{"id":178965,"date":"2019-06-30T06:30:00","date_gmt":"2019-06-29T22:30:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=178965"},"modified":"2019-06-29T21:34:59","modified_gmt":"2019-06-29T13:34:59","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91adv-energy-mater-%e7%94%a8%e4%ba%8e%e9%ab%98%e6%95%88%e6%b0%a7%e8%bf%98%e5%8e%9f%e5%82%ac%e5%8c%96%e7%9a%84%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e4%bf%ae","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=178965","title":{"rendered":"Adv. Energy Mater.: \u7528\u4e8e\u9ad8\u6548\u6c27\u8fd8\u539f\u50ac\u5316\u7684\u8fc7\u6e21\u91d1\u5c5e\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u50ac\u5316\u5242"},"content":{"rendered":"<p><strong>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>\u5316\u77f3\u71c3\u6599\u5728\u5de5\u4e1a\u548c\u65e5\u5e38\u751f\u6d3b\u4e2d\u7684\u6d88\u8017\u9020\u6210\u4e86\u4e25\u91cd\u7684\u80fd\u6e90\u548c\u73af\u5883\u95ee\u9898\uff0c\u8feb\u4f7f\u4eba\u7c7b\u793e\u4f1a\u5bfb\u627e\u66f4\u9ad8\u6548\u3001\u66f4\u6e05\u6d01\u7684\u80fd\u6e90\u4f9b\u5e94\u3002\u71c3\u6599\u7535\u6c60\u4ee5\u5176\u9ad8\u6548\u3001\u73af\u4fdd\u3001\u9ad8\u53ef\u9760\u6027\u7b49\u4f18\u70b9\u800c\u6210\u4e3a\u6700\u6709\u53d1\u5c55\u524d\u9014\u7684\u80fd\u6e90\u5668\u4ef6\u4e4b\u4e00\uff0c\u5176\u4e2d\u4f4e\u6e29\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\uff08PEMFCs\uff09\u662f\u76ee\u524d\u7814\u7a76\u6700\u591a\u3001\u53d1\u5c55\u6700\u8fc5\u901f\u7684\u4e00\u7c7b\u71c3\u6599\u7535\u6c60\u3002\u7136\u800c\uff0cPEMFCs\u7684\u5546\u4e1a\u5316\u4e00\u76f4\u53d7\u5230\u9634\u6781\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u50ac\u5316\u5242\u7684\u9650\u5236\u3002\u76ee\u524d\uff0c\u6700\u5148\u8fdb\u7684\u94c2\u57faORR\u50ac\u5316\u5242\u4ecd\u5b58\u5728\u6210\u672c\u9ad8\uff08\u71c3\u6599\u7535\u6c60\u6210\u672c\u768420%\uff09\u3001Pt\u7684\u4e25\u91cd\u7a00\u7f3a\u6027\u548c\u8010\u4e45\u6027\u5dee\u7b49\u7f3a\u70b9\u3002\u56e0\u6b64\uff0c\u5f00\u53d1Pt\u50ac\u5316\u5242\u7684\u66ff\u4ee3\u54c1\u662f\u71c3\u6599\u7535\u6c60\u5546\u4e1a\u5316\u63a8\u5e7f\u6240\u9762\u4e34\u7684\u5173\u952e\u95ee\u9898\u4e4b\u4e00\u3002\u8fd1\u5e74\u6765\uff0c\u8d1f\u8f7d\u8fc7\u6e21\u91d1\u5c5e\uff08TM\uff09\u7684\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u7531\u4e8e\u5176\u6709\u8da3\u7684\u7ed3\u6784\u53ca\u4f18\u5f02\u7684\u6027\u80fd\u800c\u53d7\u5230\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u5305\u62ec\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u3001\u591a\u76f8\u50ac\u5316\u3001\u4f20\u611f\u5668\u7b49\u3002\u5728ORR\u50ac\u5316\u5242\u9886\u57df\uff0cTM\u4fee\u9970\u7684\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u5177\u6709\u9ad8\u7684\u50ac\u5316\u6027\u80fd\u548c\u957f\u671f\u7a33\u5b9a\u6027\uff0c\u4e5f\u662f\u76ee\u524d\u7814\u7a76\u7684\u70ed\u70b9\u4e4b\u4e00\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u6700\u8fd1\uff0c<strong>Adv. Energy Mater.<\/strong>\u5728\u7ebf\u520a\u767b\u4e86<strong>\u5317\u4eac\u5927\u5b66\u4faf\u4ef0\u9f99\u6559\u6388<\/strong>\u3001<strong>\u91cd\u5e86\u5de5\u5546\u5927\u5b66\u53e4\u5174\u5174\u526f\u7814\u7a76\u5458<\/strong>\u7b49\u4eba\u603b\u7ed3\u7684\u7528\u4e8e\u9ad8\u6548\u6c27\u8fd8\u539f\u50ac\u5316\u7684\u8fc7\u6e21\u91d1\u5c5e\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u7efc\u8ff0\u3002\u9898\u76ee\u662f\u201c<strong>Efficient Oxygen Reduction Catalysts of Porous Carbon Nanostructures Decorated with Transition Metal Species<\/strong>\u201d\u3002\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u4f5c\u8005\u4ecb\u7ecd\u4e86\u8fd1\u5e74\u6765\u8fc7\u6e21\u91d1\u5c5e\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u540c\u65f6\u8fd8\u8be6\u7ec6\u4ecb\u7ecd\u4e86\u51e0\u79cd\u5236\u5907\u65b9\u6cd5\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u5bf9ORR\u50ac\u5316\u5242\u7684\u6027\u80fd\u548c\u6d3b\u6027\u90e8\u4f4d\u7684\u7814\u7a76\u8fdb\u884c\u4e86\u63a2\u8ba8\u3002\u6700\u540e\uff0c\u4f5c\u8005\u8fdb\u4e00\u6b65\u5bf9ORR\u50ac\u5316\u5242\u6240\u9762\u4e34\u7684\u6311\u6218\u548c\u524d\u666f\u8fdb\u884c\u4e86\u5c55\u671b\uff0c\u4e3a\u4eca\u540eORR\u50ac\u5316\u5242\u7684\u53d1\u5c55\u63d0\u51fa\u4e86\u81ea\u5df1\u7684\u89c1\u89e3\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n<p><strong>1\u3001\u5f15\u8a00<\/strong><\/p>\n<p><strong>2\u3001TM\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u7684\u5236\u5907\u7b56\u7565<\/strong><\/p>\n<p><strong>2.1\u3001TM\u7eb3\u7c73\u7c92\u5b50\u4fee\u9970\u7684\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><strong>2.1.1\u3001\u6a21\u677f\u6cd5<\/strong><\/p>\n<p><strong>\u56fe\u4e00\u3001\u6a21\u677f\u6cd5\u5236\u5907TM\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u4e3e\u4f8b<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-178966\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/1-26.jpg\" alt=\"\" width=\"600\" height=\"694\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/1-26.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/1-26-259x300.jpg 259w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09\u5236\u5907Co<sub>3<\/sub>O<sub>4<\/sub> IO\u548cC-Co<sub>3<\/sub>O<sub>4<\/sub> IO\u7eb3\u7c73\u7ed3\u6784\u7684\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b\uff09MnCo<sub>2<\/sub>O<sub>4<\/sub>\/3D-G\u50ac\u5316\u5242\u7684\u5408\u6210\u8def\u7ebf\uff1b<\/p>\n<p>\uff08c\uff09\u4e2d\u7a7a\u50ac\u5316\u5242\u5236\u5907\u65b9\u6cd5\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>2.1.2\u3001\u81ea\u6a21\u677f\u6cd5<\/strong><\/p>\n<p><strong>\u56fe\u4e8c\u3001\u81ea\u6a21\u677f\u6cd5\u5236\u5907TM\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u4e3e\u4f8b<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-178967\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/2-25.jpg\" alt=\"\" width=\"600\" height=\"809\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/2-25.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/2-25-222x300.jpg 222w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09\u4e00\u7cfb\u5217\u57fa\u4e8eCo-Co<sub>3<\/sub>O<sub>4<\/sub>\u7eb3\u7c73\u7ed3\u6784\u7684\u7a7a\u5fc3\u6c2e\u63ba\u6742\u78b3\u591a\u9762\u4f53\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b\uff09Co\/HNCP\u7684SEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08c\uff09Co\/HNCP\u7684TEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08d\uff09Co\/HNCP\u7684STEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08e\uff09Co,N-HCNP\u7535\u50ac\u5316\u5242\u7684\u5408\u6210\u65b9\u6848\uff1b<\/p>\n<p>\uff08f\uff09N-CNP\uff0cCO,N-CNP\u548cCO,N-HCNP\u7684\u6c2e\u5438\u9644-\u89e3\u5438\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08g\uff09N-CNP\uff0cCO,N-CNP\u548cCO,N-HCNP\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\uff08LSV\uff09\u66f2\u7ebf\u3002<\/p>\n<p><strong>2.1.3\u3001\u6df7\u5408\u6cd5<\/strong><\/p>\n<p><strong>\u56fe\u4e09\u3001\u6df7\u5408\u6cd5\u5236\u5907TM\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u4e3e\u4f8b<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-178969\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/3-28.jpg\" alt=\"\" width=\"600\" height=\"238\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/3-28.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/3-28-300x119.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09FexN\/NGA\u5236\u5907\u7a0b\u5e8f\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b\uff09FexN\/NGA\u7684SEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08c\uff09FexN\/NGA\u7684SEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08d\uff09FexN\/NGA\u7684TEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08e\uff09FexN\/NGA\u6df7\u5408\u7269\uff0cFexN + NGA\u6df7\u5408\u7269\uff0cNGA\uff0c\u6e38\u79bbFexN\u548cPt\/C\u7684LSV\u66f2\u7ebf\u3002<\/p>\n<p><strong>2.1.4\u3001\u591a\u6b65\u9aa4\u6cd5<\/strong><\/p>\n<p><strong>2.2\u3001\u539f\u5b50\u5206\u6563TM\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><strong>2.2.1\u3001\u6d78\u6e0d\u6cd5<\/strong><\/p>\n<p><strong>\u56fe\u56db\u3001\u6d78\u6e0d\u6cd5\u5236\u5907\u539f\u5b50\u5206\u6563TM\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u4e3e\u4f8b<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-178972\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/4-26.jpg\" alt=\"\" width=\"600\" height=\"680\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/4-26.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/4-26-265x300.jpg 265w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09\u591a\u5b54M-N-C\uff08M = Co\u548cFe\uff09\u7535\u50ac\u5316\u5242\u7684\u6784\u5efa\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b\uff09Fe-NC-900\u6269\u5927\u7684HAADF-STEM\u56fe\uff1b<\/p>\n<p>\uff08c\uff09Fe-NC-900\u7684HAADF-STEM\u56fe\u548cC\uff0cN\u548cFe\u539f\u5b50\u7684\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n<p>\uff08d\uff09Fe-N-C-900\u548c\u5176\u4ed6\u5bf9\u5e94\u7269\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08e\uff09Fe-ISAs\/CN\u7684\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08f\uff09Fe-ISAs\/CN\u7684HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08g\uff09Fe-ISAs\/CN\u7684\u653e\u5927\u56fe\uff1b<\/p>\n<p>\uff08h\uff09Fe-ISAs\/CN\u548c\u5176\u4ed6\u5bf9\u5e94\u7269\u7684LSV\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe\u4e94\u3001\u6d78\u6e0d\u6cd5\u5236\u5907\u539f\u5b50\u5206\u6563TM\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u4e3e\u4f8b<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-178973\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/4-27.jpg\" alt=\"\" width=\"600\" height=\"680\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/4-27.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/4-27-265x300.jpg 265w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-178974\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/5-21.jpg\" alt=\"\" width=\"600\" height=\"535\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/5-21.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/5-21-300x268.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09ZnNx\/BP\u50ac\u5316\u5242\u7684\u9ad8\u5206\u8fa8\u7387\uff08HRTEM\uff09\u56fe\uff1b<\/p>\n<p>\uff08b\uff09ZnNx\/BP\u50ac\u5316\u5242\u7684HAADF-STEM\u56fe\uff1b<\/p>\n<p>\uff08c\uff09ZnNx\/BP\u548c\u5176\u4ed6\u5bf9\u5e94\u7269\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08d\uff09(Fe,Co)\/N-C\u7684\u5f62\u6210\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08e\uff09(Fe,Co)\/N-C\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08f\uff09(Fe,Co)\/N-C\u7684\u653e\u5927HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08g\uff09(Fe,Co)\/N-C\u548c\u5176\u4ed6\u5bf9\u5e94\u7269\u5728\u9971\u548cO2\u548c0.1 M HClO<sub>4<\/sub>\u4e2d\u7684LSV\u66f2\u7ebf\u3002<\/p>\n<p><strong>2.2.2\u3001\u9178\u6d78\u6cd5<\/strong><\/p>\n<p><strong>\u56fe\u516d\u3001\u9178\u6d78\u6cd5\u5236\u5907\u539f\u5b50\u5206\u6563TM\u4fee\u9970\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u4e3e\u4f8b<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-178975\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/6-10.jpg\" alt=\"\" width=\"600\" height=\"984\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/6-10.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/6-10-183x300.jpg 183w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09Mn\/C-NO\u7684\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b\uff09Mn\/C-NO\u7684HRTEM\u56fe\uff1b<\/p>\n<p>\uff08c\uff09Mn\/C-NO\u50cf\u5dee\u6821\u6b63\u7684HAADF-STEM\u56fe\uff1b<\/p>\n<p>\uff08d\uff09Mn\/C-NO\u548c\u5176\u4ed6\u5bf9\u5e94\u7269\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08e\uff09Fe-N-SCCFs\u7684\u5f62\u6210\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08f\uff09Fe-N-SCCFs\u7684TEM\u56fe\uff1b<\/p>\n<p>\uff08g\uff09Fe-N-SCCFs\u7684HAADF-STEM\u56fe\uff1b<\/p>\n<p>\uff08h\uff09Fe-N-SCCFs\u548c\u5176\u4ed6\u5bf9\u5e94\u7269\u7684RRDE\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n<p><strong>2.2.3\u3001\u5176\u4ed6\u65b9\u6cd5<\/strong><\/p>\n<p><strong>3\u3001ORR\u6027\u80fd\u548c\u6d3b\u6027\u4f4d\u70b9\u7814\u7a76<\/strong><\/p>\n<p><strong>3.1\u3001\u6742\u539f\u5b50\u63ba\u6742\u5242<\/strong><\/p>\n<p><strong>3.2\u3001\u57fa\u4e8eM\/N-C\u7684\u50ac\u5316\u5242<\/strong><\/p>\n<p><strong>\u56fe\u4e03\u3001\u63ba\u6742\u539f\u5b50\u4f5c\u4e3a\u6d3b\u6027\u4f4d\u70b9\u7814\u7a76<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-178976\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/7-6.jpg\" alt=\"\" width=\"600\" height=\"479\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/7-6.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/7-6-300x240.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09CoNC700\u3001CoPC\u3001CoTMPP\u548cCo\u7b94\u7684Co K\u8fb9XANES\uff1b<\/p>\n<p>\uff08b~c\uff09\u542b\u6709\u6216\u4e0d\u542b5\u00d710<sup>\u22123<\/sup> M NaSCN\u7684CoNC700\u5728\uff08b\uff09\u9178\u6027\u548c\uff08c\uff09\u78b1\u6027\u6eb6\u6db2\u4e2d\u7684\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08d\uff09M\/N-CNSNs \u7684\u5236\u5907\u793a\u610f\u56fe\uff08M =Co, Ni\uff09\uff1b<\/p>\n<p>\uff08e\uff09Co\/N-CNSNs\uff0cNi\/N-CNSNs\uff0cCo\/N-CNFs\uff0c\u548cPt\/C\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08f\uff09CO\/N-CNSNs\u3001CO\uff08\u84dd\u8272\uff09\u3001C\uff08\u7070\u8272\uff09\u548cN\uff08\u9ec4\u8272\uff09\u7684DFT\u6a21\u62df\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08g\uff09\u5404C\u70b9\u53cd\u5e94\u5750\u6807\u7684\u0394G\u3002<\/p>\n<p><strong>3.3\u3001\u5176\u4ed6\u6d3b\u6027\u4f4d\u70b9<\/strong><\/p>\n<p><strong>\u56fe\u516b\u3001\u5176\u4ed6\u6d3b\u6027\u4f4d\u70b9\u7684\u7814\u7a76<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-178977\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/8-5.jpg\" alt=\"\" width=\"600\" height=\"372\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/8-5.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/06\/8-5-300x186.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\uff08a\uff09CeO<sub>2<\/sub>-Co-NC\u548cCeO<sub>2<\/sub>-NC\u7a7a\u5fc3\u7403\u7684\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b~c\uff09\u4e00\u4e2a\u6c27\u539f\u5b50\u5728\uff08b\uff09\u4e00\u4e2aCeO<sub>2<\/sub>(111)\u8868\u9762\u548c\uff08c\uff09\u4e00\u4e2aCeO<sub>2<\/sub>(111)\/Co(111)\u8868\u9762\u7684\u5316\u5b66\u5438\u9644\u6a21\u578b\u7684\u539f\u5b50\u754c\u9762\u7535\u5b50\u7ed3\u6784\u8ba1\u7b97\uff1b<\/p>\n<p>\uff08d\uff09CeO<sub>2<\/sub>(111)\/Co(111)\u5c40\u90e8\u7535\u8377\u5bc6\u5ea6\u7b49\u503c\u9762\uff1b<\/p>\n<p>\uff08e\uff09CeO<sub>2<\/sub>(111)\uff08\u4e0a\uff09\u548cCeO<sub>2<\/sub>(111)\/Co(111)\u7684\u603b\u6001\u5bc6\u5ea6\u66f2\u7ebf\uff08\u4e0b\uff09\uff1b<\/p>\n<p>\uff08f\uff09\u63d0\u51fa\u7684\u9499\u949b\u77ff\u6c27\u5316\u7269\u50ac\u5316\u5242\u7684ORR\u673a\u7406\uff1b<\/p>\n<p>\uff08g\uff09e<sub>g<\/sub>\u7535\u5b50\u70b9\u7684\u5f62\u72b6\u76f4\u63a5\u6307\u5411O\u539f\u5b50\u8868\u9762\uff1b<\/p>\n<p>\uff08h\uff09\u5404\u79cdMnCo<sub>2<\/sub>O<sub>4<\/sub>\u6c27\u5316\u7269\u7684ORR\u6d3b\u6027\u968fMn\u4ef7\u6001\u7684\u53d8\u5316\u51fd\u6570\uff1b<\/p>\n<p>\uff08i\uff09ORR\u6d3b\u6027\u968f\u6d3b\u6027\u5143\u7d20e<sub>g<\/sub>\u5360\u636e\u5728\u516b\u9762\u4f53\u4f4d\u70b9\u7684\u53d8\u5316\u51fd\u6570\u3002<\/p>\n<p><strong>4\u3001\u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u8ba4\u4e3a\u91c7\u7528\u6a21\u677f\u6cd5\u3001\u81ea\u6a21\u677f\u6cd5\u3001\u6e7f\u5316\u5b66\u6cd5\u7b49\u65b9\u6cd5\u6240\u5236\u5907\u7684TM\u4fee\u9970\u7684\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u88ab\u8ba4\u4e3a\u662f\u9ad8\u6548ORR\u7535\u50ac\u5316\u5242\u4e4b\u4e00\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u8fdb\u4e00\u6b65\u603b\u7ed3\u4e86\u5236\u5907\u7eb3\u7c73\u7ed3\u6784\u5177\u6709\u9ad8\u6d3b\u6027\u50ac\u5316\u6027\u80fd\u7684\u6307\u5bfc\u539f\u5219\uff1a1\uff09\u63d0\u9ad8\u7eb3\u7c73\u50ac\u5316\u5242\u6bd4\u8868\u9762\u79ef\uff1b2\uff09\u83b7\u5f97\u66f4\u4e30\u5bcc\u7684\u4ecb\u5b54\u7ed3\u6784\uff1b3\uff09\u63d0\u9ad8\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u7684\u77f3\u58a8\u5316\u7a0b\u5ea6\uff1b4\uff09\u63ba\u6742\u6742\u539f\u5b50\uff1b5\uff09\u5404\u7ec4\u5206\u539f\u5b50\u4ee5\u5355\u539f\u5b50\u5f62\u5f0f\u5206\u5e03\u5747\u5300\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u6307\u51fa\uff0c\u867d\u7136\u6700\u8fd1\u7684\u7814\u7a76\u8868\u660eORR\u7684\u50ac\u5316\u6027\u80fd\u662f\u4ee4\u4eba\u6ee1\u610f\u7684\u3002\u7136\u800c\uff0c\u5728\u8fdb\u4e00\u6b65\u63a2\u7d22ORR\u50ac\u5316\u5242\u65b9\u9762\u4ecd\u5b58\u5728\u4e00\u4e9b\u95ee\u9898\uff1a1\uff09TM\u57fa\u50ac\u5316\u5242\u7684\u957f\u671f\u7a33\u5b9a\u6027\u6709\u5f85\u8fdb\u4e00\u6b65\u63d0\u9ad8\uff1b2\uff09\u78b3\u57fa\u50ac\u5316\u5242\u7684\u6d3b\u6027\u8d28\u91cf\u6bd4\u4e0d\u591f\u9ad8\uff1b3\uff09\u5bf9\u65e0\u70ed\u89e3\u7684ORR\u50ac\u5316\u5242\u7684\u7814\u7a76\u8fd8\u9700\u8981\u8fdb\u4e00\u6b65\u7684\u63a2\u7d22\uff1b4\uff09\u5bf9ORR\u7684\u53cd\u5e94\u8fc7\u7a0b\u9700\u8981\u66f4\u6df1\u5165\u7684\u4e86\u89e3\uff0c\u5305\u62ec\u53cd\u5e94\u9014\u5f84\u3001\u6d3b\u6027\u4f4d\u70b9\u7684\u8bc6\u522b\u3001\u754c\u9762\u884c\u4e3a\u7b49\uff1b5\uff09\u5efa\u7acb\u6807\u51c6\u7684\u819c\u7535\u6781\u7ec4\u88c5\uff08MEA\uff09\u6d4b\u8bd5\u6761\u4ef6\u548c\u65b9\u6cd5\uff0c\u63d0\u9ad8MEA\u7684\u6d4b\u8bd5\u6027\u80fd\u3002\u4f5c\u8005\u8ba4\u4e3a\uff0c\u7814\u7a76\u9ad8\u6548\u3001\u7a33\u5b9a\u7684ORR\u50ac\u5316\u5242\u5bf9ORR\u7535\u50ac\u5316\u5242\u5728\u80fd\u6e90\u548c\u6750\u6599\u9886\u57df\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u3002\u6700\u540e\uff0c\u4f5c\u8005\u671f\u671b\u8fd9\u4e9b\u5408\u7406\u7684\u8bbe\u8ba1\u7b56\u7565\u548c\u6d3b\u6027\u4f4d\u70b9\u7684\u7814\u7a76\u603b\u7ed3\u5c06\u6709\u52a9\u4e8eORR\u7535\u50ac\u5316\u5242\u7684\u5f00\u53d1\uff0c\u5e76\u5728\u5b66\u672f\u7814\u7a76\u548c\u5de5\u4e1a\u5e94\u7528\u4e2d\u6fc0\u53d1\u51fa\u66f4\u591a\u7684\u521b\u65b0\u8fdb\u5c55\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/aenm.201900375\" target=\"_blank\" rel=\"noopener\">Efficient Oxygen Reduction Catalysts of Porous Carbon Nanostructures Decorated with Transition Metal Species<\/a>\uff08<em>Adv. Energy Mater.<\/em> <strong>2019,<\/strong> 9, 1900375\uff09<\/p>\n<p>\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/p>\n<p><strong>\u4faf\u4ef0\u9f99\u6559\u6388<\/strong>\u56e2\u961f\u957f\u671f\u4ece\u4e8b\u80fd\u6e90\u50a8\u5b58\u4e0e\u8f6c\u5316\u548c\u80fd\u6e90\u6750\u6599\u7b49\u9886\u57df\u7684\u7814\u7a76\u5de5\u4f5c\uff0c\u5bf9\u71c3\u6599\u7535\u6c60\u7535\u50ac\u5316\u5242\u548c\u65e0\u673a\u529f\u80fd\u6750\u6599\u7684\u6700\u65b0\u8fdb\u5c55\u6709\u7740\u7cfb\u7edf\u6df1\u5165\u7684\u4e86\u89e3\u3002\u5728\u7eb3\u7c73\u6750\u6599\u7684\u63a7\u5236\u5236\u5907\u3001\u7ed3\u6784\u8868\u5f81\u3001\u751f\u957f\u673a\u5236\u53ca\u5176\u50ac\u5316\u6027\u80fd\u7814\u7a76\u65b9\u9762\u79ef\u7d2f\u4e86\u4e30\u5bcc\u7684\u7ecf\u9a8c\u3002\u5728 <em>Angew. Chem. Int. Ed.<\/em>, <em>J. Am. Chem. Soc.<\/em>, <em>Adv. Mater.<\/em>, <em>Chem.Soc. Rev.<\/em> \u7b49\u671f\u520a\u5df2\u53d1\u8868\u8bba\u6587 140 \u4f59\u7bc7\uff0c\u6388\u6743\u4e13\u5229 9 \u9879\u3002<\/p>\n<p><strong>\u3010\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\u3011<\/strong><\/p>\n<p>\u56e2\u961f\u5728\u591a\u5b54\u78b3\u57fa\u5e95\u6750\u6599\u8d1f\u8f7d\u8fc7\u6e21\u975e\u8d35\u91d1\u5c5e\u79cd\u7c7b\u7eb3\u7c73\u6750\u6599\u505a\u4e86\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\uff0c\u5e76\u53d6\u5f97\u4e86\u4e00\u5b9a\u8fdb\u5c55\uff1a<br \/>\n 1. Huang, Xiaoxiao, et al. &#8220;N-Doped Carbon Nanosheet Networks with Favorable Active Sites Triggered by Metal Nanoparticles as Bifunctional Oxygen Electrocatalysts.&#8221; <em>ACS Energy Letters<\/em> 3.12 (<strong>2018<\/strong>): 2914-2920.<br \/>\n 2. Huang, Xiaoxiao, et al. &#8220;In situ Fe<sub>2<\/sub>N@N-doped porous carbon hybrids as superior catalysts for oxygen reduction reaction.&#8221; <em>Nanoscale<\/em> 9.24 (<strong>2017<\/strong>): 8102-8106.<br \/>\n 3. Huang, Xiaoxiao, et al. &#8220;Noble metal-free catalysts for oxygen reduction reaction.&#8221; <em>Science China Chemistry<\/em> 60.12 (<strong>2017<\/strong>): 1494-1507.<\/p>\n<p>\n \u672c\u6587\u7531\u6211\u4ea6\u662f\u884c\u4eba\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1a<a href=\"mailto:tougao@cailiaoren.com.\" target=\"_blank\" rel=\"noopener\">tougao@cailiaoren.com.<\/a><\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u5316\u77f3\u71c3\u6599\u5728\u5de5\u4e1a\u548c\u65e5\u5e38\u751f\u6d3b\u4e2d\u7684\u6d88\u8017\u9020\u6210\u4e86\u4e25\u91cd\u7684\u80fd\u6e90\u548c\u73af\u5883\u95ee\u9898\uff0c\u8feb\u4f7f\u4eba\u7c7b\u793e\u4f1a\u5bfb\u627e\u66f4\u9ad8\u6548\u3001\u66f4\u6e05\u6d01\u7684\u80fd\u6e90\u4f9b\u5e94\u3002\u71c3\u6599\u7535\u6c60\u4ee5\u5176\u9ad8\u6548\u3001\u73af\u4fdd\u3001\u9ad8\u53ef\u9760\u6027\u7b49\u4f18\u70b9\u800c\u6210\u4e3a&#8230;<\/p>\n","protected":false},"author":11455,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,533],"tags":[4073],"class_list":["post-178965","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-zongshu","tag-orr"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/178965"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/11455"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=178965"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/178965\/revisions"}],"predecessor-version":[{"id":179214,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/178965\/revisions\/179214"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=178965"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=178965"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=178965"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}