{"id":179297,"date":"2019-07-05T06:30:13","date_gmt":"2019-07-04T22:30:13","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=179297"},"modified":"2019-07-04T21:42:29","modified_gmt":"2019-07-04T13:42:29","slug":"%e6%8b%92%e7%bb%9d%e5%b9%b3%e5%ba%b8%ef%bc%81%e6%8f%90%e9%ab%98%e8%ae%ba%e6%96%87%e6%a1%a3%e6%ac%a1%e7%a6%bb%e4%b8%8d%e5%bc%80%e7%9a%84%e7%94%b5%e6%b1%a0%e5%8e%9f%e4%bd%8d%ef%bc%88in-situ%ef%bc%89","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=179297","title":{"rendered":"\u62d2\u7edd\u5e73\u5eb8\uff01\u63d0\u9ad8\u8bba\u6587\u6863\u6b21\u79bb\u4e0d\u5f00\u7684\u7535\u6c60\u539f\u4f4d\uff08in 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TiS<sub>2<\/sub>\u7535\u6781\u7684\u539f\u4f4dXRD\u7ed3\u679c\u53caTEM\u7ed3\u679c<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179305 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724719.png\" alt=\"\" width=\"600\" height=\"382\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724719.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724719-300x191.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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V\u65f6\uff0cK(Bi,\u00a0Sb)\u7684\u5cf0\u5f00\u59cb\u51fa\u73b0\uff0c\u8bc1\u660e\u4e86K<sub>3<\/sub>(Bi,\u00a0Sb)\u7684\u53bb\u5408\u91d1\u5316\u8fc7\u7a0b\u3002\u968f\u540e\uff0cK(Bi,\u00a0Sb)\u7ee7\u7eed\u53d1\u751f\u53bb\u94be\u5316\u8fc7\u7a0b\uff0c\u57281.2 V\u65f6\u5f00\u59cb\u751f\u6210(Bi,\u00a0Sb)\u3002\u7136\u800c\uff0c\u76f4\u5230\u6700\u540e\u5145\u7535\u81f32\u00a0V\u4e5f\u65e0\u6cd5\u89c2\u5bdf\u5230Bi<sub>1.11<\/sub>Sb<sub>0.89<\/sub>S<sub>3<\/sub>\u7684\u751f\u6210\uff0c\u8868\u660e\u4eceBi<sub>1.11<\/sub>Sb<sub>0.89<\/sub>S<sub>3<\/sub>\u751f\u6210(Bi,\u00a0Sb)\u5408\u91d1\u662f\u4e00\u4e2a\u4e0d\u53ef\u9006\u7684\u8fc7\u7a0b\u3002\u968f\u540e\u7684\u4e24\u6b21\u5145\u653e\u7535\u7ed3\u679c\u8868\u660e\u4e86\u53ef\u9006\u7684(Bi,\u00a0Sb)\u5408\u91d1\u7684\u94be\u5316\/\u53bb\u94be\u5316\u53cd\u5e94\u3002\u6574\u4e2a\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u5982\u56fe4b\uff0cc\u6240\u793a\u3002<\/p>\n<p>\u56fe3 Bi<sub>1.11<\/sub>Sb<sub>0.89<\/sub>S<sub>3<\/sub>\u5728\u524d3\u5708\u5145\u653e\u7535\u65f6\u7684\u539f\u4f4dXRD\u7ed3\u679c<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179306 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724720.png\" alt=\"\" width=\"650\" height=\"332\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724720.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724720-300x153.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p>\u56fe4 Bi<sub>1.11<\/sub>Sb<sub>0.89<\/sub>S<sub>3<\/sub>\u5728\u653e\u7535\u52300.8 V\u65f6\u7684\u9ad8\u5206\u8fa8TEM\u56fe\uff08a\uff09\u53ca\u5176\u94be\u5316\u548c\u53bb\u94be\u5316\u8fc7\u7a0b\uff08b\uff0cc\uff09<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179307 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724721.png\" alt=\"\" width=\"650\" height=\"472\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724721.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724721-300x218.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p><strong><b>2 \u539f\u4f4dX\u5c04\u7ebf\u5438\u6536\u5149\u8c31\uff08<\/b><\/strong><strong><em><b><i>in situ<\/i><\/b><\/em><\/strong><strong><b>\u00a0XAS\uff09<\/b><\/strong><\/p>\n<p>XAS\u662f\u6d4b\u91cfX\u5c04\u7ebf\u5438\u6536\u7cfb\u6570\u968fX\u5c04\u7ebf\u80fd\u91cf\u7684\u53d8\u5316\u66f2\u7ebf\u3002XAS\u4ec5\u4ec5\u5bf9\u76ee\u6807\u539f\u5b50\u7684\u8fd1\u90bb\u7ed3\u6784\u654f\u611f\u800c\u4e0d\u4f9d\u8d56\u957f\u7a0b\u6709\u5e8f\u7ed3\u6784\uff0c\u5bf9XAS\u8c31\u8fdb\u884c\u89e3\u6790\u80fd\u591f\u5f97\u5230\u6750\u6599\u7684\u5c40\u90e8\u51e0\u4f55\u7ed3\u6784\u4fe1\u606f\u548c\u7535\u5b50\u7ed3\u6784\u4fe1\u606f\u3002\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7684\u5f20\u4eae\u7b49\u4eba\u5c31\u91c7\u7528\u539f\u4f4dXAS\u6280\u672f\u5bf9Li<sub>2<\/sub>S\u7535\u6781\u7684\u5145\u7535\u65f6\u7684\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u7814\u7a76<sup>[3]<\/sup>\u3002\u56fe5a\u5c55\u793a\u4e86\u7528\u4e8e\u5f97\u5230\u539f\u4f4dXAS\u8c31\u7684\u7535\u6c60\u8bbe\u8ba1\u3002\u901a\u8fc7\u6b64\u539f\u4f4d\u7535\u6c60\uff0c\u4f5c\u8005\u5f97\u5230\u4e86Li<sub>2<\/sub>S\u7535\u6781\u5728\u7b2c\u4e00\u6b21\u548c\u7b2c\u4e8c\u6b21\u5145\u7535\u65f6\u7684XAS\u7ed3\u679c\uff08\u56fe5b\uff0cc\uff09\u3002\u5982\u56fe5b\u6240\u793a\uff0c\u5728\u7b2c\u4e00\u6b21\u5145\u7535\u65f6\uff0cXAS\u8c31\u7684\u5f62\u72b6\u4e00\u76f4\u5728\u53d1\u751f\u53d8\u5316\u3002\u5c24\u5176\u662f\u4f4d\u4e8e2473.2 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eV\u7684\u65b0\u5cf0\u3002\u8fd9\u4e2a\u662f\u591a\u786b\u5316\u9502\u7684\u6307\u7eb9\u5cf0\uff0c\u53ef\u4ee5\u53d1\u73b0\u5b83\u5728\u5145\u7535\u7684\u6700\u521d\u59cb\u5c31\u53ef\u4ee5\u89c2\u5bdf\u5230\u3002\u8fd9\u4e0e\u7b2c\u4e00\u6b21\u5145\u7535\u65f6\u7684\u73b0\u8c61\u65f6\u4e0d\u4e00\u6837\u7684\u3002\u901a\u8fc7\u4ed4\u7ec6\u5206\u6790XAS\u7684\u7ed3\u679c\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86Li<sub>2<\/sub>S\u7535\u6781\u5728\u5145\u7535\u65f6\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\uff08\u5982\u56fe6\uff09\u3002\u7b2c\u4e00\u6b21\u5145\u7535\u65f6\uff0cLi<sub>2<\/sub>S\u76f4\u63a5\u901a\u8fc7\u4e24\u76f8\u53cd\u5e94\u8f6c\u5316\u4e3a\u5143\u7d20S\uff1b\u7b2c\u4e8c\u6b21\u5145\u7535\u65f6\uff0cLi<sub>2<\/sub>S\u5219\u5148\u88ab\u6c27\u5316\u4e3a\u591a\u786b\u5316\u7269\uff0c\u968f\u540e\u8f6c\u53d8\u4e3aS\u3002<\/p>\n<p>\u56fe5\u00a0\uff08a\uff09\u7528\u4e8e\u539f\u4f4dXAS\u6d4b\u8bd5\u7684\u7535\u6c60\uff1b\uff08b\uff0cc\uff09Li<sub>2<\/sub>S\u7535\u6781\u5728\u7b2c\u4e00\u6b21\u548c\u7b2c\u4e8c\u6b21\u5145\u7535\u65f6\u7684\u539f\u4f4dXAS\u8c31<\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179308 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724722.png\" alt=\"\" width=\"650\" height=\"199\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724722.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724722-300x92.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/> \u00a0\u00a0\u00a0<\/b><\/strong><\/p>\n<p>\u56fe6\u00a0Li<sub>2<\/sub>S\u7535\u6781\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179309 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724723.png\" alt=\"\" width=\"650\" height=\"281\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724723.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724723-300x130.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/b><\/strong><\/p>\n<p><strong><b>3 \u539f\u4f4d\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08<\/b><\/strong><strong><em><b><i>in situ<\/i><\/b><\/em><\/strong><strong><b>\u00a0TEM\uff09<\/b><\/strong><\/p>\n<p>\u7535\u6781\u6750\u6599\u5728\u8fdb\u884c\u5145\u653e\u7535\u65f6\u9664\u4e86\u4f1a\u53d1\u751f\u7ed3\u6784\u548c\u5316\u5b66\u6210\u5206\u7684\u6539\u53d8\uff0c\u5176\u5f62\u8c8c\u4e5f\u4f1a\u53d1\u751f\u5f88\u5927\u7684\u53d8\u5316\u3002\u8bb8\u591a\u7535\u6781\u6750\u6599\u6027\u80fd\u7684\u6076\u5316\u5c31\u6e90\u4e8e\u4f53\u79ef\u81a8\u80c0\u53ca\u9897\u7c92\u7834\u88c2\uff0c\u56e0\u6b64\u5bf9\u6750\u6599\u8fdb\u884c\u539f\u4f4d\u7684\u5f62\u8c8c\u89c2\u6d4b\u4e5f\u5f88\u91cd\u8981\u3002\u539f\u4f4dTEM\u662f\u4e00\u9879\u975e\u5e38\u6709\u7528\u7684\u6280\u672f\uff0c\u5176\u6781\u9ad8\u7684\u5206\u8fa8\u7387\u975e\u5e38\u9002\u4e8e\u5bf9\u7eb3\u7c73\u6750\u6599\u7684\u5fae\u89c2\u5f62\u8c8c\u8fdb\u884c\u89c2\u5bdf\u3002\u6b64\u5916\uff0c\u7ed3\u5408\u9009\u533a\u7535\u5b50\u884d\u5c04\u6280\u672f\uff08SAED\uff09\uff0c\u7535\u5b50\u80fd\u91cf\u635f\u5931\u8c31\uff08EELS\uff09\u548c\u80fd\u8c31\u4eea\uff08EDX\uff09\uff0c\u6211\u4eec\u8fd8\u53ef\u4ee5\u83b7\u5f97\u6750\u6599\u7684\u7ed3\u6784\u548c\u5316\u5b66\u4fe1\u606f\u3002\u4e0a\u6d77\u5927\u5b66\u7684\u8042\u5b89\u6c11\u8bfe\u9898\u7ec4\u5c31\u91c7\u7528\u539f\u4f4dTEM\u7814\u7a76\u4e86Sb<sub>2<\/sub>Se<sub>3<\/sub>\u7535\u6781\u6750\u6599\u5728\u5145\u653e\u7535\u65f6\u7684\u5fae\u89c2\u5f62\u8c8c\u6f14\u53d8\uff0c\u5e76\u6839\u636e\u7814\u7a76\u7ed3\u679c\u627e\u5230\u4e86\u6539\u5584Sb<sub>2<\/sub>Se<sub>3<\/sub>\u7535\u5316\u5b66\u6027\u80fd\u7684\u63aa\u65bd<sup>[4]<\/sup>\u3002\u56fe7\u5c55\u793a\u4e86\u5355\u6839Sb<sub>2<\/sub>Se<sub>3<\/sub>\u7eb3\u7c73\u7ebf\u7684\u94a0\u5316\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u53d1\u73b0\u968f\u7740\u94a0\u5316\u7684\u8fdb\u884c\uff0c\u7eb3\u7c73\u7ebf\u7684\u56fe\u50cf\u886c\u5ea6\u53d1\u751f\u4e86\u53d8\u5316\uff0c\u5176\u76f4\u5f84\u53d8\u5927\u4e86\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u4ed4\u7ec6\u89c2\u5bdf\u6750\u6599\u7684\u94a0\u5316\u8fc7\u7a0b\uff0c\u4f5c\u8005\u8ba4\u4e3a\u6750\u6599\u5728\u94a0\u5316\u7684\u65f6\u5019\u6709\u4e24\u4e2a\u53cd\u5e94\u9014\u5f84\uff08\u5982\u56fe7i\uff09\uff0c\u4e00\u6761\u662f\u4ece\u63a5\u89e6\u5904\u5230Sb<sub>2<\/sub>Se<sub>3<\/sub>\u7eb3\u7c73\u7ebf\u53e6\u4e00\u7aef\uff0c\u53e6\u4e00\u6761\u8def\u5f84\u662f\u4ece\u7eb3\u7c73\u7ebf\u8868\u9762\u5230\u5185\u90e8\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4f5c\u8005\u4e5f\u5bf9\u6750\u6599\u5728\u53bb\u94a0\u5316\u65f6\u7684\u5f62\u8c8c\u6f14\u53d8\u8fdb\u884c\u4e86\u7814\u7a76\uff08\u5982\u56fe8\uff09\u3002\u968f\u7740\u53bb\u94a0\u5316\u53cd\u5e94\u7684\u8fdb\u884c\uff0c\u6750\u6599\u5185\u90e8\u5f62\u6210\u4e86\u8bb8\u591a\u7eb3\u7c73\u5b54\uff08\u76f4\u5f84\u5927\u4e8e20 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V\u65f6\uff0c\u6750\u6599\u5c3d\u7ba1\u5bb9\u91cf\u7a0d\u4f4e\uff0c\u4f46\u662f\u5177\u6709\u5f88\u597d\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p>\u56fe7\u00a0\u91c7\u7528\u539f\u4f4dTEM\u89c2\u5bdf\u5355\u6839Sb<sub>2<\/sub>Se<sub>3<\/sub>\u7eb3\u7c73\u7ebf\u7684\u94a0\u5316\u8fc7\u7a0b<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179310 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724724.png\" alt=\"\" width=\"650\" height=\"434\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724724.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724724-300x200.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/b><\/strong><\/p>\n<p>\u56fe8\u00a0Sb<sub>2<\/sub>Se<sub>3<\/sub>\u7eb3\u7c73\u7ebf\u5728\u53bb\u94a0\u5316\u65f6\u7684\u5f62\u8c8c\u6f14\u53d8<\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179311 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724725.png\" alt=\"\" width=\"650\" height=\"328\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724725.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724725-300x151.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/b><\/strong><\/p>\n<p>\u56fe9\u00a0Sb<sub>2<\/sub>Se<sub>3<\/sub>\u7eb3\u7c73\u7ebf\u5728\u4e0d\u540c\u7535\u538b\u8303\u56f4\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179312 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724726.png\" alt=\"\" width=\"650\" height=\"230\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724726.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724726-300x106.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/b><\/strong><\/p>\n<p><strong><b>4 \u539f\u4f4d\u62c9\u66fc\u5149\u8c31\uff08<\/b><\/strong><strong><em><b><i>in situ<\/i><\/b><\/em><\/strong><strong><b>\u00a0Raman\uff09<\/b><\/strong><\/p>\n<p>\u62c9\u66fc\u6548\u5e94\u8d77\u6e90\u4e8e\u6750\u6599\u5bf9\u5355\u8272\u5149\u7684\u975e\u5f39\u6027\u6563\u5c04\u3002\u5229\u7528\u62c9\u66fc\u6548\u5e94\u6211\u4eec\u5c31\u53ef\u4ee5\u5f97\u5230\u6750\u6599\u7684\u62c9\u66fc\u5149\u8c31\uff0c\u5b83\u4e0e\u5177\u6709\u62c9\u66fc\u6d3b\u6027\u7684\u5206\u5b50\u7684\u632f\u52a8\u6a21\u5f0f\u76f8\u5173\u3002\u56e0\u6b64\uff0c\u6240\u6709\u53ef\u4ee5\u5f71\u54cd\u5206\u5b50\u632f\u52a8\u6a21\u5f0f\u7684\u56e0\u7d20\uff0c\u6bd4\u5982\u6676\u4f53\u7ed3\u6784\uff0c\u5e94\u529b\u548c\u5316\u5b66\u72b6\u6001\uff0c\u90fd\u4f1a\u5f71\u54cd\u62c9\u66fc\u5149\u8c31\u3002\u53cd\u8fc7\u6765\uff0c\u6211\u4eec\u4e5f\u53ef\u4ee5\u5229\u7528\u62c9\u66fc\u5149\u8c31\u7684\u53d8\u5316\u6765\u7814\u7a76\u7535\u6781\u6750\u6599\u53d1\u751f\u7684\u6539\u53d8\u3002\u4e0e\u539f\u4f4dXRD\u76f8\u6bd4\uff0c\u539f\u4f4dRaman\u5177\u6709\u72ec\u7279\u7684\u4f18\u52bf\uff0c\u5b83\u53ef\u4ee5\u7528\u6765\u7814\u7a76\u90a3\u4e9b\u975e\u6676\u4f53\u6216\u8005\u7ed3\u6676\u6027\u5f88\u5dee\u7684\u6750\u6599\uff0c\u4e5f\u9002\u4e8e\u7814\u7a76\u754c\u9762\u5904\u7684\u53cd\u5e94\u3002\u52a0\u62ff\u5927University of Western\u7684\u5b59\u5b66\u826f\u8bfe\u9898\u7ec4\u5c31\u91c7\u7528\u539f\u4f4dRaman\u7814\u7a76\u4e86\u5168\u56fa\u6001Li-Se\u7535\u6c60\u4e2dSe\u6b63\u6781\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406<sup>[5]<\/sup>\u3002\u8be5\u8bba\u6587\u9996\u6b21\u62a5\u9053\u4e86\u53ef\u9006\u7684\u754c\u9762\u7269\u8d28\u7684\u50a8\u9502\u673a\u7406\u3002\u5982\u56fe10b\uff0cc\u6240\u793a\uff0c\u5728\u6700\u521d\u59cb\u65f6\uff0cSe\/Li<sub>3<\/sub>PS<sub>4<\/sub>\/C\u590d\u5408\u6750\u6599\u5177\u6709\u4e09\u4e2a\u5cf0\u3002\u4f4d\u4e8e239 cm<sup>&#8211;<\/sup><sup>1<\/sup>\u5904\u7684\u5cf0\u6e90\u4e8eSe\uff0c\u4f4d\u4e8e252 cm<sup>&#8211;<\/sup><sup>1<\/sup>\u4f4d\u7f6e\u7684\u5cf0\u4e0ePS<sub>4<\/sub><sub>&#8211;<\/sub><em><sub><i>x<\/i><\/sub><\/em>Se<em><sub><i>x<\/i><\/sub><\/em><sup>3<\/sup><sup>&#8211;<\/sup>\u7684\u5bf9\u79f0\u5f2f\u66f2\u6709\u5173\uff0c\u800c\u4f4d\u4e8e252 cm<sup>&#8211;<\/sup><sup>1<\/sup>\u7684\u5cf0\u5219\u53ef\u80fd\u6e90\u4e8eSe-S\u7684\u4f38\u7f29\u632f\u52a8\u3002\u8fd9\u4e2a\u7ed3\u679c\u4e5f\u8868\u660eSe\u53ef\u80fd\u4e0eLi<sub>3<\/sub>PS<sub>4<\/sub>\u56fa\u6001\u7535\u89e3\u8d28\u53d1\u751f\u4e86\u4ea4\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u751f\u6210\u4e86\u754c\u9762\u7269\u8d28PS<sub>4<\/sub><sub>&#8211;<\/sub><em><sub><i>x<\/i><\/sub><\/em>Se<em><sub><i>x<\/i><\/sub><\/em><sup>3<\/sup><sup>&#8211;<\/sup>\u3002\u5728\u653e\u7535\u7684\u65f6\u5019\uff0c239 cm<sup>&#8211;<\/sup><sup>1<\/sup>\u5904\u7684\u5cf0\u9010\u6e10\u6d88\u5931\u800c251 cm<sup>&#8211;<\/sup><sup>1<\/sup>\u7684\u5cf0\u5219\u9010\u6e10\u51cf\u5f31\uff0c\u8fd9\u8868\u660eSe<em><sub><i>n<\/i><\/sub><\/em>\u94fe\u548cPS<sub>4<\/sub><sub>&#8211;<\/sub><em><sub><i>x<\/i><\/sub><\/em>Se<em><sub><i>x<\/i><\/sub><\/em><sup>3<\/sup><sup>&#8211;<\/sup>\u53d1\u751f\u4e86\u4e0d\u540c\u7a0b\u5ea6\u7684\u9502\u5316\u3002\u636e\u6b64\u53ef\u4ee5\u63a8\u65adSe\u5b8c\u5168\u9502\u5316\u800cPS<sub>4<\/sub><sub>&#8211;<\/sub><em><sub><i>x<\/i><\/sub><\/em>Se<em><sub><i>x<\/i><\/sub><\/em><sup>3<\/sup><sup>&#8211;<\/sup>\u90e8\u5206\u9502\u5316\u3002\u5728\u5145\u7535\u7684\u65f6\u5019\uff0c\u4e0a\u8ff0\u4e24\u4e2a\u4f4d\u7f6e\u7684\u5cf0\u53c8\u9010\u6e10\u56de\u5230\u672a\u653e\u7535\u65f6\u7684\u72b6\u6001\uff0c\u6e05\u6670\u5730\u8868\u660e\u4e86Se\u548cPS<sub>4<\/sub><sub>&#8211;<\/sub><em><sub><i>x<\/i><\/sub><\/em>Se<em><sub><i>x<\/i><\/sub><\/em><sup>3<\/sup><sup>&#8211;<\/sup>\u5177\u6709\u9ad8\u5ea6\u53ef\u9006\u7684\u50a8\u9502\u7279\u6027\u3002\u6b64\u5916\uff0c\u5728\u6574\u4e2a\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u6211\u4eec\u4e5f\u53ef\u4ee5\u89c2\u5bdf\u5230\u5f52\u5c5e\u4e8eSe-S\u4f38\u7f29\u632f\u52a8\u7684252 cm<sup>&#8211;<\/sup><sup>1<\/sup>\u7684\u5cf0\u3002\u5b83\u4e5f\u53d1\u751f\u4e86\u4e0d\u660e\u663e\u7684\u53ef\u9006\u53d8\u5316\u3002\u8fd9\u79cd\u5168\u56fa\u6001\u7535\u6c60\u4f53\u7cfb\u4e2d\u7684\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u4e0e\u4f20\u7edf\u7684\u6db2\u6001\u7535\u89e3\u6db2\u57fa\u7684\u7535\u6c60\u4e0d\u540c\u3002<\/p>\n<p>\u56fe10 Se\u6b63\u6781\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff08a\uff09\u548c\u539f\u4f4dRaman\u7ed3\u679c\uff08b\uff0cc\uff09<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179313 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724727.png\" alt=\"\" width=\"650\" height=\"219\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724727.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724727-300x101.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/> \u00a0\u00a0\u00a0<\/p>\n<p><strong><b>5 \u539f\u4f4d\u539f\u5b50\u529b\u663e\u5fae\u955c\uff08<\/b><\/strong><strong><em><b><i>in situ <\/i><\/b><\/em><\/strong><strong><b>AFM\uff09<\/b><\/strong><\/p>\n<p>\u539f\u5b50\u529b\u663e\u5fae\u955c\u662f\u57fa\u4e8e\u529b\u7684\u6280\u672f\uff0c\u5728\u7535\u6c60\u9886\u57df\uff0c\u5b83\u7684\u5e94\u7528\u4e5f\u5f88\u5e7f\u6cdb\u3002\u4e00\u65b9\u9762\uff0c\u5b83\u53ef\u4ee5\u7528\u6765\u83b7\u5f97\u7535\u6781\u8868\u9762\u4e0e\u754c\u9762\u7684\u4fe1\u606f\uff0c\u89c2\u6d4b\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u819c\u548c\u9502\u679d\u6676\u7684\u5f62\u8c8c\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u5b83\u8fd8\u53ef\u4ee5\u6d4b\u91cf\u6750\u6599\u7684\u529b\u5b66\u6027\u8d28\uff0c\u6bd4\u5982\u6d4b\u91cf\u6750\u6599\u7684\u6768\u6c0f\u6a21\u91cf\u3002\u9274\u4e8e\u6b64\uff0c\u4eba\u4eec\u4e5f\u5f00\u53d1\u51fa\u4e86\u539f\u4f4dAFM\u4ee5\u5bf9\u7535\u6781\u5f62\u8c8c\u7684\u6f14\u53d8\u548c\u529b\u5b66\u6027\u8d28\u8fdb\u884c\u52a8\u6001\u89c2\u5bdf\uff0c\u5178\u578b\u7684\u6d4b\u8bd5\u914d\u7f6e\u5982\u56fe11a\u6240\u793a\u3002\u7f8e\u56fd\u897f\u5317\u592a\u5e73\u6d0b\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7684\u8bb8\u6b66\u56e2\u961f\u5c31\u91c7\u7528\u539f\u4f4dAFM\u7814\u7a76\u4e86Li\u91d1\u5c5e\u8868\u9762\u4fdd\u62a4\u5c42\u5728\u539f\u4f4d\u5145\u7535\u8fc7\u7a0b\u4e2d\u5f62\u6210\u7684\u8fc7\u7a0b<sup>[6]<\/sup>\u3002\u6839\u636e\u56fe11b-d\u53ef\u4ee5\u53d1\u73b0\uff0c\u5f53Li\u91d1\u5c5e\u5904\u5728\u5176\u5f00\u8def\u7535\u4f4d\u65f6\uff0c\u5b83\u7684\u8868\u9762\u6ca1\u6709\u53d1\u751f\u660e\u663e\u53d8\u5316\uff0c\u8868\u660e\u5176\u5728\u7535\u89e3\u6db2\u4e2d\u662f\u6bd4\u8f83\u7a33\u5b9a\u7684\u3002\u56fe11n\u663e\u793a\u4e86\u91c7\u7528\u4e24\u79cd\u65b9\u6cd5\u5f97\u5230\u7684\u8868\u9762\u7c97\u7cd9\u5ea6\uff08R<sub>q<\/sub>\u548cR<sub>a<\/sub>\uff09\u7684\u53d8\u5316\u60c5\u51b5\uff0c\u5b83\u4eec\u90fd\u6ca1\u6709\u660e\u663e\u7684\u53d8\u5316\u3002\u968f\u7740\u5145\u7535\u5f00\u59cb\u8fdb\u884c\uff0c\u8868\u9762\u819c\u5f00\u59cb\u5f62\u6210\u5e76\u9010\u6e10\u751f\u957f\u3002\u5f53\u7535\u538b\u4fdd\u6301\u57284.3V\u65f6\uff0c\u968f\u7740\u5145\u7535\u65f6\u95f4\u7684\u5ef6\u957f\uff0c\u8868\u9762\u819c\u7684\u539a\u5ea6\u4e5f\u5728\u9010\u6e10\u53d8\u5927\u3002\u56fe11o\u663e\u793a\u6750\u6599\u7684\u7c97\u7cd9\u5ea6\u4e5f\u4e00\u76f4\u5728\u589e\u52a0\uff0c\u5c3d\u7ba1\u5728\u4e0d\u540c\u9636\u6bb5\u589e\u901f\u4e0d\u540c\u3002\u5c06\u8fd9\u4e9b\u4e0d\u540c\u9884\u5904\u7406\u6761\u4ef6\u4e0b\u5f97\u5230\u7684Li\u91d1\u5c5e\u8d1f\u6781\u7ec4\u88c5\u6210Li-O<sub>2<\/sub>\u7535\u6c60\u8fdb\u884c\u6d4b\u8bd5\uff0c\u5176\u53ef\u4ee5\u7a33\u5b9a\u5faa\u73af\u7684\u6b21\u6570\u5982\u56fe12\u6240\u793a\u3002\u8fd9\u8868\u660e\u901a\u8fc7\u9884\u5904\u7406\u5728Li\u91d1\u5c5e\u8868\u9762\u751f\u6210\u4e00\u5c42\u8584\u7684\u4fdd\u62a4\u819c\u53ef\u4ee5\u4fdd\u62a4\u9502\u91d1\u5c5e\u8d1f\u6781\uff0c\u4ece\u800c\u63d0\u9ad8Li-O<sub>2<\/sub>\u7535\u6c60\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\u56fe11 \u9502\u91d1\u5c5e\u8868\u9762\u7684\u539f\u4f4d\u539f\u5b50\u529b\u663e\u5fae\u955c\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179314 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724728.png\" alt=\"\" width=\"650\" height=\"494\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724728.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724728-300x228.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p>\u56fe12 \u4e0d\u540c\u9884\u5904\u7406\u6761\u4ef6\u4e0b\u7684Li\u91d1\u5c5e\u8d1f\u6781\u7ec4\u88c5\u6210\u7684Li-O<sub>2<\/sub>\u7535\u6c60\u7684\u7a33\u5b9a\u5faa\u73af\u5bff\u547d<\/p>\n<p><strong><b>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179315 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724729.png\" alt=\"\" width=\"624\" height=\"541\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724729.png 624w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724729-300x260.png 300w\" sizes=\"(max-width: 624px) 100vw, 624px\" \/><\/b><\/strong><\/p>\n<p><strong><b>6 \u5176\u4ed6\u539f\u4f4d\u6280\u672f<\/b><\/strong><\/p>\n<p>\u9664\u4e86\u4e0a\u8ff0\u51e0\u79cd\u6700\u5e38\u7528\u7684\u539f\u4f4d\u6280\u672f\u4ee5\u5916\uff0c\u4eba\u4eec\u8fd8\u5f00\u53d1\u4e86\u5f88\u591a\u79cd\u5176\u4ed6\u7c7b\u578b\u7684\u539f\u4f4d\u7535\u6c60\u6d4b\u8bd5\u6280\u672f\u3002\u6bd4\u5982\u540c\u6837\u53ef\u4ee5\u5bf9\u6750\u6599\u8fdb\u884c\u5f62\u8c8c\u89c2\u5bdf\u7684\u539f\u4f4d\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08<em><i>in<\/i><\/em><em><i>\u00a0situ<\/i><\/em>\u00a0SEM\uff09\uff0c\u8fdb\u884c\u6676\u4f53\u7ed3\u6784\u5206\u6790\u7684\u539f\u4f4d\u4e2d\u5b50\u884d\u5c04\u6280\u672f\uff08<em><i>i<\/i><\/em><em><i>n situ<\/i><\/em>\u00a0NPD\uff09\uff0c\u4ee5\u53ca\u5bf9\u5206\u5b50\u6210\u5206\u548c\u7ed3\u6784\u8fdb\u884c\u68c0\u6d4b\u7684\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u6280\u672f\uff08<em><i>i<\/i><\/em><em><i>n situ<\/i><\/em>\u00a0IR\uff09\u7b49\u7b49\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u7684\u5f20\u8dc3\u521a\u7ec4\u5c31\u91c7\u7528\u4e86\u539f\u4f4d\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\u5bf9\u9502\u679d\u6676\u7684\u751f\u957f\u548c\u6eb6\u89e3\u8fdb\u884c\u4e86\u89c2\u5bdf\uff0c\u5176\u6240\u91c7\u7528\u7684\u88c5\u7f6e\u5982\u56fe13\u6240\u793a<sup>[7]<\/sup>\u3002\u53ef\u4ee5\u53d1\u73b0\uff0c\u7ecf\u8fc7350 s \u7684\u6c89\u79ef\u540e\uff0c\u9502\u679d\u6676\u7684\u957f\u5ea6\u5927\u7ea6\u4e3a18 \u03bcm\uff08\u56fe14c\uff09\u3002\u968f\u7740\u7535\u6d41\u53cd\u5411\uff0c\u9502\u679d\u6676\u5f00\u59cb\u9010\u6e10\u6eb6\u89e3\uff08\u56fe14d-f\uff09\u3002\u7136\u800c\uff0c\u5373\u4f7f\u4fdd\u6301\u7535\u6d41\u53cd\u5411600 s\uff0c\u56fe14f\u4e2d\u4ecd\u7136\u53ef\u4ee5\u89c2\u5bdf\u5230\u9502\u679d\u6676\u7684\u5b58\u5728\u3002\u8fd9\u4e9b\u9502\u679d\u6676\u5f88\u53ef\u80fd\u4e0e\u7535\u6781\u5931\u53bb\u8fde\u63a5\uff0c\u5f62\u6210\u4e86\u201c\u6b7b\u9502\u201d\uff0c\u4e0d\u518d\u5177\u6709\u7535\u5316\u5b66\u6d3b\u6027\u3002<\/p>\n<p>\u56fe13 \u8fdb\u884c\u539f\u4f4dSEM\u89c2\u5bdf\u7684\u88c5\u7f6e<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179316 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724730.png\" alt=\"\" width=\"600\" height=\"601\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724730.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724730-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724730-300x300.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe14 Li\u6c89\u79ef\/\u8131\u51fa\u65f6\u7684SEM\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179317 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724731.png\" alt=\"\" width=\"600\" height=\"382\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724731.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/\u56fe\u724731-300x191.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>7 \u603b\u7ed3<\/b><\/strong><\/p>\n<p>\u7531\u4e8e\u539f\u4f4d\u7814\u7a76\u6280\u672f\u5177\u6709\u52a8\u6001\uff0c\u5b9e\u65f6\uff0c\u51c6\u786e\u7684\u7279\u6027\uff0c\u7814\u7a76\u8005\u4eec\u539f\u6765\u8d8a\u504f\u5411\u4e8e\u91c7\u7528\u5b83\u4eec\u6765\u5bf9\u4e8c\u6b21\u7535\u6c60\u8fdb\u884c\u7814\u7a76\uff0c\u4ee5\u83b7\u5f97\u6df1\u523b\uff0c\u4e30\u5bcc\u548c\u6b63\u786e\u7684\u7814\u7a76\u7ed3\u679c\u3002\u88681\u5bf9\u5404\u79cd\u539f\u4f4d\u6d4b\u8bd5\u6280\u672f\u8fdb\u884c\u4e86\u6c47\u603b\uff0c\u9664\u4e86\u72ec\u7acb\u5730\u4f7f\u7528\u8fd9\u4e9b\u6280\u672f\uff0c\u8fd8\u53ef\u4ee5\u5c06\u5b83\u4eec\u8054\u5408\u8d77\u6765\u4f7f\u7528\u4ee5\u83b7\u5f97\u591a\u7ef4\u5ea6\u7684\u6750\u6599\u4fe1\u606f<sup>[8, 9]<\/sup>\u3002\u672a\u6765\uff0c\u539f\u4f4d\u7814\u7a76\u6280\u672f\u5c06\u4f1a\u5411\u7740\u66f4\u9ad8\u5206\u8fa8\u7387\uff0c\u66f4\u591a\u5e94\u7528\u65b9\u5411\uff0c\u66f4\u591a\u65b0\u6280\u672f\u53d1\u5c55\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u539f\u4f4d\u7535\u6c60\u7684\u8bbe\u8ba1\u5bf9\u4e8e\u83b7\u5f97\u597d\u7684\u539f\u4f4d\u7814\u7a76\u7ed3\u679c\u975e\u5e38\u91cd\u8981\u3002\u6b64\u5916\uff0c\u8fd9\u4e9b\u539f\u4f4d\u7814\u7a76\u6280\u672f\u4e0d\u4ec5\u53ef\u4ee5\u7528\u6765\u5bf9\u4e8c\u6b21\u7535\u6c60\u8fdb\u884c\u7814\u7a76\uff0c\u8fd8\u53ef\u4ee5\u7ecf\u8fc7\u7b80\u5355\u7684\u6539\u9020\u7528\u5728\u50ac\u5316\u548c\u73af\u5883\u7b49\u9886\u57df\u3002<\/p>\n<p>\u88681\u00a0\u5404\u79cd\u539f\u4f4d\u6d4b\u8bd5\u6280\u672f\u7684\u6c47\u603b\u4e0e\u5bf9\u6bd4<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-179318 size-full aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/2019-07-01_143352.jpg\" alt=\"\" width=\"624\" height=\"426\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/2019-07-01_143352.jpg 624w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2019\/07\/2019-07-01_143352-300x205.jpg 300w\" sizes=\"(max-width: 624px) 100vw, 624px\" \/><\/p>\n<p><strong><b>\u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n<p>[1] Z. Hu, Z. Tai, Q. Liu, S.-W. Wang, H. Jin, S. Wang, W. Lai, M. Chen, L. Li, L. Chen, Z. Tao, S.-L. Chou, Advanced Energy Materials, 9 (2019).<\/p>\n<p>[2] J. Wang, L. Fan, Z. Liu, S. Chen, Q. Zhang, L. Wang, H. Yang, X. Yu, B. Lu, ACS Nano, 13 (2019) 3703-3713.<\/p>\n<p>[3] L. Zhang, D. Sun, J. Feng, E.J. Cairns, J. Guo, Nano Lett, 17 (2017) 5084-5091.<\/p>\n<p>[4] Q. Li, P. Du, Y. Yuan, W. Yao, Z. Ma, B. Guo, Y. Lyu, P. Wang, H. Wang, A. Nie, R. Shahbazian-Yassar, J. Lu, Nano Lett, 19 (2019) 3074-3082.<\/p>\n<p>[5] X. Li, J. Liang, X. Li, C. Wang, J. Luo, R. Li, X. Sun, Energy &amp; Environmental Science, 11 (2018) 2828-2832.<\/p>\n<p>[6] B. Liu, W. Xu, J. Tao, P. Yan, J. Zheng, M.H. Engelhard, D. Lu, C. Wang, J.-G. Zhang, Advanced Energy Materials, 8 (2018).<\/p>\n<p>[7] G. Rong, X. Zhang, W. Zhao, Y. Qiu, M. Liu, F. Ye, Y. Xu, J. Chen, Y. Hou, W. Li, W. Duan, Y. Zhang, Adv Mater, 29 (2017).<\/p>\n<p>[8] D. Liu, Z. Shadike, R. Lin, K. Qian, H. Li, K. Li, S. Wang, Q. Yu, M. Liu, S. Ganapathy, X. Qin, Q.H. Yang, M. Wagemaker, F. Kang, X.Q. Yang, B. Li, Adv Mater, (2019) 1806620.<\/p>\n<p>[9] Y. Wu, N. Liu, Chem, 4 (2018) 438-465.<\/p>\n<p>\u672c\u6587\u7531<strong>\u738b\u8001\u5e08<\/strong>\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u53ef\u5145\u7535\u7535\u6c60\u7684\u53d1\u5c55\u4fc3\u6210\u4e86\u7535\u52a8\u6c7d\u8f66\u7684\u590d\u5174\uff0c\u53cd\u8fc7\u6765\uff0c\u7535\u52a8\u6c7d\u8f66\u7684\u5feb\u901f\u53d1\u5c55\u4e5f\u63a8\u52a8\u7740\u53ef\u5145\u7535\u7535\u6c60\u6280\u672f\u7684\u5feb\u901f\u8fdb\u6b65\u3002\u968f\u7740\u7535\u6c60\u7814\u53d1\u7684\u6df1\u5165\uff0c\u4f20\u7edf\u7684\u7814\u7a76\u65b9\u6cd5\u5df2\u7ecf\u4e0d\u80fd\u6ee1\u8db3\u5bf9\u7535\u6c60\u53cd\u5e94\u8fc7\u7a0b\uff0c&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":179324,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-179297","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/179297"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=179297"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/179297\/revisions"}],"predecessor-version":[{"id":179712,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/179297\/revisions\/179712"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/179324"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=179297"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=179297"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=179297"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}