{"id":178302,"date":"2019-07-08T06:19:24","date_gmt":"2019-07-07T22:19:24","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=178302"},"modified":"2019-07-07T21:19:37","modified_gmt":"2019-07-07T13:19:37","slug":"%e8%87%aa%e6%94%af%e6%92%91%e7%94%b5%e6%9e%81%e5%88%b6%e5%a4%87%e6%8a%80%e6%9c%af%e5%9c%a8%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%9e%81%e4%b8%8a%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=178302","title":{"rendered":"\u81ea\u652f\u6491\u7535\u6781\u5236\u5907\u6280\u672f\u5728\u9502\u79bb\u5b50\u7535\u6781\u4e0a\u7684\u5e94\u7528"},"content":{"rendered":"

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\u56fe7. \u5236\u5907SnS\/C\u7eb3\u7c73\u7ea4\u7ef4\u8584\u819c\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

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Zhou\u7b49\u91c7\u7528\u771f\u7a7a\u8fc7\u6ee4\u548c\u5171\u4ef7\u4ea4\u8054\u6548\u5e94\uff0c\u5236\u5907\u4e86\u8584\u7247\u77f3\u58a8\u70ef\/\u7eb3\u7c73\u7ea4\u7ef4\u7d20\/\u7845\u7684\u4e09\u660e\u6cbb\u8584\u819c\uff08GN\/NC\/Si\uff09\u3002\u5176\u4e2d\uff0cSi\u7eb3\u7c73\u9897\u7c92\u9650\u5236\u5728\u77f3\u58a8\u70ef\u9635\u5217\u4e2d\uff0c\u7eb3\u7c73\u7ea4\u7ef4\u7d20\u4f5c\u4e3a\u7a33\u5b9a\u7684\u5f39\u6027\u4f53\u3002\u7f9f\u57fa\u5316\u548c\u5171\u4ef7\u4ea4\u8054\u6548\u5e94\u4fdd\u8bc1 Si \u7eb3\u7c73\u9897\u7c92\u7684\u826f\u597d\u5206\u6563\uff0c\u63d2\u5165\u7684 Si \u7eb3\u7c73\u9897\u7c92\u4f5c\u53ef\u9694\u79bb\u77f3\u58a8\u70ef\u7247\u5c42\uff0c\u9632\u6b62\u77f3\u58a8\u70ef\u7247\u5806\u79ef\u3002\u4ee5100mA\/g\u5145\u653e100\u6b21\uff0cGN\/NC\/Si\u8584\u819c\u7684\u53ef\u9006\u5bb9\u91cf\u4ecd\u9ad8\u8fbe1251 mAh\/g\u3002\u5e94\u529b-\u5e94\u53d8\u6d4b\u8bd5\u8868\u660e\u8be5\u8584\u819c\u5177\u6709\u5f3a\u7684\u673a\u68b0\u5f3a\u5ea6\uff0c\u5177\u6709\u5f88\u597d\u7684\u67d4\u97e7\u6027\uff0c\u80fd\u7f13\u51b2Si\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u53d8\u5316\u6548\u5e94\u3002\u4e0e\u94b4\u9178\u9502\u5339\u914d\u7ec4\u88c5\u6210\u5168\u7535\u6c60\uff0c\u80fd\u70b9\u4eae\u53d1\u5149\u4e8c\u7ea7\u7ba1\u3002\u76f8\u5173\u6587\u7ae0\u53d1\u8868\u5728ACS Appl. Mater. Interfaces\u4e0a\u3002<\/p>\n

\u56fe8. \u5236\u5907GN\/NC\/Si\u8584\u819c\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

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\u56fe9. \u5236\u5907\u4e0d\u540c\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u7247\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

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Wang\u7b49\u91c7\u7528\u6eb6\u5242\u70ed\u6cd5\u7ed3\u5408\u51b7\u51bb\u5e72\u71e5\u548c\u540e\u7145\u70e7\u5904\u7406\uff0c\u5236\u5907\u4e86\u542bWS2<\/sub>\u7eb3\u7c73\u7247\u548c\u78b3\u7eb3\u7c73\u7ba1-\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\uff08CNT-rGO\uff09\u7684\u6df7\u5408\u7eb3\u7c73\u7ed3\u6784\u6eb6\u80f6\uff08WS2<\/sub>\/CNT-rGO\uff09\uff0c\u8be5\u6eb6\u80f6\u5177\u6709\u6709\u5e8f\u7684\u5fae\u901a\u9053\u4e09\u7ef4\u9aa8\u67b6\u7ed3\u6784\uff0c\u80fd\u63d0\u4f9b\u826f\u597d\u7684\u7535\u5b50\u4f20\u8f93\u8def\u5f84\uff0c\u63d0\u4f9b\u4f18\u79c0\u7684\u5bfc\u79bb\u5b50\u901a\u9053\u3002WS2<\/sub>\/CNT-rGO\u6eb6\u80f6\u7eb3\u7c73\u7ed3\u6784\u7684\u53ef\u9006\u5bb9\u91cf\u4e3a749mAh\/g\u3002\u76f8\u5173\u6587\u7ae0\u53d1\u8868\u5728Adv. Energy Mater.\u4e0a\u3002<\/p>\n

\u56fe10. \u5236\u5907WS2<\/sub>\/CNT-rGO\u6eb6\u80f6\u7eb3\u7c73\u7ed3\u6784\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

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Yan\u7b49\u5236\u5907\u4e86\u4e00\u79cd\u7531CNTs\u548c\u4e09\u7ef4\u77f3\u58a8\u6ce1\u6cab\u7ec4\u6210\u7684\u4e09\u7ef4\u8d85\u7ed3\u6784\u3002\u9996\u5148\u57fa\u4e8e\u4e09\u7ef4\u6ce1\u6cab\u954d\uff0c\u4ee5\u4e59\u70ef\u4f5c\u4e3a\u78b3\u6e90\uff0c\u751f\u957f\u77f3\u58a8\u3002\u7136\u540e\u7528HCl\u6eb6\u89e3Ni\uff0c\u5f97\u5230\u77f3\u58a8\u6ce1\u6cab\u3002\u63a5\u7740\u901a\u8fc7\u7535\u5b50\u675f\u84b8\u53d1\uff0c\u5728\u77f3\u58a8\u6ce1\u9762\u4e0a\u6c89\u79efNi\u50ac\u5316\u5242\u8584\u819c\u3002\u901a\u8fc7\u7145\u70e7\u5f62\u6210Ni\u7eb3\u7c73\u5c9b\uff0c\u4f5c\u4e3a\u79bb\u6563\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\uff0c\u786e\u4fddCNTs\u826f\u597d\u5206\u6563\u3002\u8fd9\u79cdCNT-\u77f3\u58a8\u4e09\u7ef4\u6df7\u5408\u7ed3\u6784\uff0c\u7ecf\u8fc7120\u6b21\u5faa\u73af\u540e\uff0c\u5bb9\u91cf\u5927\u4e8e800mAh\/g\u3002\u76f8\u5173\u6587\u7ae0\u53d1\u8868\u5728Carbon\u4e0a\u3002<\/p>\n

\u56fe11. \u5236\u5907CNT-\u77f3\u58a8\u4e09\u7ef4\u6df7\u5408\u7ed3\u6784\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

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2.\u5e72\u6cd5\u5236\u5907\u81ea\u652f\u6491\u7535\u6781<\/strong><\/p>\n

Krisch\u7b49\u91c7\u7528\u4e00\u79cd\u53ef\u89c4\u6a21\u5316\u3001\u73af\u5883\u53cb\u597d\u7684\u5e72\u6cd5\u52a0\u5de5\u65b9\u6cd5\uff0c\u5373\u5e72\u538b\uff0c\u5236\u5907\u5f97\u5230\u6b63\u6781\u3002\u7eb3\u7c73\u5b54\u78b3\u540c\u7d20\u5f02\u5f62\u4f53(\u5373,\u591a\u6d1e\u7684\u77f3\u58a8\u70ef\u6216hG)\u4f5c\u4e3a\u53ef\u538b\u7f29\u5bfc\u7535\u57fa\u4f53\u6765\u5bb9\u7eb3\u4e0d\u53ef\u538b\u7f29\u9634\u6781\u548c\u9633\u6781\u7535\u6c60\u7c89\u672b\u3002\u56fa\u6709\u7684\u7eb3\u7c73\u5b54\u9699\u6709\u52a9\u4e8e\u6c14\u4f53\u5728\u538b\u7f29\u65f6\u9038\u51fa\uff0c\u6210\u529f\u5730\u5f62\u6210\u65e0\u7c98\u7ed3\u5242\u548c\u65e0\u6eb6\u5242\u7684\u590d\u5408\u7535\u6781\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u5c06\u7535\u6781\u6d3b\u6027\u7269\u8d28\u3001\u591a\u6d1e\u77f3\u58a8\u70ef\u7f6e\u4e8e\u65cb\u6da1\u6df7\u5408\u5668\u4e2d\u6df7\u5408\u5747\u5300\uff0c\u5f97\u5230\u7684\u7c89\u672b\u7f6e\u4e8e\u4e24\u7247Al\u7b94\u4e4b\u95f4\uff0c\u653e\u523015mm\u7684\u4e0d\u9508\u94a2\u94a2\u6a21\u4e2d\uff0c\u4f7f\u7528\u5361\u5f17\u6c34\u538b\u673a\uff0c\u7ec4\u88c5\u597d\u7684\u94a2\u6a21\u5728\u6307\u5b9a\u7684\u538b\u529b\u4e0b\u6324\u538b10min\u3002\u64a4\u6389\u6db2\u538b\uff0c\u5c06Al\u7b94\u53bb\u9664\uff0c\u5f97\u5230\u590d\u5408\u7535\u6781\u3002\u4f5c\u8005\u8fd8\u8003\u5bdf\u4e86\u4e0d\u540c\u7684\u6db2\u538b\u538b\u529b\u548c\u6db2\u538b\u65f6\u95f4\u5bf9\u7535\u6c60\u6027\u80fd\u548c\u7ed3\u6784\u7684\u5f71\u54cd\u3002\u7ed3\u679c\u663e\u793a\uff0c\u5728500MPa\u7684\u6db2\u538b\u538b\u529b\u4e0b\u4fdd\u630110min\u300120MPa\u538b\u529b\u4e0b\u4fdd\u630110min\u548c20Mpa\u4e0b\u4fdd\u63011s\uff0c\u4e09\u79cd\u60c5\u51b5\u5f97\u5230\u7684\u7535\u6781\u6ca1\u6709\u660e\u663e\u7684\u8d28\u91cf\u635f\u5931\u3002\u5f2f\u66f2\u8bd5\u9a8c\u6d4b\u8bd5\u8868\u660e\u5b83\u4eec\u5177\u6709\u76f8\u540c\u7684\u8106\u6027\u65ad\u88c2\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u63d0\u4f9b\u4e86\u6784\u601d\u7248\u7684\u5e72\u538b\u5de5\u827a\uff0c\u5373\u6240\u8c13\u5e72\u6eda\u5bf9\u6eda\u5de5\u827a\u3002\u4e0e\u4f20\u7edf\u7684\u6eda\u5bf9\u6eda\u5de5\u827a\u7c7b\u4f3c\uff0c\u6eda\u8f6e\u53ef\u5bf9\u94fa\u5728\u96c6\u6d41\u4f53\u4e0a\u7684\u521d\u59cb\u677e\u6563\u7684\u7c89\u672b\u65bd\u52a0\u6db2\u538b\uff0c\u5f62\u6210\u673a\u68b0\u7a33\u56fa\u7684\u7535\u6781\u3002\u65bd\u52a0\u7684\u538b\u529b\u6301\u7eed\u65f6\u95f4\u53ef\u77ed\u81f3\u6570\u79d2\uff0c\u6781\u5927\u63d0\u9ad8\u751f\u4ea7\u6548\u7387\u3002\u5e72\u538b\u4e4b\u540e\uff0chG\uff1a\u6d3b\u6027\u7535\u6c60\u7c89\u672b\u7247\u53ef\u4ee5\u76f4\u63a5\u4f5c\u4e3a\u81ea\u652f\u6491\u7684\u7535\u6781\u3002<\/p>\n

\u56fe12. \u5e72\u538b\u5de5\u827a\u5236\u5907\u9502\u79bb\u5b50\u7535\u6781\u3002<\/p>\n

\"\"<\/p>\n

\u56fe13. \u6784\u601d\u7248\u7684\u6eda\u5bf9\u6eda\u5e72\u538b\u5de5\u827a\u5236\u5907\u9502\u79bb\u5b50\u7535\u6781\u3002<\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

1.Flexible free-standing carbon nanotube films for model lithium-ion batteries\uff1bdoi:10.1016\/j.carbon.2009.06.045.<\/p>\n

2.Hierarchical CuOx\u2013Co3<\/sub>O4<\/sub> heterostructure\u00a0nanowires decorated on 3D porous nitrogen-doped carbon nanofibers as flexible and free-standing anodes for high-performance lithium-ion batteries; DOI: 10.1039\/c9ta00275h.<\/p>\n

3.Hierarchical bilayered hybrid nanostructural arrays of NiCo2<\/sub>O4<\/sub> micro-urchins and nanowires as a freestanding electrode with high loading for high-performance lithium-ion batteries; DOI: 10.1039\/c7nr03979d.<\/p>\n

4.Free-Standing SnS\/C Nanofiber Anodes for Ultralong Cycle-life Lithium-ion\u00a0Batteries and Sodium-ion Batteries, Energy Storage Materials; DOI: 10.1016\/j.ensm.2018.08.005.<\/p>\n

5.Free-Standing Sandwich-Type Graphene\/Nanocellulose\/Silicon\u00a0Laminar Anode for Flexible Rechargeable Lithium Ion Batteries; DOI: 10.1021\/acsami.8b10066.<\/p>\n

6.Rapid and Up-Scalable Fabrication of Free-Standing\u00a0Metal Oxide Nanosheets for High-Performance Lithium\u00a0Storage; DOI: 10.1002\/smll.201402502.<\/p>\n

7.Ice Templated Free-Standing Hierarchically WS2<\/sub>\/CNT-rGO Aerogel for High-Performance Rechargeable Lithium and Sodium Ion Batteries; DOI: 10.1002\/aenm.201601057.<\/p>\n

8.Bundled and dispersed carbon nanotube assemblies on graphite\u00a0superstructures as free-standing lithium-ion battery anodes; DOI: 10.1016\/j.carbon.2018.10.044.<\/p>\n

9.Scalable Dry Processing of Binder-Free Lithium-Ion Battery Electrodes Enabled by Holey Graphene; DOI: 10.1021\/acsaem.9b00066.<\/p>\n

\u672c\u6587\u7cfb\u00a0LiBOB\u00a0<\/b><\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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