{"id":177024,"date":"2019-06-05T06:30:46","date_gmt":"2019-06-04T22:30:46","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=177024"},"modified":"2019-06-04T18:59:05","modified_gmt":"2019-06-04T10:59:05","slug":"nature%ef%bc%9a%e4%b8%80%e7%a7%8d%e4%bb%a4%e4%ba%ba%e5%85%b4%e5%a5%8b%e7%9a%84%e9%9d%9e%e5%af%b9%e7%a7%b0%e5%90%88%e6%88%90%e5%b7%a5%e5%85%b7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=177024","title":{"rendered":"Nature\uff1a\u4e00\u79cd\u4ee4\u4eba\u5174\u594b\u7684\u975e\u5bf9\u79f0\u5408\u6210\u5de5\u5177"},"content":{"rendered":"<p><strong>\u4f5c\u8005\u4ecb\u7ecd\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/strong>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n<p>Thorsten Bach\u4e8e1991\u5e74\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u968f\u540e\u5728NATO\u5956\u5b66\u91d1\u7684\u652f\u6301\u4e0b\u8fdb\u5165\u7f8e\u56fd\u54c8\u4f5b\u5927\u5b66\u6559\u6388D. A. Evans\u8bfe\u9898\u7ec4\u8fdb\u884c\u535a\u58eb\u540e\u7684\u7814\u7a76\uff1b2000\u5e74\u8d77\u5728\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66\u4efb\u6709\u673a\u5316\u5b66\u7b2c\u4e00\u7814\u7a76\u5ba4\u4e3b\u4efb\u81f3\u4eca\uff1b2006\u5e74\u88ab\u9009\u4e3a\u5fb7\u56fd\u79d1\u5b66\u9662\u9662\u58eb\uff1b2009\u5e74\u88ab\u9009\u4e3a\u5df4\u4f10\u5229\u4e9a\u79d1\u5b66\u9662\u9662\u58eb\u3002\u4ed6\u7684\u7814\u7a76\u96c6\u4e2d\u5728\u5305\u62ec\u6709\u673a\u5316\u5b66\u9886\u57df\uff0c\u5305\u62ec\u6709\u673a\u5149\u5316\u5b66\u3001\u5929\u7136\u4ea7\u7269\u7684\u5168\u5408\u6210\u3001\u8fc7\u6e21\u91d1\u5c5e\u4e0e\u8d85\u5206\u5b50\u50ac\u5316\u7b49\u3002\u591a\u5e74\u6765\u5728<em><i>Science, Nature, Chem. Rev., J.Am.Chem.Soc. Angew. Chem<\/i><\/em>\u7b49\u56fd\u9645\u4e00\u6d41\u671f\u520a\u4e0a\u53d1\u8868\u7814\u7a76\u8bba\u6587250\u591a\u7bc7\u3002<\/p>\n<p>Thorsten\u00a0Bach\u6559\u6388\u5728\u505a\u5b66\u672f\u62a5\u544a\uff1a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-177026 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724726-1.png\" alt=\"\" width=\"600\" height=\"396\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724726-1.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724726-1-300x198.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\u63a5\u4e0b\u6765\u4ecb\u7ecd\u4e00\u4e0b\u4e0d\u5bf9\u79f0\u5408\u6210\uff1a<\/p>\n<p>\u4e0d\u5bf9\u79f0\u5408\u6210\uff08Asymmetric synthesis\uff09\uff0c\u4e5f\u79f0\u624b\u6027\u5408\u6210\u3001\u7acb\u4f53\u9009\u62e9\u6027\u5408\u6210\u3001\u5bf9\u6620\u9009\u62e9\u6027\u5408\u6210\uff0c\u662f\u7814\u7a76\u5411\u53cd\u5e94\u7269\u5f15\u5165\u4e00\u4e2a\u6216\u591a\u4e2a\u5177\u624b\u6027\u5143\u7d20\u7684\u5316\u5b66\u53cd\u5e94\u7684\u6709\u673a\u5408\u6210\u5206\u652f\u3002<\/p>\n<p><strong><b>\u4e0d\u5bf9\u79f0\u5408\u6210\u6709\u591a\u91cd\u8981\u5462\uff1f<\/b><\/strong><\/p>\n<p>\u4e3e\u51e0\u4e2a\u7b80\u5355\u7684\u4f8b\u5b50\uff0c\u5927\u5bb6\u5c31\u77e5\u9053\u4e86\u3002\u9752\u9709\u7d20\u6211\u4eec\u518d\u719f\u6089\u4e0d\u8fc7\u4e86\uff0c\u4f5c\u4e3a\u4e00\u79cd\u836f\u529b\u5f3a\uff0c\u526f\u4f5c\u7528\u5c0f\u7684\u6297\u751f\u7d20\u836f\u7269\uff0c\u957f\u671f\u4ee5\u6765\u4e00\u76f4\u88ab\u4eba\u4eec\u5e7f\u6cdb\u7684\u4f7f\u7528\u3002\u7136\u800c\u8fd1\u4e00\u65f6\u671f\u4eba\u4eec\u53d1\u73b0\uff0c\u9752\u9709\u7d20\u5206\u5b50\u540c\u6837\u5b58\u5728\u4e24\u79cd\u624b\u6027\u5206\u5b50\uff0c\u5176\u4e2d\u4e00\u79cd\u6709\u836f\u6548\uff0c\u800c\u53e6\u4e00\u79cd\u5374\u6839\u672c\u6ca1\u6709\u3002\u6362\u53e5\u8bdd\u8bf4\uff0c\u6211\u4eec\u82b1\u4e86\u4e00\u74f6\u9752\u9709\u7d20\u7684\u94b1\uff0c\u6709\u7528\u7684\u90e8\u5206\u5374\u53ea\u6709\u534a\u74f6\uff0c\u8fd9\u5176\u5b9e\u662f\u4e00\u79cd\u5f88\u5927\u7684\u6d6a\u8d39\u3002\u5f53\u7136\u5982\u679c\u5149\u662f\u6d6a\u8d39\uff0c\u90fd\u53ef\u4ee5\u63a5\u53d7\uff0c\u4f46\u4e8b\u5b9e\u4e0a\u6709\u7684\u836f\u7269\u4e24\u79cd\u624b\u6027\u5206\u5b50\u4e2d\uff0c\u5176\u4e2d\u4e00\u79cd\u4e0d\u4ec5\u6ca1\u6709\u836f\u6548\uff0c\u53cd\u800c\u8fd8\u6709\u76f8\u5f53\u5f3a\u7684\u6bd2\u526f\u4f5c\u7528\u3002\u4e0a\u4e2a\u4e16\u7eaa\u4e2d\u53f6\uff0c\u6000\u5b55\u5987\u5973\u7ecf\u5e38\u4f7f\u7528\u4e00\u79cd\u53eb\u201c\u53cd\u5e94\u505c\u201d\u7684\u836f\u7269\u6765\u6291\u5236\u598a\u5a20\u53cd\u5e94\uff0c\u5374\u4ea7\u751f\u4e86\u5927\u91cf\u7684\u7578\u5f62\u80ce\u513f\u3002\u540e\u6765\u624d\u53d1\u73b0\u8be5\u836f\u7269\u4e24\u79cd\u624b\u6027\u5206\u5b50\u4e2d\u7684\u5176\u4e2d\u4e00\u79cd\u5177\u6709\u81f4\u7578\u5f62\u80ce\u513f\u7684\u4f5c\u7528\u3002<\/p>\n<p style=\"text-align: right;\">&#8212; \u6765\u81ea\u4f60\u719f\u6089\u7684\u767e\u5ea6<\/p>\n<p><strong><b>\u5728\u4f60\u8fd8\u5728\u753b\u95ee\u53f7\uff0c\u96be\u9053\u6211\u4e70\u7684\u836f\u548c\u6bd2\u836f\u4e5f\u5c31\u4e00\u5ff5\u4e4b\u95f4\u7684\u65f6\u5019\uff0c\u6211\u4eec\u8981\u5f00\u59cb\u4ecb\u7ecd\u4eca\u5929\u7684\u91cd\u5934\u620f\u4e86\uff01\uff01<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-177027 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724727-1.png\" alt=\"\" width=\"677\" height=\"168\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724727-1.png 677w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724727-1-300x74.png 300w\" sizes=\"(max-width: 677px) 100vw, 677px\" 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loading=\"lazy\" decoding=\"async\" class=\"wp-image-177028 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724728-1.png\" alt=\"\" width=\"650\" height=\"445\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724728-1.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724728-1-300x205.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p>\u6839\u636e\u4e00\u7cfb\u5217\u7684\u5b9e\u9a8c\uff0c\u5f97\u5230\u4e86\u6700\u4f18\u53cd\u5e94\u6761\u4ef6\uff0c\u5982\u56fe2<\/p>\n<p>\u56fe 2 \u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-177029 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724729-1.png\" alt=\"\" width=\"337\" height=\"263\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724729-1.png 337w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724729-1-300x234.png 300w\" sizes=\"(max-width: 337px) 100vw, 337px\" \/><\/p>\n<p>\u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u4e19\u4e8c\u70ef\u5355\u4f53\u7684\u53bb\u6d88\u65cb\u53cd\u5e94\uff0c\u53d1\u73b0\u5728\u6700\u4f18\u5b9e\u9a8c\u6761\u4ef6\u4e0b\uff0c\u4e0d\u540c\u4e19\u4e8c\u70ef\u5355\u4f53\u7684\u53bb\u9664\u7387\u4ece\uff0871%\u201398%\uff09,\u5177\u6709\u4e00\u5b9a\u7684\u666e\u9002\u6027\u3002<\/p>\n<p>\u56fe 3\u00a0\u5728\u53ef\u89c1\u5149\uff08\u03bb= 420nm\uff09\u7684\u7167\u5c04\u4f7f\u624b\u6027\u4e19\u4e8c\u70ef\u53bb\u6d88\u65cb<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-177030 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724730-1.png\" alt=\"\" width=\"650\" height=\"339\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/\u56fe\u724730-1.png 650w, 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href=\"https:\/\/www.nature.com\/articles\/s41586-018-0755-1\">Catalytic deracemization of chiral allenes by sensitized excitation with visible light<\/a><\/p>\n<p>https:\/\/www.nature.com\/articles\/s41586-018-0755-1<\/p>\n<p>\u672c\u6587\u7531Lion\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4f5c\u8005\u4ecb\u7ecd\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Thorsten Bach\u4e8e1991\u5e74\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u968f\u540e\u5728NATO\u5956\u5b66\u91d1\u7684\u652f\u6301\u4e0b\u8fdb\u5165\u7f8e\u56fd\u54c8\u4f5b\u5927\u5b66\u6559\u6388D. 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