noopener\">\u7535\u50ac\u5316\u65b0\u5ba0\u4e4b\u5e38\u6e29\u5e38\u538b\u6c2e\u8fd8\u539f\uff08NRR\uff09\uff0c\u6700\u5168NRR\u4ecb\u7ecd\uff0c\u4f60\u60f3\u8981\u7684\u90fd\u5728\u8fd9\uff01<\/a><\/p>\n<p><a class=\"title info_flow_news_title\" href=\"http:\/\/www.cailiaoniu.com\/169587.html\" target=\"_blank\" rel=\"noopener\">\u8ba4\u8bc6\u8fd9\u4e9b\u5e26\u4f60\u8f7b\u677e\u4e0a\u738b\u8005\u2014\u2014\u7535\u50ac\u5316\u4ea7\u6c27\uff08OER\uff09\u6d4b\u8bd5\u624b\u6bb5\u89e3\u6790<\/a><\/p>\n<p><a class=\"title info_flow_news_title\" href=\"http:\/\/www.cailiaoniu.com\/167466.html\" target=\"_blank\" rel=\"noopener\">\u4f60\u771f\u7684\u4e86\u89e3\u7535\u50ac\u5316\u4ea7\u6c22\u8fd9\u4e9b\u77e5\u8bc6\u5417\uff1f\u5df2\u4e3a\u4f60\u603b\u7ed3\u597d\uff0c\u5feb\u6233\uff01<\/a><\/p>\n<p><a class=\"title info_flow_news_title\" href=\"http:\/\/www.cailiaoniu.com\/161543.html\" target=\"_blank\" rel=\"noopener\">\u7ecf\u5178\u7efc\u8ff0\u96c6\u9526\uff1a\u8fc8\u8fdb\u5149\u7535\u50ac\u5316\u5927\u95e8\uff0c\u8bf7\u4ece\u8fd9\u5341\u7bc7\u7efc\u8ff0\u5f00\u59cb\uff01<\/a><\/p>\n<p><a class=\"title info_flow_news_title\" href=\"http:\/\/www.cailiaoniu.com\/160694.html\" target=\"_blank\" rel=\"noopener\">\u8bf7\u6536\u4e0b\u8fd9\u7bc7\u51c6\u786e\u6d4b\u91cf\u7535\u50ac\u5316\u7684\u6307\u5357<\/a><\/p>\n<p>\u672c\u6587\u7cfbJane\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6c27\u8fd8\u539f\u53cd\u5e94ORR\u662f\u76ee\u524d\u7535\u5316\u5b66\u9886\u57df\u548c\u50ac\u5316\u9886\u57df\u7814\u7a76\u6700\u5e7f\u6cdb\u7684\u8bdd\u9898\u4e4b\u4e00\uff0c\u5b83\u5728\u7535\u5316\u5b66\u80fd\u91cf\u8f6c\u5316\u548c\u80fd\u91cf\u5b58\u50a8\u4e2d\u626e\u6f14\u4e86\u91cd\u8981\u7684\u4f5c\u7528\u3002\u5c3d\u7ba1\u4eba\u4eec\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u5bf9\u5176\u7ecf\u884c\u4e86\u5927\u91cf\u7684\u7814\u7a76\uff0c\u4f46\u662f&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":177241,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-176909","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/176909"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=176909"}],"version-history":[{"count":9,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/176909\/revisions"}],"predecessor-version":[{"id":177594,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/176909\/revisions\/177594"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/177241"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=176909"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=176909"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=176909"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}