{"id":179058,"date":"2019-06-30T06:30:53","date_gmt":"2019-06-29T22:30:53","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=179058"},"modified":"2019-06-29T16:16:50","modified_gmt":"2019-06-29T08:16:50","slug":"%e8%a5%bf%e5%bb%ba%e5%a4%a7%e4%ba%91%e6%96%af%e5%ae%81%e6%95%99%e6%8e%88jmca%ef%bc%9a%e9%ab%98%e6%80%a7%e8%83%bd%e5%85%89%e4%bc%8f%e7%94%b5%e5%82%ac%e5%8c%96%e6%9d%90%e6%96%99%e6%9e%84%e7%ad%91","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=179058","title":{"rendered":"\u897f\u5efa\u5927\u4e91\u65af\u5b81\u6559\u6388JMCA\uff1a\u9ad8\u6027\u80fd\u5149\u4f0f\u7535\u50ac\u5316\u6750\u6599\u6784\u7b51\u4e0e\u50ac\u5316\u673a\u5236\u7406\u89e3"},"content":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff08Dye-sensitized solar cells,\u00a0DSSCs\uff09\u5177\u6709\u76f8\u6bd4\u4f20\u7edf\u7845\u57fa\u592a\u9633\u80fd\u7535\u6c60\uff0c\u7531\u4e8e\u5176\u7406\u8bba\u8f6c\u5316\u6548\u7387\u9ad8\u3001\u73af\u5883\u53cb\u597d\u3001\u5236\u9020\u6210\u672c\u4f4e\u3001\u5de5\u827a\u7b80\u5355\u7b49\u7279\u70b9\u5df2\u6210\u4e3a\u7ee7\u7845\u57fa\u548c\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60(\u7837\u5316\u9553\u3001\u78b2\u5316\u9549\u7b49)\u4e4b\u540e\u65b0\u4e00\u4ee3\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\u6700\u91cd\u8981\u7684\u7814\u7a76\u65b9\u5411\uff0c\u4f5c\u4e3a\u4e00\u79cd\u6e05\u6d01\u80fd\u6e90\u6280\u672f\u5907\u53d7\u5173\u6ce8\u3002<\/p>\n

\u5bf9\u7535\u6781\u50ac\u5316\u5242\u5bf9\u4e8eDSSC\u7684\u6574\u4f53\u6027\u80fd\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u826f\u597d\u7684\u5bfc\u7535\u6027\u548c\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u662f\u7406\u60f3\u5bf9\u7535\u6781\u50ac\u5316\u5242\u7684\u6027\u80fd\u9700\u6c42\u3002\u8fd1\u671f\uff0c\u897f\u5b89\u5efa\u7b51\u79d1\u6280\u5927\u5b66\u529f\u80fd\u6750\u6599\u7814\u7a76\u6240\u4e91\u65af\u5b81\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u201c<\/b><\/strong>\u80fd\u6e90\u6750\u6599<\/b><\/strong>\u9ad8\u6548\u548c\u8d44\u6e90\u5316\u5229\u7528\u201d<\/b><\/strong>\u7814\u7a76\u56e2\u961f<\/b><\/strong>\u5728\u56fd\u9645\u6750\u6599\u9886\u57df\u6743\u5a01\u671f\u520aJournal of Materials Chemistry A<\/i><\/b><\/em><\/strong>\u53d1\u8868\u8bba\u6587\uff0c\u8bba\u6587\u521b\u65b0\u6027\u5730\u5229\u7528\u751f\u7269\u57fa\u78b3\u6750\u6599\uff08\u8f83\u9ad8\u7684\u5bfc\u7535\u6027\uff09\u548c\u94cc\u57fa\u53cc\u91d1\u5c5e\u5316\u5408\u7269\uff08\u826f\u597d\u7684\u50ac\u5316\u6d3b\u6027\uff09\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\uff0c\u5c06\u82a6\u835f\u76ae\u5e9f\u5f03\u7269\u5236\u5907\u7684\u751f\u7269\u591a\u5b54\u78b3\uff08Bio-based porous carbon\uff0cBPC\uff09\u5f15\u5165\u5230\u94cc\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\uff08ZnNb2<\/sub>O6<\/sub>\uff09\uff0c\u5f62\u6210\u590d\u5408\u6750\u6599\uff0c\u63d0\u9ad8\u4e86\u7eb3\u7c73\u9897\u7c92\u7684\u5206\u6563\u6027\u548c\u7535\u5b50\u4f20\u8f93\u80fd\u529b\uff0c\u663e\u8457\u5730\u6539\u5584\u4e86\u5bf9\u7535\u6781\u6750\u6599\u7684\u5bfc\u7535\u6027\u3001\u50ac\u5316\u6d3b\u6027\u548c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u5c06\u5176\u4f5c\u4e3a\u5bf9\u7535\u6781\u50ac\u5316\u5242\u5e94\u7528\u4e8eDSSCs\uff0c\u53d6\u5f97\u4e868.83%\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387\u3002\u6b64\u5916\uff0c\u8bba\u6587\u901a\u8fc7\u7b2c\u4e00\u6027\u539f\u7406\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u4ece\u7406\u8bba\u4e0a\u9610\u660e\u4e86\u5bf9\u7535\u6781\u6750\u6599\u4f18\u5f02\u7535\u50ac\u5316\u6d3b\u6027\u7684\u672c\u5f81\u8d77\u6e90\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\u00a0\u751f\u7269\u8d28\u78b3\u8d1f\u8f7d\u94cc\u57fa\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u5e94\u7528\u6548\u679c\u53ca\u5408\u6210\u793a\u610f\u56fe\u3002<\/p>\n

\u00a0\"\" \u00a0\u00a0<\/p>\n

\u56fe2<\/p>\n

\"\"<\/p>\n

\u00a0(a) BPC\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u8c31\uff1b(b)\u00a0ZnNb2<\/sub>O6<\/sub>\/BPC\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u8c31\uff1b(c)\u00a0BPC\u3001ZnNb2<\/sub>O6<\/sub>\u3001ZnNb2<\/sub>O6<\/sub>\/BPC\u7684\u62c9\u66fc\u5149\u8c31\uff1b(d)\u00a0BPC\u7684\u6c2e\u6c14\u5438-\u8131\u9644\u53ca\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\uff1b(e)\u00a0ZnNb2<\/sub>O6<\/sub>\u7684\u6c2e\u6c14\u5438-\u8131\u9644\u53ca\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\uff1b(f) ZnNb2<\/sub>O6<\/sub>\/BPC\u7684\u6c2e\u6c14\u5438-\u8131\u9644\u53ca\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\u3002<\/p>\n

\u56fe3\u00a0<\/p>\n

\"\"<\/p>\n

\u9ad8\u5206\u8fa8X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31(a)Zn 2p\uff1b(b)Nb 3d\uff1b(c)ZnNb2<\/sub>O6<\/sub>\u7684O\u00a01s\uff1b(d)BPC\u7684C\u00a01s\uff1b(e)\u00a0Zn 2p\uff1b(f)\u00a0Nb 3d\uff1b(g)\u00a0ZnNb2<\/sub>O6<\/sub>\/BPC\u7684O\u00a01s\uff1b(h)\u00a0ZnNb2<\/sub>O6<\/sub>\/BPC\u7684C 1s\u3002<\/p>\n

\u56fe4<\/p>\n

\"\"<\/p>\n

\u00a0(a) BPC\uff1b(b)\u00a0ZnNb2<\/sub>O6<\/sub>\uff1b(c)\u00a0ZnNb2<\/sub>O6<\/sub>\/BPC\u7684\u663e\u5fae\u7ed3\u6784\u3002<\/p>\n

\u56fe5\u00a0<\/p>\n

\"\"\u00a0 \u00a0<\/p>\n

(a)\u4e0d\u540c\u5bf9\u7535\u6781\u7ec4\u88c5DSSC\u7684\u5149\u4f0f\u66f2\u7ebf\u56fe\uff1b(b) \u4e0d\u540c\u5bf9\u7535\u6781\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\uff1b(c)\u4e0d\u540c\u5bf9\u7535\u6781\u7ec4\u88c5\u5bf9\u79f0\u7535\u6c60\u7684\u5854\u83f2\u5c14\u6781\u5316\u66f2\u7ebf\u56fe\uff1b(d) \u4e0d\u540c\u5bf9\u7535\u6781\u7ec4\u88c5\u5bf9\u79f0\u7535\u6c60\u7684Nyquist\u56fe\uff1b(e)\u00a0\u5c40\u90e8\u653e\u5927\u7684Nyquist\u963b\u6297\u56fe\uff1b(f)\u4e0d\u540c\u5bf9\u7535\u6781\u7ec4\u88c5DSSC\u7684\u6697\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\u56fe\u3002<\/p>\n

\u56fe6<\/p>\n

\"\"<\/p>\n

(a-d)\u4e0d\u540c\u5bf9\u7535\u6781\u7684100\u5708\u5faa\u73af\u4f0f\u5b89\u56fe\uff1b(e-h) \u4e0d\u540c\u5bf9\u7535\u6781\u7684\u6c27\u5316\u8fd8\u539f\u5cf0\u7535\u6d41\u5bc6\u5ea6\u53d8\u5316\u53caCV\u5faa\u73af100\u5708\u524d\u540e\u7535\u6781\u8868\u9762\u5bf9\u6bd4\u56fe\u3002<\/p>\n

\u56fe7\u00a0\u4e0d\u540c\u5bf9\u7535\u6781\u7ec4\u88c5\u5bf9\u79f0\u7535\u6c60\u7684\u591a\u5708\u626b\u63cfNyquist\u56fe\u3002<\/p>\n

\"\"<\/p>\n

(a)BPC\uff1b(b)\u00a0ZnNb2<\/sub>O6<\/sub>\uff1b(c)\u00a0ZnNb2<\/sub>O6<\/sub>\/BPC\uff1b(d)Pt\u3002<\/p>\n

\u56fe8\u00a0<\/p>\n

\"\"<\/b><\/strong><\/p>\n

(a)\u00a0ZnNb2<\/sub>O6<\/sub>\u7684\u6001\u5bc6\u5ea6\uff1b(b-d)Pt\u3001Zn\u3001Nb\u7684\u6001\u5bc6\u5ea6\u3002<\/p>\n

\u56fe9\u00a0I3<\/sub>–<\/sup>\u00a0\u5206\u5b50\u5728ZnNb2<\/sub>O6<\/sub>\u6676\u9762(110)\u548c(100)\u7684\u8868\u9762\u5438\u9644\u3002<\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/b><\/strong><\/p>\n

\u8fd9\u9879\u5de5\u4f5c\u5c06\u7406\u8bba\u548c\u5b9e\u9a8c\u76f8\u7ed3\u5408\uff0c\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u548c\u5b9e\u9a8c\u7814\u7a76\uff0c\u4ece\u80fd\u5e26\u548c\u8868\u9762\u5438\u9644\u4e24\u4e2a\u65b9\u9762\uff0c\u9610\u660e\u4e86\u5bf9\u7535\u6781\u6750\u6599\u7684\u50ac\u5316\u673a\u5236\uff0c\u4e3a\u9ad8\u6027\u80fd\u5bf9\u7535\u6781\u6750\u6599\u7684\u8bbe\u8ba1\u3001\u6784\u7b51\u3001\u53ca\u6027\u80fd\u4f18\u5316\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u7684\u7b56\u7565\u3002<\/p>\n

\u7b80\u8bc4\uff1a<\/b><\/strong><\/p>\n

\u80fd\u6e90\u5371\u673a\u548c\u73af\u5883\u6c61\u67d3\u662f\u5f53\u4eca\u4e16\u754c\u4eba\u7c7b\u793e\u4f1a\u9762\u4e34\u7684\u4e24\u5927\u96be\u9898\uff0c\u53ef\u518d\u751f\u80fd\u6e90\u7684\u5229\u7528\u662f\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u7684\u5173\u952e\u3002\u592a\u9633\u80fd\u548c\u751f\u7269\u8d28\u80fd\u4f5c\u4e3a\u8d44\u6e90\u91cf\u6700\u5927\u7684\u53ef\u518d\u751f\u80fd\u6e90\uff0c\u5176\u9ad8\u6548\u5f00\u53d1\u548c\u5229\u4e8e\u5bf9\u4e8e\u80fd\u6e90\u7684\u53ef\u518d\u751f\u5229\u7528\u548c\u793e\u4f1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u610f\u4e49\u91cd\u5927\u3002\u897f\u5b89\u5efa\u7b51\u79d1\u6280\u5927\u5b66\u4e91\u65af\u5b81\u6559\u6388\u65b0\u80fd\u6e90\u6750\u6599\u7814\u7a76\u56e2\u961f\uff0c\u4f9d\u6258\u8be5\u6821\u56fd\u5bb6\u6218\u7565\u6027\u65b0\u578b\u4e13\u4e1a\u201c\u8d44\u6e90\u5faa\u73af\u79d1\u5b66\u4e0e\u5de5\u7a0b\u201d\u548c\u201c\u529f\u80fd\u6750\u6599\u201d\uff0c\u805a\u7126\u4e8e\u592a\u9633\u80fd\u548c\u751f\u7269\u8d28\u80fd\u7684\u5229\u7528\uff0c\u5f00\u5c55\u4e0e\u65e0\u673a\u975e\u91d1\u5c5e\u6750\u6599\u76f8\u5173\u7684\u57fa\u7840\u7814\u7a76\u548c\u6280\u672f\u5e94\u7528\u5f00\u53d1\uff0c\u529b\u56fe\u901a\u8fc7\u65b0\u80fd\u6e90\u6750\u6599\u7684\u7814\u7a76\u548c\u5f00\u53d1\uff0c\u89e3\u51b3\u56fd\u5bb6\u53d1\u5c55\u8fc7\u7a0b\u4e2d\u7684\u91cd\u5927\u80fd\u6e90\u9700\u6c42\uff0c\u5b9e\u73b0\u8d44\u6e90\u5316\u5faa\u73af\u7efc\u5408\u5229\u7528\u3002<\/p>\n

\u8bba\u6587\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

C.Wang, S. Yun<\/b><\/strong>*<\/b><\/strong>, Q. Fan, Z. Wang, Y. Zhang, F. Han, Y. Si and A. Hagfeldt, J. Mater. Chem. A<\/i><\/em>, 2019, 7, 14864-14875. A hybrid niobium-based oxide with bio-based porous carbon as an efficient electrocatalyst in photovoltaics: a general strategy for understanding the catalytic mechanism.<\/a><\/p>\n

DOI: 10.1039\/C9TA03540K<\/p>\n

https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2019\/ta\/c9ta03540k\/unauth#!divAbstract<\/p>\n

\u672c\u6587\u7cfb\u897f\u5b89\u5efa\u7b51\u79d1\u6280\u5927\u5b66\u529f\u80fd\u6750\u6599\u7814\u7a76\u6240\u4e91\u65af\u5b81\u6559\u6388\u56e2\u961f\u4f9b\u7a3f<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff08Dye-sensitized solar cells,\u00a0DSSCs\uff09\u5177\u6709\u76f8\u6bd4\u4f20\u7edf\u7845\u57fa\u592a\u9633\u80fd\u7535\u6c60\uff0c\u7531\u4e8e\u5176\u7406\u8bba\u8f6c\u5316\u6548\u7387\u9ad8\u3001\u73af\u5883\u53cb\u597d…<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-179058","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/179058"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=179058"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/179058\/revisions"}],"predecessor-version":[{"id":179191,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/179058\/revisions\/179191"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=179058"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=179058"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=179058"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}