{"id":177985,"date":"2019-06-17T06:56:40","date_gmt":"2019-06-16T22:56:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=177985"},"modified":"2019-06-16T20:57:30","modified_gmt":"2019-06-16T12:57:30","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e5%8c%96%e5%ad%a6%e6%89%80%e6%9d%8e%e7%8e%89%e8%89%af%e9%99%a2%e5%a3%ab%e7%bb%bc%e8%bf%b0%ef%bc%9a%e7%9f%b3%e5%a2%a8%e7%82%94%e5%8f%8a%e5%85%b6%e7%bb%84%e8%a3%85%e4%bd%93","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=177985","title":{"rendered":"\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u674e\u7389\u826f\u9662\u58eb\u7efc\u8ff0\uff1a\u77f3\u58a8\u7094\u53ca\u5176\u7ec4\u88c5\u4f53\u7cfb\uff1a\u5408\u6210\u3001\u529f\u80fd\u5316\u548c\u5e94\u7528"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u77f3\u58a8\u7094(Graphdiyne, GDY)\u662f\u4e00\u79cd\u65b0\u578b\u7684\u5355\u539f\u5b50\u5c42\u539a\u5ea6\u7684\u4e8c\u7ef4\u78b3\u6750\u6599\uff0c\u5176\u72ec\u7279\u7684sp\u548csp2\u5171\u6742\u5316\u5e26\u6765\u7684\u4e30\u5bcc\u7684\u78b3\u5316\u5b66\u952e\u3001\u5929\u7136\u5b54\u6d1e\u7ed3\u6784\u4ee5\u53ca\u8868\u9762\u7535\u8377\u5206\u5e03\u4e0d\u5747\u5300\u6027\u5f15\u53d1\u4e86\u8bb8\u591a\u5947\u7279\u7684\u6027\u8d28\uff0c\u5f15\u8d77\u4e86\u79d1\u5b66\u754c\u548c\u5de5\u4e1a\u754c\u7684\u6781\u5927\u5174\u8da3\u3002\u57fa\u4e8e\u77f3\u58a8\u7094\u7684\u53ef\u63a7\u751f\u957f\u53ef\u4ee5\u83b7\u5f97\u4e0d\u540c\u5f62\u8c8c\u7684\u805a\u96c6\u6001\u7ed3\u6784\uff0c\u5982\u7eb3\u7c73\u7ebf\u3001\u7eb3\u7c73\u7ba1\u9635\u5217\u3001\u7eb3\u7c73\u7247\u548c\u6709\u5e8f\u6761\u7eb9\u9635\u5217\u7b49\u3002\u8fd1\u5e74\u6765\uff0c\u77f3\u58a8\u7094\u7684\u72ec\u7279\u4f18\u52bf\u4f7f\u5176\u5728\u80fd\u6e90\u3001\u50ac\u5316\u3001\u5149\u7535\u8f6c\u6362\u3001\u751f\u547d\u79d1\u5b66\u53ca\u5fae\u7535\u5b50\u5b66\u7b49\u9886\u57df\u7684\u57fa\u7840\u79d1\u5b66\u548c\u5e94\u7528\u79d1\u5b66\u7814\u7a76\u8868\u73b0\u51fa\u5de8\u5927\u7684\u6f5c\u529b\uff0c\u5e76\u53d6\u5f97\u4e86\u5f15\u53d1\u65b0\u80fd\u6e90\u4e1a\u754c\u77a9\u76ee\u7684\u6210\u679c\u3002\u00a0<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u674e\u7389\u826f\u9662\u58eb\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Advanced Materials<\/em><\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cGraphdiyne and its Assembly Architectures: Synthesis, Functionalization, and Applications<\/strong>\u201d<\/strong>\u7684\u7efc\u8ff0\u3002\u5728\u8be5\u7efc\u8ff0\u4e2d\uff0c\u9996\u5148\u6df1\u523b\u5206\u6790\u4e86\u77f3\u58a8\u7094\u7684\u672c\u5f81\u6027\u8d28\uff0c\u5168\u9762\u4ecb\u7ecd\u77f3\u58a8\u7094\u53ca\u77f3\u58a8\u7094\u7eb3\u7c73\u7ed3\u6784\u53ef\u63a7\u5236\u5907\u6700\u65b0\u8fdb\u5c55\uff0c\u7136\u540e\u7cfb\u7edf\u603b\u7ed3\u4e86\u77f3\u58a8\u7094\u5728\u50ac\u5316\u3001\u5149\u7535\u3001\u80fd\u91cf\u5b58\u50a8\u548c\u8f6c\u6362\u3001\u751f\u547d\u79d1\u5b66\u3001\u73af\u5883\u7b49\u9886\u57df\u7684\u57fa\u7840\u548c\u5e94\u7528\u7814\u7a76\u53d6\u5f97\u7684\u8fdb\u5c55\uff0c\u5e76\u7ed3\u5408\u5b9e\u9645\u5e94\u7528\u4e2d\u5173\u952e\u6027\u95ee\u9898\u63d0\u51fa\u77f3\u58a8\u7094\u65b0\u578b\u7535\u5316\u5b66\u754c\u9762\uff0c\u4e3a\u89e3\u51b3\u7535\u5316\u5b66\u80fd\u6e90\u8f6c\u6362\u5668\u4ef6\u4e2d\u8bf8\u591a\u5173\u952e\u79d1\u5b66\u95ee\u9898\u5e26\u6765\u65b0\u7684\u8ba4\u8bc6\uff0c\u6700\u540e\u4f5c\u8005\u8fd8\u8ba8\u8bba\u4e86\u77f3\u58a8\u7094\u7684\u672a\u6765\u53d1\u5c55\u65b9\u5411\u3002<\/p>\n

\u00a0\u3010<\/strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/strong><\/p>\n

\u56fe1 \u53ef\u63a7\u5408\u6210\u4e0d\u540c\u5f62\u8c8c\u77f3\u58a8\u7094<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u8868\u9762\u751f\u957f\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(b) \u8f6c\u79fb\u5230SiO2<\/sub>\/Si\u886c\u5e95\u4e0a\u539f\u4f4d\u751f\u957f\u8584\u819c\u7684OM\u56fe\u50cf\uff1b<\/p>\n

(c) \u8f6c\u79fb\u5230SiO2<\/sub>\/Si\u886c\u5e95\u4e0a\u8584\u819c\u7684AFM\u56fe\u50cf\uff1b<\/p>\n

(d) \u7eb3\u7c73\u7247\u7684\u4f4e\u500d\u548c\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf\uff1b<\/p>\n

(e) \u7eb3\u7c73\u7247\u7684\u5b9e\u9a8cSAED\u56fe\u6848\uff1b<\/p>\n

(f) \u5177\u6709AA\u5806\u53e0\u6a21\u5f0f\u7684GDY\u6a21\u578b\u4ee5\u53ca\u5bf9\u5e94\u5806\u53e0\u6a21\u578b\u7684\u6a21\u62dfSAED\u6a21\u5f0f\uff1b<\/p>\n

(g) \u5177\u6709AB\u5806\u53e0\u6a21\u5f0f\u7684GDY\u6a21\u578b\u4ee5\u53ca\u5bf9\u5e94\u5806\u53e0\u6a21\u578b\u7684\u6a21\u62dfSAED\u6a21\u5f0f\uff1b<\/p>\n

(h) \u5177\u6709ABC\u5806\u53e0\u6a21\u5f0f\u7684GDY\u6a21\u578b\u4ee5\u53ca\u5bf9\u5e94\u5806\u53e0\u6a21\u578b\u7684\u6a21\u62dfSAED\u6a21\u5f0f\uff1b<\/p>\n

(i) GDNWs\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

(j) GDYNT\u7684\u9876\u89c6\u56fe\uff1b<\/p>\n

(k) GDYNT\u7684\u4fa7\u89c6\u56fe\uff1b<\/p>\n

(l) GDY\u5e26\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(m) GDY\u7eb3\u7c73\u94fe\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(n) Cu\u57fa\u5e95\u4e0aGDY\u7eb3\u7c73\u58c1\u7684\u9876\u89c6SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe2 \u77f3\u58a8\u7094\u96f6\u4ef7\u539f\u5b50\u50ac\u5316\u5242<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5408\u6210\u539f\u5b50\u50ac\u5316\u5242\u7684\u65b9\u6cd5\uff1b<\/p>\n

(b) Ni\/GDY\u7684HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n

(c) Fe\/GDY\u7684HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n

(d) Ni\/GD\u548cNi\u7b94\u5728Ni K-edge\u7684\u975e\u539f\u4f4dEXAFS\u5149\u8c31\uff1b<\/p>\n

(e) Fe\/GDY and Fe\u7b94\u5728Fe K-edge\u7684\u975e\u539f\u4f4dEXAFS\u5149\u8c31\uff1b<\/p>\n

(f) Ni-on-GDY\u4e0a\u771f\u5b9e\u7a7a\u95f4HOMO\u548cLUMO\u7b49\u9ad8\u7ebf\u56fe\uff1b<\/p>\n

(g) H\u7684\u5316\u5b66\u5438\u9644\u80fd\u4e0e\u81ea\u7531\u80fd\u66f2\u7ebf\uff08\u0394G\uff09\u7684\u5173\u7cfb\u3002<\/p>\n

\u56fe<\/strong>3 <\/strong>\u9ad8\u6d3b\u6027\u9ad8\u7a33\u5b9a\u6027\u77f3\u58a8\u7094\u57fa\u7535\u89e3\u6c34\u50ac\u5316\u5242<\/strong><\/p>\n

\"\"<\/p>\n

(a) eGDY\/MDS\u7684\u4f4e\u500d\u653e\u5927SEM\u56fe\u50cf\uff1b<\/p>\n

(b) eGDY\/MDS\u7684\u9ad8\u500d\u653e\u5927SEM\u56fe\u50cf\uff1b<\/p>\n

(c) eGDY\/MDS\u7684\u6001\u5bc6\u5ea6\u56fe\uff1b<\/p>\n

(d) MDS\uff08\u84dd\u7ebf\uff09\u548ceGDY\uff08\u7d2b\u8272\u865a\u7ebf\uff09\u7684\u6001\u5bc6\u5ea6\u56fe\uff1b<\/p>\n

(e) eGDY\/MDS\u7684\u7535\u8377\u5bc6\u5ea6\u5dee\u5f02\u56fe\uff1a\u4fef\u89c6\u56fe\uff1b<\/p>\n

(f) eGDY\/MDS\u7684\u7535\u8377\u5bc6\u5ea6\u5dee\u5f02\u56fe\uff1a\u4fa7\u89c6\u56fe\uff1b<\/p>\n

(g) \u57281.0 M KOH\u4e2d\u83b7\u5f97\u7684\u6837\u54c1\u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

(h) \u57280.5 M H2<\/sub>SO4<\/sub>\u4e2d\u83b7\u5f97\u7684\u6837\u54c1\u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

(i) \u50ac\u5316\u5242\u7684\u77ac\u6001\u5149\u7535\u6d41\u54cd\u5e94\uff1b<\/p>\n

(j) FeCH@GDY\/NF\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(k) FeCH@GDY\/NF\u7684\u9ad8\u5206\u8fa8\u7387TEM\u56fe\u50cf\uff1b<\/p>\n

(l) \u5728OER\u6d4b\u8bd5\u524d\u540e\u8bb0\u5f55\u7684FeCH@GDY\/NF\u548cFeCH\/NF\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

(m) \u5728\u5faa\u73af\u6d4b\u8bd5\u524d\u540e\u8bb0\u5f55\u7684FeCH@GDY\/NF\u548cFeCH\/NF\u7684LSV\u66f2\u7ebf\u3002<\/p>\n

\u56fe4 \u9ad8\u6d3b\u6027\u9ad8\u7a33\u5b9a\u6027\u77f3\u58a8\u7094\u5728\u5149\u7535\u89e3\u6c34\u50ac\u5316\u5242<\/strong><\/p>\n

\"\"<\/p>\n

(a) PEC\u88c5\u7f6e\u4e2dGDY\/BiVO4<\/sub>\u5149\u9633\u6781\u7684\u793a\u610f\u56fe\u4ee5\u53ca\u5728\u754c\u9762\u5904\u5149\u751f\u6fc0\u5b50\u7684\u8fc1\u79fb\uff1b<\/p>\n

(b) \u6240\u5236\u5907GDY\/BiVO4<\/sub>\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(c) \u6240\u5236\u5907GDY\/BiVO4<\/sub>\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

(d) \u5728Xe\u706f\u7167\u5c04\uff08\u5b9e\u7ebf\uff09\u548c\u9ed1\u6697\uff08\u865a\u7ebf\uff09\u6761\u4ef6\u4e0b\uff0cBiVO4<\/sub>\u548cGDY\/BiVO4<\/sub>\u5149\u9633\u6781\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

(e) \u57284\u5c0f\u65f6\u8bd5\u9a8c\u4e2dBiVO4<\/sub>\u548cGDY\/BiVO4\u5149\u9633\u6781\u7684J<\/em>-t\u66f2\u7ebf\uff1b<\/p>\n

(f) BiVO4<\/sub>\u548cGDY\/BiVO4<\/sub>\u8584\u819c\u7684\u5149\u81f4\u53d1\u5149\u66f2\u7ebf\uff1b<\/p>\n

(g) BiVO4<\/sub>\u548cGDY\/BiVO4<\/sub>\u5149\u9633\u6781\u7684\u7a7a\u7a74\u6ce8\u5165\u4ea7\u7387\uff1b<\/p>\n

(h) \u57283D GDY\u7eb3\u7c73\u7247\u9635\u5217\u4e0a\u6784\u5efa2D\/2D\u77f3\u58a8\u78b3\u6c2e\u5316\u7269\/GDY\u5f02\u8d28\u7ed3\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(i) g-C3<\/sub>N4<\/sub>\/GDY\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(j) g-C3<\/sub>N4<\/sub>\/GDY\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

(k) \u5728\u9ed1\u6697\u548c\u8f90\u5c04\u6761\u4ef6\u4e0bg-C3<\/sub>N4<\/sub>\/GDY\u5149\u9634\u6781\u7684OCP\u54cd\u5e94\uff1b<\/p>\n

(l) \u5149\u7167\u4e0b\u6d4b\u5b9ag-C3<\/sub>N4<\/sub>\u548cg-C3<\/sub>N4<\/sub>\/GDY\u5149\u7535\u9634\u6781\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\uff1b<\/p>\n

(m) g-C3<\/sub>N4<\/sub>\u548cg-C3<\/sub>N4<\/sub>\/GDY\u5149\u9634\u6781\u7684Bode\u76f8\u56fe\uff1b<\/p>\n

(n) \u5728\u6697\u548c\u5149\u6761\u4ef6\u4e0b\u6d4b\u91cf\u7684\u4e0d\u540c\u5149\u7535\u9634\u6781\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u6cd5\u626b\u63cf\u7ed3\u679c\u3002<\/p>\n

\u56fe5 \u9ad8\u6548\u77f3\u58a8\u7094\u57fa\u6709\u673a\u53cd\u5e94\u50ac\u5316\u5242<\/strong><\/p>\n

\"\"<\/p>\n

(a) GDY\u4e0a\u7a33\u5b9aPt NPs\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(b) Pt-GDY\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

(c) Pt-GDY\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

(d) 2-\u6c27\u4ee3-4-\u82ef\u57fa\u4e01\u9178\u4e59\u916f\uff08EOPB\uff09\u7684\u6c22\u5316\u793a\u610f\u56fe\u3002\uff1b<\/p>\n

(e) EOPB\u5728Pt-C\u548cPt-GDY\u50ac\u5316\u5242\u4e0a\u8f6c\u5316\u7684\u6bd4\u8f83\uff1b<\/p>\n

(f) \u6e29\u5ea6\u5bf9EOPB\u8f6c\u5316\u7387\u7684\u5f71\u54cd\uff1b<\/p>\n

(g) EOPB\u6d53\u5ea6\u5bf9\u5176\u8f6c\u5316\u7387\u7684\u5f71\u54cd\uff1b<\/p>\n

(h) \u8f6c\u6362\u7387\u4e0e\u5faa\u73af\u6b21\u6570\u7684\u5173\u7cfb\uff1b<\/p>\n

(i) \u4f7f\u7528Pt-GDY\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5bf9\u4e0d\u540c\u7684\u916e\u548c\u919b\u8fdb\u884c\u6c22\u5316\uff1b<\/p>\n

(j) \u63d0\u51fa\u7684\u919b\u548c\u916e\u6c22\u5316\u6210\u76f8\u5e94\u7684\u9187\u6216\u4e8c\u82c4\u919a\u7684\u50ac\u5316\u673a\u7406\u3002<\/p>\n

\u56fe6 \u77f3\u58a8\u7094\u5728\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u7684\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

(a) GDY\u5728CuNW\u7eb8\u4e0a\u751f\u957f\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(b) \u6bd4\u5bb9\u91cf\u7684\u53d8\u5316\u4ee5\u53caGDY1\u548cGDY2\u57285 Ag-1<\/sup>\u5904\u7684\u957f\u671f\u7a33\u5b9a\u6027\uff1b<\/p>\n

(c) \u63d0\u51fa\u7684\u9ad8\u500d\u7387\u6027\u80fd\u673a\u5236\uff1b<\/p>\n

(d) \u5de6\u56fe\uff1aPY-GDY\u548cPM-GDY\u53ef\u80fd\u7684\u5408\u6210\u9014\u5f84\uff1b\u53f3\u56fe\uff1a\u7167\u7247\u663e\u793a\u4eba\u624b\u4e0a\u7684\u53ef\u7a7f\u6234\u8f6f\u5305\u7535\u6c60\u53ef\u4ee5\u70b9\u4eaeLED\u706f\uff1b<\/p>\n

(e) \u5728500 mA g-1<\/sup>\u7535\u6d41\u4ee5\u53ca0.005\u548c3 V\u7535\u538b\u8303\u56f4\u6761\u4ef6\u4e0b\uff0cPY-GDY\u57fa\u7535\u6781\u7684\u6052\u7535\u6d41\u5145\u7535\/\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(f) \u5728500 mA g-1<\/sup>\u7535\u6d41\u4ee5\u53ca0.005\u548c3 V\u7535\u538b\u8303\u56f4\u6761\u4ef6\u4e0b\uff0cPM-GDY\u57fa\u7535\u6781\u7684\u6052\u7535\u6d41\u5145\u7535\/\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(g) PY-GDY\u57fa\u7535\u6781\u5bf9LIB\u7684\u901f\u7387\u6027\u80fd\uff1b<\/p>\n

(h) PM-GDY\u57fa\u7535\u6781\u5bf9LIB\u7684\u901f\u7387\u6027\u80fd\u3002<\/p>\n

\u56fe7 \u77f3\u58a8\u7094\u884d\u751f\u7269\u5728\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u7684\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u56db\u79cd\u4f18\u5316\u7684Li+C28<\/sub>Cl6<\/sub>\uff08A1-A4\uff09\u914d\u5408\u7269\u548c2Li+C28<\/sub>Cl6<\/sub>\uff08B1\uff09\u7684\u51e0\u4f55\u7ed3\u6784\u548c\u5f62\u6210\u80fd\u91cf\uff1b<\/p>\n

(b, c) Cl-GDY\u4e2d\u53ef\u80fd\u7684Li\u50a8\u5b58\u4f4d\u70b9\uff1b<\/p>\n

(d) LIB\u7535\u6781\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

(e) Cl-GDY\u7535\u6781\u572850 mAg-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(f) \u67d4\u6027\u7535\u6781\u5728200 mAg-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

(g) \u67d4\u6027\u7535\u6781\u57282 Ag-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

(h) HsGDY\u7684\u5408\u6210\u793a\u610f\u56fe\uff1b<\/p>\n

(i) Li\u5b58\u50a8\u673a\u5236\uff08\u5de6\uff09\u548c\u7531HsGDY\uff08\u53f3\uff09\u5236\u6210\u7684\u53ef\u5f2f\u66f2\u900f\u660eLIB\uff1b<\/p>\n

(j) \u57280.1 Ag-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0bHsGDY\u57fa\u7535\u6781\u7684\u5145\u7535-\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(k) \u67d4\u6027LIB\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

(l) \u67d4\u6027\u7535\u6781\u57280.1 Ag-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

(m) \u67d4\u6027\u7535\u6781\u57281 Ag-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe<\/strong>8\u00a0<\/strong>\u77f3\u58a8\u7094\u5728\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\u7684\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

(a) PCBSD\u548c\u77f3\u58a8\u7094\u7684\u5206\u5b50\u7ed3\u6784\u4ee5\u53ca\u7531\u4e8e\u5b83\u4eec\u4e4b\u95f4\u7684\u03c0-\u03c0\u5806\u53e0\u76f8\u4e92\u4f5c\u7528\u800c\u5728\u5806\u53e0C-PCBSD\u819c\u4e0a\u7684\u9762\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(b) \u9499\u949b\u77ff\u5e73\u9762\u5f02\u8d28\u7ed3\u592a\u9633\u80fd\u7535\u6c60\u7684\u5668\u4ef6\u7ed3\u6784\uff1b<\/p>\n

(c) \u5177\u6709C-PCBSD:GD\u57fa ETL\u7684\u5178\u578b\u9499\u949b\u77ff\u5668\u4ef6\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

(d) \u5728AM 1.5 G\uff08100 mW cm-2<\/sup>\uff09\u7167\u5ea6\u4e0b\u548c\u9ed1\u6697\u4e2d\u7684\u51a0\u519b\u5668\u4ef6\u7684J-V<\/em>\u66f2\u7ebf\uff1b<\/p>\n

(e) TiO2<\/sub>\/C-PCBSD:GD\u57fa\u5668\u4ef6\u57280.92 V\u6761\u4ef6\u4e0b\u6700\u5927\u529f\u7387\u70b9\u7684\u6700\u5927\u7a33\u6001\u5149\u7535\u6d41\u8f93\u51fa\u53ca\u5176\u76f8\u5e94\u7684\u529f\u7387\u8f93\u51fa\uff1b<\/p>\n

(f) \u5728\u5ba4\u6e29\u4e0b\u5728\u5927\u6c14\uff08\u9ed1\u6697\uff09\u4e2d\u8bc4\u4f30\u7684TiO2<\/sub>\u548cTiO2<\/sub>\/C-PCBSD:GD\u57faPSCs\u7684\u5f52\u4e00\u5316PCE\u503c\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\uff1b<\/p>\n

(g) p-i-n\u5668\u4ef6\u7684\u67b6\u6784\uff1b<\/p>\n

(h) \u57fa\u4e8ePCBM(GDY)\/ZnO(GDY)\u7684\u5668\u4ef6\u7684\u5149\u7535\u6d41\u548c\u6697\u7535\u6d41\uff1b<\/p>\n

(i) PCBM\/ZnO\u548cCBM(GD)\/ ZnO(GD)\u4f5c\u4e3aETL\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

\u56fe9 \u77f3\u58a8\u7094\u5728\u7535\u5316\u5b66\u9a71\u52a8\u5668\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u77f3\u58a8\u7094\u81f4\u52a8\u5668\u7684\u7ec4\u88c5\u8fc7\u7a0b\u548c\u76f8\u5e94\u81f4\u52a8\u673a\u5236\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(b) \u968f\u7740\u9891\u7387\u7684\u589e\u52a0\uff0c\u77f3\u58a8\u7094\u81f4\u52a8\u5668\u7684\u8870\u51cf\u5e94\u53d8\uff1b<\/p>\n

(c) \u5cf0\u5230\u5cf0\u4f4d\u79fb\u4e0e\u4e09\u4e2a\u81f4\u52a8\u5668\u7684\u9891\u7387\u7684\u5173\u7cfb\uff1b<\/p>\n

(d) \u4e0d\u540c\u7c7b\u578b\u7684\u81f4\u52a8\u6750\u6599\u7684\u8f6c\u6362\u6548\u7387\u6bd4\u8f83\uff1b<\/p>\n

(e) \u77f3\u58a8\u7094\u81f4\u52a8\u5668\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b<\/p>\n

(f) \u5f53\u9047\u5230\u7535\u523a\u6fc0\u65f6\uff0c\u77f3\u58a8\u7094\u7684\u81f4\u52a8\u5e94\u53d8\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(g) \u4e00\u4e2a\u77f3\u58a8\u7094\u5355\u5143\u4e2d\u7684\u70ef\u70c3-\u7094\u70c3\u590d\u5408\u7269\u7684\u8f6c\u53d8\u673a\u7406\uff1b<\/p>\n

(h) \u901a\u8fc7SECM\u65b9\u6cd5\u5728\u5404\u79cd\u65bd\u52a0\u7535\u538b\u4e0b\uff0c\u77f3\u58a8\u7094\u3001\u77f3\u58a8\u70ef\u548c\u78b3\u7eb3\u7c73\u7ba1\u8584\u819c\u7684\u7ebf\u6027\u5e94\u53d8\uff1b<\/p>\n

(i) \u4e09\u79cd\u6750\u6599\u5e94\u53d8\u4fdd\u7559\u7684\u7406\u8bba\u503c\u3002<\/p>\n

\u56fe10 \u77f3\u58a8\u7094\u5728\u751f\u7269\u63a2\u6d4b\u53ca\u8bca\u7597\u9886\u57df\u7684\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u901a\u8fc7\u4e0d\u540c\u9014\u5f84\u8fdb\u884c\u57fa\u4e8eGD\u7684\u591a\u91cdDNA\u68c0\u6d4b\u7684\u65b9\u6848\uff1b<\/p>\n

(b) FAM\u6807\u8bb0\u7684H1N1 ssDNA\u7684\u8367\u5149\u5149\u8c31\uff1b<\/p>\n

(c) \u6709\u65e0GDY\u7684ssDNA\u548cdsDNA\u63a2\u9488\u7684\u8367\u5149\u5f3a\u5ea6\uff1b<\/p>\n

(d) GDY-PEG\u7684\u5236\u5907\u65b9\u6848\uff1b<\/p>\n

(e) \u4e0d\u540c\u6d53\u5ea6GDY-PEG\u7684UV-vis-NIR\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

(f) \u4f7f\u7528808nm\u6fc0\u5149\u7167\u5c04\u4e0d\u540c\u79cd\u6d53\u5ea6\u7684\u7eaf\u6c34\u548cGDY-PEG\u6c34\u6eb6\u6db2\u7684\u6e29\u5ea6\u66f2\u7ebf\uff1b<\/p>\n

(g) \u4f7f\u7528808\u6fc0\u5149\u7167\u5c045\u5206\u949f\u7136\u540e\u5173\u95ed\u6fc0\u5149\u6761\u4ef6\u4e0bGDY-PEG\u6c34\u6eb6\u6db2\u7684\u5149\u70ed\u54cd\u5e94\uff1b<\/p>\n

(h) \u65f6\u95f4\u4e0e\u4eceg\u56fe\u4e2d\u7684\u51b7\u5374\u65f6\u95f4\u83b7\u5f97\u7684\u6e29\u5ea6\u9a71\u52a8\u529b\u7684\u8d1f\u81ea\u7136\u5bf9\u6570\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

(i) GDY-PEG\u6c34\u6eb6\u6db2\u5728808 nm\u6fc0\u5149\u7167\u5c045\u6b21ON \/ OFF\u5faa\u73af\u4e0b\u7684\u5149\u70ed\u8f6c\u5316\u5faa\u73af\u8bd5\u9a8c\u3002<\/p>\n

\u56fe11 \u77f3\u58a8\u7094\u5728\u6cb9\u6c34\u5206\u79bb\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

(a) GDYMS\u5236\u5907\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(b) \u6709\u673a\u6eb6\u5242\uff08CHCl3<\/sub>\uff09\u7684\u7eaf\u5316\uff1b<\/p>\n

(c) \u6cb9\uff08\u6c7d\u6cb9\uff09\u7684\u7eaf\u5316\uff1b<\/p>\n

(d) \u4e09\u805a\u6c30\u80fa\u6d77\u7ef5\u7167\u7247\uff1b<\/p>\n

(e) \u8d1f\u8f7d11% GDY\u7684GDYMS\u6837\u54c1\u7684\u7167\u7247\uff1b<\/p>\n

(f) \u8d1f\u8f7d15% GDY\u7684GDYMS\u6837\u54c1\u7684\u7167\u7247\uff1b<\/p>\n

(g) \u8d1f\u8f7d17% GDY\u7684GDYMS\u6837\u54c1\u7684\u7167\u7247\uff1b<\/p>\n

(h) \u8d1f\u8f7d19% GDY\u7684GDYMS\u6837\u54c1\u7684\u7167\u7247\uff1b<\/p>\n

(i) \u8d1f\u8f7d24% GDY\u7684GDYMS\u6837\u54c1\u7684\u7167\u7247\uff1b<\/p>\n

(j) GDYMS-15\u5bf9\u5404\u79cd\u6709\u673a\u6eb6\u5242\u548c\u6cb9\u7684\u5438\u9644\u80fd\u529b\uff1b<\/p>\n

(k) GDYMS-15\u5bf9\u77f3\u6cb9\u919a\u548cCHCl3<\/sub>\u7684\u5438\u9644\u518d\u5faa\u73af\u6027\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4f5c\u8005\u5728\u672c\u7efc\u8ff0\u4e2d\u5168\u9762\u4ecb\u7ecd\u4e86\u77f3\u58a8\u7094\u7684\u57fa\u672c\u6027\u8d28\u53ca\u5176\u7eb3\u7c73\u7ec4\u88c5\u7ed3\u6784\uff0c\u6982\u62ec\u4e86\u77f3\u58a8\u7094\u7684\u5e94\u7528\u548c\u76f8\u5e94\u7684\u673a\u5236\uff0c\u5e76\u5bf9\u5176\u8fdb\u884c\u4e86\u5c55\u671b\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u8fd8\u6307\u51fa\u76ee\u524d\u53ef\u518d\u751f\u548c\u6e05\u6d01\u80fd\u6e90\u5668\u4ef6\u7684\u8bf8\u591a\u74f6\u9888\u95ee\u9898\u90fd\u6709\u671b\u901a\u8fc7\u77f3\u58a8\u7094\u6765\u89e3\u51b3\uff0c\u7136\u800c\u77f3\u58a8\u7094\u7684\u7814\u7a76\u8fd8\u5904\u4e8e\u8d77\u6b65\u9636\u6bb5\uff0c\u6709\u5fc5\u8981\u8fdb\u4e00\u6b65\u5f00\u53d1\u5176\u4ed6\u65b9\u6cd5\u6765\u5236\u5907\u65b0\u578b\u77f3\u58a8\u7094\uff0c\u53d1\u5c55\u53ef\u63a7\u5236\u5907\u6676\u6001\u77f3\u58a8\u7094\u3001\u5355\u5c42\u6216\u51e0\u5c42\u77f3\u58a8\u7094\u7684\u65b0\u65b9\u6cd5\uff0c\u53d1\u5c55\u77f3\u58a8\u7094\u5f02\u539f\u5b50\u7cbe\u51c6\u63ba\u6742\u7684\u6709\u6548\u65b9\u6cd5\uff0c\u540c\u65f6\u5f00\u53d1\u80fd\u591f\u7cbe\u786e\u5feb\u901f\u8fdb\u884c\u77f3\u58a8\u7094\u7ed3\u6784\u8868\u5f81\u65b0\u65b9\u6cd5\uff0c\u8fdb\u800c\u6269\u5927\u5176\u57fa\u7840\u548c\u5e94\u7528\u79d1\u5b66\u7814\u7a76\u7684\u6df1\u5ea6\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aGraphdiyne and its Assembly Architectures: Synthesis, Functionalization, and Applications<\/a>\u00a0(Adv. Mater. 2019, DOI: 10.1002\/adma.201803101)<\/strong><\/p>\n

\u672c\u6587\u7531biotech\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002<\/strong>\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u77f3\u58a8\u7094(Graphdiyne, GDY)\u662f\u4e00\u79cd\u65b0\u578b\u7684\u5355\u539f\u5b50\u5c42\u539a\u5ea6\u7684\u4e8c\u7ef4\u78b3\u6750\u6599\uff0c\u5176\u72ec\u7279\u7684sp\u548csp2\u5171\u6742\u5316\u5e26\u6765\u7684\u4e30\u5bcc\u7684\u78b3\u5316\u5b66\u952e\u3001\u5929\u7136\u5b54\u6d1e\u7ed3\u6784\u4ee5\u53ca\u8868\u9762\u7535\u8377…<\/p>\n","protected":false},"author":7746,"featured_media":177986,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[3265],"class_list":["post-177985","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu","tag-3265"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/177985"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7746"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=177985"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/177985\/revisions"}],"predecessor-version":[{"id":178024,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/177985\/revisions\/178024"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/177986"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=177985"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=177985"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=177985"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}