{"id":177696,"date":"2019-06-18T06:30:49","date_gmt":"2019-06-17T22:30:49","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=177696"},"modified":"2019-06-17T18:29:44","modified_gmt":"2019-06-17T10:29:44","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e6%b5%99%e6%b1%9f%e5%a4%a7%e5%ad%a6nature-commun-%e5%9f%ba%e4%ba%8e%e6%9f%b1%e8%8a%b3%e7%83%83%e6%9e%84%e5%bb%ba%e7%9a%84%e8%b6%85%e5%88%86%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=177696","title":{"rendered":"\u6d59\u5927Nature Commun.: \u57fa\u4e8e\u67f1\u82b3\u70c3\u6784\u5efa\u7684\u8d85\u5206\u5b50\u591a\u80bd\u7528\u4e8e\u53ef\u63a7\u81ea\u7ec4\u88c5\u548c\u5149\u52a8\u529b\u6cbb\u7597"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u591a\u80bd\u5177\u6709\u751f\u7269\u76f8\u5bb9\u6027\u9ad8\u3001\u7ec6\u80de\u900f\u8fc7\u6027\u597d\u3001\u514d\u75ab\u539f\u6027\u4f4e\u7b49\u4f18\u70b9\uff0c\u662f\u5728\u751f\u7269\u5316\u5b66\u9886\u57df\u4e2d\u7684\u7eb3\u7c73\u6216\u5927\u5c3a\u5ea6\u529f\u80fd\u6750\u6599\u7684\u6700\u4f73\u9009\u62e9\u4e4b\u4e00\u3002\u901a\u8fc720\u79cd\u5929\u7136\u6c28\u57fa\u9178\u7684\u7ec4\u5408\u53ef\u4ee5\u5236\u5907\u51fa\u591a\u79cd\u591a\u6837\u7684\u80bd\u57fa\u6750\u6599\uff0c\u5305\u62ec\u7528\u4e8e\u7ec6\u80de\u5916\u57fa\u8d28\u7684\u6c34\u51dd\u80f6\u3001\u7528\u4e8e\u751f\u7269\u4f20\u611f\u53ca\u50ac\u5316\u7684\u590d\u5408\u6750\u6599\u7b49\u3002\u5176\u4e2d\u6700\u4ee4\u4eba\u611f\u5174\u8da3\u7684\u662f\u7ecf\u4e24\u4eb2\u6027\u591a\u80bd\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u7eb3\u7c73\u6750\u6599\uff1a\u7531\u4e8e\u4eb2\u758f\u6c34\u4f5c\u7528\u548c\u80bd\u94fe\u4e4b\u95f4\u7684\u6c22\u952e\uff0c\u4f4d\u4e8e\u7ec4\u88c5\u4f53\u5916\u8868\u9762\u7684\u4eb2\u6c34\u7aef\u57fa\u53ef\u4ee5\u5f15\u5165\u591a\u79cd\u529f\u80fd\u6027\u5e8f\u5217\uff0c\u4ece\u800c\u4f7f\u7ec4\u88c5\u4f53\u5f97\u4ee5\u5b9e\u73b0\u591a\u79cd\u591a\u6837\u7684\u751f\u7269\u5b66\u529f\u80fd\uff0c\u4fc3\u8fdb\u4e86\u591a\u80bd\u7ec4\u88c5\u6750\u6599\u5728\u751f\u7269\u5b66\u65b9\u9762\u7684\u5e94\u7528\u3002\u901a\u8fc7\u591a\u80bd\u5e8f\u5217\u8c03\u63a7\u548c\u5916\u90e8\u523a\u6fc0\uff0c\u4e24\u4eb2\u6027\u591a\u80bd\u80fd\u591f\u81ea\u7ec4\u88c5\u5f62\u6210\u7eb3\u7c73\u7ea4\u7ef4\u3001\u7eb3\u7c73\u7ba1\u3001\u56ca\u6ce1\u548c\u7eb3\u7c73\u9897\u7c92\uff08NPs\uff09\u3002\u8fd9\u4e9b\u591a\u80bd\u81ea\u7ec4\u88c5\u6750\u6599\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u836f\u7269\u9012\u9001\u3001\u7ec6\u80de\u6210\u50cf\u548c\u7ec4\u7ec7\u5de5\u7a0b\u7b49\u751f\u7269\u5b66\u524d\u6cbf\u7814\u7a76\u3002\u7136\u800c\uff0c\u5927\u591a\u6570\u60c5\u51b5\u4e0b\u591a\u80bd\u94fe\u4e00\u65e6\u5408\u6210\uff0c\u80bd\u94fe\u7684\u5171\u4ef7\u4fee\u9970\u53ca\u5171\u4ef7\u6539\u6027\u9700\u8981\u91cd\u65b0\u56fa\u76f8\u5408\u6210\u548cHPLC\u5206\u79bb\uff0c\u6b65\u9aa4\u7e41\u7410\u4e14\u4e0d\u7ecf\u6d4e\u3002\u540c\u65f6\uff0c\u4e24\u4eb2\u6027\u591a\u80bd\u7684\u81ea\u7ec4\u88c5\u5f62\u8c8c\u4e0d\u6613\u63a7\u5236\u3002\u8fd9\u4e9b\u7f3a\u70b9\u963b\u788d\u4e86\u57fa\u4e8e\u591a\u80bd\u7684\u751f\u7269\u6750\u6599\u7684\u76f8\u5173\u63a2\u7d22\u548c\u5e94\u7528\u3002
\n \u8fd1\u5e74\u6765\uff0c\u57fa\u4e8e\u67f1\u82b3\u70c3\u7684\u8d85\u5206\u5b50\u4e24\u4eb2\u5206\u5b50\u6b63\u88ab\u5e7f\u6cdb\u5730\u5e94\u7528\u4e8e\u53ef\u63a7\u81ea\u7ec4\u88c5\u53ca\u751f\u7269\u6750\u6599\u3002\u4e0e\u5176\u5b83\u5927\u73af\u5316\u5408\u7269\u76f8\u6bd4\uff0c\u67f1\u82b3\u70c3\u7684\u529f\u80fd\u5316\u7b80\u4fbf\u3001\u4e3b\u5ba2\u4f53\u4eb2\u548c\u6027\u5f3a\u548c\u591a\u91cd\u523a\u6fc0\u54cd\u5e94\u6027\u8d4b\u4e88\u4e86\u8fd9\u4e9b\u8d85\u5206\u5b50\u4e24\u4eb2\u5206\u5b50\u7ec4\u88c5\u4f53\u53ef\u63a7\u7684\u5f62\u8c8c\u548c\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u4f8b\u5982\u7528\u4e8e\u63a7\u5236\u91ca\u653e\u7684\u56ca\u6ce1\u548c\u7528\u4e8e\u7ec6\u80de\u6210\u50cf\u7684\u7eb3\u7c73\u7c92\u5b50\u3002\u56e0\u6b64\uff0c\u5c06\u57fa\u4e8e\u67f1\u82b3\u70c3\u7684\u8d85\u5206\u5b50\u4e24\u4eb2\u5206\u5b50\u4e0e\u591a\u80bd\u81ea\u7ec4\u88c5\u7ed3\u5408\u8d77\u6765\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u524d\u666f\u7684\u8c03\u63a7\u591a\u80bd\u884c\u4e3a\u7684\u65b9\u6cd5\uff0c\u53ef\u4ee5\u7528\u4e8e\u591a\u80bd\u81ea\u7ec4\u88c5\u7684\u5f62\u8c8c\u63a7\u5236\u5e76\u8fdb\u4e00\u6b65\u6539\u5584\u7ec4\u88c5\u4f53\u7684\u529f\u80fd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u6d59\u6c5f\u5927\u5b66\u5316\u5b66\u7cfb\u9ec4\u98de\u9e64\u6559\u6388<\/strong>\u3001\u9ad8\u5206\u5b50\u7cfb\u6bdb\u5ce5\u4f1f\u6559\u6388<\/strong>\u548c\u7f8e\u56fd\u56fd\u7acb\u536b\u751f\u7814\u7a76\u9662\u55bb\u56fd\u707f\u535a\u58eb<\/strong>\u56e2\u961f\u5408\u4f5c\u62a5\u9053\u4e86\u4e00\u79cd\u6784\u7b51\u8d85\u5206\u5b50\u591a\u80bd\u7684\u7b80\u5355\u65b9\u6cd5\uff0c\u5176\u53ef\u63a7\u7684\u591a\u80bd\u81ea\u7ec4\u88c5\u62e5\u6709\u591a\u79cd\u5f62\u8c8c\u5e76\u80fd\u5e94\u7528\u4e8e\u5149\u52a8\u529b\u6cbb\u7597\u4e2d\u3002\u4ed6\u4eec\u5229\u7528\u57fa\u4e8e\u67f1[5]\u82b3\u70c3\u7684\u4e3b\u5ba2\u4f53\u8bc6\u522b\u6280\u672f\u6765\u6784\u5efa\u8d85\u5206\u5b50\u591a\u80bd\uff0c\u907f\u514d\u4e86\u591a\u80bd\u6539\u826f\u65f6\u7684\u5171\u4ef7\u5408\u6210\uff0c\u63d0\u9ad8\u4e86\u81ea\u7ec4\u88c5\u884c\u4e3a\u7684\u53ef\u63a7\u6027\u3002\u4ed6\u4eec\u8fdb\u4e00\u6b65\u5229\u7528\u8d85\u5206\u5b50\u591a\u80bd\u5f62\u6210\u7684\u7eb3\u7c73\u7c92\u5b50\u8868\u9762\u7684\u534a\u80f1\u6c28\u9178\u6b8b\u57fa\u548c\u7eb3\u7c73\u7c92\u5b50\u5185\u90e8\u8f93\u6c34\u7684\u5185\u6838\u5c01\u88c5\u4e86\u5149\u52a8\u529b\u6cbb\u7597\u7528\u7684\u5149\u654f\u5242\u56db\u82ef\u57fa\u535f\u5549\u3002\u4f53\u5185\u548c\u4f53\u5916\u7684\u7814\u7a76\u8868\u660e\uff0c\u8d85\u5206\u5b50\u7684\u4fee\u9970\u7b56\u7565\u53caERGDS\u5e8f\u5217\u56fa\u6709\u7684\u9776\u5411\u6027\u5927\u5927\u63d0\u9ad8\u4e86\u5176\u5149\u52a8\u529b\u6cbb\u7597\u6548\u7387\u3002\u8fd9\u79cd\u8d85\u5206\u5b50\u591a\u80bd\u5728\u80bf\u7624\u7684\u7cbe\u51c6\u6cbb\u7597\u3001\u591a\u80bd\u4fee\u9970\u4e0e\u6539\u826f\u65b9\u9762\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cSupramolecular peptide constructed by molecular Lego allowing programmable self-assembly for photodynamic therapy<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u4e8e\u77e5\u540d\u5b66\u672f\u671f\u520aNature Commun.<\/strong>\u4e0a\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u6d59\u6c5f\u5927\u5b66\u5316\u5b66\u7cfb\u535a\u58eb\u751f\u6731\u9ec4\u5929\u4e4b<\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u8d85\u5206\u5b50\u80bd\u7684\u8bbe\u8ba1\u4e0e\u7ed3\u6784\u793a\u610f\u56fe<\/strong>
\n \"\"\uff08a\uff09PA\uff0cPyP\u548cP5\u7684\u5316\u5b66\u7ed3\u6784\u53ca\u5176\u8868\u793a\uff1b<\/p>\n

\uff08b\uff09\u53ef\u63a7\u591a\u80bd\u81ea\u7ec4\u88c5\u548c\u5149\u52a8\u529b\u6cbb\u7597\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u4e8c\u3001\u4e0d\u540c\u6e29\u5ea6\u4e0b\u4e3b\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\u7684\u7814\u7a76<\/strong>
\n \"\"\uff08a\uff09G1 + P5\uff085.00 mM\uff09\u76842D NOESY\u8c31\u56fe\uff08400 MHz\uff0cD2<\/sub>O\uff0c25 \u2103\uff09\uff1b<\/p>\n

\uff08b~c\uff09G1 + P5\uff085 mM\uff09\u5206\u522b\u5728\uff08b\uff0925 \u2103\u3001\uff08c\uff0945 \u2103\u548c\uff08d\uff0950 \u2103\u4e0b\u76841H NMR\u8c31\u56fe\uff08400 MHz\uff0cD2<\/sub>O\uff09\u3002<\/p>\n

\u56fe\u4e09\u3001\u8d85\u5206\u5b50\u591a\u80bd\u7684\u81ea\u7ec4\u88c5\u8c03\u63a7\u53ca\u7ec4\u88c5\u5f62\u8c8c<\/strong>
\n \"\"SEM\u548cTEM\u56fe\u50cf\uff1aa\uff0cd PA\uff1bb\uff0ce P5 + PyP\uff0c25 \u00b0C\uff1bc\uff0cf P5 + PyP\uff0c45 \u2103\u3002<\/p>\n

\u56fe\u56db\u3001TPP@NPs\u7684\u7ec6\u80de\u6444\u53d6<\/strong>
\n \"\"\uff08a\uff09\u6e38\u79bbTPP\uff08\u7ea2\u7ebf\uff09\u548cTPP@NPs\uff08\u9ed1\u7ebf\uff09\u4e0d\u540c\u65f6\u95f4\u5b75\u80b2\u4e0b\u7684\u76f8\u5bf9\u7ec6\u80de\u6444\u53d6\uff1b<\/p>\n

\uff08b\uff09\u7ec6\u80de\u5185\u541e\u6291\u5236\u5242\u5bf9A549\u7ec6\u80de\u6444\u53d6TPP @ NPs\u7684\u5f71\u54cd\uff1b<\/p>\n

\uff08c\uff09\u901a\u8fc7TPP @ NPs\uff08\u7ea2\u8272\uff09\uff0cLyso-tracker Green\uff08\u67d3\u6eb6\u9176\u4f53\uff0c\u7eff\u8272\uff09\u548cDAPI\uff08\u67d3\u7ec6\u80de\u6838\u6838\uff0c\u84dd\u8272\uff09\u67d3\u8272\u7684A549\u7ec6\u80de\u76842D CLSM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e94\u3001\u4f53\u5916\u5149\u52a8\u529b\u6cbb\u7597\u7ed3\u679c<\/strong>
\n \"\"\uff08a\uff09NPs\u548cTPP@NPs\u5728\u9ed1\u6697\u6761\u4ef6\u4e0b\u5bf9A549\u7ec6\u80de\u7684\u7ec6\u80de\u6bd2\u6027\uff1b<\/p>\n

\uff08b\uff09TPP\u548cTPP@NPs\u5728660 nm\u6fc0\u5149\u7167\u5c04\u4e0b\uff0c\u4e0d\u540c\u7167\u5c04\u65f6\u957f\u5bf9A549\u7ec6\u80de\u7684\u7ec6\u80de\u6bd2\u6027\u5f71\u54cd\uff1b<\/p>\n

\uff08c\uff09\u5149\u52a8\u529b\u6cbb\u7597\u6548\u7387\uff08\u7ec6\u80de\u51cb\u4ea1\u7387\uff09\uff1b<\/p>\n

\uff08d\uff09\u4e0d\u540c\u6d53\u5ea6\u7684TPP@NPs\u5bf9ECs\u548cA549\u7ec6\u80de\u7684\u5149\u6bd2\u6027\uff1b<\/p>\n

\uff08e\uff09A549\u7ec6\u80de\u7684\u6d3b\u6b7b\u7ec6\u80de\u67d3\u8272\uff1a\uff08i\uff09\u5bf9\u7167\u7ec4\uff0c\uff08ii\uff09\u5355\u72ec\u6fc0\u5149\u7167\u5c04\u7ec4\uff0c\uff08iii\uff09\u5355\u72ec\u52a0TPP@NPs\u7ec4\u548c\uff08iv\uff09TPP@NPs\u52a0\u6fc0\u5149\u7167\u5c04\u7ec4\u3002\u6fc0\u5149\u8fb9\u754c\u4ee5\u767d\u8272\u865a\u7ebf\u6807\u51fa\uff0c\u6697\u533a\u5c11\u91cf\u7ec6\u80de\u6b7b\u4ea1\u53ef\u80fd\u662f\u7531\u4e8e\u6fc0\u5149\u51c6\u76f4\u6027\u6b20\u4f73\u6240\u81f4\u3002<\/p>\n

\u56fe\u516d\u30014T1\u8377\u7624\u5c0f\u9f20\u7684\u4f53\u5185PDT\u7ed3\u679c<\/strong>
\n \"\"\uff08a\uff09\u80bf\u7624\u4f53\u79ef\u53d8\u5316\uff1b<\/p>\n

\uff08b\uff09\u5728\u4e00\u6b21\u6ce8\u5c04\u540e\uff0c\u7528\u4e0d\u540c\u5242\u91cf\u548c\u4e0d\u540c\u6cbb\u7597\u65b9\u5f0f\u5904\u7406\u76844T1\u8377\u7624\u5c0f\u9f20\u7684\u6700\u7ec8\u80bf\u7624\u91cd\u91cf\uff1b<\/p>\n

\uff08c\uff09\u6700\u7ec8\u80bf\u7624\u56fe\u7247\uff1b<\/p>\n

\uff08d\uff09\u5728\u4e00\u6b21\u6ce8\u5c04\u540e\uff0c\u7528\u4e0d\u540c\u5242\u91cf\u548c\u4e0d\u540c\u6cbb\u7597\u65b9\u5f0f\u5904\u7406\u76844T1\u8377\u7624\u5c0f\u9f20\u7684\u4f53\u91cd\u53d8\u5316\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aSupramolecular peptide constructed by molecular Lego allowing programmable self-assembly for photodynamic therapy<\/a>\uff08Nat. Commun.,<\/em> 2019,<\/strong> 10(1): 2412.\uff09<\/p>\n

\n \u672c\u6587\u7531\u6211\u4ea6\u662f\u884c\u4eba\u7f16\u8bd1\u3002<\/p>\n

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